• Journal of Korean Society of Forest Science
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• v.111 no.4
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• pp.490-501
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• 2022

In this study, the isoprene and terpene emissions from 32 major urban tree species were investigated. We conducted sampling using a dynamic enclosure system between June and July 2021. Seedlings aged < three years were enclosed in a chamber consisting of a 400 L transparent Tedlar bag. The air flow from the outlet of the chamber was sampled using Tenax-filled sorbent tubes under standard conditions (temperature: 30°C; PAR: 1,000 μmol/m²/sec). A thermal desorption gas chromatography/mass spectrometry system was used to analyze the following 38 biogenic volatile organic compounds: isoprene, monoterpenes, sesquiterpenes, oxygenated monoterpenes, and oxygenated sesquiterpenes. Isoprene emitters included Quercus mongolica, Salix koreensis, Robinia pseudoacacia, and Salix chaenomeloides. Monoterpene emitters included Pinus strobus, Cedrela sinensis, and Cercis chinensis. The monoterpene emission profiles were dominated by á-pinene, myrcene, camphene, and limonene. The predominant oxygenated monoterpene and oxygenated sesquiterpene were eucalyptol and caryophyllene oxide, respectively. For all species, the contributions of sesquiterpenes and oxygenated sesquiterpenes were relatively low.

• Journal of the Korean Institute of Gas
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• v.17 no.1
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• pp.35-41
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• 2013

In this study, flame retardancy of polyurethane foam and phenolic foam were investigated by addition of phosphorous flame retardants. The thermal degradation behavior of polyurethane foam and phenolic foam in the presence of flame retardants has been studied by thermogravimetric analysis(TGA). Heat release rate(HRR), mean HRR, mass loss rate(MLR), total smoke released(TSR) and limited oxygen index(LOI) were tested by cone calorimeter. From the test results, Phenolic foam showed low HRR, MLR and TSR than polyurethane foam.

• Journal of the Korean Society of Propulsion Engineers
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• v.18 no.1
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• pp.73-84
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• 2014

The present paper includes recent research works on the estimation of physical properties like equivalence ratio and heat release rate of flame through chemiluminescence measurement. Modern combustion devices require a precise control to increase combustion stability as well as to suppress pollutant emissions. The determination of combustion characteristics from chemiluminescence provides practical advantages over other techniques. However, the technique is dependent on equivalence ratio, combustion pressure, inlet temperature, turbulent intensity and fuel type. The intensity ratio of $OH^*$ and $CH^*$ has a strong relation with an equivalence ratio for methane/air premixed flames. The global measurement of chemiluminescence is accepted as a good indicator for a global heat release rate.

• Fire Science and Engineering
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• v.24 no.3
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• pp.58-65
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• 2010

The fire accidents having recently occurred are getting more and more larger and causing lots of damage in terms of property loss and casualties increase, so there is in need of technical fire safety development like comprehensive prevention solution in order to effectively prevent. Especially, the needing of new paradigm for advanced fire safe technology is gathering strength in high-rise modern building construction. Therefore, we want to find out on this paper what is a correlation between heat release rate measurement and smoke release volume by three parts of oxygen consumption calorimeter in bench scale calorimeter (cone calorimeter/ISO 5660/Avg.500Kw), Medium scale calorimeter (Room corner tester, Single burning Item/ISO 9750, EN 13823/Avg.3MW), and large scale calorimeter (Industry calorimeter/Avg. 10MW). Thus, Smoke detective of new paradigm devised by making use of a correlation between heat release and smoke production is to help reduce loss property and casualties. Ultimately, based on this theory, a new concept of fire alarm and evacuation system will be developed and expected to apply to a skyscraper.

• Polymer(Korea)
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• v.31 no.5
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• pp.404-409
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• 2007

Polyurethane nanocomposites with inorganic nano fillers for the improvement thermal stability were prepared by the urethane reaction. Fire retardation properties of polyurethane nanocomposites were investigated by cone calorimeter and limited oxygen index (LOI). Maximum heat release rate of MMT-PU and $Bi_2O_3-PU$ polyurethane nanocomposites were decreased as 50% than polyurethane matrix and fire retardation properties of $MMT/Bi_2O_3-PU$ nanocomposte had the best improvement. The LOI of polyurethane nanocomposites also were improved as filling fillers in the nanocomposites over 20. The maximum heat release rates of MMT-PU, $Bi_2O_3-PU\;and\;MMT/Bi_2O_3-PU$ polyurethane nanocomposites were 764, 707, $635kW/m^2$, respectively and $MMT/Bi_2O_3-PU$ polyurethane nanocomposite exhibited the highest value of fire-retardant. We confirmed that polyurethane nanocomposites improved the fire retardation properties.

• Nuclear industry
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• v.20 no.6 s.208
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• pp.31-44
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• 2000

본 연구에서 액체금속로의 노심용융(core meltdown)으로 인한 초 즉발 임계(super-prompt critical)의 출력 폭주 사고시, 노심의 반응도 및 열수력 특성 변화와 에너지 방출량등을 계산하기 위하여, Bethe-Tait 방버론을 수정, 보완한 분석 모델이 개발되었다. 주요 보완 내용으로서는, 금속 연료 노심의 단상 액체 영역에서의 선형의(Linear) threshold 형태의 상태 방정식뿐만 아니라 포화 증기(saturated fuel vapor) 영역에서의 상태 방정식이 개발되었고, 이에 따른 노심 붕괴 반응도(disassembly reactivity)의 분석 모델이 개발되었다. 또한 도플러 반응도 효과를 고려하기 위한 분석모델도 아울러 개발되었다. 상기 보완 모델을 실행할 수 있는 수치 해석 프로그램이 개발되었고, 이를 활용하여 KALIMER에서 HCDA가 발생하였을 경우 노심에서의 에너지 방출량 계산이 수행되었다. 분석결과 도플러 효과와 포화 증기 영역에서의 압력 증가 및 노심팽창의 중요성이 확인되었다. 도플러 효과가 고려되지 않을 경우 HCDA는 분석된 모든 반응도 삽입률에 대하여 폭발적인 에너지 방출과 함께 사고가 종결되는 것으로 평가되었다. 그러나 도플러 상수가 최적 평가치인 -0.002인 경우 50$/s이하의 반응도 삽입률에서는 노심은 비등점(0.8KJ/g)에 도달치 않았으며, 설계 기준 사고인 100$/s의 경우에도 노심은 포화 증기 영역에 머물고 압력이 급격히 증가하는 단상(single phase)액체 영역의 threshold 값에 미치지 않기 때문에 사고는 핵연료 증기(vapor)의 점진적인 분산과 함께 종결되는 것으로 분석되며, 총 에너지 발생량은 약 1,800MJ로서 기계적 손상 에너지로 전환되는 분율을 고려할 때 KALIMER 원자로 용기의 구조 설계 기준치에 비해 상당한 여유도를 갖는 것으로 평가되었다.

• Journal of Korean Society of Forest Science
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• v.110 no.4
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• pp.543-553
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• 2021

This research focused on the investigation of isoprene and terpene emissions from 30 major urban tree species. We conducted sampling using a specific dynamic enclosure system between August and September 2020. Seedlings less than three years old were enclosed in a chamber consisting of a 400 L transparent Tedlar bag. The air-flows from the chamber's outlet were sampled using Tenax-filled sorbent tubes in the presence of standard conditions (temperature: 30℃, PAR: 1,000 μmol/m²/sec). A thermal desorption GC/MS system was used to analyze 38 BVOC compounds (isoprene, monoterpene, sesquiterpene, oxygenated monoterpene, and sesquiterpene). Isoprene emitters included Phyllostachys bambusoides, Quercus serrata, Daphniphyllum macropodum, and Buxus Koreana. Monoterpene emitters included Pinus rigida, Acer pictum subsp. mono, Larix kaempfer, Magnolia denudata, Metasequoia glyptostroboides, Pinus koraiensis, Pinus densiflora, and Abies holophylla. The monoterpene emission profiles were dominated by α-pinene, myrcene, limonene, β-pinen, and sabinene, while caryophyllene and farnesene were the prominent sesquiterpenes. Predominant oxygenated monoterpene compounds were also discovered as pulegone, borneol, menthol, eucalyptol, and nerol, while caryophyllene oxide were the prominent oxygenated sesquiterpenes. Sesquiterpenes and oxygenated sesquiterpenes had relatively lower contributions for all species.

• Polymer(Korea)
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• v.29 no.6
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• pp.593-598
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• 2005

This work studied the loading capabilities and release behaviors of poly(ethylene-alt-maleic anhydride) (PEMAh)/poly(4-vinyl pyridine) (P4VP) multilayer films formed by the layer-by-layer(LbL) sequential self-assembly method, using Rodamine 6G(R6G) as an indicator. Thickness of the multilayer, and loading and subsequent release behavior of R6G from the multilayer were studied using UV-visible spectroscopy. The amount of R6G loaded in multilayer film increased linearly with increasing film thickness. pH-Sensitive permeability was observed, where lower pH environments increased both release rate and release amount. By additional assembling of PEMAh/poly(ethyleneimine) (PEI) capping layers on top of (PEMAh/P4VP)n multilayers, the release of R6G was better controlled.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2010.10a
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• pp.362-365
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• 2010

본 연구에서는 소나무와 굴참나무의 생엽을 대상으로 기후변화에 따른 연소특성을 분석하고자 월별 기온 및 습도 등과 같은 기상조건별 연소특성을 비교하는 연구를 수행하였다. 소나무의 경우, 연중 내내 생엽의 채취가 가능하지만 굴참나무의 경우에는 생엽 채취가 가능한 6월부터 10월까지를 실험 대상으로 선정하였다. 기상조건은 각 시료별 생엽을 채취한 일자의 기상청 발표 자료를 적용하였으며, 연소특성분석은 콘칼로리미터, 연기밀도시험기, 발화점시험기 등과 같은 장비들을 활용하였다. 분석결과로는 열방출량을 비롯하여, 연기방출량, 함수율, 발화점 등을 측정하여 비교하였다.

• 한국해양학회지
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• v.7 no.1
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• pp.19-23
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• 1972

Based on the data collected during January of 1963, 1964 and 1965, heat transfer from the sea to the air over the south-western part of the Japan Sea was evaluated by the formula of Jacobs. The mean sensible heat transfer and the rate of evaporation in the mild winter of 1964 were 360ly day$\^$-1/ and 8.1mm day$\^$-1/, respectively. However, these values increased as much as 690ly day$\^$-1/ and 14.4mm day$\^$-1/ in the severe winter of 1963. The heat hudget of the Japan Sea in January were related to the magnitude of cold water mass formed in August in the Korea Strait.