• Title/Summary/Keyword: 아교

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Analysis of animal glue by pyrolysis/GC/MS (열분해/GC/MS에 의한 아교의 분석)

  • Park, Jongseo
    • Analytical Science and Technology
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    • v.28 no.3
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    • pp.221-227
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    • 2015
  • Animal glue is a traditional material that was used widely as an adhesive in cultural artifacts, such as Buddhist paintings, dancheong (traditional multicolored paintwork on wooden buildings), mother-of-pearl inlay, and so on. Spectroscopic methods, such as infrared spectroscopy, have been used for the analysis of animal glue. However, such methods do not yield sufficient information about the constituents of the glue. Because pyrolysis/GC/MS analysis is able to estimate the components of a material through the examination of its pyrolyzed products, it is useful for the analysis of polymeric material. In this study, pyrolysis/GC/MS analysis was used to determine the chemical composition of animal glue. The appropriate conditions for analyzing animal glue were established by examining pyrolysis temperature, quantity of the sample, and the repeatability of the method. Some products of pyrolysis were identified. We also analyzed commercial gelatin and animal glue using the established method and found almost no differences in chromatograms among the samples. The results will be used as supporting data to confirm the use of animal glue in cultural artifacts and to replace traditional animal glue by commercial gelatin.

Low-Intensity Pulsed Ultrasound Promotes Healing with Increases Collagen Deposition and Collagen mRNA Expression in Skin Wound of Rat (저강도 맥동초음파에의한 피부 상처 치유 촉진과 아교질 축적 및 아교질 mRNA 발현 증가)

  • Lee, Jae-Hyoung;Jeka, Seung-Joo;Kwon, Pil-Seung
    • Journal of the Korean Society of Physical Medicine
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    • v.8 no.3
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    • pp.449-456
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    • 2013
  • 목적: 본 연구는 저강도 맥동 초음파적용이 흰쥐의 전층 상처 치유와 아교질 축적 및 아교질 mRNA발현에 미치는 영향을 규명할 목적으로 시행하였다. 방법: 12마리의 Sprague-Dawley계 흰쥐를 저강도 맥동 초음파군(n=6)과 대조군(n=6)에 무작위 배정하고 등에 $19.63mm^2$ 크기의 전층 적출 상처를 만든 다음 저강도 맥동 초음파군은 3 MHz, 순환주기 20%, SATA 강도 $0.4W/cm^2$로 1일 1회, 1회 5분씩 초음파를 적용하고, 대조군은 가짜 초음파를 적용하였다. 7일간 처치 후 초음파군과 대조군의 아교질 축적, 아교질 mRNA 발현, 상처치유율, 절반치유시간을 비교하였다. 결과: 초음파군의 아교질 축적(p<05)과 아교질 mRNA 발현(p<.01)이 대조군보다 유의하게 증가하였고, 상처치유율(p<.05)과 절반치유시간(p<.0)도 초음파군의 대조군보다 유의하게 빨랐다. 결론: 본 연구에서 전층 상처에 저강도 맥동 초음파를 적용한 결과 상처 치유가 촉진되었고 육아조직에 아교질 축적이 증가하였다. 이러한 결과는 맥동 초음파의 기계적 자극이 제 1형 아교질 mRNA 전사활동을 촉진시키는 것으로 사료된다.

Effect of Glue and Alum Mixing Ratio on the Color Variation of Traditional Sizing Hanji (아교포수 방법이 전통한지의 색상 변화에 미치는 영향)

  • Lee, Yu-Ju;Choi, Tae-Ho
    • Journal of Conservation Science
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    • v.35 no.2
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    • pp.153-158
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    • 2019
  • The traditional sizing treatment for the Hanji is performed to give the following functions. Those are to stabilize the paint of the painting, to prevent the paint of painting and moisture from smearing into the painting itself, to prevent the paint of the painting and moisture from passing to the lining paper, and to make the colors of painting match the surrounding.This study analyzed a result of the effect of Hanji sizing characteristic according to glue and alum mixing ratio and applying times, affects to pigments of painting and fastness of Hanji using accelerated aging test. As a result of color measurement of sizing treated Hanji, the concentration of glue and the number of application increased, the brightness and the $L^*$ value decreased but the yellowness index increased.

A Study on Characteristics of Animal Glue depending on Pretreatment and Evaluation Condition (아교 전처리 및 평가 조건에 따른 특성연구)

  • Oh, Seong Min;Yu, Ji A;Lee, Na Ra;Kim, Tae Heon;Kim, Seong Eun;Chung, Yong Jae
    • Journal of Conservation Science
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    • v.35 no.6
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    • pp.701-708
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    • 2019
  • Animal glue is a natural adhesive made from processed skins or bones of animals. It is widely used in wooden crafts, papercrafts, dancheong painting, and pictures. Accurate evaluation of the quality of animal glues during production and use is difficult because there is no formal method for testing the glue's properties during pretreatment and measurement conditions. Thus, in this study, a series of tests were carried out by changing the conditions of swelling, temperature, and concentration of animal glue and gelatin sold on the market. Twelve types of animal glues were evaluated, having a viscosity range of 12.67 cP to 29.43 cP. The results showed that the physical characteristics of the glues were stable when allowed to swell for six h in distilled water(23℃). When 10%(by weight in distilled water) of the animal glue was measured in the reflective mode of a spectrophotometer, the optical characteristics of the glues were stable. Powdered animal glues have a medium brightness and middle-high chroma. Relative to powdered glues, stick animal glues have a low brightness and a medium chroma. Based on the results of this study, it is expected that the data can be assembled into a form so that animal glue workers can use it as a reference for the preparation of evaluation standards for testing the characteristics of animal glues.

A Study on Transparency and Characteristics of Natural Adhesives Made of Urushiol and Glue (우루시올과 아교를 배합한 천연 접착제의 투명성 및 접착 특성 연구)

  • Kim, Eun Kyung;Ahn, Sun Ah;Jang, Sungyoon
    • Journal of Conservation Science
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    • v.31 no.2
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    • pp.115-123
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    • 2015
  • This study aims to increase the transparency of the natural adhesives made with lacquer and glue. For the purpose, samples were prepared by mixing urushiol with glue in varied proportion and the characteristics and adhesive properties were investigated. By adding glue on urushiol, IR spectra of the natural adhesives became similar to that of glue as the N-H band related with protein of glue increased, while that of methylene C-H bond related to urushiol decreased. Samples were dried within a day and maintained a bright color without blackening by oxidation during the curing process. The natural adhesives with urushiol and glue showed various range of viscosity and tensile shear strength as Cemedine C or Epoxy resin according to mixing ratio. In addition, the sample of mixing ratio of 6:4 showed bright and transparency in appearance and tensile shear strength similar to that of Araldite AY103-1/HY956 for earthenware layer.

The Effects of Emotional Intelligence on Happiness among Early Ehildhood Teachers: The Mediating Effects of Job Stress and Teaching Efficacy (영유아교사의 정서지능이 행복감에 미치는 영향: 직무스트레스 및 교사효능감의 매개효과)

  • Lee, Eun Suk;Lee, Kyung Nim
    • Korean Journal of Childcare and Education
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    • v.11 no.2
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    • pp.221-238
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    • 2015
  • This study examined the effects of emotional intelligence, teaching efficacy and job stress on happiness among early childhood teachers. Data were collected from 246 early childhood teachers. To collect the data, emotional intelligence, teaching efficacy, job stress, and happiness instruments were used. All research variables were measured using self-reported questionnaires, and were analyzed with one-way ANOVA, t-test, Pearson's correlation and pathway analysis. The results indicated teachers' happiness had no difference by demographic variables. Emotional intelligence had a direct effect and an indirect effect through teaching efficacy and job stress on happiness among early childhood teachers. Teaching efficacy and job stress had a direct effect on happiness among early childhood teachers. Additionally, emotional intelligence was the most important variable predicting early childhood teachers' happiness. Teaching efficacy and job stress had a mediating effect between emotional intelligence and happiness.

A Study on demands of education training about copyright for infant and early childhood education institutions (영유아교육기관을 위한 저작권 교육 연수 요구조사)

  • Oh, Eun-Sun;Lee, So-Hyun
    • Journal of Digital Contents Society
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    • v.17 no.5
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    • pp.349-357
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    • 2016
  • The purpose of this study is to analyze demands of education training about copyright for Infant and early childhood education institutions. This study investigated demands of education training about copyright for infant and early childhood education institutions targeting 248 directors and teachers. Using a questionnaire, research data was analyzed using the program spss. Demands of education training about copyright for infant and early childhood education institutions appeared differently depending on education institution type, position, education career, etc. copyright training topics include the highest demands for understanding of the copyright associated with the work of the early childhood education. Training contents had higher demands for using typeface(font) and video material. So these results reported that directors and teachers require copyright education relating to the work of Early childhood education. The results of this study suggest the implications for developing and implementing copyright training programs for Infant and Early childhood education institutions.

An Analysis of Research Trends on Early Childhood Teacher's Emotional Experience - Focusing on Domestic Journals - (영유아교사의 정서경험에 관한 연구 동향 분석: 국내학회지를 중심으로)

  • Kim, Soo Jung
    • Korean Journal of Child Education & Care
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    • v.18 no.3
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    • pp.51-64
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    • 2018
  • Objective: By doing a more comprehensive review of recent domestic studies related to the emotions experienced by the early childhood teachers, the current study aims to suggests the direction of various emotional research experiences; and provide the basic data necessary for the development and application of a program that helps early childhood teachers experience more positive emotions in the child care setting and effectively addresses the negative emotional experience. Methods: 87 previous studies which were published in the journals related to various emotional experiences experienced by the early childhood teacher since 2008 were analyzed. Results: It was found that the emotion - related articles of early childhood teachers showed that, compared with before 2012, it increased after 2013. Also, the tendency of the data collection method was mostly composed of the papers using the questionnaire method using the test and the scale. As the most studied topic related to the emotional experience of early childhood teachers, the negative emotional experiences were the exhaustion experienced by the teachers. And the most studied topics on positive emotional experiences were the happiness experienced by early childhood teachers; The research that explores the variables related to the happiness experienced by the early childhood teachers was the majority. Conclusion/Implications: The analysis of this study suggests a systematic understanding of emotions experienced by early childhood teachers and suggests future directions for supporting healthy emotional experiences.

The Effect of Glue Solution on Manufacturing of White Clay Pigment (백토안료의 전통제법 중 아교수 영향에 관한 연구)

  • Kang, Yeong Seok;Jeong, Hye Young;Go, In Hee
    • Journal of Conservation Science
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    • v.32 no.3
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    • pp.417-423
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    • 2016
  • The effect of the glue solution were investigated in the grinding and elutriation process for manufacturing of White clay pigment. In grinding process, glue solution decreased the production of a too fine powder and enhanced the degree of sorting of ground pigments. The grinding performance and limit are generally influenced by the frictional force. Therefore, the friction force was measured in accordance with the grinding conditions. As a result of measuring a friction force, when using glue solution it showed the lowest friction. Finally, the application of glue solution in grinding process is believed to enhance the degree of sorting of ground pigments by reducing frictional force. In elutriation process, the application of glue solution enabled the screening of larger particles in the same conditions by reducing the sedimentation velocity. This result is due to increase in the viscosity of the glue solution according to glue concentration. As a result, the application of glue solution in elutriation process is though to enlarges the range of the selectable particle size and to enable the segmentation of the particles.

Confirming Animal Glue in Dancheong Sample by Pyrolysis/GC/MS (열분해/GC/MS에 의한 재현 단청 시편에서 아교의 확인)

  • Park, Jong Seo;Kim, Mi Jeong;Kim, Soon Kwan
    • Journal of Conservation Science
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    • v.32 no.1
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    • pp.21-32
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    • 2016
  • Animal glue is a traditional material used extensively as adhesive and binder in mother-of-pearl, wooden structure, traditional painting, etc. Analysis of animal glue is usually performed with IR(infrared spectroscopy) based on the IR absorption of functional group. But, it has a limitation in confirming animal glue when a sample consists of several materials because of overlapping of the absorption band. Py/GC/MS(pyrolysis/gas chromatography/mass spectrometry) is a useful tool in analyzing the constituent of polymeric materials like animal glue by identifying their pyrolysate with very small amount of sample. In this study, confirmation of animal glue in a Dancheong sample was tried with this method. Characteristic pyrolytic compounds of animal glue and tung oil used in Dancheong were identified. Dancheong sample painted with Noerok as a coloring material, animal glue and tung oil was prepared and it was possible to find characteristic peaks of animal glue after thermal degradation and artificial weathering experiment. From this, we found that animal glue can be detected using py/GC/MS in cultural heritage samples consisting of several materials and in different condition. IR was also tried to analyze Dancheong sample and the results were compared with those of py/GC/MS for the detection of animal glue.