• Title/Summary/Keyword: 열응력 완화

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고무소재의 열응력

  • Gang, Sin-Yeong;Hong, Chang-Guk
    • Rubber Technology
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    • v.11 no.1
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    • pp.12-26
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    • 2010
  • 각종 산업제품의 주요 부품으로 사용되고 있는 고무재료는 사용 중 온도변화에 의해 체적 또는 길이 변화를 수반할 수 있어 결과적으로 고무제품의 성능이나 효율이 영향을 받게 된다. 특히 고온에서 고무제품의 치수변화를 제한하거나 일정치수를 강제할 경우 열수축이나 열팽창에 의해 응력이 발생하게 된다. 따라서 온도 변화에 따른 열응력의 측정은 고무제품의 정밀성과 성능을 평가하는 중요한 수단을 제공한다. 본 연구에서는 고무소재의 열응력 측정을 위한 새로운 측정방법을 개발하였고 이와 관련 새로운 시험장치를 설계, 제작하였다. 고무시편에 일정 변형의 인장을 준 상태에서 가열하면 열응력이 발생한다. 이 때의 열응력은 고무분자 사슬들의 운동성에 기인하며 배향된 고무분자 사슬들이 열역학적으로 랜덤 사슬형태로 돌아가려는 엔트로피적 힘이다. 따라서 온도가 높을수록 그 수축력은 증가하게 된다. 또한 고무분자 사슬의 사전 변형이 증가하면 그 열응력은 증가한다. 이때 열응력은 측정시간이 지남에 따라 최대치에 도달한 후 완화되며 그 완화속도는 설정온도에 의해 영향을 받는다. 여기서는 온도변화에 따른 고무시편의 열응력 측정결과를 소개하고, 고무분자 사슬의 엔트로피 변화와 점탄성적 흐름, 그리고 가열에 따른 고무 시편의 팽창 또는 수축이 열응력에 미치는 영향 등을 논의하였다. 특히 천연고무와 SBR 고무시편의 열응력 차이를 분자사슬의 운동과 연관하여 검토하였고, 가교밀도와 가교시스템이 각각 다른 고무시편에 대해 열응력 발생과에 따른 상관관계를 고찰하였다. 또한 시편의 형태와 두께가 열응력 발생에 미치는 영향도 검토하였다. 충전 배합고무의 경우 열응력에 영향을 미치는 인자로 고무분자 사슬의 운동성과 가교밀도 외에 고무재료와 충전제 사이의 물리 화학적 상호작용도 매우 중요한 요소가 된다. 배합고무에서 충전제의 영향을 검토하기 위해 실리카와 카본블랙을 선택하였고 배합고무의 열응력을 각각 측정하여 이들의 보강효과가 열응력에 미치는 영향에 대해 논하였다.

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Thermal Stress Relief through Introduction of a Microtrench Structure for a High-power-laser-diode Bar (높은 광출력을 갖는 Laser Diode Bar의 열응력 개선: 마이크로-홈 도입을 통한 응력 분포 변화 분석)

  • Jeong, Ji-Hun;Lee, Dong-Jin;O, Beom-Hoan
    • Korean Journal of Optics and Photonics
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    • v.32 no.5
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    • pp.230-234
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    • 2021
  • Relief of thermal stress has received great attention, to improve the beam quality and stability of high-power laser diodes. In this paper, we investigate a microtrench structure engraved around a laser-diode chip-on-submount (CoS) to relieve the thermal stress on a laser-diode bar (LD-bar), using the SolidWorks® software. First, we systematically analyze the thermal stress on the LD-bar CoS with a metal heat-sink holder, and then derive an optimal design for thermal stress relief according to the change in microtrench depth. The thermal stress of the front part of the LD-bar CoS, which is the main cause of the "smile effect", is reduced to about 1/5 of that without the microtrench structure, while maintaining the thermal resistance.

Thermodynamic Properties and Self Diffusions from Rheological Parameters of Eyring-Halsey Model (Eyring-Halsey 모델의 유동파라메타로부터 열역학 성질과 자체 확산)

  • Kim, Nam Jeong
    • Journal of the Korean Chemical Society
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    • v.58 no.3
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    • pp.251-257
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    • 2014
  • The stress relaxation of poly(methyl acrylate)-poly(acrylonitrile) copolymer samples were carried out in air and distilled water at various temperatures using the tensile tester with the solvent chamber. The rheological parameters were obtained by applying the experimental stress relaxation curves to the theoretical equation of the Eyring-Halsey non-Newtonian model. The self diffusion, hole volume, viscosities, and thermodynamic parameters of copolymer samples were calculated from rheological parameters and crystallite size in order to study of flow segments in amorphous region. It was observed that the rheological parameters of these copolymer samples are directly related to the self diffusion, hole volume, viscosities, and thermodynamic parameters of flow segments.

Self Diffusions and Rheological Properties of Polyamide Polymer Materials in Various Solvents (용매 환경에서의 폴리아미드 고분자 재료의 자체확산과 유변학적인 특성)

  • Kim, Nam Jeong
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.4
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    • pp.1050-1059
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    • 2019
  • The self diffusion, hole volume, and flow thermodynamic parameters of polyamide fibers were calculated from rheological parameters and crystallite size in order to study of flow segments in amorphous region. The stress relaxation of polyamide filament fibers were carried out in air and various solvents at various temperatures using the tensile tester with the solvent chamber. The rheological parameters were obtained by applying the experimental stress relaxation curves to the theoretical equation of the Ree-Eyring and Maxwell non-Newtonian model. It was observed that the rheological parameters of these polyamide filament fibers are directly related to the relaxation spectra, self diffusion, viscosities, and activation energies of flow segments.

A study on relaxation of thermal stresses of heat-resistant systems (열차단 시스템에 있어서의 열응력 완화에 대한 연구)

  • Choi, Deok-Kee;Kim, Chang-Soo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.22 no.1
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    • pp.16-22
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    • 1998
  • This paper addresses a method which can be used for analyzing thermal stresses of a functionally graded material(FGM) using semi-analytical approach. FGM is a nonhomogeneous material whose composition is changed continuously from a metal surface to a ceramic surface. An infinite one dimensional FGM plate is considered. The temperature distribution in the FGM is obtained by approximate Green's function solution. To expedite the convergence of the solutions, alternative Green's function solution is derived and shows good agreement with results from finite difference method. Thermal stresses are calculated using temperature distribution of the plate.

Stress Relaxation of mayonnaise Colloidal Solution (마요네즈 콜로이드 용액의 응력완화에 관한연구)

  • 윤승희
    • The Korean Journal of Rheology
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    • v.7 no.1
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    • pp.28-34
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    • 1995
  • 고체가 아닌 계인 마요네즈에 대해 Couette형 점도계를 사용하여 일정한 전단속도에 서 시간과 더불어 전단응력이 감소하는 응력완화 곡선을 온도 2$0^{\circ}C$, $25^{\circ}C$, 3$0^{\circ}C$, 34$^{\circ}C$, 4$0^{\circ}C$ 에서 얻었다 이현상을 설명하기 위하여 구조가 형성되는 flow unit 2와 구조가파괴되는 flow unit 3에 대한 fraction (X2, X3)사이의 평형을 생각하고 X2 와 X3 에 해당하는 항에 실 험적 조건인 s=p(t0+t)의 관계를 적용하여 다음과 같은 응력완화에 관한 식을 구하고 이식을 실험결과에 적용하여 유동파라메타를 구하였으며 그 파라메타중의 평형상수 k와 실험 온도 를 이용하여 열역학 파라메타를 구하였다.

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Self Diffusion Coefficients and Free Hole Volumes of Poly(acrylonitrile)-poly(vinyl chloride) Copolymers (Poly(acrylonitrile)-poly(vinyl chloride) 공중합체의 자체 확산 계수와 유동 자유 홀부피)

  • Kim, Nam-Jeong
    • Elastomers and Composites
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    • v.46 no.3
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    • pp.245-250
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    • 2011
  • The self diffusions and hole volumes of amorphous region of poly(acrylonitrile)-poly(vinyl chloride) fibers were investigated by experiments of stress relaxation. The experiments of stress relaxation were carried out using the tensile tester with the solvent chamber. The flow parameters of filament fibers were obtained by applying the experimental stress relaxation curves to the theoretical equation of stress relaxation. From the flow parameters, the hole volumes, self diffusions, viscosities and thermodynamic parameters of solid polymers were calculated. It was observed that the flow parameters of these samples are directly related to the hole volumes, self diffusions and flow activation energies of flow segments.

Thermal shock test of SiC/C functionally graded materials (FGM) and thermal stress simulation (SiC/C 경사기능재료의 열충격 시험과 열응력 모사)

  • 김유택;이성철;최근혁
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.4
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    • pp.612-618
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    • 1998
  • Monolithic SiC and SiC/C FGM layers were deposited on the graphite substrates by the CVD method and their thermal properties of the two specimens were investigated by thermal shock test for comparison. Temperature profiles and thermal stress distributions on thermal shock test were calculated by a commercially used computer program to see the thermal stress differences inside of two specimens. The specimens coated with FGM were expected to show a efficient relaxation of thermal stresses at the interface and they were not cracked under the actual $\Delta$T=1600 K experimental condition. This result proved that the experimental results were well accorded with the expectation from the theoretical calculations.

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The Analysis of Elasto-Plastic Thermal Stresses for Welding Part in Double Capstan Drum (더블 캡스턴 드럼의 용접부에 대한 탄소성 열응력해석)

  • 김옥삼
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.36 no.4
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    • pp.329-336
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    • 2000
  • Welding is a important technological method in mechanical engineering. $CO_2$MAG(metal active gas) welding means that metal part in double capstan drum for the inshore and costal vessels are joined by melting(with or without a filler material) or that new material is added to a metal part by melting. The thermal stresses appear due to a non-uniform temperature field, inhomogeneous material properties, external restraint and volume changes during phase transformations. In this study analysis the elasto-plastic thermal stresses distribution of welding part in double capstan drum for the inshore and costal vessels using finite element method (FBM). Therefore it calculates the numerical value that can be applied to the optimum design of welding parts and the shapes. The significant results obtained in this study are summarized as fellows. At early stage of the cooling after welding process, the abrupt thermal stresses gradient has been shown in the vicinity of welding part. In the thermal stresses analysis due to temperature gradient and heat shocking maximum stress was occurred of welding part and stresses were distributed from 54MPa~48MPa.

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