• Journal of the Korea Organic Resources Recycling Association
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• v.27 no.3
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• pp.27-39
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• 2019

In this study, thermal-alkali pre-treatment (THAP) optimal condition and co-digestion efficiency with THAP of the mixture food waste and sewage sludge were evaluated for improving the performances of co-digestion for mixed food waste and sewage sludge. The optimal condition of THAP was evaluated for solubilization COD, CST(Capillary Suction Time), TTF(Time to Filter), and volatile fatty acids (VFAs) with THAP temperature and NaOH concentration. In addition, the co-digestion of mixed food waste and sewage sludge were evaluated using biochemical methane potential (BMP) test. The optimal THAP reaction temperature and NaOH concentration of food waste and sewage sludge were $140^{\circ}C$ and 60 meq/L to solubilization COD over 20%, CST and TTF under 60sec and VFAs concentration over 12,000 mg-COD/L, respectively. The optimal condition of co-digestion of mixed food waste and sewage sludge equal to THAP condition. Therefore, it was determined that the optimal condition of THAP reaction temperature and NaOH concentration for co-digestion of mixed food waste and sewage sludge were $140^{\circ}C$ and 60 meq/L, respectively.

• Applied Chemistry for Engineering
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• v.30 no.2
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• pp.212-218
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• 2019

To investigate the effect of the oxyfluorination of carbon nanotubes (OF-CNTs) on electroless Ni deposition and electromagnetic interference shielding efficiency (EMI SE), CNTs were treated with a mixture of oxygen and fluorine gases and sequentially deposited with nickel. These samples were then manufactured into thin films on a polyimide film to evaluate their EMI SE. The surface chemical property of OF-CNTs was investigated by X-ray photoelectron spectroscopy. From the results of thermogravimetric and scanning electron microscopic analyses, it was found that both the amount of deposited Ni and the surface morphology changed depending on oxyfluorination. Moreover, the Ni-deposited CNTs pretreated with $O_2:F_2=1:9vol%$ exhibited the maximum EMI SE as approximately 19.4 dB at 1 GHz. These results were attributed to the formation of oxygen and fluorine functional groups on the surface of CNTs due to the oxyfluorination, and the functional groups enabled to deposit a suitable amount of Ni and improve the dispersion in the deposited solution.

• Applied Chemistry for Engineering
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• v.22 no.4
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• pp.405-410
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• 2011

High-performance of an electric double layer capacitance (EDLC) electrode was prepared by the amino-fluorination of activated carbon by using $NF_3$ gas. The pore structure and surface chemistry were investigated based on the specific capacitance of EDLC. The amino-fluorination of activated carbon introduced functional groups of nitrogen and fluorine which are beneficial for the specific capacitance of EDLC without the change of pore structures. The E-NF100AC electrode, which has nitrogen and fluorine functional groups less than 1 at%, showed the highly improved specific capacitance of 528 (${\pm}9$) F/g at 2 mV/s showing 122% improved value when comparing with that of non-functionalized E-RAC electrodes. Whereas, the E-NF200AC electrode, which has nitrogen and fluorine functional groups over 1 at%, showed the decreased specific capacitance because of perfluorinated introduction. So, it is concluded that the proper contents of nitrogen and fluorine groups improved the specific capacitance of EDLC.

• KSBB Journal
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• v.18 no.2
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• pp.111-116
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• 2003

Hydrogen producing acidogenic microorganisms were self-immobilized using organic-inorganic hybrid polymer within 5 minutes. During the continuous tratment of synthetic wastewater at a hydraulic retention time of 20 hours, at 37$^{\circ}C$, pH 5.0, the self-immobillized granules were maintained in a stirred tank reactor. The black colored granules gradually became milky. Image analysis showed that the mean diameter of the milky colored granules ranged from 1.5 to 20. mm. The maximum bio-gas procuction rate was 380 ml/L/hy and the concentration of H$_2$was around 50%, while no methane was detected. Granular ECP was extracted and its content was measured to elucidate the role of the organic-inorganic hybrid polymer. Further increases of granule concentration are expected to increase the hydrogen production rate.

• Fire Science and Engineering
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• v.27 no.5
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• pp.44-56
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• 2013

This research is to identify how much toxic combustion gases are produced from Korea standardized real fire test (Class A&B) by using Room Corner Tester (RCT) and how much those gases are possibly dangerous to testing personnel by estimating the level of carboxyhemoglobin (% COHb). It is confirmed that testing personnel can be affected as more than 40% COHb from Class A 9th and 10th rating in respiration minute volume (RMV) 2 and from Class A 5th to Class A 10th rating in RMV 3 during the time for initial three minutes. Also, in the case of Class B real fire tests, although it is considered rather safe for the initial 1 minute, testing personnel can be affected as more than 20% COHb from Class B 16th to 20th rating in RMV 3 during total test time. Currently, the Korea standard is only focusing on the protection measures against the heat, but the it is neglecting the protection measures against toxic combustion gases. Therefore, according to this study, it is strongly recommended that testing personnel should wear a self-contained breathing apparatus, or the equivalence depending on the real fire test rating.

• Journal of Hydrogen and New Energy
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• v.33 no.6
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• pp.636-642
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• 2022

The "Hydrogen Economic Activation Road map" was announced in 2019, and hydrogen demand is expected to exceed 470,000 tons per year in 2022 and keep increasing. Under this circumstance, it has become important to understand the greenhouse gas (GHG) emissions associated with various hydrogen production pathways. In this study, the evaluation of life cycle GHG emissions regarding the hydrogen produced as by-product from coke oven gas (COG) in steel mill is conducted. To cover the possible range of operations, three literatures were reviewed and their data of inputs and outputs for the process were adopted for calculation. Life cycle inventories and emission factors were mostly referred to GaBi and Intergovernmental Panel on Climate Change (IPCC) guidelines, respectively. When there are multiple products from a single process, the energy allocation method was applied. Based on these sources and the assumptions, the life cycle emission values of COG-based hydrogen were found to be 3.8 to 4.7 kg/CO₂-eq./kg-H₂.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.1
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• pp.25-33
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• 2018

Renewable energy has been of interests in the area of modern alternative fuels. Biogas is produced in waste landfill sites through anaerobic digestion processes, including hydrolysis, acidogenesis, organic acid fermentation (acetogenesis), and methane fermentation (methanogenesis). High contents of fine dust and moisture limited its utilization for direct combustion, town gas and vehicle fuel. Thus, this study proposed a new design for a cooling device using a centrifugal cyclone for simultaneous removal of fine dust and moisture as a pretreatment in the purification processes. A heat exchanger and an ID fan, which are installed inside and outside of the cyclone, in order to cool the humid gas below the freezing point and form a foggy mist. Such an atmosphere enhanced to capture fine dust as recirculating the cold mist flow. The water removal rate was 80.8% at a relative humidity of 95%, and the particle removal efficiency was 98.3% for $2.5{\mu}m$. Simultaneous removal efficiency was 70.8% and 99.6% for particle and moisture respectively.

• Journal of Environmental Science International
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• v.20 no.10
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• pp.1233-1241
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• 2011

The main objective of this experimental investigation was $CH_4$ recovery from biogas generated in municipal and wastewater treatment plant. The polysulfone hollow fiber membrane was prepared in order to investigate the permeation properties of $CH_4$ and $CO_2$. Permeability of $CO_2$ in Polysulfone membrane was 11-fold higher than of $CH_4$ gas. A membrane pilot plant for upgrading biogas was constructed and operated at a municipal wastewater treatment plant. The raw biogas contained 66 ~ 68 Vol % $CH_4$, the balance being mainly $CO_2$. The effect of the operating pressure of feed and permeate side and feed flowrate on $CH_4$ recovery concentration and efficiency were investigated with double stage membrane pilot plant. The $CH_4$ concentration in the retentate stream was raised in these tests to 93 Vol % $CH_4$.

• Journal of the Korean Operations Research and Management Science Society
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• v.15 no.1
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• pp.37-46
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• 1990

Biomass to methane production is a good supply of substitutable energy resources. The economic viability of these systems depends a great deal on cost effective production methods and facilities. The operational problem is to determine the time eto allocate to each batch of several feedstocks for each digester and to determine the number of batches for each digester so as to maximize biogas production for two identical digesters over a fixed planning horizon. This paper provides an efficient approximation procedure which is based on decomposition of the problem and the analysis of incremental gas production function for each feedstock. The computational experience for the heuristic procedure was also reported.

• Proceedings of the Korean Society of Disaster Information Conference
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• 2016.11a
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• pp.275-277
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• 2016

본 논문에서는 Door Fan Test 수행 사례를 중심으로 사전 준비에 필요한 사항에 대해 분석하였다. 분석 결과 관통부 주위 개구부, 벽체 틈새 개구부 등 방화구역의 누설부위를 통해 약제가 누출되는 문제가 있었다. 원인으로는 전기배선 공사로 인해 내화충전된 부분을 제거하고 공사 후 다시 충전하지 않는 경우, 벽과 천장사이의 틈을 내화 실란트 등으로 마감을 하지 않은 경우가 대부분이었다. 이와 같이 누설부위가 많은 경우 테스트의 결과 불합격이 나오게 되며, 이러한 문제점을 개선하기 위해 사전현장조사를 통해 방호구역의 누설부위를 조사하고 보완조치를 진행한 후 테스트를 수행하는 절차가 필요하였다. 한편, 테스트 운영에 관한 사항으로는 해당 실(room)을 위한 충분한 유량 미확보, 장애물로 인한 와류형성, 차압측정구의 설치문제 등이 있었다. 이를 개선하기 위해서 공기를 유입하는 실은 외부로부터 충분한 공기유입이 있어야하며, 팬 앞의 장애물을 제거하거나 팬의 설치 위치를 조정하는 것이 필요하며, 공기의 유동이 가장 적은 곳에 측정구를 설치하는 등의 조치가 필요하다.