• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.91.1-91.1
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• 2011

고체산화물 연료전지(Solid Oxide Fuel Cell이하 SOFC)는 연료가 갖는 화학에너지를 연소과정 없이, 공기와 H2, CO, CH4와 같은 환원성 가스를 공급받아 $600{\sim}1000^{\circ}C$에서 전기화학적 반응을 통하여 직접 전기를 얻는 방식이다. SOFC는 $700^{\circ}C$ 이상의 고온에서 고체산화물이 연료와 공기가 반응하여 전기와 열을 동시에 생산하기 때문에 carnot cycle의 제한을 받지 않아 발전효율이 40% 이상으로 고효율이고, NOx 및 SOx를 배출하지 않아 무공해이며, moving parts가 없어 소음이 나지 않고, 건설과 증설이 지역이나 기후 조건에 제약 없이 용이하고, 다양한 용량이 가능하며, 고가의 백금 촉매를 사용하지 않으며, 수소, 석탄가스, 천연가스 등의 연료를 사용할 수 있는 장점이 있음, 또한 다향한 형태로 제작할 수 있으며 전해질이 고체에서 전해질 손실 및 보충에 문제가 없고 타 연료전지에 비해 개질기가 필요 없어 발전시스템이 간단하고 경량화가 가능하다. 전사법은 paste를 제작하여 전사용지에 Screen printing하여 건조 후 coating하는 방법으로 기존의 여러 coating 방법보다 제작이 용이하고 소재의 크기, 두께조절이 간편하며, 구성층의 표면조도나 굴곡에 대응이 용이한 방법이다. 본 실험에서는 paste 제조, 전사법을 이용하여 Anode, AFL, Electrolyte, CFL, Cathode전사지를 제작하고 이를 세라믹 평관형 지지체에 변수로 두께 조건별 Coating 한 후 $1400^{\circ}C$ 소결을 진행하여 SEM 분석으로 미세구조 관찰, 출력특성 및 Impedance을 확인하였다.

• Journal of Energy Engineering
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• v.11 no.2
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• pp.114-121
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• 2002

Alkali metal compounds existed in original coal or sorbents are exhausted as vapor or small particle at the outlet of combustor when operating PFBC power plant. These compounds can be removed with dust removal equipment, but total generation efficiency will be decreased because of lower operating temperature of dust removal equipment. Alkali metal contained in vapor phase is initially deposited onto turbine blade results in serious corrosion. The concentration of alkali vapor in the PFBC flue gas is 20∼40 ppm which is dependent on mineral characteristics and composition as well as operating condition of PFBC. However, the allowance limit of alkali metal vapor is assigned as less than 50 ppb for gas turbine when coal or oil is used as fuel. Therefore, alkali metal vapor in PFBC or IGCC process should be removed by solid sorbents to prevent corrosion of turbine blade and improve plant efficiency. In the present investigation, powder of Bauxite, Kaolinite and Limestone is used in the preparation of cylinder-type pellet which is inserted into the pressurized alkali removal reactor for the alkali absorption experiment. Experimental results showed that the alkali removal efficiency in the order of Bauxite, Kaolinite and Limestone. Alkali vapor removal efficiency is related with reaction temperature, porosity of pellet and alkali vapor concentration of flue gas.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2002.11a
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• pp.83-84
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• 2002

사이클론 집진기(이하 "사이클론"으로 표기)는 1800년대 후반에 기본개념이 싹트기 시작한 이후 100년 이상의 역사를 지닌 집진 장치로서, 구성이 단순하고, 고온 및 고압에서도 동작이 가능하며, 에너지 소모가 적고, 제조비용과 유지비용이 저렴한 특징을 지니고 있다. 현재 산업체에 설치되어 있는 싸이클론은 대용량의 가스처리, 입경 10-200$\mu\textrm{m}$까지의 분진처리, 낮은 초기설치비, 유지보수 및 조작의 간편성 때문에 산업체 여러 분야에서의 응용성은 다양하고 응용범위도 상당히 넓다고 할 수 있으며 석탄가스화 복합발전 플랜트, 쓰레기 소각로, 순환유동층 보일러 등에 널리 사용되고 있다. (중략)

• Journal of the Korea Institute of Building Construction
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• v.20 no.4
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• pp.331-338
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• 2020

The aim of the research is to evaluate the possibility of using coal gasification slag (CGS) as a combined aggregate for concrete mixture. To achieve this goal, the fundamental properties and the durability of concrete were analyzed depending on various combining ratio of CGS into both fine aggregate with favorable gradation and relatively coarse particles. According to the results of the experiment, slump and slump flow were increased with content of CGS regardless of crushed fine aggregate with good and poor gradations while the air content was decreased. For the compressive strength of the concrete, in the case of using the crushed aggregate with good gradation, increasing CGS content decreased compressive strength of the concrete, while when the concrete used crushed aggregate with poor gradation, the compressive strength was the maximum at 50% of CGS content. As a durability assessment, drying shrinkage was decreased and carbonation resistance was improved by increasing CGS content. On the other hand, for freeze-thawing resistance, CGS influenced adverse effect on freeze-thawing resistance. Therefore, it is known that an additional air entrainer is needed to increase the freeze-thawing resistance when CGS was used as a combined aggregate for concrete.

• Journal of the Korean Society of Propulsion Engineers
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• v.17 no.6
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• pp.67-74
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• 2013

IGCC(Integrated Gasification Combined Cycle) system is candidates which can solve the environmental problems including global warming, since it can be easily combined with CCS(Carbon Capture System). In this research, combustion instability characteristics were studied at various fuel which are composed of $H_2/CH_4/CO$ mixture. Mode analysis for instabilities observed experimentally was conducted and the linearly increasing tendency of frequency was observed as the hydrogen content in fuel increases.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.3
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• pp.194-201
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• 2019

This study analyzed the properties of concrete depending on the coal gasification slag(CGS) contents in order to examine the applicability of CGS as the fine aggregate for concrete. Experimental results, trended that the slump and slump flow increased with increasing CGS contents, and air contents has decreased. Evaluation index for segregation of normal strength concrete(EISN) is showed was good from CGS 25% when using crushed sand A(CSa) and CGS 50% when using mixed sand(MS). The compressive strength decreased with increasing CGS contents when CSa was used. However, when MS was used, the maximum value was CGS 50% due to parabolic tendency. Depending on fine aggregates type, compared with compressive strength of CSa was about 8% higher than that of MS, and depending on the use or unuse of CGS, more advantageous at higher strength than low strength. As a result of relative performance study on the quality of concrete according to the CGS contents, it is considered that CGS can be positively contributed to enhancement of workability and strength development when mixed with fine aggregate around 25~50%.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.364-367
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• 2008

This present paper describes concepts of the real-time operation monitoring system as a tool for enhancing the reliability and raising the availability of the first Korea IGCC (Integrated Gasification Combined Cycle) power plant. This system consists of five (5) modules : (1) Data Validation Module, (2) Performance Calculation Module (3) Performance Diagnostic Module, (4) Trip Information Module, and (5) Statistics Analysis Module. Among these modules, Performance Calculation Module is explained in more detail. The objective of this module is to continuously evaluate the degradation (decrease in performance) of the IGCC plant and its equipment in order to provide plant operators additional information to help them identify problems, improve performance.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.41 no.8
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• pp.639-648
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• 2013

This paper describes on the NOx/CO emission characteristics, temperature characteristics and flame structures when firing coal derived synthetic gas especially for gases of Buggenum and Taean IGCC. These combustion characteristics were observed by conducting ambient-pressure elevated-temperature combustion tests in GE7EA model combustor when varying heat input and nitrogen dilution ratio. Nitrogen addition caused decrement in adiabatic flame temperature, thus resulting in the NOx reduction. At low heat input condition, nitrogen dilution raised the CO emission dramatically due to incomplete combustion. These NOx reduction and CO arising phenomena were observed at certain flame temperature of $1500^{\circ}C$ and $1250^{\circ}C$, respectively. As increasing nitrogen dilution, adiabatic flame temperature and combustor liner temperature were decreased and singular points were detected due to change in flame structure such as flame lifting. From the results, the effect of nitrogen dilution on the NOx/CO and flame structure was examined, and the test data will be utilized as a reference to achieve optimal operating condition of the Taean IGCC demonstration plant.

• Korean Chemical Engineering Research
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• v.51 no.4
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• pp.506-512
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• 2013

Biomass and low-grade coals are known to be better potential sources of energy compared to crude oil and natural gas since these materials are readily available and found to have large reserves, respectively. Gasification of these carbonaceous materials produced syngas for chemical synthesis and power generation. Woodchip, sawdust and lignite were gasified with steam in a thermobalance reactor under atmospheric pressure in order to evaluate their kinetic rate information. The effects of gasification temperature ($600{\sim}900^{\circ}C$) and partial pressure of steam (20~90 kPa) on the gasification rate were investigated. The three different types of gas-solid reaction models were applied to the experimental data to predict the behavior of the gasification reactions. The modified volumetric model predicted the conversion data well, thus the model was used to evaluate kinetic parameters in this study. The observed activation energy of biomass, sawdust and lignite gasification reactions were found to be in reasonable range and their rank was found to be sawdust > woodchip > lignite. The expression of apparent reaction rates for steam gasification of the three solids was proposed to provide basic information on the design of coal gasification processes.

• Korean Chemical Engineering Research
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• v.44 no.4
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• pp.356-362
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• 2006

The $SO_2$ reduction using CO and $H_2$ over Sn-Zr based catalysts was performed in this study. Sn-Zr based catalysts with Sn/Zr molar ratio (0/1, 1/4, 1/1, 2/1, 3/1, 1/0) were prepared by the precipitation and co-precipitation method. The effect of the temperature on the reaction characteristics of the $SO_2$ reduction with a reducing agent such as $H_2$ and CO was investigated under the conditions of space velocity of $10,000ml/g_{-cat.}h$, $([CO(or\;H_2)]/[SO_2])$ of 2.0. As a result, the activity of Sn-Zr based catalysts were higher than $SnO_2$ and $ZrO_2$. The reactivity for the $SO_2$ reduction with CO was higher than that with $H_2$, and sulfur yield in the $SO_2$ reduction by $H_2$ was higher than that by CO. The reactivity for the $SO_2$ reduction with $H_2$ was increased with the reaction temperature regardless of Sn-Zr based catalyst with a Sn/Zr molar ratio. $SnO_2-ZrO_2$ (Sn/Zr=1/4) had highest activity at $550^{\circ}C$, in the $SO_2$ reduction with $H_2$ and $SO_2$ conversion of 94.4％ and sulfur yield of 66.4％ were obtained at $550^{\circ}C$. On the other hand, in the $SO_2$ reduction by CO, the reactivity was decreased with the increase over $325^{\circ}C$. At the optimal temperature of $325^{\circ}C$, $SO_2$ conversion and sulfur yield were about 100％ and 99.5％, respectively, in the $SO_2$ reduction over $SnO_2-ZrO_2$ (Sn/Zr=3/1). Also, the $SO_2$ reduction using syngas with $CO/H_2$ ratio over $SnO_2-ZrO_2$ (Sn/Zr=2/1) was performed in order to investigate the application possibility of the simulated coal gas as the reductant in DSRP. As a result, the reactivity of the $SO_2$ reduction using syngas with $CO/H_2$ ratio was increased with increasing the CO content of syngas. Therefore, it could be known that DSRP using the simulated coal gas over Sn-Zr based catalyst is possible to be realized in IGCC system