• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.1
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• pp.1-8
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• 2023

In this study, to reduce CO₂ emission in the cement manufacturing process, we evaluated the limestone that is used as a raw material for cement, substituted with steel slag by the various substituted levels. Based on the chemical composition of each raw materials including limestone, and blast furnace slow cooling slag, converter slag, and KR slag as an alternative raw material, we simulated the optimal cement raw mixture by the substitution levels of limestone. Test results indicated that the steel slags contain a certain level of CaO that can be used as alternative decarbonated raw materials, and it has enough to partially reduce the amount of limestonem. And we estimated the maximum usable levels of each raw material. In particular, it was confirmed that by using a mixture of these raw materials rather than using them one by one, the effect of reducing limestone was increased and CO₂ emission from the cement manufacturing process could be reduced.

• Explosives and Blasting
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• v.21 no.1
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• pp.19-27
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• 2003

국내 석회석 광산에서는 벤치 발파패턴을 현장의 KNOW-HOW에 따라 가장 경제저인 발파패턴을 적용하고 있다. 그러나 인건비 재료비등 제반경비가 상승함에 따라 좀 더 효율적인 발파방법의 개선이 요구되고 있는 바, 현 석회석 광산에서의 발파패턴을 보다 개선하여 경제적인 발파패턴을 적용하고, 그에 따른 고려해야 할 사항들을 본 논문에서 연구 하고자 한다. 따라서 국내 석회석 광산의 발파 패턴과 외국의 광산발파 패턴을 비교하고, 수치해석을 적용하여 기존의 발파 패턴에서 장약길이, 공간격, 장약량의 변화, 천공경은 102mm에서 115mm로 변화하고 장양방법을 단일장약에서 이중장약으로 변화하여 동해 쌍용자원에서 시험을 실시하였다. 연구 결과 장약길이의 20% 감소는 Power Factor를 (20%)낮게 하나, 파쇄효과는 28% 감소하고 Back Break가 (7%)이상 발생하였으며, 천공경을 115mm로 적용하고, 장약길이를 11% 감소를 위하여 이중장약을 적용하여 Power Factor를 10% 낮게 하였을 때 파쇄효과는 22.45%가 증대되었으며, 기존 동일 패턴에 Booster를 추가로 적용하였을 때 파쇄효과는 13.21% 가 증대되었고, Power Factor는 11% 가 감소되는 것을 알 수 있었다.

• Journal of the Mineralogical Society of Korea
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• v.22 no.3
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• pp.261-277
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• 2009

This study is aimed to emphasize the significance of ore selection in lime manufacturing through the evaluation of applied-mineralogical impact factors of crude ores controlling calcination characteristics for some domestic limestones used currently for lime manufacturing. To do this work, systematic characterization and determination were carried out for the limestone ores and their calcination products in a fixed calcining condition (target temperature: $1000^{\circ}C$, retention time: 30 minutes, 2, 4, 10, 16 hours), and the results were correlated and discussed. Selected high-Ca limestones in this study are as much as > 98 wt%, but they are somewhat diverse in crystallinity, texture, and impurity composition. Synthesized quicklimes are varied depending on such a difference in ore characters. The Pungchon limestone has relatively very low calcination rate, and the limestones from the Gabsan formation and the Jeongseon formation exhibit good quality in calcination rate and decrepitation. Among these samples, the limestone ore from the Jeongseon formation is evaluated to be the best for crude ore in manufacturing of highly-reactive quicklime. In addition, it is characteristic that the Gabsan limestone comparative rich in Fe-bearing mineral such as pyrite and goethite is more conspicuous in sintering effect.

• Cement Symposium
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• no.23
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• pp.66-74
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• 1995

• Proceedings of the KSEEG Conference
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• 2002.04a
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• pp.221-223
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• 2002

• Tunnel and Underground Space
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• v.13 no.6
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• pp.421-433
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• 2003

Demand for limestone production from both the underground and opencast mines in Korea is gradually increasing. Increase in productivity with safe mining operations is the emphasis laid on the mining industry. KIGAM has undertaken a detailed investigation to apply RMR and Q classification system for the design of underground limestone mining operations. The field investigations were confined to the underground mines of Daesung Mining Development Co. Ltd. and Pyunghae Mines of Korean Airport Service. Modification to the standard RMR and Q for limestone mines in Korea along with the correlation between these two systems are discussed while attempts were also made to calculate the width of a safe unsupported span.

• Korean Chemical Engineering Research
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• v.57 no.5
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• pp.743-748
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• 2019

This study focuses on the simulation of wet flue gas desulfurization process for improving the production of gypsum by the utilization of low-grade limestone. At present, high-grade limestone with a $CaCO_3$ content of 94% is used for producing merchantable gypsum. In modeling process, a lot of reactions are considered to develop model. First, the limestone dissolution is simulated by RSTOIC model. Second, SOx absorption and crystallization is used by RCSTR model. Finally the gypsum is separated by using SEPERATORS model. Modeling steps make it easy to reflect further side reactions and physical disturbances. In optimization condition, constraints are set to 93% purity of gypsum, 94% desulfurization efficiency, and total use of limestone at 3710 kg/hr. Under these constraints, the mass flow of low-grade limestone was maximized. As a result, the maximum blending quantity of low-grade limestone for 2,100 kg of high-grade limestone that satisfies constraints is about 1,610 kg.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.1
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• pp.20-25
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• 2021

The cement clinker, the main raw material of cement, is manufactured using limestone as the main material. Depending on the quality of limestone, the use of subsidiary materials changes, and has a great influence on the production of cement clinkers. In this study, the effect of CaO content of limestone, a cement clinker material, on Raw Mill grinding and sintering of cement clinker was investigated. The grinding time of the union materials changed in the content of limestone CaO was measured to identify the grinding properties. The raw material combination was cleaned within a range of 1,350-1,500℃. The sintering performance of cement clinker by Burnability index calculation was identified. The lower the grade of limestone, the lower the grinding quality of the raw material combination. The lower the CaO content of limestone, the greater the variation in F-CaO for sintering temperature. The lower the class of limestone, the higher B. I. value was calculated, indicating the lower cement clinker sintering. In addition, the mineral analysis results of cement clinker showed that if the F-CaO value was low due to the increase in sintering temperature, the Belite content decreased and the Alite content increased. In the case of Alite, the ratio of R-type decreased and that of M-type increased as the content of limestone CaO increased.

• Economic and Environmental Geology
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• v.44 no.3
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• pp.217-228
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• 2011

The feasibility study for the stabilization process using 5 amendments was performed to quantify As-immobilization efficiency in farmland soils around Samkwang abandoned mine, Korea. For the batch experiments, with 2% and 3% of granular lime(2-5 mm in diameter), leaching concentration of As from the soil decreased by 86% and 95% respectively, compared to that without the amendment. When 5% and 10% of granular limestone was added in the soil, As concentration decreased by 82% and 95%, showing that lime and limestone has a great capability to immobilize As in the soil. From the results of batch experiments, continuous column(15 cm in dimeter and 100 cm in length) tests using granular lime and limestone as amendments was performed. Without the amendment, As concentration from the effluent of the column ranged from 167 ${\mu}g$/L to 845 ${\mu}g$/L, which were higher than Korea Drinking Water Limit(50 ${\mu}g$/L). However, only with 1% and 2% of lime, As concentration from the column dramatically decreased by 97% for 9 years rainfall and maintained below 50 ${\mu}g$/L. With 5% of limestone and the mixed amendment(1% of lime + 2% of limestone), more than 95% diminution of As leaching from the column occurred within I year rainfall and maintained below 20 ${\mu}g$/L, suggesting that the capability of limestone to immobilize As in the farmland soil was outstanding and similar to that of lime. Results of experiments suggested that As stabilization process using limestone could be more available to immobilize As from the soil than using lime because of low pH increase and thus less harmful side effect.

• Resources Recycling
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• v.26 no.6
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• pp.10-19
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• 2017

It is studied the effect of crystal structure of domestic High-Ca limestones using absorbent for desulfurization on the grinding characteristics and dissolution rates in wet flue gas desulfurization process of domestic coal fired power plant. It compared the crystal structure, grinding work index and dissolution rates with 4 Limestones from Jecheon-Danyang with different crystal structure, and we found that grinding work index differ in crystal size and crystal structure of limestones : The lower the value of the grinding work index is, the higher the dissolution rates of limestones. Confirmed that we have important indicators of grinding characteristics for crystal structure with CaO content of limestones.