• Title/Summary/Keyword: 수은화합물

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최근의 메탈하라이드램프의 개발

  • 지철근
    • 전기의세계
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    • v.25 no.6
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    • pp.29-30
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    • 1976
  • 종래의 고압수은램프의 결점인 광색 및 연색성을 개선한 것이며 고압수은방전등의 석영발광관내에 각종 금속할로겐화합물을 봉입한 것이 메탈하라이드램프이다. 근래의 연구결과로 발광효율의 대폭적인 향상이 이루어지고 있다. 메탈하라이드램프를 크게 나누면 양광램프, 고효율 하라이드램프, 형광 고효율 하라이드램프 등으로 된다. 메탈하라이드램프는 경질유리외관내에 석영발광관을 봉착시킨 고압방전등으로 종래의 수은램프와 외관상 근사하지만 발광물질로서 금속할로겐화합물이 봉입되어 있으므로 램프설계에 있어서는 여러가지 배료가 이루워저야 한다.

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Localization and Accumulated Concentration Changes of Mercury Compound in Reproductive Organs of Female Mice with Time (암컷 마우스 생식기관 내 수은 화합물의 위치와 시간에 따른 축적된 수은 농도 변화)

  • Kim, Young Eun;Kim, Yu Seon;Cho, Hyun Wook
    • Journal of Life Science
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    • v.28 no.7
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    • pp.811-818
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    • 2018
  • This study was performed to investigate the localization and concentration changes of mercury compound in female reproductive organs with time. Methylmercuric chloride was subcutaneously injected weekly into pubescent female mice for 3 weeks. For the concentration changes of mercury with time, the mice were sacrificed at 10, 150, and 300 days post treatment (DPT). Body and organ weights were not significantly different between the control and mercury-treated groups, except for 10 DPT in body weight. Localization of accumulated mercury was identified by the autometallography method. Localization of mercury compounds in the uterus, ovary, and ovum was analyzed with a light microscope. In the uterus, mercury was densely located in the stroma cells and surface epithelium of the perimetrium at 10 DPT. Mercury concentration was decreased at 150 DPT and did not appear at 300 DPT. In the ovary, mercury particles were distributed in the stroma cells of the cortex region, cells of the theca around the follicle, and the corpus luteum at 10 DPT. Mercury was concentrated in the medulla region at 150 DPT and was not distributed at 300 DPT. In the ovum, mercury particles were mainly located in the marginal region at 10 and 150 DPT. Mercury concentration was decreased and evenly distributed at 300 DPT. These results suggest that hormone synthesis, implantation, and developing embryos will be affected by mercury compound in the female mouse.

Preconcentration and Speciation of Trace Mercury Compounds in Water Sample Using Dithizonates Extraction and Reverse Phase Liquid Chromatography (디티존 착물 추출과 역상 액체 크로마토그래피를 이용한 물시료 중의 미량 수은 화합물의 농축 및 화학종의 분리)

  • Suh, Jung-Ki;Cho, Kyung-Haeng;Lee, Sang-Haak
    • Analytical Science and Technology
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    • v.13 no.1
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    • pp.81-88
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    • 2000
  • A rapid preconcentration method was developed for the speciation of the trace mercury compounds in water sample. The mercury compounds were extracted and preconcentrated simply as their dithizone complexes by passing through the dithizone impregnated ultra-high molecular weight polyethylene (UHMWPE) membrane solvent inlet filter following sanification in methanol solvent. The concentrated dithizonates were separated by liquid chromatography on a $C_{18}$ column. Complete resolution was obtained between methyl-, ethyl-, phenyl-, and inorganic mercury with a mobile phase of 0.05 M acetate buffer (pH=4)/THF/methanol(3:5:2). The separnted mercury chelates were detected by spectrophotometrically at 475 nm. The proposed method was successfully applied to the speciation of mercury compounds in waste water with detection limit at the subnanogram/mL level.

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Decontamination of Mercury Contained in CCFLs (Cold Cathode Fluorescence Light) Disassembled from Waste LCDs (Liquid Crystal Display) (폐 LCD (Liquid Crystal Display) 해체 후 분리된 CCFL (Cold Cathode Fluorescence Light) 내 수은의 건식 제거 공정)

  • Park, Jae Layng;Lee, Sungkyu;Kang, Leeseung;Lee, Chan Gi;Cho, Sung-Su;Hong, Myung Hwan;Hong, Hyun Seon
    • Resources Recycling
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    • v.23 no.2
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    • pp.61-70
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    • 2014
  • LCD televisions and monitors use cold cathode fluorescence lamps (CCFLs) to illuminate the screen. Most CCFLs contain mercury and they have to be carefully handled at the end of their lives as per minimum treatment standards under the Waste Electrical and Electronic Equipment (WEEE) and Restriction of Hazardous Substances (RoHS) directives. CCFLs were carefully separated from mold frames of waste LCD units for primary decontamination of mercury/fluorescent compound mixture using CCFL decontamination system designed and fabricated in the present research. Residual mercury was further removed by employing a pyro-process, where crushed CCFL tubes transferred from primary decontamination process were subject to heat treatment at $550^{\circ}C$ in a box furnace: more than 99% of mercury was removable from waste CCFLs.

Studies on the Contents of Mercury in Korean Soy-bean sprouts and Persimmons in Markets (한국시판식품(韓國市販食品) (콩나물, 감)중(中)의 Hg 함량조사(含量調査) (수은화합물(水銀化合物)에 관(關)한 연구(硏究) 제1보(第1報)))

  • Lee, Eun-Ock
    • Journal of Nutrition and Health
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    • v.2 no.2
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    • pp.87-89
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    • 1969
  • 1. The contents of mercury in Korean soy-bean sprouts and persimmons were determined, 2. The contents of mercury in soy-bean sprouts was 0.088 ppm in mean value. 3. The contents of mercury in mollowed persimmon was 0.104 ppm in mean value.

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Affinity of Mercury to SH Compounds Compared by Using the Paper Chromatography (Paper Chromatogaphy 법(法)에 의한 SH화합물간(化合物間)의 수은(水銀)에 대(對)한 친화력(親和力) 비교(比較))

  • Kim, Young-Hee;Lee, Man-Jeang
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.10 no.1
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    • pp.67-76
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    • 1981
  • By using the paper chromatograph technique affinity of amino acids to the mercury was compared with that of sodium thiosulfate, 2,3-dimercaptopropanol(BAL) and inosinic acid. Among the amino acids of testment three acids (Cysteine, Cystine and Methionine) which posses sulfide or disulfide radical exhibited a spot which combined more apparently with the mercury than other amino acids. However, in the mixed solutions of thiosulfate, BAL or inosinic acid with those amino acid and mercury, the mercury was moved into thiosulfate, BAL or inosinic acid spot. It was clear from the results that affinity of sodiume thiosulfate, BAL and inosinic acid to the mercury is higher than that of amino acids.

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Changes in the Concentration and Localization of Accumulated Mercury in Kidney, Liver, and Spleen of Mice over Time (생쥐 신장, 간, 비장 내 시간에 따른 수은 농도 변화와 수은 화합물의 위치)

  • Kim, Yu Seon;Kim, Young Eun;Cho, Hyun Wook
    • Journal of Life Science
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    • v.29 no.8
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    • pp.879-887
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    • 2019
  • This study investigated the localization and changes in the concentration of injected mercury in the kidney, liver, and spleen of mice. To evaluate changes in the concentration of mercury over time, the mice were euthanized 10, 150, and 300 days post-treatment. Localization of accumulated mercury was identified by the autometallography method. Mercury was densely located in the supranuclear cytoplasm of epithelial cells of proximal tubules of the kidney but was not detected in the glomerulus 10 days post-treatment. In the liver, mercury was mainly found in hepatocytes around the portal vein and in sinusoidal Kupffer cells 10 days post-treatment. Mercury was scattered throughout both white and red pulp of the spleen 10 days post-treatment. In terms of changes in the concentration of mercury, the levels were lower in the renal cortex and medulla 150 and 300 days post-treatment as compared with those 10 days post-treatment. Mercury was found at low concentrations in liver hepatocytes 150 and 300 days post-treatment. The mercury concentration was also low in both the white and red pulp of the spleen 150 and 300 days post-treatment. Therefore, the concentrations of accumulated mercury in the kidney, liver, and spleen 150 and 300 days post-treatment were lower than those 10 days post-treatment. We identified the localization of mercury in cells and tissues of several organs and observed that accumulated mercury in organs decreased naturally over time.

Evaluation of Lead, Copper, Cadmium, and Mercury Species in the Leachate of Steel Making Slag by Seawater (해수에 의한 제강 슬래그의 납, 구리, 카드뮴 및 수은 화합물의 용출특성 평가)

  • Lee, Han-Kook;Lee, Dong-Hoon
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.1
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    • pp.75-84
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    • 2005
  • The aim of this study is to evaluate the leaching characteristics of lead, copper, cadmium, and mercury from steel making slag by seawater. To demonstrate the leaching characteristics of heavy metals from steel making slag by seawater, it was carried to various leaching tests such as regular leaching tests, liquid/sold(LS) leaching test and pH static test. From the leachability of $Pb^{+2},\;Cu^{+2},\;and\;Cd^{+2}$ from steel making slag in pH static test, it is distinguished between distilled water and seawater. With distilled water, it is very low between pH 7-8 and pH 11-12. On the other hands, with the seawater, its leaching is higher than that of distilled water. In particular, concentration of $Hg^{+2}$ leached from slag by seawater is lower than that of distilled water. Meanwhile, we found that the heavy metals from steel making slag would be dissolved and precipitated using geochemcial equilibrium program such as visual minteq. Lead and copper leached from steel making slag with seawater were dissolved nearly in the range of pH 11-12, but in the range of pH 7-10 those were precipitated about 90%. And cadmium leached from steel making slag with seawater were dissolved completely. On pH static test with distilled water, lead leached from steel making slag seemed to be similar to pH static test with seawater. However, copper and cadmium leached from steel making slag were dissolved. In general, the species of lead leached from steel making slag were formed mainly of $PbCl^+,\;PbSO_4$, the species of copper were formed mainly of $CuSO_4,\;CuCO_3$, the species of cadmium were formed mainly of $CdCl^+,\;CdSO_4$ due to being sorbed with the anions($Cl^-,\;CO_3^{-2},\;SO_4^{-2}$) of the seawater. Both pH static test with seawater and distilled water, it is not in the case of the mercury. Most of mercury leached from steel making slag was precipitated(SI=0). Because the decreasing of $Hg^{+2}$ concentrations depends ferociously on the variation of chloride($Cl^-$) existed in the seawater. $Hg^{+2}$ leached from steel making slag could be sorbed strongly with chloride($Cl^-$) compared of carbonate($CO_3^{-2}$) and sulfate($SO_4^{-2}$) in the seawater. On the basis of that result, we found that the species of mercury was formed of calomel($Hg_2Cl_2$) as one of finite solid. Due to forming a calomel($Hg_2Cl_2$) in the seawater, the stability of mercury species by steel making slag should be higher than those of lead, copper, and cadmium species. Regarding the results stated above, we postulated that the steel making slag could be recycled to sea aggregates due to being distinguishing leachability of heavy metals($Pb^{+2},\;Cu^{+2},\;Cd^{+2},\;and\;Hg^{+2}$) between leaching tests by distilled water and seawater.