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Flame-retarding effects depending on the number of phosphonate groups attached to phosphorus flame-retarding compounds and coating binder resins (인계 난연화합물 및 코팅 바인더 수지에 부착된 phosphonate group에 따른 난연효과)

  • Park, Hyo-Nam;Kim, Hae-Rim;Choi, Seong-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.38 no.6
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    • pp.1678-1686
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    • 2021
  • In this study, we prepared phosphorous flame-retarding coating solutions by mixing triphosphate (3 phosphonate), phytic acid (6 phosphonate), or ammonium polyphosphate (10 phosphonate) with boric acid as a crosslinking agent and acryl resin binder. Prepared phosphorous flame-retarding coating solutions were coated onto non-woven fabrics, respectively, to obtain high flame-retarding effects. These prepared flame-retardant non-woven fabrics were evaluated using smoke density standard test (ASTM E662), limit oxygen index standard test (ISO E622), and vertical burning standard test (UL 94). Their flame-retarding effects were affected by the number of phosphonate groups. Regardless of natural or synthetic binder resins, their effects showed the following order: ammonium polyphosphate > phytic acid > triphosphate. Natural hydrocarbon compounds were also examined to determine the possible retardancy of binder resins. Results showed that natural hydrocarbon binder resins could be used for preparing fire-retardant nonwoven fabrics.

Drought risk analysis based on a scenario-neutral approach considering future climate change scenarios: focused on Yongdam Dam basin (미래 기후변화를 고려한 시나리오 중립 접근법 기반 가뭄 위험도 분석: 용담댐 유역을 중심으로)

  • Jiyoung Kim;Jiyoung Yoo;Tae-Woong Kim
    • Proceedings of the Korea Water Resources Association Conference
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    • 2023.05a
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    • pp.199-199
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    • 2023
  • 최근 기후변화의 영향으로 가뭄, 홍수 등 재해의 발생 빈도 및 강도가 증가하고 있다. 미래에는 온실가스 배출량의 증가로 극한 기상현상은 더욱 심화될 전망이다. 이러한 위험에 효율적으로 대비하기 위해 기후변화 시나리오를 고려하여 미래를 전망하는 것은 매우 중요하며, 최근 연구자들은 불확실성을 고려하기 위해 다양한 시나리오를 적용하고 있는 추세이다. 다만, 기후변화 시나리오를 입력자료로 하여 분석을 수행하는 경우, 새로운 기후변화 시나리오가 생성될 때 기존 기후변화 영향 평가는 무의미해지며, 기존 결과의 신뢰도 또한 감소하게 된다. 지금까지 사용된 시나리오 기반 접근법의 한계를 보완하여 시나리오 중립(Scenario Neutral, SN) 접근법이 개발되었고, 이는 다양한 기후변화 시나리오에 대한 시스템의 반응을 평가하는데 유용하다. 본 연구에서는 시나리오 중립 접근법을 활용하여 가뭄 위험도를 분석하였으며, 이를 위해 금강 유역 내 용담댐 유역을 대상으로 분석을 수행하였다. 입력자료로는 용담댐 유역의 1966~2020년 일단위 강수량 자료를 사용하였고, 문헌 조사를 통해 미래 기후변화에 따른 강수량 변화 추이를 파악하였다. 연평균 강수량의 증가와 여름 강수량의 증가를 기준으로 삼아 증가 비율에 따른 노출 공간을 생성했으며, 목표 변화에 따른 교란된 시계열을 도출해냈다. 이후, 각각의 시계열에 대한 이변량 가뭄빈도분석을 수행하여 재현기간을 산정한 뒤, 목표 변화에 따른 위험도를 비교하였다. 그 결과, 연평균 강수량과 여름 강수량이 현재와 유사한 경우 100년 빈도 가뭄이 발생할 확률은 0.84, 연평균 강수량의 증가가 110%, 여름 강수량의 증가가 115%일 경우 100년 빈도 가뭄이 발생할 확률은 0.79이었다. 추후 실제 미래 기후변화 시나리오를 적용하여 기준치에 따른 만족도를 분석한다면, 가뭄 대응에 유용한 의사결정 도구로 활용될 수 있을 것이다.

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Improvement in Sensitivity by Increasing the Frequency of SAW Sensors for DNA Detection (DNA 측정용 SAW 센서의 주파수 증대에 의한 감도향상)

  • Sakong, Jung-Yul;Kim, Jae-Ho;Lee, Soo-Suk;Roh, Yong-Rae
    • The Journal of the Acoustical Society of Korea
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    • v.26 no.1
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    • pp.42-47
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    • 2007
  • In this paper. we have studied improvement in sensitivity by increasing the frequency of SAW sensors for detecting the immobilization and hybridization of DNA. The sensor consists of twin SAW delay lines operating at 200MHz, a sensing channel and a reference channel. fabricated on $36^{\circ}$ rotated Y-cut X-propagation $LiTaO_3$ crystals. The optimum concentration of probe and target DNA was decided for the improvement of detection mechanism. and digital syringe pump system was used to reduce the human errors. The hybridization between immobilized probe DNA and target DNA on the gold-coated delay line results in mass loading on the delay line of the sensing channel. Thus, the relative frequency change was monitored in relation to the mass loading. The measurement results showed a good response of the sensor to the DNA hybridization with a maximum sensitivity level up to 0.066ng/m1/Hz.

Research of PPI prediction model based on POST-TAVR ECG (POST-TAVR ECG 기반의 PPI 예측 모델 연구)

  • InSeo Song;SeMo Yang;KangYoon Lee
    • Journal of Internet Computing and Services
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    • v.25 no.2
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    • pp.29-38
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    • 2024
  • After Transcatheter Aortic Valve Replacement (TAVR), comprehensive management of complications, including the need for Permanent Pacemaker Implantation (PPI), is crucial, increasing the demand for accurate prediction models. Departing from traditional image-based methods, this study developed an optimal PPI prediction model based on ECG data using the XGBoost algorithm. Focusing on ECG signals like DeltaPR and DeltaQRS as key indicators, the model effectively identifies the correlation between conduction disorders and PPI needs, achieving superior performance with an AUC of 0.91. Validated using data from two hospitals, it demonstrated a high similarity rate of 95.28% in predicting PPI from ECG characteristics. This confirms the model's effective applicability across diverse hospital data, establishing a significant advancement in the development of reliable and practical PPI prediction models with reduced dependence on human intervention and costly medical imaging.

A Pictorial Review of Radiologic Findings of Foreign Bodies in the Thorax (흉부 이물의 영상의학적 소견 )

  • Hee Soo Won;Yoon Ki Cha;Jeung Sook Kim;Seo Jin Jang;So Hyeon Bak;Hyun Jung Yoon
    • Journal of the Korean Society of Radiology
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    • v.83 no.2
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    • pp.293-303
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    • 2022
  • Thoracic foreign bodies (FBs) are serious and relatively frequent in emergency departments. Thoracic FBs may occur in association with aspiration, ingestion, trauma, or iatrogenic causes. Imaging plays an important role in the identification of FBs and their dimensions, structures, and locations, before the initiation of interventional treatment. To guide proper clinical management, radiologists should be aware of the radiologic presentations and the consequences of thoracic FBs. In this pictorial essay, we reviewed the optimal imaging settings to identify FBs in the thorax, classified thoracic FBs into four types according to their etiology, and reviewed the characteristic imaging features and the possible complications.

Public Electric Car Charging Locations Based on Car Navigation Data in Seoul (네비게이션 데이터를 바탕으로 한 서울시의 공공 전기차 충전소 위치)

  • Taekyung Kim;Jangyoung Kim;Yoon Gi Yang
    • Information Systems Review
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    • v.18 no.4
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    • pp.1-15
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    • 2016
  • Electric cars are expected to increase quality of life by reducing air pollution and to contribute to economic growth by creating new businesses. However, electric car adoption has lagged and has not satisfied public expectation. One of the primary reasons for this outcome is the slow charging speed or inconvenience of charging a battery. Under the insufficient diffusion of electric cars, pushing business entities to construct charging facilities is undesirable for a policy maker to increase the adoption rate because of cost and management issues. This study adopts the design science methodology to interpret the problem of deploying electric car charging stations in the view of information systems. A trip planning algorithm is suggested on the basis of the theory of range anxiety. We investigate issues related to the current charging locations using data from drivers' car navigation devices. We also review its applicability to trip planning to obtain insights.

Microwave hybrid sintering of NTC themistor (마이크로파 하이브리드 소결법에 의한 NTC 서미스터의 제조)

  • 최영락;안진용;안주삼;백동규;최승철
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.3
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    • pp.508-512
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    • 1998
  • The NTC thermistors were sintered by using microwave hybrid heating method at $1100^{\circ}C$~$1300^{\circ}C$ and those electrical properties were investigated. The obtained $B_{25^{\circ}C/85^{\circ}C}$ values from temperature dependence of electrical resisitivity were around 3100~3200 K which were almost the same values as conventionally sintered ones. Compared with conventional sintering process, this process could complete whole sintering process within 20 minutes. This the processing time and energy consumption could be reduced through this rapid heating by using microwave hybrid heating.t there were showed only two peaks, glycolide melting peak and lower molecular weight melting peak without lauryl alcohol. Conversion increased slowly with the reaction time up to 50 minutes, and then gave a sudden increase above that. The reaction time to disappear in glycolide melting peak during polymerization was shortened with the increase of lauryl alcohol content. Zero-shear viscosity of polyglycolic acid decreased with the increase of free acid content in glycolide.ssional energy and bending hysteresis increased. \circled3 Surface characteristics such as friction coefficient and thickness variation of highly shrinkage fabrics became relatively roughened state. \circled4 Since stiffened and roughened characteristics of highly shrinkage fabrics, drapabilities of them were significantly lowered. Additionally thermal insulation property of high shrinkage fabric was higher than that of low shrinkage fabric due to bulky and thickened feature. From the results, it is considered that the silk fabrics with high filling shrinkage have the good bulkiness and heat keeping properties and thus they have the suitable characteristics for high quality men's and women's formal garments.

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The Effect of Empowering Leadership on Employee's Work Engagement and Job Satisfaction: Moderating Effect of Behavioral Integrity (임파워링 리더십이 조직구성원의 직무열의와 직무만족에 미치는 영향: 행동적 진실성의 조절효과를 중심으로)

  • Ko, Min Jeong;Hah, Juhee
    • Asia-Pacific Journal of Business Venturing and Entrepreneurship
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    • v.15 no.4
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    • pp.217-230
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    • 2020
  • In a view of rapidly changing business environment, the success and competing power of organizations depend on committed, highly motivated and satisfied human resources. Empowerment is mainly concerned with establishing and building trust between management and employees, and motivating their participation. Also, behavioral integrity emphasizing on the characteristics of effective leaders has shown as direct action that strengthens positive consequences in organizations. However, research regarding behavioral integrity is very limited. Based on the Self-determination Theory, this paper investigates the effect of empowering leadership on employee's job satisfaction and work engagement. Multi-group analysis based on behavioral integrity is also analyzed. An online survey was conducted and 298 employees' data were collected. Using structural equation modeling, results suggest as follows. First, empowering leadership had a positive effect on individual's job satisfaction mediated by their work engagement. Second, the result of the multi-group analysis showed that the effect of empowering leadership on work engagement is stronger in the group with high behavioral integrity. Contrary to the prediction, the result doesn't support the moderating effect on job satisfaction. These findings contribute to our understanding of empowering leadership process. Based on the results, several theoretical and managerial implications are discussed.

Effect of Additives on Preparation of Silver Chloride Nanoparticles using AOT-Based W/O Microemulsions (AOT W/O 마이크로에멀젼을 이용한 AgCl 나노입자 제조에서 첨가제의 영향)

  • Jung, KilYong;Lim, JongChoo
    • Korean Chemical Engineering Research
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    • v.46 no.2
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    • pp.330-339
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    • 2008
  • Effect of additives such as NP series nonionic surfactant and cosurfactant on AgCl nanoparticles was investigated where nanoparticles were prepared using two different types of water-in-oil (W/O) microemulsions containing silver nitrate and sodium chloride, respectively. Phase behavior experiments showed that the region of one phase W/O microemulsion was found to be broadened with an increase in the ethylene oxide length of a nonionic surfactant mainly due to an increase in hydrophilic nature of a surfactant. Photomicrographs obtained by transmission electron microscopy indicated that an increase in ethylene oxide length of a nonionic surfactant results in both increases in particle size and size distribution. Phase behavior experiments for the systems containing AOT surfactant, isooctane and aqueous solution of an inorganic salt showed that addition of a cosurfactant caused a shrinkage in phase region of one phase W/O microemulsion, especially water contents contained in W/O microemulsion with an increase in the chain length or the concentration of a cosurfactant used. Photomicrographs obtained by transmission electron microscopy indicated that characteristics of AgCl nanoparticles produced were dependent both on the radius of spontaneous curvature and film rigidity of a microemulsion.

The Crystal and Molecular Structure of p-Phenylenediamine Dihydroperchlorate (p-Phenylenediamine Dihydroperchlorate의 결정 및 분자구조)

  • Ahn Choong Tai
    • Journal of the Korean Chemical Society
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    • v.21 no.5
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    • pp.320-329
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    • 1977
  • p-Phenylenediamine dihydroperchlorate, $C_6H_4N_2H_4{\cdot}2HC1O_4$, crystallizes in space group $P\={1}$ with $a=4.79{\pm}0.02,\;b=9.03{\pm}0.02,\;c=7.12{\pm}0.03{\AA},\;{\alpha}=109.4{\pm}0.2,\;{\beta}=79.6{\pm}0.2,\;r=104.6{\pm}0.2^{\circ},\;Z=1$. The structure has been solved by the Patterson and Fourier methods. The refinement by block-diagonal least-squares cycles gives R = 0.13 for 387 observed reflexions collected on equi-inclination Weissenberg photographs with CuK${\alpha}$ radiation. There are two different types of five hydrogen bonds. The first type consists of one trifurcated N${\cdot}{\cdot}{\cdot}$O hydrogen bond and the second of two normal N${\cdot}{\cdot}{\cdot}$O hydrogen bonds, both of which exist between the amino group and the perchlorate, groups. A p-phenylenediamine group is approximately planar within an experimental error and bonded to twelve perchlorates: ten perchlorates forming hydrogen bonds and two being contacted with the van der Waals forces. A perchlorate group is surrounded by six p-phenylenediamines and four perchlorates; among the six p-phenylenediamines, five of them are hydrogen-bonded, and the rest contacted with the van der Waals force.ce anaysis of our samples and investigated the variarions in the values of parameters obtained through fitting the theoretical impedance to the experimental impedance. The characters of the dielectric constant and the impedance showed abnormal variations for the 0.2 at K-doped NSBN ceramics, which we were able to interpret in terms of the variations in the number A-site vacancies with the K doping ratio. From these results, A-site vacancies are thought to be space charges that influence the ferroelectric properties of NSBN ceramics.

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