• Title/Summary/Keyword: 열화학 처리

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Sensitive Characteristics of Hot Carriers by Bias Stress in Hydrogenated n-chnnel Poly-silicon TFT (수소 처리시킨 N-채널 다결정 실리콘 TFT에서 스트레스인가에 의한 핫캐리어의 감지 특성)

  • Lee, Jong-Kuk;Lee, Yong-Jae
    • Journal of Sensor Science and Technology
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    • v.12 no.5
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    • pp.218-224
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    • 2003
  • The devices of n-channel poly silicon thin film transistors(TFTs) hydrogenated by plasma, $H_2$ and $H_2$/plasma processes are fabricated. The carriers sensitivity characteristics are analyzed with voltage bias stress at the gate oxide. The parametric sensitivity characteristics caused by electrical stress conditions in hydrogenated devices are investigated by measuring the drain current, threshold voltage($V_{th}$), subthreshold slope(S) and maximum transconductance($G_m$) values. As a analyzed results, the degradation characteristics in hydrogenated n-channel polysilicon thin film transistors are mainly caused by the enhancement of dangling bonds at the poly-Si/$SiO_2$ interface and the poly-Si grain boundary due to dissolution of Si-H bonds. The generation of traps in gate oxide are mainly dued to hot electrons injection into the gate oxide from the channel region.

플라즈마 전처리를 통한 금속기판 위 탄소나노튜브의 저온 합성

  • Sin, Ui-Cheol;Kim, Jin-Ju;Lee, Byeong-Ju;Jeong, Gu-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.67-67
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    • 2010
  • 탄소나노튜브(CNT)는 우수한 기계적, 화학적, 전기적 특성으로 인해 다양한 분야에서 차세대 응용재료로서 각광을 받고 있다. 다양한 CNT의 합성방법 중 CNT 구조제어가 가장 용이한 방법으로는 열화학증기증착법(TCVD)와 플라즈마지원(PE) CVD법이 있으며, 대량합성을 위해서는 TCVD가 보다 일반적으로 이용되어지고 있다. 일반적으로 CNT를 합성하기 위해서는 전이금속의 촉매가 필요하며 촉매의 활성화 및 탄소를 포함하는 원료가스의 분해를 위하여 고온공정이 요구된다. 그러나 향후 산업적 응용을 고려한다면 저온합성법의 개발은 시급하게 해결해야 할 과제로 인식되고 있다. 또한 기판 위에 CNT를 합성하는 경우 촉매와 기판재료 사이의 합금화를 방지하기 위하여 산화막층을 삽입하게 되는데, 이는 CNT의 높은 전도성을 이용하고자 할 경우 저해요소로 작용하게 된다. 따라서 CNT를 완충층의 도움 없이 금속기판 위에 직접 성장시키는 기술 역시 향후 CNT응용에 있어서 중요한 과제라 할 수 있다. 상기와 같은 배경으로 본 연구에서는 금속기판 위 CNT의 저온성장을 목적으로 연구를 진행하였다. CNT 합성기판으로는 SUS316L 및 Inconel과 같은 촉매금속을 자체 함유한 금속기판을 선정하였고, 플라즈마 전처리를 통한 기판표면 제어를 통하여 CNT의 저온성장을 도모하였다. 직류전원의 아르곤 플라즈마를 이용하여 금속기판을 처리하였을 때 기판온도 및 플라즈마 파워가 증가함에 따라 기판의 표면조도가 증가하는 것을 AFM분석을 통해 확인할 수 있었다. 아세틸렌 가스를 원료가스로 이용한 TCVD합성에 있어서는 플라즈마 처리한 기판이 무처리 기판보다 동일 합성온도에서 더 두꺼운 CNT박막을 형성하였고, 합성온도는 $400^{\circ}C$ 부근까지 내릴 수 있었다. 이는 플라즈마 처리로 증가된 기판의 표면조도가 저온에서 CNT의 핵생성에 유리하게 작용했음을 추측하게 한다.

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Effect of pretreatment and packaging methods on quality of cold vacuum dried peach (전처리 및 포장방법이 냉풍감압건조 복숭아의 품질에 미치는 영향)

  • Kwon, Gi-Man;Kim, Jae-Won;Youn, Kwang-Sup
    • Food Science and Preservation
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    • v.20 no.3
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    • pp.317-322
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    • 2013
  • This study was conducted to investigate the effects of pretreatment and different packaging methods on the physicochemical properties of cold vacuum-dried peaches. All the dried peach samples were stored such as $N_2$ gas substitution, vacuum and passive packaged with polyethylene (PE) film and oriented polypropylene (OPP)/aluminum (Al)/PE film at $40^{\circ}C$ for 50 days. The weight change, pH, soluble solids content, titratable acidity, soluble solid-acid ratio (SS/TA), delta E, browning degree and phenolic compounds were analyzed. The weight change and pH were lower in the 0.1% vitamin C-treated group and were significantly lowest in the vacuum-treated OPP/AL/PE. The soluble solids content and the SS/TA were higher in the non-treated groups than in the vitamin C-treated groups. According to the packaging methods, the $L^*$ values were higher in the vacuum, $N_2$ gas and passive package, in that order. In addition, the browning degree and the delta E value were lower in the pretreated groups and significantly lowest in the vacuum-treated OPP/AL/PE with 0.1% vitamin C group. The phenolic compounds were high for the pretreated groups, according to the packaging methods (vacuum > $N_2$ gas> passive), and the OPP/AL/PE was significantly higher than the PE. These results suggest that different packaging materials and pretreatment methods affected the quality of the dried peaches, and the vacuum-OPP/AL/PE film packaging group showed a high quality.

The Research for effect of lubricant oil aging on environmental performance (자동차 윤활유의 성상 및 열화가 환경성에 미치는 영향 연구)

  • Kim, Jeong-Hwan;Kim, Ki-Ho;Ha, Jong-Han;Jin, Dong-Young;Myung, Cha-Lee;Jang, Jin-Young
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.1
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    • pp.12-24
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    • 2017
  • The main purpose of this research is for the investigation on the impact of engine oil aging on PM and DPF. It is widely known that lubricant specifications and consumption from an ICE have significantly influenced on the regulated and unregulated harmful emissions as the engine operating conditions. Considering DPF clogging phenomena with lubricant-derived soot/ash components, simulated aging mode for the DPF was newly designed for engine dynamometer testing. PM/ash accumulation cycle were developed in reflecting real-world engine operating conditions for the increment of engine oil consumption and natural DPF regeneration for the ash accumulation. The test duration for DPF aging reached around 100hrs with high- and low-SAPS engine oils, respectively. Using high SAPs engine oil made more PM/ash accumulation compared with low SAPs engine oils and it could accelerate fouling of EGR in engine. Fouling of EGR made effects on more harmful exhaust gases emissions. The test results on engine lubricant under engines operating conditions will deliver for the establishment of regulated and unregulated toxic emissions policy, lubricant quality standard.

Current on the Heat Loss in Greenhouses during Winter Season - Case Study Based on Gyeongnam Area - (동절기 온실의 열 손실에 관한 실태조사 - 경남지역을 중심으로 -)

  • Im, Jae Un;Yun, Sung Wook;Kim, Hyeon Tae;Yoon, Yong Cheol
    • Journal of Bio-Environment Control
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    • v.22 no.1
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    • pp.73-79
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    • 2013
  • An experiment was conducted to study incidences of heat loss in greenhouse in Gyeongnam province using thermal imaging camera in order to determine ways minimizing greenhouse heat loss. Measurements of this work showed that temperature differences between two experiment zones before and after installation of thermal curtains were about $2.0{\sim}3.0^{\circ}C$ and $1.0{\sim}2.0^{\circ}C$ respectively. There was a high correlation between the temperature data measured using a thermal imaging camera and a temperature sensor. There was no serious difference among areas, but between places on the first and second floor with thermal curtains for heat insulation, there was a relatively larger heat loss on the first floor than the second floor. Then in general the greenhouse types had no particular bearing on this matter, there was a relatively large heat loss in the parts of side wall window, the gaps and the parts folded of horizontal thermal curtains, the gutter parts, and the gaps of thermal curtain in the side wall window and facade back side for heat insulation, aren't completely sealed. It was found that there was a substantial heat loss due to infiltration through cracks on covering material, doors, ventilating openings, roof gables and floors, in particular.

A study on the Properties of Composite Systems Using Polymer-Modified Mortar and Epoxy Resins for Waterproofing and Anti-Corrosion of Concrete Structures (시멘트 혼입 폴리머와 에폭시수지를 복합한 수처리 콘크리트구조물용 방수방식재료의 성능평가에 관한 연구)

  • Bae Kee-Sun;Jang Sung-Joo;Oh Sang-Keun
    • Journal of the Korea Concrete Institute
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    • v.17 no.1 s.85
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    • pp.3-10
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    • 2005
  • The purpose of this study is to investigate the properties of composite systems using polymer cement and epoxy resins for waterproofing and anti-corrosion to concrete structures such as water supply facilities and sewage-works. For the waterproofing and anti-corrosion of concrete structures, there can be required various properties such as absorption capacity and water permeability, adhesion and tensile strength, hair crack-resistance, impact-resistance, repeated low and high temperature test and chemical resistance, soundness for drinking water, soundness for drinking water and etc. In this study these engineering properties of composite systems using polymer-modified mortar and epoxy resins were examined and could be confirmed to satisfy the guidelines of KS. Especially, it was turn out that the adhesion properties was excellent and high crack-resistance up to 1.49 mm will be perform.

Effects of Shield Materials on the Growth and Yield Characteristics of Melon Grown inside a Plastic Greenhouse in Summer Season (고온기 멜론 시설재배 시 자재별 차광 효과)

  • Lee, Jae Han;Lee, Jung Sup;Kwon, Joon Kook;Yeo, Kyung Hwan;Bang, Ji Woong;Kim, Jin Hyun;Lee, Choung Keun;Park, Kyoung Sub;Myung, Dong Ju
    • Journal of Bio-Environment Control
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    • v.30 no.4
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    • pp.304-311
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    • 2021
  • This Experiment was conducted to determine the effects of light shield materials when melon grown inside a plastic greenhouse in summer season. The average temperatures were 36.6℃, 34.5℃ and 34.0℃ respectively for the control(non-shield), coating agent, and the white net. The light transmittances were 69% and 75%, respectively inside the greenhouse treated with the coating agent and white net immediately after applicants, compared with that inside the control greenhouse. At the 40 and 80 days after treatment, the light transmittances for the coating agent were 92% and 98%, respectively, indicating it was slowly decomposed and removed, but there was no change in the transmittance for the white net. While the leaf number did not differ among the treatments, the plant height was higher in the white net and shading agent than in control. The weight of the leaves, fresh-weight and dry-weight were no different from that of shading, but it became heavier in the later stages. The marketable fruit yield was increased by 6% for white nets and 5% for the coating agent compared to control, there was no statistical significance. Therefore, coating agent is considered as an effective method to lower temperature during high temperature period, but it is preferable to use it in consideration of cultivation period, because the coating agent is gradually removed.

Application and conservation of 3D technology for the restoration of the original shape of military boots excavated in the DMZ (비무장지대 출토 군화의 형태 복원을 위한 3차원 디지털 기술의 적용 및 보존처리)

  • OH Seungjun;WI Koangchul
    • Korean Journal of Heritage: History & Science
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    • v.56 no.2
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    • pp.124-133
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    • 2023
  • Preservation processing for two combat boots was executed through application of 3-dimensional digital technology and with use of preservation materials providing outstanding reversibility and stability. The aim of this was to establish a method to preserve the relics of fallen Korean War soldiers that had been excavated by the soldiers remains excavation corps of the Ministry of National Defense. It was possible to estimate the foot size of the soldiers who would have worn the combat boots via 3-dimensional digital scanning and modeling of the boots. In this process, the original form of the combat boots was restored through the use of 3D-printed structures. The original form was restored through a process of removing contaminants from the excavated relics and performing a conditioning treatment, and through use of an antique-color treatment after bonding and filling in the sections that had been ripped or deteriorated. Following the aforementioned preservation processes, it was possible to confirm that both of the combat boots had soles and top sections made of rubber, and portions of the top section and ankle section of the boots were made of synthetic rubber. As such, it was confirmed that these were similar to the Shoe Pac(M-1944, 12-inch) winter boots that had been manufactured for the purposes of waterproofing and/or protection against cold, and introduced in 1944. Such results confirmed that it is possible to discover the manufacturing techniques, materials, and uses of relics excavated through application of preservation processing, thereby illustrating the importance of the convergent research of scientific preservation processing and 3-dimensional digital technology.

The Effect of Mechanochemical Treatment of the Catalyst in the Preparation of Carbon Nanotubes and their Electrical Properties (탄소나노튜브 합성 및 전기적 특성에 미치는 촉매의 메카노케미컬 처리효과)

  • ;;Fumio Saito
    • Journal of the Korean Ceramic Society
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    • v.38 no.12
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    • pp.1110-1114
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    • 2001
  • We report the mechanochemical effect of an Fe(NO$_3$)$_3$$.$9H$_2$O-Al(OH)$_3$sample as catalytic precursor mixed-ground by mixer mill on the growth of carbon nanotubes using thermal chemical vapor deposition method. From and TEM observations, carbon products grown on a ground catalyst were more uniform than those grown on an unground catalyst and most of them were identified as carbon nanobubes. Also, it was observed that field emission properties of products on ground catalyst were superior to those of unground catalyst.

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Browning inhibition of fresh-cut lotus roots by blanching in Glycyrrhiza glabra L. and Astragalus membranaceus Bunge extracts (감초, 황기 추출물로 블랜칭 처리한 신선편이 연근의 갈변 억제)

  • Kim, Han-Bit;Chung, Hun-Sik;Moon, Kwang-Deog
    • Food Science and Preservation
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    • v.21 no.2
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    • pp.151-156
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    • 2014
  • This study was conducted to inhibit the browning of fresh-cut lotus roots by blanching in a Glycyrrhiza glabra L. and Astragalus membranaceus Bunge extract solution (0.5%). Lotus roots were cut to 1 cm using a knife. The fresh-cut lotus roots were blanched at $50^{\circ}C$ in distilled water (DW, Cont), Glycyrrhiza glabra L. extract solution (GE), and Astragalus membranaceus Bunge extract solution (AE). After treatment, they were packaged with 0.04 mm PE bags and were stored at $10^{\circ}C$ for 12 days. Their color, hardness, DPPH radical scavenging activity, pH, and total soluble solids were then investigated. During storage, the samples treated with GE and AE had high $L^*$ values. They were also found to have higher values compared to the control group in the analysis of the browning index. No difference was found, however, in the hardness analysis. With regard to the DPPH radical scavenging activity, the sample treated with Glycyrrhiza glabra L. extract had the highest activity. In the pH analysis, all the groups were found to have a decrease tendency for all the storage periods. The total soluble solids decreased in the control group and slightly increased in the AE and GE groups. These results show that blanching in Glycyrrhiza glabra L. or Astragalus membranaceus Bunge extract is effective for preventing the browning of fresh-cut lotus roots.