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http://dx.doi.org/10.7846/JKOSMEE.2013.16.2.115

Removal Characteristics of Mixed Heavy Metals from Aqueous Solution by Recycled Aggregate as Construction Waste  

Shin, Woo-Seok (Institute of Marine Science and Technology Research, Hankyong National University)
Kim, Young-Kee (Institute of Marine Science and Technology Research, Hankyong National University)
Publication Information
Journal of the Korean Society for Marine Environment & Energy / v.16, no.2, 2013 , pp. 115-120 More about this Journal
Abstract
This study examined the removal rate of mixed heavy metals from aqueous solution using recycled aggregate. The recycled aggregate is favorable for the absorbent because it contains about 95% (CaO, $SiO_2$, $Al_2O_3$ and $Fe_2O_3$), which are major ingredient of adsorbent for heavy metal. The kinetic data presented that the slow course of adsorption follows the Pseudo first and second order models. The equilibrium data were well fitted by the Langmuir model and showed the affinity order: $Cu^{2+}$ > $Pb^{2+}$ > $$Zn^{2+}{\simeq_-}Ni^{2+}$$ > $Cd^{2+}$. The results also showed that adsorption rate slightly increased with increasing pH from 6 to 10. Moreover, this trend is similar to results obtained as function of loading amount of recycled aggregate. Meanwhile, an unit adsorption rate was slightly decreased. From these results, it was concluded that the absorbents can be successfully used the removal of the heavy metals from the aqueous solutions.
Keywords
Recycled Aggregate; Mixed Heavy Metal; Adsroption; Capping Material; Marine Sediment;
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Times Cited By KSCI : 3  (Citation Analysis)
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1 USEPA, 2005, Contaminated sediment remediation guidance for hazardous waste sites.
2 Kim, K.I., Choi, J.S., Im, H.G., 2006, "Reforming resource circulation policy for sustainable material management, Korea Environment Institute.
3 Ryou, J.S., Song, I.H., 2011, "An experimental study on field application of self-compacting concrete using recycled fine aggregate", Journal of the Korea institute for structural maintenance inspection, Vol. 10, 55-60.   과학기술학회마을   DOI   ScienceOn
4 Kim, E.H., Kim, J.K., Sung, N.C., 1997, "A study on removal of heavy metals and pH increasing effects in plating wastewater using oyster shells", Korea Society of Waste Management, Vol. 34, 414-419.
5 Kim, J.B., Oh, J.I., Park, C.S., 2002, "AMD (Acid Mine Drainage) neutralization using recycled-concrete aggregates", J. KSEE, Vol. 24, 21-30.   과학기술학회마을
6 Lee, H.S., Oh, Y.S., Lee, W.C., 2004, "A basic study on the recovery of Ni, Cu, Fe, Zn ions from wastewater with the spent catalyst", J. Kor. Inst. Res. Recycling, Vol. 13, 3-8.   과학기술학회마을
7 Ahmaruzzaman, M., 2011, "Industrial wastes as low-cost potential adsorbents for the treatment of wastewater laden with heavy metals", Adv. Colloid Interface Sci., Vol. 166, 36-59.
8 American Water Works Association, 1999, "water quality & treatment hand book", McGraw-Hill.
9 Allahverdi, A., Kani, E.N., 2009, "Construction wastes as raw materials for Geopolymer binders", International J. Civil Engin., Vol. 7, 154-160.
10 Chen, G.Z., Fray, D.J., 2001, "Cathodic refining in molten salts: Removal of oxygen, sulfur and selenium from static and flowing molten copper", J. Appl. Electrochem., Vol. 31, 155-164.   DOI   ScienceOn
11 Clayden, N.J., Esposito, S., Aronne, A., Pernice, P., 1991, "Solid state 27Al NMR and FTIR study of lanthanum aluminosilicate glasses", J. Non-Cryst. Solids, Vol. 11, 258-268.
12 Gray, C.W., Dunhan, S.J., Dennis, P.G., Zhao, F.J., McGrath, S.P., 2006, "Field evaluation of in situ remediation of a heavy metal contaminated soil using lime and red mud", Environ. Pollut., Vol. 142, 530-539.   DOI   ScienceOn
13 Ho, Y.S., McKay, G., 1999a, "Thesorption of lead(II) ions on peat", Water Res., Vol. 33, 578-584.   DOI   ScienceOn
14 Ho, Y.S., McKay, G., 1999b, "Pseudo-second order model for sorption processes", Proc. Biochem., Vol. 34, 451-465.   DOI   ScienceOn
15 Ortego, J.D., Barroeta, Y., 1991, "Leaching effects on silicate polymerization, A FTIR and 29Si NMR study of lead and zinc in Portland cement", Environ. Sci. Technol., Vol. 25, 1171-1174.   DOI
16 Hui, K.S., Chao, C.Y.H., Kot, S.C., 2005, "removal of mixed heavy metal ions in wastewater by zeolite 4A and residual products from recycled coal fly ash", J. Hazard. Mater., Vol. B127, 89-101.
17 Liu, Y., Naidu, R., Ming, H., 2011, "Red mud as an amendment for pollutants in solid and liquid phases", Geoderma., Vol. 163, 1-12.   DOI   ScienceOn
18 Mollah, M.Y.A., Lu, F., Cocke, D.L., 1998, "An X-ray diffraction (XRD) and fourier transform infrared spectroscopic (FT-IR) characterization of the speciation of arsenic (V) in Portland cement type-V", Sci. total Environ., Vol. 57, 224-231.
19 Palmer S.J., Nothling, M., Bakon, K., Frost, R., 2010, "Thermally activated seawater neutralised red mud used for the removal of arsenate, vanadate and molybdate from aqueous solution", J. colloid Interface Sci., Vol. 342, 147-154.   DOI   ScienceOn
20 Quy, T. N., Bruce, A. M., 2001, "Lead adsorption and precipitation reactions on soil minerals", Symposia papers presented before the division of Environmental Chemistry American Chemical Society, Vol. 41, 609-613.
21 Smiljani , S., smiciklas, I., Peri -Gruji , A., Lon ar, B., Mitric, M., 2010, "Rinsed and thermally treated red mud sorbents for aqueous $Ni^{2+}$ ions", chem. Eng. J., Vol. 162, 75-83.   DOI   ScienceOn
22 Srivastava, P., Singh, B., Angove, M., 2005, "Competitiveadsorption behavior of heavy metals on kaolinite", J. ColloidInterface Sci., Vol. 290, 28-38.   DOI   ScienceOn
23 Weng, C.H., Huang, C.P., 1994, "Treatment of metal industrial waste water by fly ash and cement fixation", J. Environ. Eng., Vol. 120, 1470-1487.   DOI   ScienceOn
24 Hyodo, M., Kuwabara, T., Sato, S., Nonaka, T., 2008, "Recycling of fine demolished concrete as functional overlying sand", Trans. The Japanese Society of Irrigation, Drainage and Rural Engineering (JSIDRE), Vol. 257, 19-25.
25 Yu, P., Kirkpatrick, R.J., Poe, B., McMillan, P.F., Cong, X., 1999, "Structure of calcium silicate hydrate (C-S-H): near-, mid-, and far-infrared spectroscopy", J. Am. Ceram. Soc., Vol. 82, 742- 750.