• Title/Summary/Keyword: 상대구조계수

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Pore Structures and Mechanical Properties of Early Frost Damaged Concrete using Electric Arc Furnace Slag as Aggregate (초기동결 피해를 받은 전기로 산화 슬래그 혼입 콘크리트의 공극 구조 및 역학적 특성)

  • Lee, Won-Jun;Choi, So-Yeong;Kim, Il-Sun;Yang, Eun-Ik
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.2
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    • pp.68-77
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    • 2020
  • The purpose of the paper is to evaluate the pore structure and mechanical properties of early frost damaged concrete using electric arc furnace slag as aggregate. From the results, when the concrete is exposed to frost damage at an early age, the peak point of pores 100 to 150 ㎛ in diameter were transferred into larger one. When the freezing duration is not exceeded 24 hours, it is possible that the pore distribution of under the 200 ㎛ is maintained and pore size of over 500 ㎛ is not formed, and, the freezing resistance of concrete using EFG could be improved. When BFS was mixed in concrete using EFG as coarse aggregate, the relative strength is higher than that of natural coarse aggregate. Meanwhile, the elastic modulus and resonance frequency did not change significantly due to the early frost damage as compared with the compressive strength. So, it is necessary to analyze the correlation between the experimental results in order to evaluate the performance degradation due to early frost damage.

Effect of DC bias on structure of hydrogenated amorphous silicon and microcrystalline silicon

  • 이윤정;주성재;임승현;윤의준
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.84-84
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    • 2000
  • 수소화된 비정질 실리콘(a-Si:H)과 미세결정질 실리콘 ($\mu$c-Si:H)은 저온.건식 공정인 PECVD로 값싼 유리 기판을 사용하여 넓은 면적에 증착이 가능하다는 큰 장점으로 인해 광전소자(photovoltaic device)와 박막 트랜지스터(TFTs)등에 폭넓게 응용되어 왔으며 최근에는 nm 크기의 실리콘 결정(nc-Si)에서 가시광선 영역의 발광 현상이 발견됨에 따라 광소자로서의 특성을 제어하기 위해서는 성장 조건과 공정 변수에 따른 구조 변화에 대한 연구가 선행되어야 한다. 본 연구에서는 UHV-ECR-PECVD 법을 이용하여 H2로 희석된 SiH4로부터 a-Si:H과 $\mu$c-Si:H를 증착하였다. 그림 1은 SiH4 20sccm/H2 50sccm/25$0^{\circ}C$에서 기판의 DC bias를 변화시키면서 박막을 증착시킬 때 나타나는 박막의 구조 변화를 raman spectrum의 To phonon peak의 위치와 반가폭의 변화로 나타낸 것이다. 비정질 실리콘 박막은 DC bias를 증가시킴에 따라 무질서도가 증가하다가 어떤 critical DC bias에서 최대치를 이룬후 다시 질서도가 증가한다. 이온의 충격력에 의해 박막내에 응력이 축적되면 박막의 에너지 상태가 높아지고 이 축적된 응력이 ordering에 대한 에너지 장벽을 넘을 수 있을 만큼 커지게 되면 응력이 풀리면서 ordering이 가능해지는 것으로 생각된다. 그림 2는 수소 결합 형태의 변화이다. 박막의 무질서도가 증가할 경우 알려진 바와 같이 2000cm-1근처의 peak은 감소하고 2100cm-1 부근이 peak이 증가하는 현상을 보였다. 본 논문에서는 여러 공정 변수, 특히 DC bias에 따르는 박막의 구조 변화와 다른 성장 조건(온도, 유량비)이 critical DC bias나 결정화, 결정성 등에 미치는 영향에 대한 분석결과를 보고하고자 한다.등을 이용하여 광학적 밴드갭, 광흡수 계수, Tauc Plot, 그리고 파장대별 빛의 투과도의 변화를 분석하였으며 각 변수가 변화함에 따라 광학적 밴드갭의 변화를 정량적으로 조사함으로써 분자결합상태와 밴드갭과 광 흡수 계수간의상관관계를 규명하였고, 각 변수에 따른 표면의 조도를 확인하였다. 비정질 Si1-xCx 박막을 증착하여 특성을 분석한 결과 성장된 박막의 성장률은 Carbonfid의 증가에 따라 다른 성장특성을 보였고, Silcne(SiH4) 가스량의 감소와 함께 박막의 성장률이 둔화됨을 볼 수 있다. 또한 Silane 가스량이 적어지는 영역에서는 가스량의 감소에 의해 성장속도가 둔화됨을 볼 수 있다. 또한 Silane 가스량이 적어지는 영역에서는 가스량의 감소에 의해 성장속도가 줄어들어 성장률이 Silane가스량에 의해 지배됨을 볼 수 있다. UV-VIS spectrophotometer에 의한 비정질 SiC 박막의 투과도와 파장과의 관계에 있어 유리를 기판으로 사용했으므로 유리의투과도를 감안했으며, 유리에 대한 상대적인 비율 관계로 투과도를 나타냈었다. 또한 비저질 SiC 박막의 흡수계수는 Ellipsometry에 의해 측정된 Δ과 Ψ값을 이용하여 시뮬레이션한 결과로 비정질 SiC 박막의 두께를 이용하여 구하였다. 또한 Tauc Plot을 통해 박막의 optical band gap을 2.6~3.7eV로 조절할 수 있었다. 20$0^{\circ}C$이상으로 증가시켜도 광투과율은 큰 변화를 나타내지 않았다.부터 전분-지질복합제의 형성 촉진이 시사되었다.이것으로 인하여 호화억제에 의한 노화 방지효과가 기대되었지만 실제로 빵의 노화는 현저히 진행되었다. 이것은 quinua 대체량 증가에 따른 반죽의 안정성이 저하되어 버린 것으로 생각되어진다. 더욱이 lipase를 첨가하면 반죽이 분화하는 경향이 보여졌지만 첨가량 75ppm에 있어서 상당히 비용적의 증대가 보였다. 이것은 lipase의 가수분해에 의해

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Development of Battery-free SAW Integrated Microsensor for Real Time Simultaneous Measurement of Humidity and $CO_2$ component (습도와 $CO_2$ 농도의 실시간 동시감지를 위한 무전원 SAW 기반 집적 센서 개발)

  • Lim, Chun-Bae;Lee, Kee-Keun;Wang, Wen;Yang, Sang-Sik
    • Journal of the Microelectronics and Packaging Society
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    • v.16 no.1
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    • pp.13-19
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    • 2009
  • A 440MHz wireless and passive surface acoustic wave (SAW) based chemical sensor was developed on a $41^{\circ}YX\;LiNbO_3$ piezoelectric substrate for simultaneous measurement of $CO_2$ gas and relative humidity (RH) using a reflective delay line pattern as the sensor element. The reflective delay line is composed of an interdigital transducer (IDT) and several shorted grating reflectors. A Teflon AF 2400 and a hydrophilic $SiO_2$ layer were used as $CO_2$ and water vapor sensitive films. The coupling of mode (COM) modeling was conducted to determine optimal device parameters prior to fabrication. According to simulation results, the device was fabricated and then wirelessly measured using the network analyzer. The measured reflective coefficient $S_{11}$ in the time domain showed high signal/noise (S/N) ratio, small signal attenuation, and few spurious peaks. In the $CO_2$ and humidity testing, high sensitivity ($2^{\circ}/ppm$ for $CO_2$ detection and $7.45^{\circ}/%$RH for humidity sensing), good linearity and repeatability were observed in the $CO_2$ concentration ranges of $75{\sim}375ppm$ and humidity levels of $20{\sim}80%$RH. Temperature and humidity compensations were also investigated during the sensitivity evaluation process.

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Reliability Analysis of Maximum Overtopping Volume for Evaluating Freeboard of Vertical Breakwaters (직립식 방파제의 마루높이 산정을 위한 최대월파량에 대한 신뢰성 해석)

  • Lee, Cheol-Eung
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.23 no.2
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    • pp.154-162
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    • 2011
  • A reliability analysis model is developed for evaluating the crest freeboard of vertical breakwaters based on the concepts of maximum overtopping volume of individual wave. A reliability function is formulated by defining the margin of admissible overtopping volume and maximum overtopping volume that is depend on the number of overtopping waves, dimensionless crest freeboard, and mean overtopping discharge. In addition, Level III MCS technique is straightforwardly suggested by which the related empirical parameters to reliability function can be considered to be random variables with the wide range of different uncertainties. It can be possible to calculate the probabilities of failure according to the relative crest freeboard with the variations of the incident wave directions, the structural types of vertical breakwaters, and admissible overtopping volumes in conditions of the long and short crested-waves.

Numerical Simulation of Dynamic Soil-pile-structure Interaction in Liquefiable Sand (액상화 가능한 지반에 근입된 지반-말뚝-구조물 동적 상호작용의 수치 모델링)

  • Kwon, Sun-Yong;Yoo, Min-Taek;Kim, Seok-Jung
    • Journal of the Korean Geotechnical Society
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    • v.34 no.7
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    • pp.29-38
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    • 2018
  • Three-dimensional continuum modeling of dynamic soil-pile-structure interaction embedded in a liquefiable sand was carried out. Finn model which can model liquefaction behavior using effective stress method was adopted to simulate development of pore water pressure according to shear deformation of soil directly in real time. Finn model was incorporated into Non-linear elastic, Mohr-Coulomb plastic model. Calibration of proposed modeling method was performed by comparing the results with those of the centrifuge tests performed by Wilson (1998). Excess pore pressure ratio, pile bending moment, pile head displacement-time history according to depth calculated by numerical analysis agreed reasonably well with the test results. Validation of the proposed modeling method was later performed using another test case, and good agreement between the computed and measured values was observed.

A Study on the Nuclear Structure through the Multipurpose Coincidence Measurement System Development ( I ) - The Electromagnetic Properties of the Gamma Transitions in $^{75}As$- (다목적 동시측정 장치 개발에 의한 원자핵 구조 연구(I) - $^{75}As$의 감마 전이에 대한 전자기적 특성 -)

  • Chung, Won-Mo;Chung, Kap-Soo;Joo, Koan-Sik;Na, Sang-Kyun;Hwang, Han-Yull
    • Journal of Radiation Protection and Research
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    • v.18 no.1
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    • pp.53-61
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    • 1993
  • The gamma-gamma coincidence measurements and angular correlation measurement associated with the electron capture of $^{75}Se$ have been carried to understand the structure for the odd nuclei $^{75}As$ with two HPGe detectors. As a result, we could determined the band structure of 5/2 state to be of 1/2 [310] band which is based on $f_{5/2}$ proton state. Also we obtained the multipole admixture in the state of 279.5keV by using the mixing ratios of $121.1{\sim}279.5keV$ cascade. Subsequently, it is determined that 25.56% electric quadrupole transition is involved in the state of 279.5keV.

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Estimate of Wave Overtopping Rate on Armoured Slope Structures Using FUNWAVE-TVD Model (FUNWAVE-TVD 모델을 이용한 경사구조물의 월파량 산정)

  • Moon Su Kwak
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.36 no.1
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    • pp.11-19
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    • 2024
  • In this study, the program was modified by adding the empirical formula of EurOtop (2018) to enable calculation of wave overtopping on armoured slope structures in the FUNWAVE-TVD model using the fully nonlinear Boussinesq equation. The validity of the modified numerical model was verified by comparing it with CLASH data and experiment data for the rubble mound structure. This model accurately reproduced the change in wave overtopping rate according to the difference in the roughness factor of the armoured block, and well reproduced the rate of decrease in wave overtopping rate due to the increase in relative freeboard. The overtopping rate of the armoured slope structures showed significant differences depending on the positioning condition of the armoured blocks. When Tetrapods were placed with regular positioning, the overtopping rate increased significantly compared to when they were placed with random positioning, and it was consistent with when they were placed with Rocks. Meanwhile, when rocks were placed in one row, the wave overtopping rate was greater than when rocks were placed in two rows, which is believed to be due to the influence of the roughness and permeability of the structure's surface.

An In-silico Simulation Study on Size-dependent Electroelastic Properties of Hexagonal Boron Nitride Nanotubes (인실리코 해석을 통한 단일벽 질화붕소 나노튜브의 크기 변화에 따른 압전탄성 거동 예측연구)

  • Jaewon Lee;Seunghwa Yang
    • Composites Research
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    • v.37 no.2
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    • pp.132-138
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    • 2024
  • In this study, a molecular dynamics simulation study was performed to investigate the size-dependent electroelastic properties of single-walled boron nitride nanotubes(BNNT). To describe the elasticity and polarization of BNNT under mechanical loading, the Tersoff potential model and rigid ion approximation were adopted. For the prediction of piezoelectric constants and Young's modulus of BNNTs, piezoelectric constitutive equations based on the Maxwell's equation were used to calculate the strain-electric displacement and strain-stress relationships. It was found that the piezoelectric constants of BNNTs gradually decreases as the radius of the tubes increases showing a nonnegligible size effect. On the other hand, the elastic constants of the BNNTs showed opposites trends according to the equivalent geometrical assumption of the tubular structures. To establish the structure-property relationships, localized configurational change of the primarily bonded B-N bonded topology was investigated in detail to elucidate the BNNT curvature dependent elasticity.

Maximum Shear Modulus of Sand - Tire Chip Mixtures under Repetitive KO Loading Conditions (반복하중 재하 시 모래-타이어칩 혼합토의 최대전단탄성계수 변화)

  • Ryu, Byeonguk;Park, Junghee;Choo, Hyunwook
    • Journal of the Korean GEO-environmental Society
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    • v.22 no.12
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    • pp.41-50
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    • 2021
  • This study investigated the changes in engineering characteristics of sand-tire chip mixtures during repetitive loading. To quantify the changes in the maximum shear modulus according to the tire chip content in the mixtures and the particle size ratio between sand particle and tire chip, the samples were prepared with tire chip content of TC = 0, 10, 20, 40, 60, and 100%, and the particle size ratios SR were also set to be SR = 0.44, 1.27, 1.87, and 4.00. The stress of the prepared sample was applied through a pneumatic cylinder. The experiment was conducted in the order of static loading (= 50 kPa), cyclic loading (= 50-150 kPa), static loading (= 400 kPa) and unloading. The stress applied to tested mixtures was controlled by a pressure panel and a pneumatic valve by using an air compressor. The shear wave velocity was measured during static and cyclic loadings by installing bender elements at the upper and lower caps of the mold. The results demonstrated that the change in maximum shear modulus of all tested materials with varying SR during repetitive loading is the most significant when TC ~ 40%. In addition, the mixture with smaller SR at a given TC shows greater increase in maximum shear modulus during repetitive loading.

Structure Development of Uniaxially Drawn Poly(trimethylene terephthalate)/ Poly(ethylene terephthalnte) Blends (일축 연신에 의한 폴리(트리메틸렌 데레프탈레이트)/ 폴리(에틸렌 데레프탈레이트) 블렌드의 구조 변화)

  • 전병환;김환기;강호종
    • Polymer(Korea)
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    • v.28 no.1
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    • pp.67-76
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    • 2004
  • The effects of drawing temperature and draw down ratio on thermal properties, crystallinity and orientation of poly(trimethylene terephthalate)/poly(ethylene terephthalate) (PTT/PET) 100/0 ,90/10, and 80/20 blends have been investigated. The crystallinity and glass transition temperature increased while cold crystallization temperature and cold enthalpy decreased due to the development of orientation and stress induced crystallization by the cord drawing. Introducing PET to PTT decreased the crystallinity of PTT. However, it enhanced the orientation of PTT/PET blends drawn at below the glass transition temperature of PET. This lead to the increase of tensile modulus and tensile strength of PTT/PET blends. The shrinkage increased with increasing orientation, which might be minimized by the development of crystalline morphology of PTT in the course of cold drawing.