• Title/Summary/Keyword: 실리케이트

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Evaluation of Adhesion Performance of High-Fireproofing Alumino-silicate Inorganic Mortar (알루미노 실리케이트계 고내화성 모르타르의 부착성능 평가)

  • Cho, Hyeon-Seo;Lee, Gun-Cheol
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.6
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    • pp.569-576
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    • 2018
  • In modern society, a huge number of the buildings have been constructed with RC structure. RC structures have many structural instabilities due to earthquake, typhoon, construction fault, design phase errors. Therefore, many reinforcement methods are being implemented to solve this problem. In the reinforcement method, the organic epoxy adhesive used in the FRP reinforcing method is abruptly damaged when exposed to high temperature, which is directly connected to the fall of the reinforcing material. Therefore, the present study was conducted to develop inorganic refractory mortar with a certain level of adhesion ability to reduce the heat transferred to FRP reinforcement when exposed to high temperatures. As a result of the test, it showed high adhesion strength at room temperature condition with the inclusion of EVA resin, and showed no performance deterioration up to about $300^{\circ}C$ even under heating conditions. Also, it was confirmed that the backside temperature was lower as the thickness increased, and converged to a constant temperature of about $780^{\circ}C$ after 2 hours of heating.

Separation of Ni(II), Co(II), Mn(II), and Si(IV) from Synthetic Sulfate and Chloride Solutions by Ion Exchange (황산과 염산 합성용액에서 이온교환에 의한 니켈(II), 코발트(II), 망간(II) 및 실리케이트(IV)의 분리)

  • Nguyen, Thi Thu Huong;Wen, Jiangxian;Lee, Man Seung
    • Resources Recycling
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    • v.31 no.3
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    • pp.73-80
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    • 2022
  • Reduction smelting of spent lithium-ion batteries at high temperature produces metallic alloys. Following solvent extraction of the leaching solutions of these metallic alloys with either sulfuric or hydrochloric acid, the raffinate is found to contain Ni(II), Co(II), Mn(II), and Si(IV). In this study, two cationic exchange resins (Diphonix and P204) were employed to investigate the loading behavior of these ions from synthetic sulfate and chloride solutions. Experimental results showed that Ni(II), Co(II), and Mn(II) could be selectively loaded onto the Diphonix resin from a sulfate solution of pH 3.0. With a chloride solution of pH 6.0, Mn(II) was selectively loaded onto the P204 resin, leaving Ni(II) and Si(IV) in the effluent. Elution experiments with H2SO4 and/or HCl resulted in the complete recovery of metal ions from the loaded resin.

A prospective clinical of lithium disilicate pressed zirconia and monolithic zirconia in posterior implant-supported prostheses: A 24-month follow-up (리튬 디실리케이트-지르코니아 이중도재관과 단일구조 지르코니아로 제작된 구치부 고정성 임플란트 지지 보철물의 전향적 임상연구: 24개월 추적관찰)

  • Roh, Kyoung-Woo;Jeon, Young-Chan;Jeong, Chang-Mo;Yun, Mi-Jung;Huh, Jung-Bo;Lee, So-Hyoun;Yang, Dong-Seok;Bae, Eun-Bin
    • The Journal of Korean Academy of Prosthodontics
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    • v.57 no.2
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    • pp.134-141
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    • 2019
  • Purpose: The purpose of this study was to compare the clinical outcomes of lithium disilicate ceramic pressed zirconia prostheses and monolithic zirconia prostheses and to investigate the complications after two years of follow-up in posterior edentulous site. Materials and methods: A total 17 patients (male: 12, female: 5) were treated with 60 posterior fixed implant-supported prostheses (LP. lithium disilicate ceramic pressed zirconia prostheses: n = 30, MZ. monolithic zirconia prostheses: n = 30). After 24-month, clinical examination of Implant survival rate, marginal bone resorption, probing depth, plaque index, bleeding index, calculus and complications were evaluated. Results: There were no failed implants and all implants were normal in function without mobility. Marginal bone resorption was lower in LP group than MZ group at 12-month (P < .05), and 12-month probing depth and calculus deposit in LP group were significantly higher than MZ group (P < .05). Most common complications in MZ were marginal bone resorptions more than 1.5.mm and 2 chipping occurred in LP group. Conclusion: Within the limitations of the present study, lithium disilicate ceramic pressed zirconia is considered as a predictable treatment option as much as monolithic zirconia in posterior fixed implant-supported prostheses.

Structural Changes of Nylon 6/Clay Nanocomposite Film on Drawing Condition (Nylon 6/Clay 나노복합재 필름의 연신조건에 따른 구조적 변화)

  • 강영아;김경효;이양헌;조현혹
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.352-353
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    • 2003
  • Clay 분산 유/무기 나노복합재 제조기술은 실리케이트 층상구조의 점토광물을 나노 스케일의 시트상의 기본 단위로 박리(exfoliation)하여 고분자수지에 분산시킴으로써 범용 고분자의 낮은 기계적 물성의 한계를 엔지니어링 플라스틱 수준으로까지 올리고자 하는 것으로서, 기존의 무기 충진재 및 강화재의 입자크기(〉1 $\mu\textrm{m}$)를 나노 스케일까지 분산시켜 기존 무기물 충진 복합재의 단점을 한층 보완하는 것을 목표로 하고 있어 성능 및 원가 면에서 매우 유리한 방법으로 21세기의 복합재료 생산시장의 판도에 상당한 변화를 가져오게 할 수 있는 핵심기술이라 할 수 있다. (중략)

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중금속이 칼슘설포알루미네이트의 클링커 반응 및 에트링자이트 생성에 미치는 영향

  • 유광석;안지환;천성민;김환
    • Cement Symposium
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    • no.32
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    • pp.103-106
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    • 2005
  • 유해 중금속을 다량 함유하고 있는 산업폐기물의 고화 처리에 사용되는 칼슘설포알루미네이트(4CaO$\cdot$$3Al_2O_3$$\cdot$$SO_4$이후부터 CSA로 기입) 의 제조를 위해 철강부산물인 압연 슬러지를 활용하여 그 특성에 대해 조사하였다. 본 연구에서는 철강 부산물인 압연슬러지 외에 석회석 미분물, 인산부산 석고를 혼합하여 칼슘알루미네이트상을 합성하였다. 합성 결과 소성온도 1250$^{\circ}C$에서부터 CSA가 합성되었고, 이와 함께 칼슘실리케이트 (2CaO$\cdot$$SiO_2$)와 칼슘알루미노페라이트(4CaO$\cdot$$Al_2O_3$$\cdot$$Fe_2O_3$)도 함께 합성되었다. CSA 합성에 미치는 중금속 영향을 관찰한 결과 원료의 중금속이 CSA 합성 온도를 낮추는 효과가 있는 것으로 나타났다. CSA를 이용한 철강산업 폐기물의 중금속 고용 처리 연구에서도 본 실험에서 합성된 CSA가 폐기물의 중금속 고화 처리에 효과가 있는 것으로 나타났다.

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Development and Application of Activated Silicate for Chemical Grouting (지반주입용 활성 실리케이트 약액 (ASG) 의 개발 및 적용)

  • 천병식;류동성;조산연
    • Proceedings of the Korean Geotechical Society Conference
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    • 1999.10a
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    • pp.131-136
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    • 1999
  • In this study, novel activated silicate grout solution for injection grouting was prepared by the reaction of ordinary waterglass with alkaline earth metal salts mixture by means of the high-speed stirring method with strong shearing force, and its chemical and physical properties were investigated. The variation of its gelation time plotted with the amount of dilution water showed that this novel silicate had better gelation characteristics in comparison with ordinary waterglass. And some other engineering characteristics of this grout such as durability and mechanical properties were investigated experimentally. The whole experimental results established that this novel silicate grout was a good alternative with an existing ordinary waterglass grouting method.

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Low temperature solution growth of silicon on foreign substrates (이종기판을 사용한 저온에서의 실리콘 박막 용액 성장법)

  • Soo Hong Lee;Martin A. Green
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.4 no.1
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    • pp.42-45
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    • 1994
  • Deposition of silicon on pretreated sapphire and glass substrates has been investigated by the solution growth method at low temperatures. An average 14 $\mu\textrm{m}$ thickness of silicon was grown over a large area on sapphire substrate originally coated with a much thinner silicon layer [0.5 $\mu\textrm{m}$ (100) Si/(1102) sapphire)] at low temperatures from $380~460^{\cire}C$. Successful results were obtained from surface treated glass substrates in the temperatures range from $420~520^{\circ}C$.

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Synthesis and Characteristics of Organo-Layered Silicate as an Filler of Polymeric Nanocomposites from $delta-Na_2Si_2O_5$ ($delta-Na_2Si_2O_5$ 로부터 고분자 나노복합 소재용 유기 층상 실리케이트 합성 및 특성)

  • 김윤섭;고형신
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.226-226
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    • 2003
  • 일반적으로, 고분자 매트릭스에 층상 점토광물이 분산되어 얻어지는 복합재료는 세가지 형태를 이룬다. 첫째 통상의 복합재료는 고분자 매트릭스 내에 점토입자가 고루게 분산된 상태를 말하며, 둘째 점토 층 사이에 고분자 모노머나 올리고머가 일부분 삽입된 삽입형 복합재료(intercalated composite)이며, 셋째 점토 층 사이에 삽입된 모노머나 올리고머의 경화 또는 중합반응을 통해 점토내의 한층 한층 균일하게 매트릭스 내에 분산된 박리형 나노복합소재(exfoliated nanocomposite) 이다. 이들 복합재료들 중 박리형 나노복합소재는 적은 양의 점토가 단위 층으로 고분자 매트릭스에 완전히 분산되어 다양한 물성의 향상이 기대되는 재료이다. 따라서 최근 고분자의 기계적 강도, 팽윤 저항성 그리고 차폐특성 둥 전반적인 물성을 향상시키는 방법으로 층상 점토광물의 층 사이에 다양한 유기물을 삽입하여 층간거리를 확장시킨 유기 점토광물을 제조하고 이를 고분자 소재에 첨가하여 박리형 나노복합소재를 제조하는 방법이 많은 연구가 수행되고 있다.

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Development of Deterioration Restraining Agent Using Polycondensed Silicate and Monomers (실리케이트와 모노머합성을 통한 콘크리트 열화억제제 개발)

  • Kim, Do-Gyeum;Cho, Myeng-Suk;Song, Young-Chul;Kwak, Ju-Ho;Ryu, Gum-Sung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.563-566
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    • 2005
  • Concrete structures have been damaged by salt, carbonization, freezing and thawing and the others. Therefore, it is needed to protect durability and performance according to the appropriate materials and methods in the concrete structures. In general, several types of polymer and silicate are used as protecting deterioration agents of concrete structures, but these agents have many problems because of low durability and properties. In this study, It developed the deterioration restraining agent using polycondensed silicate and monomer that can block a deterioration cause such as $CO_2$ gas, salt and water from the outside and enhance waterproofing ability by reinforcing the concrete surface when applying it to concrete structures. Also, it developed the systems for improving concrete performance using a deterioration restraining agent.

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Development of the Preventing Aging Technology Using Silicate Type Penetration Reinforcing Agent (실리케이트계열의 표면침투보강재를 이용한 열화방지기술개발)

  • Kim, Do-Gyeum;Cho, Myeng-Suk;Song, Young-Chul;Ryu, Gum-Sung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.313-316
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    • 2006
  • The most serious cause of deterioration in the concrete structures is reinforcing corrosion due to the chloride attack and carbonation. Therefore, it is needed to protect durability and performance according to the appropriate materials and methods in the concrete structures. In general, several types of polymer and silicate are used as protecting deterioration agents of concrete structures, but these agents have many problems because of low durability and properties. The object of this study is to develop a preventing aging technology. The work involves the development of silicate type penetration reinforcing agent.

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