• Title/Summary/Keyword: 오염물질수지

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Remediation for Gasoline Contaminated Soils with SVE (soil vapor extraction) Including a Post-treatment System of Extraction Gases (배출가스의 후처리 공정을 포함한 토양증기추출법을 이용한 가솔린 오염 토양 복원)

  • 이민희;강현민;이병헌;빈정인
    • Journal of Soil and Groundwater Environment
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    • v.9 no.2
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    • pp.28-40
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    • 2004
  • Box experiments were performed to evaluate the removal efficiency of SVE (soil vapor extraction) for gasoline in soil. An activated carbon sorption tower and a biofilter were operated as post-treatment processes to remove VOCs extracted from extraction wells of SVE. An acrylic resin box (65 cm${\times}$20 cm${\times}$30 cm) was used to make artificial soil layers and two injection wells and one extraction well were built for SVE process in the box. Gases from extraction wells flew into the activated carbon sorption tower or the biofilter. Gasoline concentrations of VOCs emitted from the extraction well were compared with those after post treatments. More than 92% of initial gasoline mass in soil were removed by SVE within few days, suggesting that SVE is very available to remove VOCs from contaminated soils. To treat VOCs from extraction wells of SVE, an activated carbon sorption tower and a biofilter were attached to SVE process and their gasoline removal efficiencies were measured. These post treatment systems lowered gasoline concentrations to below 1.0 ppm within few days. Average remediation efficiency was 98% of gasoline for the activated carbon sorption tower and 84.1% for the biofilter. The maximum removal capacity of a biofilter was 10.7 g/L/hr, which was ten times higher than general biofilter removal capacity. Results from the study suggest that the activated carbon sorption tower and the biofilter would be available for the post treatment process to remove VOCs generated from SVE process.

Analysis of Bacterials Community Structure in Leadchate-Contaminated Groundwater using Denaturing Gradient Gel Electrophoresis (Denaturing Gradient Gel Electrophoresis를 이용한 매립지 침출수로 오염된 지하수의 세균 군집 분석)

  • Kim Jai-Soo;Kim Ji-Young;Koo So-Yeon;Ko Kyung-Seok;Lee Sang-Don;Cho Kyung-Suk;Koh Dong-Chan
    • Microbiology and Biotechnology Letters
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    • v.34 no.2
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    • pp.166-173
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    • 2006
  • This research has been performed to clarify the relationship between hydrogeochemistry and bacterial community structure in groundwater contaminated with landfill leachate. We collected and analyzed samples from 5 sites such as leachate (KSG1-12), treated leachate (KSG1-16), two contaminated groundwaters (KSG1-07 and KSG1-08) and non-contaminated groundwater (KSG1-13). pH was 8.83, 8.04, 6.87, 6.87 and 6.53 in order; redox potential (Eh) 108, 202, 47, 200 and 154 mV; electric conductivity (EC) 3710, 894, 1223, 559 and 169.9 $\mu$S/cm; suspended solids (SS) 86.45, 13.74, 4.18, 0.24 and 11.91 mg/L. In KSG01-12, the ion concentrations were higher especially in $Cl^-$ and $HCO_3^-$ than other sites. The concentrations of Fe, Mn and $SO_4^{2-}$ were higher In KSG1-07 than in KSG1-08, and vise versa in $NO_3^{2-}$. In the comparison of DGGE fingerprint patterns, the similarity was highest between KSG1-13 and KSG1-16 (57.2%), probably due to common properties like low or none contaminant concentrations. Otherwise KSG1-08 showed lowest similarities with KSG1-13 (25.8%) and KSG1-12 (27.6%), maybe because of the degree of contamination. The most dominant bacterial species in each site were involved in $\alpha$-Proteobacteria (55.6%) in KSG1-12, $\gamma$-Proteobacteria (50.0%) in KSG1-16, $\beta$-Proteobacteria (66.7%) in KSG1-07, $\gamma$-Proteobacteria (54.5%) in KSG1-08 and $\beta$-Proteobacteria (36.4%) in KSG1-13. These results indicate that the microbial community structure might be changed according to the flow of leachate in grounderwater, implying changes in concentrations of pollutants, available electron accepters and/or other environmental conditions.

An Assessment on the Behavior of Nitrogenous Materials during the First High-rate Phase in Composting Process (퇴비화 공정의 1차 발효단계에서 질소성 물질의 거동 평가)

  • Jeong, Yeon-Koo;Kim, Jin-Soo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.8 no.3
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    • pp.81-88
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    • 2000
  • Composting of N-rich wastes such as food waste and wastewater sludges can be associated loss of with substantial gaseous N, which means loss of an essential plant nutrient but may also lead to environmental pollution. We investigated the behavior of nitrogenous materials during the first high-rate phase in composting of food waste. Air dried food waste was mixed with shredded waste paper or wood chip and reacted in a bench scale composting reactor. Samples were analyzed for pH, ammonia, oxidized nitrogen and organic nitrogen. The volatilized ammonia nitrogen was also analyzed using sulfuric acid as an absorbent solution. Initial progress of composting reaction greatly influenced the ammonification of organic nitrogen. A well-balanced composting reaction with an addition of active compost as an inoculum resulted in the promoted mineralization of organic nitrogen and volatilization of ammonia. The prolongation of initial low pH period delayed the production of ammonia. It was also found that nitrogen loss was highly dependent on the air flow supplied. With an increase in input air flow, the loss of nitrogen as an ammonia also increased, resulted in substantial reduction of ammonia content in compost. The conversion ratio of initial nitrogen into ammonia was in the range of 28 to 38% and about 77~94% of the ammonia produced was escaped as a gas. Material balance on the nitrogenous materials was demonstrated to provide an information of importance on the behavior of nitrogen in composting reaction.

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Development of an 1-Dimensional Dynamic Numerical Model for BTX Removal Process Analysis by Gaseous-Biofilm Filtration (기체상-생물막 여과 공법의 BTX 제거 공정 해석을 위한 1차원 동적 수치모델 개발)

  • Kim, Yeong-Kwan;Choi, Sung-Chan;Kim, Seog-Ku;Lee, Yong-Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.12
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    • pp.689-695
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    • 2015
  • A biofilm filtration for the removal of gaseous pollutants has been recognized as a process with a complex interaction between the gas flow characteristics and the process operating variables. This study aims to develop an one dimensional dynamic numerical model which can be utilized as a tool for the analysis of biofilm filtration process operated in plug flow mode. Since, in a plug flow system, minor environmental changes in a gaseous unit process cause a drastic change in reaction and the interaction between the pollutants is an influencing factor, plug flow system was generalized in developing the model. For facilitation of the model development, dispersion was simplified based on the principles of material balance. Several reactions such as competition, escalation, and control between the pollutants were included in the model. The applicability of the developed model was evaluated by taking the calibration and verification steps on the experimental data performed for the removal of BTX at both low and high flow concentration. The model demonstrated a correlation coefficient ($R^2$) greater than 0.79 under all the experimental conditions except for the case of toluene at high flow condition, which suggested that this model could be used for the generalized gaseous biofilm plug flow filtration system. In addition, this model could be a useful tool in analyzing the design parameters and evaluating process efficiency of the experiments with substantial amount of complexity and diversity.

Biodegradation of Phenol by Comamonas testosteroni DWB-1-8 Isolated from the Activated Sludge of Textile Wastewater (섬유 폐수 활성 슬러지에서 분리한 Comamonas testosteroni의 생물학적 페놀 분해)

  • Kwon, Hae Jun;Choi, Doo Ho;Kim, Mi Gyeong;Kim, Dong-Hyun;Kim, Young Guk;Yoon, Hyeokjun;Kim, Jong-Guk
    • Journal of Life Science
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    • v.30 no.2
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    • pp.156-161
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    • 2020
  • Since industrialization, the production and utilization of various chemicals has contributed to improving the quality of our lives, but the subsequent discharge of massive waste is inevitable, and environmental pollution is becoming more serious every day. Exposure to chemicals as a result of environmental pollution is having a negative effect on human health and the ecosystem, and cleaning up the polluted environment that can affect our lives is a very important issue. Toxic aromatic compounds have been detected frequently in soil, groundwater, and wastewater because of the extensive use of oil products, and phenol, which is used to produce synthetic resins, textiles, and dyes, is one of the major pollutants, along with insecticides and preservatives. Phenol can cause dyspnea, headache, vomiting, mutation, and carcinogenesis. Phenol-degrading bacterium DWB-1-8 was isolated from the activated sludge of textile wastewater; this strain was identified as Comamonas testosteroni by 16S rRNA gene sequencing. The optimal culture conditions for the cell growth and degradation of phenol were 0.7% K2HPO4, 0.6% NaH2PO4, 0.1% NH4NO3, 0.015% MgSO4·7H2O, 0.001% FeSO4·7H2O, an initial pH of 7, and a temperature of 30℃. The strain was also able to grow by using other toxic compounds, such as benzene, toluene, or xylene (BTX), as the sole source of carbon.

Material Characteristics and Nondestructive Deterioration Assessment for the Celestial Chart Stone, Korea (천상열차분야지도 각석의 재질특성과 비파괴 훼손도 평가)

  • Yoo, Ji Hyun;Lee, Myeong Seong;Choie, Myoungju;Ahn, Yu Bin;Kim, Yuri
    • The Journal of the Petrological Society of Korea
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    • v.27 no.4
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    • pp.207-222
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    • 2018
  • Celestial Chart Stones (original and reproduction) in the National Palace Museum are representative scientific cultural heritage of Korea. Material analysis and nondestructive deterioration assessment were conducted for long-term preservation of these stones. Material analysis revealed that the original was composed of slate and the reproduction was made of dolostone. The original consists of quartz, mica, dolomite minerals, while the reproduction was made up of dolomite, calcite and forsterite. Major deterioration factors of the original stone were cracks and breakouts. In case of the reproduction, scratches and artificial materials were mainly observed. The green and black surface contaminants present at the sides and back of the two celestial chart stones were interpreted as resin-based paint materials. The physical property evaluation using ultrasonic velocity showed a low velocity in the upper left side of the original, while the front right side of the reproduction showed a weak property. Meanwhile, the To-Tc method using ultrasonic velocity was applied to major cracks that impede stability of the original. As a result, it has been calculated that the beginning and the center of the crack are the deepest.

Study on the Continuous Composting Process to Reduce the Use of Bulking Agent in Pig Slurry (톱밥 절감형 돈분 슬러리 연속 퇴비화 공정 연구)

  • Ryoo, J,.W.
    • Journal of Animal Environmental Science
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    • v.13 no.2
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    • pp.121-128
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    • 2007
  • To develop the composting system to reduce the use of bulking agent, continuous composting was performed with farmer scale facility, The plant comprises a horizontal pit reactor closed inside a greenhouse and equipped with a turning machine moving on rails. The pit was 9m wide and 50m long and the maximum height of loaded materials was $1.8m^2$. The materials remained in the reactor for 5 months. During the composting process, temperature and water content measured and water balance was evaluated. The reaction temperature of composting was changed $30{\sim}50^{\circ}C$ and high in the middle and low in under composting piles. The moisture contents of the compost were approximately 70% during the experiment. The amount of effluent was 10.6% and $3.16m^3$ of pig slurry per $1m^3$ of bulking agent was treated during continuous composting process. BOD and SS reduction of the effluent in continuous composting was 86.5% and 92.2%, respectively. Indoor relative humidity in night time was changed between 80 and 100%.

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Groundwater Flow Modeling for a Finite Unconfined Sandy Aquifer in a Laboratory Scale (사질 자유면 대수층 모형에서의 지하수 모델링)

  • 이승섭;김정석;김동주
    • Journal of the Korean Society of Groundwater Environment
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    • v.6 no.4
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    • pp.188-193
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    • 1999
  • Transport of pollutants in aquifer largely depends on groundwater flow which is governed by aquifer hydraulic parameters. Determination of these parameters and associated groundwater modeling become essential for adequate remediation of contaminate groundwater. The objective of this paper is to analyze groundwater flow and determine the optimum hydraulic parameters by performing groundwater modeling based on sensitivity analysis for unconfined sandy gavel aquifer constructed in a laboratory scale under various boundary condition. Results revealed that the simulated drawdown was lower than the observed drawdown irrespective of boundary conditions. and specific yield (S$_{y}$) had less effect on the grondwater flow than permeability (K) in the aquifer. Water balance analysis showed that the measured drawdown in neighboring observation wells during pumping was higher than either simulated or recovered water table. The indicated that a difference might exist in the water tables between aquifer and wells. The difference was investigated by time domain reflectometry (TDR) measurements on water contents in the region of water table and capillary fringe, and explained by a delayed response of water table during gravitational drainage as the water table was lowered as a result of pumping.g.

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A Study on RFID Tag Recognition for Metal Pipe in Fish Cultivating Industry (양식용 철제 가두리에 대한 RFID 태그 인식률 개선에 관한 연구)

  • Park, Sung-Mee;Kim, Chae-Soo
    • Journal of Korea Society of Industrial Information Systems
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    • v.17 no.7
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    • pp.209-214
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    • 2012
  • RFID(Radio Frequency IDentification) is an emerging technology which brings enormous productivity benefits in applications where objects have to be identified automatically. But despite of RFID's advantage, it is not easy to realize the RFID technology in business world. The failure to read RFID tags is the most urgent problem that should be solved for RFID application. Specially, in metal and liquid material, recognition rate of RFID tag is lower than others. Though some special tags for metal and liquid have been invented, it has not prevalent in business world on account of high price. In this paper, styrofoam pad is suggested to improve recognition rate of RFID tag for metal pipe which is used in fish cultivating industry. We makes experiment using Taguchi method and analyze the effects on styrofoam thickness, attachment location of tag, and angle of antenna.

Numerical Simulation the Effect of Stormwater Treatment on the Water Quality Improvement in a Small Reservoir (초기우수처리에 따른 소규모 저수지 수질개선 효과 수치모의)

  • Ye, Lyeong;Liu, Huan;Lee, Heung-Soo;Kim, Yu-Kyung;Chung, Se-Woong
    • Proceedings of the Korea Water Resources Association Conference
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    • 2007.05a
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    • pp.2064-2068
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    • 2007
  • 합류식 하수도는 오수와 우수를 동시에 배제하는 하수관거 시스템으로 시공이 쉽고 건설비용이 저렴한 반면에 강우시 차집되지 않고 월류되는 유출량으로 인해 수체에 악영향을 초래한다. 관거에서 유출되는 유출수는 강우 초기에 유역에서 집중적으로 유출되는 비점오염원과 하수 및 관거내 오염물질 등을 동반하여 수질 개선을 어렵게 하고 수질 악화를 가중시킨다. 본 연구에서는 기존 유역에 설치된 합류식 하수관거를 분류식으로 개선하고 강우시 초기 세척에 의해 유입하는 비점오염원을 삭감하기 위한 초기우수 처리시설 설치에 따른 M 저수지 수질개선 효과를 수치모델을 사용하여 모의하였다. 저수지의 수질예측은 횡방향 평균 2차원 저수지 수리 및 수질모델인 CE-QUAL-W2를 사용하였다. 저수지 유입량은 군산기상대에서 관측한 일별 강우량 자료를 이용하여 일별 유출량을 산정하였고, 댐 방류량 자료는 M저수지의 2006년 일별 관측수위를 이용하여 유입량과 수위-체적 곡선으로부터 산정하였다. 모델의 보정은 2005년 5월과 8월에 측정한 수질자료를 이용하여 수행하였으며, 저수지의 관측값과 모의결과는 저수지 중앙부 대표지점에서 이루어졌으며, 모델은 관측값을 잘 반영하였다. 모의 결과 M 저수지의 연평균 BOD농도는 합류식(1.25 mg/L)에 비해 분류식 하수 관거(0.91 mg/L)를 도입할 경우 27.2% 개선되었으며, 초기우수 처리시설(0.84 mg/L)을 추가 할 경우 32.8%까지 개선효과가 상승하였다. 기존 합류식 하수관거의 경우 연간 유출부하량은 7,713 kg/yr이었으며, 분류식으로 전환할 경우 2,256 kg/yr, 초기우수처리시설을 추가할 경우 902 kg/yr로 삭감되는 것으로 예측되었다. 분류식하수관거와 초기우수처리를 모두 이행할 경우, BOD와 COD 기준이 호수 수질 기준 II등급 이내로 유지되며, T-P 농도는 0.02mg/L 이하로 유지되어 6월 이후 여름철에 저수지내 조류성장 억제에 효과가 클 것으로 예측되었다. 하수관거 정비사업을 통해 M 저수지는 기존의 농업용 저수지의 목표수질뿐만 아니라, 친수공간으로써 적합한 II등급 수질을 유지할 수 있을 것으로 판단되었다.

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