• Composites Research
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• v.33 no.3
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• pp.125-132
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• 2020

The polymerization shrinkage behavior of dimethacrylate-based composite (Clearfil AP-X, Kuraray) and silorane-based composite (Filtek P90, 3M ESPE) used for dental composite restorations was measured using digital image correlation method. The stress distribution on the surface of specimen was calculated by finite element analysis with equivalent elastic modulus and was compared with the measured shrinkage distribution. Camera images were monitored by a CCD camera during and after the irradiation of light. As a result of the DIC analysis, a non-uniform shrinkage distribution was observed in both composite resins, and the resin core inside the ring specimen had free flowability, leading to in greater shrinkage strain than the resin/ring interfacial region. It was observed that as the distance from the center of the resin increased, the radial average shrinkage strain decreased. The radial average shrinkage strain during light irradiation occurred to be 33% for P90 and 57% for AP-X of the entire strain at the end of the test. The shrinkage behavior of P90 and AP-X was measured to be significantly different from each other during light irradiation. In the resin near the resin/ring interface, it was confirmed that the tensile strain rapidly formed to increase after light irradiation, causing a tensile stressed, interface weak.

• Journal of the Korean Society of Hazard Mitigation
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• v.7 no.3
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• pp.19-31
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• 2007

Humidity and strain were estimated for understanding the relation between humidity change by self-desiccation and shrinkage in high-performance concrete with low water binder ratio and containing fly ash and blast furnace slag. Internal humidity change and shrinkage strain were about 10%, 10%, 7%, 11%, 11% and $320{\times}10^{-6}$, $270{\times}10^{-6}$, $231{\times}10^{-6}$, $371{\times}10^{-6}$, $350{\times}10^{-6}$ respectively on OPC30, O30F10, O30F20, O30G40, O30G50 and from the results, fly ash made humidity change and strain decrease but slag increase comparing with ordinary portland cement. Considering only relation internal humidity and shrinkage by self-desiccation, humidity change and shrinkage represented the strong linear relation regardless of mineral admixture. For specifying the relation on internal humidity change and autogenous shrinkage strain, shrinkage model was established which is driven by capillary pressure in pore water and surface energy in hydrates on the assumption of a single network and extended meniscus in pore system of concrete. This model and experimental results had a similar tendency so it would be concluded that the internal humidity change by self-desiccation in HPC originated in small pores less than 20nm, therefore controlling plan on autogenous shrinkage might be focused on surface tension of water and degree of saturation in small pore.

• Journal of Korean Society of Steel Construction
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• v.16 no.1 s.68
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• pp.135-144
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• 2004

Since Modern bridges have a tendency to make the spans continuous and longer, the effect of concrete shrinkage and creep is very important and must be evaluated appropriately for the durability and safety of steel-concrete composite bridges. However, highway design specification in current use prescribes $180^{1\;2}$ as the final shrinkage strain. which is for less value than one resulted from many experimental researches and cause some problems in the construction of composite bridges due to the understimation of shrinkage strain. Thus, in this paper nonlinear analysis with time-steps applying the CEB-FIP(90) provision have been conducted for plate girder bridge, box girder bridge and Preflex beam bridge and the linear equivalent shrinkage strain for the design of composite bridges. which produces the stress equal to the values from the nonlinear analysis, has been calculated by comparing the results with the values following highway design specification. The results yield appropriately double values than $180^{1\;2}$ which highway design specification prescribes.

• Composites Research
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• v.27 no.3
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• pp.90-95
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• 2014

Cure shrinkage during cure process of polymer matrix composites develope residual stress that cause some structural deformation, such as spring-in, spring-out and warpage. The carbon/epoxy prepreg used in this study is Hexply M21EV/34%/UD268NFS/IMA-12K supplied by Hexcel corp. Cure shrinkage and degree of cure measured by TMA(thermomechanical analyzer) and DSC(differential scanning calorimetry). Cure shrinkages are measured by TMA within a temperature range of $140{\sim}240^{\circ}C$ in a nitrogen atmosphere, and degree of cure determined by the heat of reaction using dynamic and isothermal DSC runs in argon atmosphere. As a result, the cure shrinkage is increased dramatically in a degree of cure range between 27~80%. the higher the cure temperature, the lower the degree of cure occurring to begin cure shrinkage.

• Proceedings of the Korean Fiber Society Conference
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• 1998.10a
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• pp.83-86
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• 1998

PVC사의 연신은 Fig. 1과 같이 끊는 물 속에서 이루어지며 연신 후 정전기 방지를 위해 유제를 습식 방법으로 처리한다. 따라서 건조와 heat set chamber에 들어가기 전 어느 정도의 수분과 유제를 함유한 체 각각의 chamber를 통과하며 건조, heat set된다. 본 연구의 목표는 연신 후 squeezing roller의 접압에 따른 건조시간의 관계와 heat set온도, 시간에 따른 열 수축률의 관계를 알아보고자 한다. (중략)

• Proceedings of the KAIS Fall Conference
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• 2003.06a
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• pp.359-361
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• 2003

본 연구에서는 무선부품의 일종인 cavity filter 금형을 제작하였고, 도금용 ARS 수지와 PC/ARS Alloy 수지를 사용하여 일반사출성형과 금형온도가 높은 MmSH방식, 두 타입으로 성형품을 제작하였다. 성형품의 수축률 변화는 MmSH 방식일 때 ABS 수지로 제작한 성형품의 단위캐비티 격막부분에서 수축률이 감소되었다. 중량변화는 ABS와 PC/ABS Alloy로 제작된 성형품 모두 MmSH 방식일 때 증가하였고. 성형품의 표면 거칠기도 모두 MmSH 방식일 때 거칠기가 감소되었다.

• Resources Recycling
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• v.25 no.6
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• pp.73-81
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• 2016

Geopolymers produced from aluminosilicate materials such as metakaolin and coal ash react with alkali activators and show higher fire resistance than portland cement, due to amorphous inorganic polymer. The percentage of thermal shrinkage of geopolymers ranges from less than 0.5 % to about 3 % until $600^{\circ}C$, and reaches about 5 ~ 7 % before melting. In this study, geopolymers paste having Si/Al = 1.5 and being mixed with carbon nanofibers, silicon carbide, pyrex glass, and vermiculite, and ISO sand were studied in order to understand the compressive strength and the effects of thermal shrinkage of geopolymers. The compressive strength of geopolymers mixed by carbon nanofibers, silicon carbide, pyrex glass, or vermiculite was similar in the range from 35 to 40 MPa. The average compressive strength of a geopolymers mixed with 30 wt.% of ISO sand was lowest of 28 MPa. Thermal shrinkage of geopolymers mixed with ISO sand decreased to about 25 % of paste. This is because the aggregate particles expanded on firing and to compensate the shrinkage of paste. The densification of the geopolymer matrix and the increase of porosity by sintering at $900^{\circ}C$ were observed regardless of fillers.

• The Journal of Korean Academy of Prosthodontics
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• v.52 no.3
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• pp.195-201
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• 2014

Purpose: This study was designed to compare the amount of polymerization shrinkage of dual-cure resin cements according to different polymerization modes and to determine the effect of light activation on the degree of polymerization. Materials and methods: Four kinds of dual-cure resin cements were investigated: Smartcem 2, Panavia F 2.0, Clearfil SA Luting and Zirconite. Each material was tested in three different polymerization modes: self-polymerization only, immediate light polymerization and 5 minutes-delayed light polymerization. The time-dependent polymerization shrinkage-strain was evaluated for 30 minutes by Bonded-disk method at $37^{\circ}C$. Five recordings of each material with three different modes were taken. Data were analyzed using one-way ANOVA and multiple comparison Scheffe′test (${\alpha}$=.05). Results: All materials, except Panavia F 2.0, exhibited the highest polymerization shrinkage-strain through delayed light-activated polymerization. No significant difference between light activation modes was found with Panavia F 2.0. All materials exhibited more than 90% of polymerization rate in the immediate or delayed light activated group within 10 minutes. Conclusion: As a clinical implication of this study, the application of delayed light activation mode to dual-cure resin cements is advantageous in terms of degree of polymerization.

• Journal of Korean Society of Forest Science
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• v.108 no.3
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• pp.341-348
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• 2019

In order to reduce the safety risk of forestry operations, this research was conducted to examine the suitability of chainsaw protective pants after repeated laundering, testing four different products that are currently used in hand-held chainsaw operations. Laundering was repeated 10, 20, 30, 40, and 50 times. After washing, we measured the shrinkage ratio of 17 measurement positions mostly affecting the safety of forest operations and suggested the expected safety life cycle of chainsaw protective clothes. The results showed that most of the products have only one measurement position where the standard shrinkage ratio (<6%) was exceeded after 20 washings, and that the lateral direction of measurement positions shrank more than the vertical one. The numbers of repeated launderings and measurement positions were found to be significant factors influencing the shrinkage ratio (p<0.05). In the shrinkage rates for 17 measurement positions, there were significant correlations between five of the measurement positions (a, b, g, j, and n) and the number of repeated launderings (p<0.05). Therefore, the results suggest that about 10 months would be suitable for an adequate safety lifetime for chainsaw protective pants. The relationship between the number of repeated launderings and the measurement positions will be further analyzed in detail to examine the durability of chainsaw protective pants.

• Journal of Adhesion and Interface
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• v.11 no.2
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• pp.57-62
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• 2010

Photo-curable material can be crosslinked among molecules by light source such as UV and visible light materials. Material properties are controlled by crosslink reaction. Shrinkage is occured during the curing reaction of material structure. Phenomenon of shrinkage stress occurs inside the product and reduce the stability of the product causes problems. Heat shrink the evaluation of the phenomenon has been formalized. But the evaluation of photo shrink is not enough. In this experiment, real-time contract with shrinkage tester phenomena and analysis degree of shrinkage of the material differences. According to the research, experimental results and theoretical analysis of the results were big differences. Shrinkage, especially for a number of different functional groups that were very different theory. These differences are occurred by the molecular structure different and not enough reaction.