• Title/Summary/Keyword: 열분석적 특성

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A Study on Spatial Distribution of Villages in Border Region according to Change in Civilian Control Line (민간인통제선 변화에 따른 접경지역 마을의 공간적 분포에 관한 연구)

  • JEONG, Haeyong
    • Journal of the Korean Association of Geographic Information Studies
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    • v.24 no.2
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    • pp.91-101
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    • 2021
  • This study attempted to conduct the study from a macro perspective more specifically through the temporal and spatial analysis of Minbuk villages according to a change in a Civilian Control Line, such as a social and spatial distribution and a change of the existing Minbuk villages. To this end, this study conducted the spatial analysis for the change in the Minbuk villages according to the adjustment of the Civilian Control Line in time series by using a map of the Armistice Agreement Vol. 2, Google Earth, a digital cadastral map, an administrative district map, and the like are used as spatial data, and summarizing and constructing, as attribute data, a statistical yearbook, Ministry of Defense and Cheorwon-Gun notification data, a Land Use Regulation Information System, and cadastral map attribute information. After the enactment of the Military Facility Protection Act, the analysis was performed on a 20-year basis based on the 1976 statistical yearbook of which the Civilian Control Line was drawn. As a result, the total area of the Civilian Control Zone in Cheorwon from 1975 to 2015 decreased by 105.8 km2, and 9 of 14 Minbuk villages were released and only 6 villages existed. The unoccupied villages were analyzed as 14 villages, 10 fewer than the existing surveyed or statistical villages. The movement of the Civilian Control Line to the north may disappear the unique characteristics of the Minbuk villages but should be done carefully as it is closely related to the lives of the current residents, and policies should be established in terms of sustainable development and conservation of the villages. This study is significant in conducting the temporal and spatial analysis, which is the basis of the Minbuk regions and the Minbuk villages, and may be used as basic data necessary for subsequent analysis study.

Synthesis of Chromium Nitride and Evaluation of its Catalytic Property (크롬 질화물(CrN)의 합성 및 촉매특성에 관한 연구)

  • Lee, Yong-Jin;Kwon, Heock-Hoi
    • Applied Chemistry for Engineering
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    • v.17 no.5
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    • pp.451-457
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    • 2006
  • We synthesized phase pure CrN having surface areas up to $47m^2/g$ starting from $CrCl_{3}$ with $NH_{3}$. Thermal Gravimetric Analysis coupled with X-ray diffraction was carried out to identify solid state transition temperatures and the phase after each transition. In addition, the BET surface areas, pore size distributions, and crystalline diameters for the synthesized materials were analyzed. Space velocity influenced a little to the surface areas of the prepared materials, while heating rate did not. We believe it is due to the fast removal of reaction by-products from the system. Temperature programmed reduction results revealed that the CrN was hardly passivated by 1% $O_{2}$. Molecular nitrogen was detected from CrN at 700 and $950^{\circ}C$, which may be from lattice nitrogen. In temperature programmed oxidation with heating rate of 10 K/min in flowing air, oxidation started at or higher than $300^{\circ}C$ and resulting $Cr_{2}O_{3}$ phase was observed with XRD at around $800^{\circ}C$. However the oxidation was not completed even at $900^{\circ}C$. CrN catalysts were highly active for n-butane dehydrogenation reaction. Their activity is even higher than that of a commercial $Pt-Sn/Al_{2}O_{3}$ dehydrogenation catalyst in terms of volumetric reaction rate. However, CrN was not active in pyridine hydrodenitrogenation.

Application of K-DRUM Model for Pakistan Kunhar River Basin Considering Long-term Snow Melt and Cover (장기 융·적설을 고려한 파키스탄 Kunhar강 유역 K-DRUM모형 구축 및 적용)

  • Park, Jin Hyeog;Hur, Young Teck;Noh, Joon Woo;Kim, Seo-Won
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.6
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    • pp.2237-2244
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    • 2013
  • In this study, physics based K-DRUM(K-water Distributed RUnoff Model) using GIS spatial hydrologic data as input data was developed to account for the temperature variation according to the altitude change considering snow melt and cover. The model was applied for Pakistan Kunhar River Basin($2,500km^2$) to calculate long-term discharge considering snow melt and cover. Time series analysis of the temperature and rainfall data reveals that temperature and rainfall of the river basin differs significantly according to altitude change compared to domestic basin. Thus, applying temperature and altitude lapse rate during generate input data generation. As a result, calculated discharge shows good agreement with observed ones considering snow melt and accumulation characteristic which has the difference of 4,000 meter elevation above sea level. In addition, the simulated discharge strongly showed snow melting effect associated with temperature rise during the summer season.

The Study for the characteristics of mechanically and thermally treated PET films (기계적 및 열적 처리된 PET 필름의 특성에 관한 연구)

  • 이종영;노지영;박성수
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.11 no.5
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    • pp.197-202
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    • 2001
  • The influence of thermal treatment and cold drawing was investigated for poly(ethy1ene terephthalate) films fabricated with various experimental conditions. Samples were elongated at room temperature under stepwise-drawing condition with the cross-head speed kom 0.5 to 500 mrdmin in an universal tester. Stress oscillation was observed in the stress-stnin curve of the samples heat-treatd at 50, 72 and $129^{\circ}C$ for 30 min, but it was not observed in the samples heat-treatd at $83^{\circ}C$ for 30 min. Thermal analyses of the samples were carried out in differential scanning calorimeter at the heating rate df $10^{\circ}C$/min/min, and the glass transition temperature, crystallization peak, enthalpy of fusion and degree of crystallinity were measured. The dynamic mechanical analyses of the samples were also carried out in a multiplefimction internal kiction pendulum at 1 Hz with the heating rate of $1.5^{\circ}C$/min, and it was found that the elastic modulus increases in the order of non-treated, heat-treated, and elongated samples.

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Dehydration Characteristics of Cationic Surfactant-Modified Montmorillonite (양이온성 계면활성제로 표면개질된 몬모릴로나이트의 탈수 특성)

  • Seung Yeop Lee;Soo Jin Kim
    • Journal of the Mineralogical Society of Korea
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    • v.15 no.4
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    • pp.305-314
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    • 2002
  • The dehydration of hexadecyltrimethylammonium (HDTMA)-exchanged montmorillonite has been studied using X-ray diffractometry (XRD) and differential scanning calorimetry (DSC). The dehydration in HDTMA-montmorillonite seems to influence the swelling behavior of the organo-clay during heating. The basal d(001) spacing vs temperature curve of the HDTMA-montmorillonite has one broad swelling edge with a shoulder on the low-temperature side. We believe that the shoulder at $100^{\circ}C$ for the HDTMA-montmorillonite is due to interlayer swelling induced by the initial rearrangement of surfactants, and the second edge at $200^{\circ}C$ is caused by interlayer swelling resulting from the secondary vertical reorientation of alkyl chains. It seems that the dehydration of organo-clay induces a reorientation of the alkyl chains by transition to more vertical position relative to the silicate sheets, allowing instantly greater d-spacing.

A Study on the Analysis of Heat and Metallurgical Structure of Connection Parts for Residual Current Protective Devices (저압용 누전차단기 접속부의 발열 및 금속 조직 분석에 관한 연구)

  • Choi Chung-Seog;Shong Kil-Mok;Kim Dong-Ook;Kim Dong-Woo;Kim Young-Seok
    • Fire Science and Engineering
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    • v.18 no.4
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    • pp.57-63
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    • 2004
  • We investigated heat properties of connection terminal in residual current protective devices(RCD) according to contact pressure for low voltage appliance. And we analyzed voltage and current waveform and oxide propagation when the poor-contact happened between terminal and wire. When contact pressure between terminal and connection wire was not applied, the heat was generated and an oxide was formed on the surface of the wire. The temperature of the insulation surrounding terminal was ascended sharply by poor-contact, micro-sparks and continuous arc sound happened in interior terminal. When the poor-contact by vibration occurred inner conductor of terminal and wire, an oxide was propagated on contact surface and the temperature was increased at 869℃. Thus, we found that the risk of electrical disaster is high in terminal and connection wire parts.

A Study on Demand Forecasting of Export Goods Based on Vector Autoregressive Model : Subject to Each Small Passenger Vehicles Quarterly Exported to USA (VAR모형을 이용한 수출상품 수요예측에 관한 연구: 소형 승용차 모델별 분기별 대미수출을 중심으로)

  • Cho, Jung-Hyeong
    • International Commerce and Information Review
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    • v.16 no.3
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    • pp.73-96
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    • 2014
  • The purpose of this research is to evaluate a short-term export demand forecasting model reflecting individual passenger vehicle brands and market characteristics by using Vector Autoregressive (VAR) models that are based on multivariate time-series model. The short-term export demand forecasting model was created by discerning theoretical potential factors that affect the short-term export demand of individual passenger vehicle brands. Quarterly short-term export demand forecasting model for two Korean small vehicle brands (Accent and Avante) were created by using VAR model. Predictive value at t+1 quarter calculated with the forecasting models for each passenger vehicle brand and the actual amount of sales were compared and evaluated by altering subject period by one quarter. As a result, RMSE % of Accent and Avante was 4.3% and 20.0% respectively. They amount to 3.9 days for Accent and 18.4 days for Avante when calculated per daily sales amount. This shows that the short-term export demand forecasting model of this research is highly usable in terms of prediction and consistency.

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An experimental study on preparation of precipitated calcium carbonate using Ca component dissolution characteristics and liquid carbonation by the Industrial byproducts (산업부산물의 Ca 성분 용출 특성 및 액상탄산화 반응을 이용한 침강성 탄산칼슘 제조에 관한 실험적 연구)

  • Lim, Yun-Hui;Lee, Ju-Yeol;Shin, Jae-Ran;Choi, Chang-Sik;Hong, Bum-Ui;Kang, Ho Jong;Park, Byung Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.1
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    • pp.116-126
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    • 2015
  • The present study utilized a shuttle mechanism of wet chemical absorption using MEA. In addition, industrial by-products containing a large amount of inorganic alkali substances were utilized for wet carbonization process. Chemical pretreatment of industrial by-products extracted calcium ions. ICP result of calcium ion was obtained up to 17,900 ppm(17.9%) by acidic substance. And also, In this work, 94% of recovery rate was obtained using wet MEA absorption process from $CO_2$ flow at the ambient condition. Through the liquid carbonation process, a sludge was fixed with rate of 0.175 mg of $CO_2$ per mg of sludge. It was found from XRD results that the structure of final product was composed of a calcite structure which is general structure of $CaCO_3$.

Studies on the Sorption and Fixation of Cesium by Vermiculite (II)

  • Lee, Sang-Hoon
    • Nuclear Engineering and Technology
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    • v.6 no.2
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    • pp.97-111
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    • 1974
  • The adsorption mechanism of Cs-137 in low level radioactive solution by vermiculite treated with Na ion is studied in order to investigate its effective utilization for the radioactive effluent treatment. The beneficial role of Na-vermiculite is that Na ion can induce the wider c-axis spacing in which Cs ion can be sorbed in vermiculite. Cation exchange capacity and distribution coefficient of cesium seems to be influenced by the variation of c-axis spacing of vermiculite. Comparative identification and detection with the characteristic analyses of X-ray diffraction and electron diffraction patterns, diffrential thermal analysis and electron microscopy of Na-, K- and Cs-vermiculite are studied for the phemomena of Cs adsorption by vermiculite. This importance of the utilization in terms of adsorption and fixation of cesium involving vermiculite is discussed. It is found that the Na-vermiculite is valuable outside charging material for high level radioactive liquid waste storage tank of underground to protect the pollution of the underground water.

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Friction Force Microscopy Analysis of Diamond-like Carbon Films (다이아몬드상 카본 박막의 Friction Force Microscopy 분석)

  • Choi, Won-Seok;Lee, Jong-Hwan;Song, Beom-Young;Heo, Jin-Hee;You, Jin-Soo;Hong, Byung-You
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.181-181
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    • 2008
  • DLC (Diamond-like Carbon) 박막은 높은 내마모성과 낮은 마찰 계수, 화학적 안정성 및 적외선 영역에서의 높은 투과율과 낮은 광 반사도, 높은 전기저항과 낮은 유전율, 전계방출특성 등 여러 가지 장점을 가진 물질이다[1]. 최근에는 DLC 박막의 여러 장점들과 산과 염기 유기용매에 대한 화학적 안정성으로 인하여 인조관절에서 인공심장의 판막에 이르기까지 의공학 관련 부품소재로 응용되고 있으며 내구성과 안정성에 있어서 탁월한 성능을 보여주고 있다. 또한 DLC 박막의 높은 경도와 낮은 마찰 계수, 부드러운 박막 표면 (수nm의 RMS 거칠기)의 장점을 살려 마그네틱 미디어와 하드디스크의 슬라이딩 표면에 사용되어지고, MEMS (Micro-Electro Mechanical System) 소자와 MMAs (Moving Mechanical Assemblies)의 고체윤활코팅으로 활용하여 미세기계의 내구성과 성능 향상을 도모할 수 있다. 이와 같이 DLC 박막은 다양한 분야에 응용되고 있으며, 박막이 지닌 여러 가지 장점들로 인하여 더 많은 분야에 응용될 가능성을 지닌 물질이다. 그러나 수 ${\mu}m$이상의 두께에서 박막이 높은 잔류응력 (residual stress)을 가지고, 열에 취약하여 이의 개선에 관한 연구들이 진행되어 지고 있다 [2]. 따라서 사용되는 목적에 따라 용도에 맞는 양질의 DLC 박막을 합성하기 위해선 합성 장치의 개발과 다양한 실험을 통한 최적의 합성조건 도출 등의 노력이 요구된다. 또한 DLC 박막 합성시의 여러 가지 증착 방법에 따른 박막 물성에 대한 재현성 확보 및 박막 증착에 관한 명확한 메커니즘 규명이 아직까지는 불분명하여 이에 관한 연구가 시급하다. 따라서 본 연구에서는 MEMS 소자와 MMAs의 고체윤활코팅으로 사용가능한 DLC 박막을 RF PECVD (Plasma Enhanced Vapor Deposition) 방식으로 합성하고 후열처리 온도에 따른 DLC 박막의 마찰계수 변화를 박막에 훼손을 주지 않는 FFM (Friction Force Microscopy) 방식을 사용하여 분석하였다.

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