• Title/Summary/Keyword: 안티몬

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Polycrystalline silicon doping using antimony thin film as doping source (안티몬 박막을 도우핑소스로 찬 다결정실리콘 도우핑)

  • 이인찬;마대영;김상현;김영진;김기완
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1993.11a
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    • pp.55-59
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    • 1993
  • In this study, we developed new process for doping poly-Si film. Sb(antimony) thin film was used as doping source. Sb was evaporated on poly-Si film deposited by LPCVD fallowed by annealing. We investigate sheet resistance variation with annealing temperature and time. Finally we adapted this process to poly-Si TFT fabrication.

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Studies on the Releasing Effect of Cerium in Calcium Analysis by Atomic Absorption Spectrometry (원자흡수 분광법에 의한 칼슘분석에서 세륨의 해방효과에 관한 연구)

  • Kee Chae Park;Hee Seon Choi;Soo Han Kwon
    • Journal of the Korean Chemical Society
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    • v.29 no.2
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    • pp.129-136
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    • 1985
  • In the atomic absorption spectrometry using an air-acetylene flame, the interferences of Zr, Sn, Al, Sb, $SO_4^{2-},\;VO_3^-,\;and\;SiO_3^{2-}$, on the calcium absorption and the repression of this interference by the addition of cerium have been studied. The interference by Zr, Sn, Al, Sb, $SO_4^{2-},\;VO_3^-,\;and\;SiO_3^{2-}$ existed as the same concentration as calciurn ($3.0 {\times} 10^{-4}$M) in the sample solution are completely released by the addition of cerium twice as much as interfering cation. The interferences by the mixed interfering cations (Zr, Sn, Al and Sb) and by the mixed interfering anions ($SO_4^{2-},\;VO_3^-,\;and\;SiO_3^{2-}$) are larger than by each interfering cation and anion, and the releasing effect by cerium ($1.5 {\times} 10^{-2}$M) is effective up to some degree of the concentration of mixed interfering cations and of mixed interfering anions. The releasing effect by cerium to the mixed solution of interfering cations and anions is applicable to quite wide range of concentration.

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AFM Studies on the Surface Morphology of Sb-doped $SnO_2$ Thin Films Deposited by PECVD (AFM을 이용한 PECVD에 의해 증착된 Sb-doped $SnO_2$ 박막의 표면형상에 관한 연구)

  • Yun, Seok-Yeong;Kim, Geun-Su;Lee, Won-Jae;Kim, Gwang-Ho
    • Korean Journal of Materials Research
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    • v.10 no.8
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    • pp.525-531
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    • 2000
  • Sb-doped tin oxide films were deposited on Cornig glass 1737 substrate by plasma enhanced chemical vapor deposition (PECVD) technique. The films deposited at different reaction parameters were then examined by using XRD and AFM. The relatively good crystalline thin film was formed at $450^{\circ}C$, input gas ratio R[$P_{SbCl}P_{{SnCl}_4}$]=1.12 and r.f. power 30W. The surface roughness of the film formed by PECVD compared to TCVD was more smooth. Higher concentration of Sb dopant, lower deposition temperature, and thinner thickness of deposited film led to de-creasing surface roughness of the formed thin films.

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Content of plasticizers and heavy metals in the selling PVC wallpapers (시판 PVC 벽지 중 가소제 및 중금속 함량)

  • Lee, Cheol-Won;Jung, Tak-Kyo;Kim, Man-Goo
    • Analytical Science and Technology
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    • v.21 no.2
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    • pp.135-142
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    • 2008
  • Plasticizer and heavy metals in domestic PVC wallpaper manufactured in Korea after 2005 were analyzed to identify the contained quantity in comparison with the 2002 manufactured PVC wallpapers. Plasticizer of wallpapers was analyzed by the method KSM1991 which uses soxhlet extraction with n-hexane and GC/FID. Heavy metals were pre-treated with 0.07 mol/L hydrochloric acid (HCl) and analyzed by ICP/OES according to the EN 71-part 3 method. DEHP, DINP, DEP, acetyl tributyl citrate were identified from wallpaper. Contents of DEHP, DINP were 0.2~11.3%, 17.9~27.8% respectively in 6 wallpapers, DEP and acetyl tributyl citrate were 1.5%, 8.9% respectively in one wallpaper. Plasticizers have changed from DEHP that has possibility of hazards to DINP, DEP and acetyl tributyl citrate as compared with 2002. Heavy metals were detected under guide line from all of the wallpapers except fire-retardant wallpaper contain antimony. While PVC wallpaper was improved by use of various plasticizer, functional wallpapers such as fire-resistant wallpaper contain high antimony in this study.

A Study on Migration of Heavy Metals from Kitchen Utensils Including Glassware, Ceramics, Enamel, Earthenware and Plastics (유리제 등 조리기구 중 중금속 이행에 관한 연구)

  • Choi, Jae-Chon;Park, Se-Jong;Goh, Hyeah;Lee, Ju Yeun;Eom, Mi Ok;Kim, Meehye
    • Journal of Food Hygiene and Safety
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    • v.29 no.4
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    • pp.334-339
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    • 2014
  • The purpose of our study was to investigate the migration level of lead (Pb), cadmium (Cd), antimony (Sb), arsenic (As), hexavalent chromium ($Cr^{6+}$) and mercury (Hg) from cookwares into food simulants and to evaluate the safety of each heavy metals. The test articles for heavy metals were glassware, ceramics, enamel, earthenware, polypropylene and polyethylene cookwares for Pb and Cd, enamel for Sb, earthenware for As, polyethylene and polypropylene cookwares for $Cr^{6+}$ and Hg. All the article samples of 391 intended for contact with foods were purchased in domestic markets. Pb, Cd, Sb and As were analyzed by Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES), $Cr^{6+}$ by UV visible spectrophotometer and Hg by mercury analyzer. The migration levels of heavy metals in all the samples were within the migration limits of Ministry of Food and Drug Safety (MFDS). As a result of safety evaluation, our results showed that the estimated daily intakes (EDI, mg/kg bw/day) were $9.12{\times}10^{-6}$ and $8.83{\times}10^{-7}$ for Pb and Cd from ceramics and $1.19{\times}10^{-5}$, $1.23{\times}10^{-5}$ and $7.52{\times}10^{-6}$ for Pb, Cd and Sb from enamel. Tolerable daily intakes (TDI, mg/kg bw/day) were established respectively as 0.0036, 0.00081, 0.0021, and 0.0006 for Pb, Cd, As and Hg by JECFA (Joint FAO/WHO Expert Committee on Food Additives), as 0.0060 for Sb by WHO (World Health Organization). When comparing with TDIs, the EDIs accounted for 0.25% and 0.11% for Pb and Cd from ceramics and 0.33%, 1.52% and 0.13% for Pb, Cd and Sb from enamel.

A Study on Sb2O3 Beam Tuning and Monitoring in Antimony Implantation - (안티몬 이온주입시 Sb2O3 빔튜닝 방법 및 모니터링 연구)

  • 김상용;최민호;김남훈;정헌상;장의구
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.5
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    • pp.476-480
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    • 2004
  • The characteristics of antimony implants are relatively well-known. Antimony has lower diffusion coefficient, shorter implantation range, and smaller scattering as compared with conventional dopants such as phosphorous and arsenic. It has been commonly used in the doping of buried layer in Bi-CMOS process. In this paper, characteristics and appropriate condition of monitoring in antimony implant beam tuning using Sb$_2$O$_3$were investigated to get a reliable process. TW(Thema Wave) and R$_{s}$(Sheet Resistance) test were carried out to set up condition of monitoring for stable operation through the periodic inspection of instruction condition. The monitoring was progressed at the point that the slant of R$_{s}$ varied significantly to Investigate the variation of instruction accurately.

Effects of Antimony and Lead in Galvanizing Bath on Spangle Formation in Galvanized Steel Sheet Coatings (용융아연도금강판의 스팡글 형성에 미치는 도금욕 중 안티몬 및 납의 영향)

  • 김상헌;김형민;정원섭;전선호
    • Journal of the Korean institute of surface engineering
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    • v.33 no.5
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    • pp.387-397
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    • 2000
  • Antimony in the galvanizing bath had greater effect on the growth of grains in the solidification of molten coating layer and on the decrease of its surface roughness than lead. Particularly 0.01 wt % antimony in the galvanizing bath showed much stronger effect than expected considering its low surface tension value. These effects were seemingly originated from the development of preferred orientation of (0002) plane parallel to steel surface. Antimony was found to be widely distributed in form of orderly arrangement throughout the coating layer unlike lead from the results of surface analyses on coating layers as received and on those as etched in chromating solution. In addition, supercooling in the 0.07 % antimony and the 0.2 % lead galvanizing bath was also measured to be in the range of$ 2~4^{\circ}C$ and $9~11^{\circ}C$ respectively, and it indicates that antimony forms fine dendrite expanded rapidly on the steel surface.

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Fabrication and Properties of pn Diodes with Antimony-doped n-type Si Thin Film Structures on p-type Si (100) Substrates (p형 Si(100) 기판 상에 안티몬 도핑된 n형 Si박막 구조를 갖는 pn 다이오드 제작 및 특성)

  • Kim, Kwang-Ho
    • Journal of the Semiconductor & Display Technology
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    • v.16 no.2
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    • pp.39-43
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    • 2017
  • It was confirmed that the silicon thin films fabricated on the p-Si (100) substrates by using DIPAS (DiIsoPropylAminoSilane) and TDMA-Sb (Tris-DiMethylAminoAntimony) sources by RPCVD method were amorphous and n-type silicon. The fabricated amorphous n-type silicon films had electron carrier concentrations and electron mobilities ranged from $6.83{\times}10^{18}cm^{-3}$ to $1.27{\times}10^{19}cm^{-3}$ and from 62 to $89cm^2/V{\cdot}s$, respectively. The ideality factor of the pn junction diode fabricated on the p-Si (100) substrate was about 1.19 and the efficiency of the fabricated pn solar cell was 10.87%.

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Ethanol Electro-Oxidation and Stability of Pt Supported on Sb-Doped Tin Oxide (안티몬 도핑된 주석 산화물에 담지된 백금 촉매의 에탄올 산화 반응 및 안정성 연구)

  • Lee, Kug-Seung;Park, Hee-Young;Jeon, Tae-Yeol;Sung, Yung-Eun
    • Journal of the Korean Electrochemical Society
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    • v.11 no.3
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    • pp.141-146
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    • 2008
  • Electrocatalytic activities and stabilities of Pt supported on Sb-doped $SnO_2$ (ATO) were examined for ethanol oxidation reactions. Pt colloidal particles were deposited on ATO nanoparticles (Pt/ATO) and the prepared electrocatalysts were characterized by X-ray diffraction, transmission electron microscopy (TEM), and cyclic voltammetry. Electrochemical activity of the Pt/ATO for ethanol electro-oxidation was compared to those of Pt supported on carbon (Pt/C) and commercial PtRu/C. The activitiy of the Pt/ATO was much higher than those of the Pt/C and commercial PtRu/C. The Pt/ATO exhibited much higher electrochemical stabilities than the Pt/C in 0.5M ${H_2}{SO_4}$ and in 0.5M ${H_2}{SO_4}$/1M ${C_2}{H_5}OH$. According to TEM, the growth rate of Pt particles was lower in the Pt/ATO than it was in the Pt/C. The ATO nanoparticle appears to be a promising support material that promotes electrochemical reactions and stabilizes catalyst particles in direct ethanol fuel cell.

Reduced Effect of kV-CBCT Dose by Use of Shielding Materials in Radiation Therapy (방사선 치료 시 차폐물질 사용에 따른 kV-CBCT 선량감소 효과)

  • Jo, Hyeonjong;Park, Euntae;Kim, Junghoon
    • Journal of the Korean Society of Radiology
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    • v.12 no.4
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    • pp.467-474
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    • 2018
  • CBCT is useful for improving the accuracy of the treatment site, but Repeated use increases the exposure dose. In this study, we aimed to provide basic data for dose reduction in CBCT implementation by dataization the simulating and dose reduction effect using shielding substance. Material in this study, Analyzation the photon beam by simulate the CBCT Through MCNPX and then calculate the absorption dose of body organ at shooting moment of thoracic abdominal position as target UF-Revise simulated body. At this time. Dose reduction effects at this time were evaluated according to the texture of materials and presence of shielding materials( lead, antimony, barium, sulfate, tungsten, bismuth). When CBCT was taken without shielding, the dose was calculated to be high in the breast and spine, and the dose in the esophagus and lung was calculated to be low. The doses according to the shield material were calculated as barium sulfate, antimony, bismuth, lead, and tungsten. The shielding rate was the highest in the thymus (73.6%) and the breast (59.9%) compared with the dose reduction according to presence or absence of the shield. However, it showed the lowest shielding rate in lung (2.1%) and spine (12.6%).