• Title/Summary/Keyword: 열분석적 특성

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Crystallization Kinetics by Thermal Analysis (DTA) on Starting Glass Compositions for PDP(Plasma Display Panel) Rib (열분석에 의한 PDP 격벽용 출발유리조성의 결정화 특성 연구)

  • Jeon, Young-Wook;Cha, Jae-Min;Kim, Dae-Whan;Lee, Byung-Chul;Ryu, Bong-Ki
    • Journal of the Korean Ceramic Society
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    • v.39 no.8
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    • pp.721-727
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    • 2002
  • In order to overcome trade-off among compositions, process and properties of the glasses with high PbO-base composition for PDP Rib, we studied glass crystallization and crystallization kinetics by Differential Thermal Analysis(DTA). Glass powder was obtained through melting/cooling/grinding, with 3 wt%TiO2 addition for the crystal nucleation and growth in $62PbO-19B_2O_3-10SiO_2-9(Al_2O_3-K_2O-BaO-ZnO)$(in wt%) composition glass. This powder was heat-treated for 1 to 10 h at $445^{\circ}C$ for nucleation. DTA measurements were performed to obtain the crystallization peak with $5∼25^{\circ}C/min$ heating rates. DTA crystallization peak temperature increased with increasing the heating rate and decreased with increasing the heating time. Because the Avrami parameter (n) was approximately 1, the surface crystallization occurred. The maximum nucleation time was 2 h.

Dynamic shear behavior of geosynthetic-soil interface considering thermalchemical factors (열-화학적 인자를 고려한 복층터널의 지반-토목섬유의 접촉면 전단거동)

  • Jang, Dong-In;Kwak, Chang-Won;Park, Inn-Joon
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.18 no.2
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    • pp.213-220
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    • 2016
  • The needs for the utilization of space in the urban ara due to the increasing population and traffic volume. A Double-deck tunnel can be an appropriate solution. Geosynthetics are inevitably installed between ground and tunnel lining, therefore, geosynthetic-soil interface is also comprises. Dynamic shear behavior of geosynthetic-soil interface affects the dynamic behavior of tunnel, and experimental study is required since the behavior is very complicated. In this study, chemical factors such as acid and basic element in the groundwater and temperature are considered in the laboratory test. Multi-purpose Interface Apparatus(M-PIA) is utilized and submerging periods are 60 and 960 days. Consequently, dynamic shear degradation of geosynthetic-soil interface considering chemical and thermal factors are verified.

Structural Characteristics and Physical Properties of Wild Silk Fibres; Antheraea pernyi and Antheraea yamamai (야잠사의 구조특성 및 물리적 성질)

  • 권해용;박영환
    • Journal of Sericultural and Entomological Science
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    • v.36 no.2
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    • pp.138-146
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    • 1994
  • The structural characteristics of Antheraea yamamai and Antheraea pernyi silk were investigated by using x-ray diffraction method, IR spectroscopy and polarizing microscopy. The amino acid composition, fiber density, thermal decomposition temperature and glass transition temperature were also measured for relating these physical properties to the structure in comparison with those of Bombyx mori silk fiber. There was no significant structural difference between A. yamamai and A. pernyi silk fiber on an examination of x-ray diffraction curve and IR spectrum. Both of these wild silk fibers showed double diffraction peaks at the Bragg angle 2Θ16.7˚ and 20.5˚by x-ray diffraction analysis as well as IR absorption peaks for the bending vibration of specific groups related to ala-ala amino acid sequence. On the other hand, the x-ray diffraction curve and IR spectrum of Bombyx mori silk fiber are different from those of wild silk fibers, indicating different crystal structure as well as amino acid sequences. It showed under the polarizing microscope examination that the birefringence and optical orientation factor of wild silk fibers are much lower than those of B. mori silk. Also, the surface of degummed wild silk fibers was characterized by the longitudinal stripes of microfibrils in the direction of fiber axies. The amino acid composition, which is strongly related to the fine structure and properties, was not significantly different between these two wild silk fibers. However, the alanine content was somewhat less and polar amino acid content more for A. yamamai. As a result of fiber density measurement, the specific gravities of B. mori, A. pernyi and A. yamamai were 1.355~1.356, 1.308~1.311, 1.265~1.301g/㎤ in the order, respectively. The calculated crystallinity(%) was 64% for B. mori and 51~52% for wild silk fibers, which showed same trend by IR method in spite of somewhat higher value. The thermal decomposition behaviour was examined by DSC and TGA, showing that the degradation temperature was in the order of B mori, A. prernyi and A. yamamai at around 350$^{\circ}C$. It was also observed by TGA that the decomposition seems to proceed step by step according to their specific regions in the fiber structure, resulting the difference in their thermal stabilities. The glass transition temperature was turned out to be 220$^{\circ}C$ for B. mori, 240$^{\circ}C$ A. yamamai and 255$^{\circ}C$ A. pernyi by the dynamic mechanical analysis. It is expected that the chemical properties are affected by the dynamic mechanical behavior in accordance with their structural characters.

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Computational Efficiency of Thermo-Elasto-Viscoplastic Damage and Contact Analyses by Domain/Boundary Decomposition (영역/경계 분할에 의한 열탄점소성 손상 및 접촉 해석의 효율화)

  • Kim, Sung-Jun;Shin, Eui-Sup
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.22 no.2
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    • pp.153-161
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    • 2009
  • A domain/boundary decomposition method is applied for efficient analyses of thermo-elasto-viscoplastic damage and contact problems under the assumption of infinitesimal deformation. For the decomposition of a whole domain and contact boundaries, all the equality constraints on the interface and contact interfaces are restated with simple penalty functional. Therefore, the non-linearity of the problem is localized within finite element matrices in a few subdomains and on contact interfaces. By setting up suitable solution algorithms, the computational efficiency can be improved considerably. The general tendency of the computational efficiency is illustrated with some numerical experiments.

Computational Analysis of Air Flows Inside Korean Traditional House (친환경 전통건축의 내부기류 전산해석)

  • Kim, Jay-Won;Aan, Eun-Yeong
    • Journal of Korea Multimedia Society
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    • v.15 no.3
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    • pp.380-387
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    • 2012
  • The present investigation is to examine the thermal behaviors of air flows inside Korean traditional house made of the construction materials transmitted. The methodology is numerical predictions of air flows depend on the temperature distribution inside the indoor spaces. The transient computational simulations are performed along with the different house types, weather condition, and operating time. Thermal properties of building units have been obtained by the parallel measurements and utilized in the numerical works. Consequently, the details of flows and temperature of air in the houses illustrate the thermal design of the traditional Korean house satisfy the requirements of human living.

Preparation of Graphene/Polybenzoxazine Conductive Composite Thin Film through Thermal Treatment (열 처리를 통한 그래핀/폴리벤족사진 전도성 복합 박막 제조)

  • Ko, Young Soo;Cha, Ji-Jung;Yim, Jin-Heong
    • Polymer(Korea)
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    • v.37 no.4
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    • pp.513-517
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    • 2013
  • A novel conductive composite thin film was prepared for the first time by hybridization between polybenzoxazine (PBZ) having high heat resistance property and conductive graphene. Mechanically robust conductive graphene/PBZ composite thin films could effectively be prepared by a simple thermal treatment, which simultaneously induces reduction of graphene oxide (GO) and crosslinking reaction of benzoxazine monomer. Graphene sheets seem to be uniformly dispersed up to 3 wt% graphene content in the composite thin film as shown in the results of chemical/crystal structural and morphological analyses. This efficient route for making graphene/PBZ composite thin film would provide simultaneous improvement of mechanical property as well as electrical conductivity.

A Study on the Transport-related Impacts of Flexible Working Policy using Activity-Based Model (활동기반모형을 이용한 유연근무제의 교통부문 영향 연구)

  • CHO, Sung-Jin;BELLEMANS, Tom;JOH, Chang-Hyeon;CHOI, Keechoo
    • Journal of Korean Society of Transportation
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    • v.35 no.6
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    • pp.511-524
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    • 2017
  • This study aims to evaluate the availability of ABM (Active-Based Model), FEATHERS, as a policy evaluation tool. To achieve the goal, scenario analysis on flexible working policy was conducted to measure its impact on activity-travel behavior. As a consequence, there seems no significant change in worker's daily life, other than mitigating traffic congestion due to decreasing commuting travel in the rush hour. The result of VKT (vehicle kilometers traveled) shows an opposite pattern according to given household/individual constraints. The scenario analysis on telecommuting indicates a decreasing trend in both travel frequency and distance because of the diminished number of commuting trips. As the activity space of telecommuters is shifted to a residential area, there are more short-distance trips by using non-motorized transport, which leads to decrease in VKT (using a private vehicle). Thus, the sensitivity of VKT by population groups varies due to transport mode shift (between personal and another mode) and growing non-work trips (using a private mode). This study found few things. First, it is necessary to evaluate the details of policy impact by population groups since it can be varied depending on household/individual characteristics. Second, the case study shows a promising performance of ABM as policy measurement that provides reality in policy evaluation. Third, ABM allows us to do more accurate analysis (i.e. time-series analysis by population groups) of policy assessment than those of FSM (Four-Step Model). Lastly, a further effort in data collection, literature review, and expert survey should be made to enhance the accuracy and confidence of future research.

A Qualitative Study on Continuing Bonds Experienced by Adolescent Victims' Parents of the Ferry Sewol Disaster : Focusing on implications for Grief Counseling by applying the Bereavement Two Track Model (세월호 재난으로 자녀를 잃은 부모의 지속유대 경험에 대한 질적 연구 : 사별 2축 이론을 적용한 애도상담에의 시사점을 중심으로)

  • Jeon, Ji-Yeol;Lee, Dong-Hun
    • The Journal of the Korea Contents Association
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    • v.22 no.7
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    • pp.443-477
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    • 2022
  • The purpose of this study was to explore the continuing bonds experienced by adolescent victims' 15 parents of the Sewol ferry disaster. The research aim is to classify the continuing bonds into representational, functional, emotional, and relationship characteristics through contents analysis and identify them. The way dimension was found to be continuing bond through "physical objects and space," "dream and spiritual exchange," "personal memorial and ritual activities," "thoughts of deceased children," and "surviving children." In the "functional dimension," it was found that sustainable ties help families find new meanings and purposes in their lives and comfort them by making them feel they are with their children. In addition, at the emotional level, they experienced 'positive emotions' while feeling with their children, and experienced 'pain', and some research participants found it difficult to sustain the bond itself. At the level of each relationship characteristic, the relationship between parents and children was an extension of the relationship even after the child was deceased, and the relationship characteristics were reproduced. The implications for grief counseling were presented by applying a dead two-axis model to the results of this study.

Factors Affecting Turnover Intention among Rehabilitation Specialist (장애인 재활전문가의 이직의도에 미치는 영향요인)

  • Youn, Ye-Sook;Cho, Sung-Yeol;Byun, Yong-Chan;Song, Geun-Chang
    • The Journal of the Korea Contents Association
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    • v.19 no.1
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    • pp.559-573
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    • 2019
  • The purpose of this study is to investigate factors affecting turnover intentions of rehabilitation specialists by using data on the "improvement of labor conditions and human rights of rehabilitation Specialist" which was conducted both in 2016 and in 2017. The turnover intention of the rehabilitation specialists was analyzed with personal factors, job-related factors, and factors related with client violence, discrimination, and burnout. Among these factors, variables of wage satisfaction, job satisfaction, and client violence have statistically significant effect on the turnover intention of rehabilitation specialists. While the variables of wage satisfaction and job satisfaction are likely to decrease the turnover intention of rehabilitation specialists, the variable of client violence significantly increase the turnover intention of rehabilitation specialists. The results of this analysis implies that the labor conditions including salary, the work environment for the rehabilitation specialists, and client education should be improved and strengthened to decrease the turnover intention of the rehabilitation specialists.

A Study on the Analysis Method of Technology Trend on Tactical Data Link Using Intellectual Property Information (지식재산 정보를 이용한 전술데이터링크 기술동향 분석방법 연구)

  • Noh, Giseop
    • The Journal of the Convergence on Culture Technology
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    • v.7 no.1
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    • pp.539-544
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    • 2021
  • The tactical data link is a military data network to improve the ability to recognize battlefield situations. The ROK military is promoting the tactical data link performance improvement programs. Tactical data link is essential to combine and integrate various platforms, sensor data, and command and control (C2) systems. Therefore, the research on related technical fields is required. However, the tactical data link has not disclosed detailed technical information due to the characteristics of military operation. In this paper, we propose a data-based automated analysis methodology using intellectual property information to understand the technology trend of tactical data link. In this paper, data related to intellectual property is automatically collected and pre-processed, and analyzed in terms of time series. In addition, the current status of each institution of patent technology information was generated, and the process of identifying key-researchers through network analysis was presented with providing results of our approach in this paper.