• Journal of the Korean Chemical Society
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• v.50 no.5
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• pp.355-361
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• 2006

The critical micelle concentration (CMC) and the counterion binding constant (B) in a mixed micellar state of the sodium dodecylbenzenesulfonate (DBS) with the polyoxyethylene(23) lauryl ether (Brij 35) at 25oC in water and aqueous solutions of n-butanol (0.1M, 0.2M, and 0.3M) were determined as a function of a1 (the overall mole fraction of DBS) by the use of electric conductivity method and surface tensiometer method. Various thermodynamic parameters (Xi, i, Ci, aiM, , and Hmix) were calculated by means of the equations derived from the nonideal mixed micellar model. The effect of n-butanol on the micellization of the DBS/Brij 35 mixtures has been also studied by analyzing the measured and calculated thermodynamic parameters.

• The Journal of Engineering Geology
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• v.13 no.2
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• pp.227-238
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• 2003

Understanding of a creep behavior in rocks under a constant load, due to visco-elastic properties of rock, is an essential element to predict a long term ground deformation. In order to clarify the creep characteristics of the mudstone in Duho formation at Pohang basin, deposited during Tertiary, a series of laboratory tests including physical properties, unconfined compressive strength and uniaxial creep tests, was performed. The mudstone showed a higher creep potential due to 26% of clay minerals such as illite and chlorite. The unconfined compressive strength of the rock was $462{\;}kg/\textrm{cm}^2$ in average, and four creep tests were performed under constant stress of 40 to 70 % of the strength. The creep constants in the empirical and theoretical equations were deduced from the time-strain curves obtained from the tests. Among the several equations, the empirical equation proposed by Griggs and theoretical equation of Burger’s model are appreciated as the best one to express the creep behavior of the mudstone. Instantaneous elastic strain was linearly increased with stress level but strain velocity during the first creep is decreased with a similar pattern by time lapse regardless the stress level.

• Journal of Welding and Joining
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• v.13 no.2
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• pp.96-105
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• 1995

A modified method for the analysis of short fatigue crack growth has been presented, and calculations based upon the modified method are compared with experimental results for S45C carbon steel. It is also shown that the modified method is in good agreement with experimental data. The proposed equation for the fatigue crack growth rates includes a material constant which relates the threshold level to the endurance limit, a correction for elastic-plastic behaviour and a means for dealing with the effects of crack closure. In this study one of the modifications is to substitute the Forman' s elastic expression of the stress intensity factor range into the geometrical factor The other is a consideration of the bending effect which is developed from the moment caused by the eccentric cross sectional geometry as the crack grows. Thus, this method is useful for residual life prediction of the mechanical structures as well as the welding structures.

• Journal of Korea Soil Environment Society
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• v.4 no.1
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• pp.97-108
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• 1999

Reduction 2, 4, 6-trinitrotoluene by zero valent iron was studied in a batch reactor under anoxic conditions. Results showed that the removal of trinitrotoluene (TNT)followed a pseudo-first order reaction and the rate was linearly dependent on the available reactive surfau area of the zero valent iron surface area, resulting a rate constant of 0.0981min$^{1}m$$^{-2}m$. High concentrations of the final product, presumably triaminotoluene which needs to be treated by other means, accumulated in the solution. However , little amount of TAT was extracted from the metal surface by using acetonitrile or phosphate buffered water (pH 7.0). Other common major intermediate in biological TNT degradation, a group of aminodinitrotoluenes, was not detected in the solution. Therefore, it is postulated that the reduction of nitro group by $Fe^0$ occurs simultaneously in all three positions and a TNT reduction model by zero valent iron was suggested.

• Journal of the Korean Chemical Society
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• v.48 no.3
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• pp.236-242
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• 2004

The critical micelle concentration (CMC) and the counterion binding constant (B) in a mixed micellar state of the Dodecylpyridinium chloride (DPC) with the Cetyldimethylethylammonium bromide (CDEAB) at 25$^{\circ}C$ in aqueous solutions of n-butanol were determined as a function of ${\alpha}_1$ (the overall mole fraction of DPC) by the use of electric conductivity method. Various thermodynamic parameters (($X_i,\;{\gamma}_i,\;C_i,\;a^M_i,\;{\beta},\;and {\Delta}H_{mix})$were calculated by means of the equations derived from the nonideal mixed micellar model. The effect of n-butanol on the mixed micellization of the DPC/CDEAB mixtures has been also studied by analyzing the measured and calculated thermodynamic parameters (CMC, B 및 $;{\Delta}G_o\;^m$).

• Journal of the Earthquake Engineering Society of Korea
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• v.11 no.6
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• pp.33-39
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• 2007

The seismic source parameters of the Uljin earthquake on 29 May 2004, including focal depth, focal mechanism, magnitude, and moment tensor elements for source characteristics, are analysed using moment tensor seismic source inversion. The Green‘s function for 3 crust models representing the southern Korean Peninsula are used. Also 3 kinds of epicenters are used to find optimum solution for seismic source parameters. Results show that seismic source parameters have a little dependency of azimuthal distribution and epicentral distances of seismic stations. Final results show that the event, considering 6 moment tensor elements, is caused by the typical reverse fault with nearly NS strike. The focal mechanism implies that the tectonic force around epicenter area currently has compressive environment, with nearly EW principal axis. The focal depth is estimated to be about 12km. The resultant focal mechanism show fairly good agreement to those of other studies. However, focal depth is much different from that of other studies.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.22 no.6
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• pp.627-637
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• 2009

Composite materials have been employed in the various engineering applications due to high mechanical performances including high strength-weight ratio and high degree of free formability. Due to complex manufacturing process, however, it can have intrinsic randomness in the material constants which affect the deterministic behavior of the composite structures. In this study, we suggest a formulation for stochastic finite element analysis considering the spatial randomness of Poisson's ratio. Considering the reciprocal relation between elastic moduli and Poisson's ratios in the two mutually orthogonal axes, one of two values of Poisson's ratio can be expressed in terms of the other. Using this, the relation between stress resultants and strains is derived in the ascending order of power of the stochastic field function, which can be directly used in the formulation to obtain the coefficient of variation of responses. The adequacy of the proposed scheme is demonstrated by comparison with the results of Monte Carlo analysis.

• Korean Chemical Engineering Research
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• v.59 no.3
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• pp.379-392
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• 2021

In this study, an improved acetone-water fractional precipitation process for paclitaxel using ultrasonic cavitation bubbles and gas bubbles was developed. Compared to the conventional method, the time required for precipitation has been reduced by 20~25 times. In addition, the particle size of paclitaxel decreased by 3.5~5.5 times and the diffusion coefficient of paclitaxel increased by 3.5~6.7 times. In the case of precipitation using ultrasonic cavitation bubbles, as the ultrasonic power increased and the temperature decreased, the precipitation rate constant increased. In the case of precipitation using gas bubbles, as the gas flow rate increased and the temperature decreased, the precipitation rate constant increased. Thermodynamic parameters revealed the exothermic, irreversible, and nonspontaneous nature of the improved fractional precipitation.

• Journal of Korea Water Resources Association
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• v.54 no.11
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• pp.863-873
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• 2021

The mechanical dispersion which dominates solute transport in porous media is caused by the difference in flow velocity within pores. Longitudinal dispersion coefficient and longitudinal dispersivity that are hydro-dispersive parameters of advection-dispersion equation can only be obtained by experiment. Hydraulic mean radius that represents the amount and intensity of flowing water within pores can be obtained by the formula using the factors for physical properties. A slug injection test was conducted and a power type empirical formula for obtaining a longitudinal dispersivity using a hydraulic mean radius in rockfill porous media was derived. It is possible to obtain the longitudinal dispersivity depending on transport distance because it contains a formula for a scale constant, and expected to be applicable to waterways filled with homogeneous gravel and small flow rate.

• Korean Journal of Mineralogy and Petrology
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• v.33 no.3
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• pp.143-152
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• 2020

Birnessite is a layered manganese oxide mineral with ~7 Å of d-spacing. Because of its high cation exchange capacity, birnessite greatly impacts the chemical compositions of ground water and fluids in sediment pores. Understanding the cation exchange mechanisms requires atomistic investigations of the crystal structures and coordination environments of hydrated cations in the interlayer. In this study, we conducted classical molecular dynamics (MD) simulations, an atomistic simulation method of computational mineralogy, for triclinic Na-birnessite and K-birnessite whose chemical formula are from previous experiments. We report our MD simulation results of the crystal structures, coordination environments of Na⁺ and K⁺, and the polytypes of birnessite and compare them with available experimental results. The simulation results well reproduced experimental lattice parameters and provided atomic level information for the interlayer cation and water molecule sites that are difficult to distinguish in X-ray experiments. We also report that the polytype of the Mn octahedral sheets is identical between Na- and K-birnessite, but the cation positions differ from each other, demonstrating a correlation between the coordination environment of the interlayer cations and the crystal lattice parameters. This study shows that MD simulations are very promising in elucidating ion exchange reactions of birnessite.