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Effect of Additives on Preparation of Silver Chloride Nanoparticles using AOT-Based W/O Microemulsions  

Jung, KilYong (Department of Chemical and Biochemical Engineering, Dongguk Univ.)
Lim, JongChoo (Department of Chemical and Biochemical Engineering, Dongguk Univ.)
Publication Information
Korean Chemical Engineering Research / v.46, no.2, 2008 , pp. 330-339 More about this Journal
Abstract
Effect of additives such as NP series nonionic surfactant and cosurfactant on AgCl nanoparticles was investigated where nanoparticles were prepared using two different types of water-in-oil (W/O) microemulsions containing silver nitrate and sodium chloride, respectively. Phase behavior experiments showed that the region of one phase W/O microemulsion was found to be broadened with an increase in the ethylene oxide length of a nonionic surfactant mainly due to an increase in hydrophilic nature of a surfactant. Photomicrographs obtained by transmission electron microscopy indicated that an increase in ethylene oxide length of a nonionic surfactant results in both increases in particle size and size distribution. Phase behavior experiments for the systems containing AOT surfactant, isooctane and aqueous solution of an inorganic salt showed that addition of a cosurfactant caused a shrinkage in phase region of one phase W/O microemulsion, especially water contents contained in W/O microemulsion with an increase in the chain length or the concentration of a cosurfactant used. Photomicrographs obtained by transmission electron microscopy indicated that characteristics of AgCl nanoparticles produced were dependent both on the radius of spontaneous curvature and film rigidity of a microemulsion.
Keywords
AgCl Nanoparticle; AOT; W/O Microemulsion; Nonionic Surfactant; Cosurfactant;
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Times Cited By KSCI : 5  (Citation Analysis)
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