• Title/Summary/Keyword: 액상률

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Rheological Behaviors of Concentrated Silica Particle Suspensionsprepared by Sol-Gel Method (솔젤법으로 제조된 고농도 실리카 입자 분산계의 유변학적 거동)

  • 양승만
    • The Korean Journal of Rheology
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    • v.10 no.1
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    • pp.24-30
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    • 1998
  • 솔젤법을 이용하여 단분산의 실리카 입자를 제조하고 농도변화에 따른 실리카 분산 액의 유변학적 거동을 해석하였다. 단분산 실리카 입자의 제조는 솔젤법을 이용한 액상반으 으로 제조하였고 입자의 안정화를 위하여 입자표면에 실란커플링제를 코팅하여 유기용매에 서 안정성을 갖도록 하였다. 분산액의 농도에 따른 유변학적 거동을 조사하기 위하여 부피 분율( )이 0.05인 희박 분산계로부터 =0.55의 고농도 분산계를 제조하였다. 솔젤법을 통하 여 단분산 실리카 입자를 성공적으로 제조하였으며 실란커플링제인 ${\gamma}$-methacryloxypropyl triethoxysilane로 입자의 표면을 화학적 방법으로 처리하여 유기용매 상에서 알킬기의 작용 에 의한 hard-sphere'특성을 나타내도록 하였으며 동시에 분산안정성을 유지할수 있었다. 입자 분산계는 =0.25이하의 부피농도에서는 분산용매와 같은 뉴톤거동을 보여주었으며 이 이이상의 농도에서는 비뉴톤거동인 전단담화(shear thinning)현상과 high shear limiting viscosity를 나타내었다. 이결과는 Krieger-Dougherty 식을 따름이 확인되었으며 부피분율 =0.50정도까지도 이식이 잘적용됨을 확인하였다. 부피분율 =0.50 이상의 고농도 입자 분산계 는 급격한 점도의 증가와 함께 전단담화와 전단탁화(shear thickening)현상이 모두 관찰되었 다. 특히 전단탁화를 일으키는 특헝전단변형률(cr)이하의 전단변형률에서는 안정되고 빠른 점성반응(viscous response)을 보여주었으나 특성 전단변형률 부근과 이상의 전단변형률 영 역에서는 매우 불안한 거동이 보여짐을 확인하였다. 그러나 이러한 점도 거동은 가역적이며 전단변형률을 증가시킬때와 감소시킬 때의 유변학적 거동이 거의 일치하였다.

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Evaluation of the Seismic Stability of Fill Dam by Shaking Table Tests (진동대 시험을 통한 Fill Dam의 내진 안정성 평가)

  • Yoon, Won-Sub;Chae, Young-Su;Park, Myeon-Gu
    • Journal of the Korean Geosynthetics Society
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    • v.10 no.4
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    • pp.81-92
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    • 2011
  • In order to understand evaluation of the seismic stability of a fill dam, we made chambers of 1:100, 1:70, and 1:50 (the ratio of the miniature), considering the law of similarity based on drawings of three representative cross sections. And we measured an increase in acceleration, excess pore water pressure, and vertical/horizontal displacement after applying Hachinohe wave (long period), Ofunato wave (short period), and artificial wave, complying with the domestic standards, in order to evaluate the stability and interaction between the ground, the structure, and fluids based on the measurements. As a result, we could observe that displacement of the target cross section was relatively small compared to the allowed level of 30 cm, ensuring proper stability for an earthquake. Regarding the acceleration measurements, the increase rate was 20% for Hachinohe wave and Ofunato wave but 30% for the artificial wave. With respect to the excess pore water pressure, it was lower than 1 (which is the permissible ratio for liquefaction) ensuring proper stability as well.

Removal Characteristics of Mixed Heavy Metals from Aqueous Solution by Recycled Aggregate as Construction Waste (건설폐기물인 순환골재를 이용한 수용액상에서의 혼합 중금속 제거 특성)

  • Shin, Woo-Seok;Kim, Young-Kee
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.16 no.2
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    • pp.115-120
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    • 2013
  • This study examined the removal rate of mixed heavy metals from aqueous solution using recycled aggregate. The recycled aggregate is favorable for the absorbent because it contains about 95% (CaO, $SiO_2$, $Al_2O_3$ and $Fe_2O_3$), which are major ingredient of adsorbent for heavy metal. The kinetic data presented that the slow course of adsorption follows the Pseudo first and second order models. The equilibrium data were well fitted by the Langmuir model and showed the affinity order: $Cu^{2+}$ > $Pb^{2+}$ > $$Zn^{2+}{\simeq_-}Ni^{2+}$$ > $Cd^{2+}$. The results also showed that adsorption rate slightly increased with increasing pH from 6 to 10. Moreover, this trend is similar to results obtained as function of loading amount of recycled aggregate. Meanwhile, an unit adsorption rate was slightly decreased. From these results, it was concluded that the absorbents can be successfully used the removal of the heavy metals from the aqueous solutions.

Study on the Microstructure and Mechanical Properties of High Volume Fraction TiB2-Al1050 Metal Matrix Composites (고체적률 TiB2-Al1050 금속복합재료의 미세조직 및 기계적 특성 연구)

  • Ko, Seongmin;Park, Hyeonjae;Lee, Yeong-Hwan;Shin, Sangmin;Lee, Donghyun;Jo, Ilguk;Lee, Sang-Bok;Lee, Sang-Kwan;Cho, Seungchan
    • Composites Research
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    • v.32 no.1
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    • pp.1-5
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    • 2019
  • In this study, Al1050 composites reinforced with uniformly dispersed, high volume fraction $TiB_2$ particles were fabricated by liquid pressing process and analyzed to microstructure, mechanical properties. Hardness, ultimate tensile strength and compressive yield strength of the 56 vol.% $TiB_2$-Al1050 composite increased to 10, 4.5 and 9.8 times, respectively, compared with those of the Al1050 due to dispersion hardening effect of uniformly dispersed $TiB_2$ in the Al matrix.

Detailed Investigation on the Dynamic Excess Pore Water Pressure through Liquefaction Tests using Various Dynamic Loadings (다양한 진동하중의 액상화 시험을 통한 동적 과잉간극수압에 대한 상세분석)

  • Choi, Jae-Soon;Jang, Seo-Yong;Kim, Soo-Il
    • Journal of the Earthquake Engineering Society of Korea
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    • v.11 no.2 s.54
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    • pp.81-94
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    • 2007
  • In most experimental researches on the liquefaction phenomenon, an earthquake as a random vibration has been regraded as a sinusoidal wave or a triangular wave with an equivalent amplitude. Together with the development in the part of signal control and data acquisition, dynamic experimental equipments in the soil dynamics have also developed rapidly and further more, several real earthquakes have been simulated in the large model test such as shaking table tests and centrifuge tests. In Korea, several elementary laboratory tests to simulate the real earthquake load were performed. From these test results, it was reported that the sinusoidal wave cannot reliably reflect the soil dynamic behavior under the real earthquake motion. In this study, 4 types of dynamic motions such as the sinusoidal wave, the triangular wave, the incremental triangular wave and several real earthquake motions which were classified with shock-type and vibration-type were loaded to find something new to explain the change of the excess pore water pressure under the real earthquake load. Through the detailed investigation and comparison on all test results, it is found that the dynamic flow is generated by the soil plastic deformation and the velocity head of dynamic flow is changed the pressure head in the un-drained condition. It can be concluded that the change of the excess pore water pressure is related to the pressure head of dynamic flow. Lastly, a new hypothesis to explain such a liquefaction initiation phenomenon under the real earthquake load is also proposed and verified.

A Study on Improvement of Liquid Aluminum sulfate Manufacturing Process Using Automation Measurement System (자동화 계측 시스템 설계를 통한 액상황산알루미늄 제조 공정의 개선에 관한 연구)

  • Ryu, Jeong Tak
    • Journal of Korea Society of Industrial Information Systems
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    • v.22 no.5
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    • pp.31-37
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    • 2017
  • In this Paper, we have Improved the Manufacturing Process of Liquid Aluminum Sulfate using the Design of Automated Measurement Systems. The Manufacturing Process of Liquid Aluminum Sulfate uses a Large Weight. The Quality of a Product Depends Highly on the Proportion of the Raw Material Input in the Production Process. Therefore, it is Very Important to Accurately Measure the Amount of Raw Material. For Automation Design, Load Cell Sensor which can Measure Large Weight Accurately and PLC Technology which is most used in Automation Process are Applied. The Content of Aluminum Oxide in the Aluminum Sulfate Produced before the Automation Design Varies from 8.023% to 8.250%. However, after Automation Design, the Amount of Change from 8.09% to 8.19% was Greatly Reduced. As a Result, we could Reduce the Quality Defect rate Due to Weighing Errors and Reduce Safety Accidents by Applying Automation System.

Enhancement in the physical properties of inorganic pigment layer in the color block by incorporation of n liquid additive (액상첨가제에 의한 칼라로도 블록 무기 안료층의 특성 향상)

  • Lee, D.M.;Park, D.W.;Lee, J.H.;Kim, S.M.;Kim, D.Y.;Kim, J.J.;Kim, J.K.;Cho, H.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.16 no.5
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    • pp.222-226
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    • 2006
  • Effects of a carboxylated styrene-butadiene-based liquid additive on the microstructure, mechanical strength and decolorization resistance of inorganic pigment layer in the color block have been examined. More dense inorganic pigment layer characterized by lower apparent porosity, lower water absorption and uniform pigment distribution has been achieved by incorporation of a liquid additive. Also significant enhancements in the mechanical strength and decolorization resistance have been observed.

An experimental study on preparation of precipitated calcium carbonate using Ca component dissolution characteristics and liquid carbonation by the Industrial byproducts (산업부산물의 Ca 성분 용출 특성 및 액상탄산화 반응을 이용한 침강성 탄산칼슘 제조에 관한 실험적 연구)

  • Lim, Yun-Hui;Lee, Ju-Yeol;Shin, Jae-Ran;Choi, Chang-Sik;Hong, Bum-Ui;Kang, Ho Jong;Park, Byung Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.1
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    • pp.116-126
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    • 2015
  • The present study utilized a shuttle mechanism of wet chemical absorption using MEA. In addition, industrial by-products containing a large amount of inorganic alkali substances were utilized for wet carbonization process. Chemical pretreatment of industrial by-products extracted calcium ions. ICP result of calcium ion was obtained up to 17,900 ppm(17.9%) by acidic substance. And also, In this work, 94% of recovery rate was obtained using wet MEA absorption process from $CO_2$ flow at the ambient condition. Through the liquid carbonation process, a sludge was fixed with rate of 0.175 mg of $CO_2$ per mg of sludge. It was found from XRD results that the structure of final product was composed of a calcite structure which is general structure of $CaCO_3$.

Fabrication of Organic-Inorganic Nanocomposite Blade for Dicing Semiconductor Wafer (반도체 웨이퍼 다이싱용 나노 복합재료 블레이드의 제작)

  • Jang, Kyung-Soon;Kim, Tae-Woo;Min, Kyung-Yeol;Lee, Jeong-Ick;Lee, Kee-Sung
    • Composites Research
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    • v.20 no.5
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    • pp.49-55
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    • 2007
  • Nanocomposite blade for dicing semiconductor wafer is investigated for micro/nano-device and micro/nano-fabrication. While metal blade has been used for dicing of silicon wafer, polymer composite blades are used for machining of quartz wafer in semiconductor and cellular phone industry in these days. Organic-inorganic material selection is important to provide the blade with machinability, electrical conductivity, strength, ductility and wear resistance. Maintaining constant thickness with micro-dimension during shaping is one of the important technologies fer machining micro/nano fabrication. In this study the fabrication of blade by wet processing of mixing conducting nano ceramic powder, abrasive powder phenol resin and polyimide has been investigated using an experimental approach in which the thickness differential as the primary design criterion. The effect of drying conduction and post pressure are investigated. As a result wet processing techniques reveal that reliable results are achievable with improved dimension tolerance.

인산가용화균 PeniciLLium sp. PS-113의 액상비료 제제화

  • Tae, Eon-Hui;Lee, Tae-Geun;Gang, Seon-Cheol
    • 한국생물공학회:학술대회논문집
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    • 2001.11a
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    • pp.398-399
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    • 2001
  • A fungus. Penicillium sp. PS-113. with high phosphate-solubilizing activities was isolated from soil and tested the viability in POA medium supplemented with various concentrations of Trio in order to develop a dispersing agent for liquid formulation. Moreover, the number of Penicillium sp. PS-113 conidia, stored at $4^{\circ}C$ and $25^{\circ}C$ with Trio(0.1%) and various concentrations of additives($Cu^{++}$ $Mo^{++}$, bio-ceramic, Tween 80, PEG 200. diatomite. SDS), was counted on PDA at the intervals of 2 weeks. As a result, the liquid formulation containing 0.1 %( v/v) Trio was remarkably improved in dispersing ability and the viability of the conidia, and each of the supplements (0,01% $Mo^{++}$, 0.5% bio-ceramic. 1.0% Tween 80, 1.0% PEG 200) was similar to the 0.1% Trio.

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