• Korean Journal of Environmental Agriculture
• /
• v.12 no.1
• /
• pp.51-57
• /
• 1993

Objective of this research was to assess the influence of reaction time on the heavy metal-organic ligand complexation by employing kinetic models. Aqueous solutions of humic (HA) or fulvic acid (FA) were reacted with metal solutions with 1:1 ratio to form complexes. Efficiency of organic ligand on metal removal was determined by separating the precipitates from solution using $0.45\;{\mu}m$ filter paper. Complexation between Cu or Pb and HA or FA followed the first- or multiple first order kinetics, largely depending on metal concentration and kind of organic ligand. Amounts of precipitates were increased proportionally with reaction time but reached to quasiequilibrium where rate of precipitate formation was not varied with time. Copper-ligand complexation was, irrespective of ligand, fitted to the single first order kinetics at Cu concentrations lower than $300{\mu}M$, but this was fitted to the multiple first order kinetics at Cu concentrations higher than $300{\mu}M$. As increasing Cu concentrations, the precipitates formed more readily, judging from the increased rate constants (${\kappa}$). In the multiple first order kinetics, ${\kappa}$ was decreased as reaction steps proceeded. Most of Cu-ligand precipitates were formed within 15 min. FA precipitated Cu more rapidly than HA did. ${\kappa}$ for Pb-HA complexation was decreased but that for Pb-FA reaction was increased, as increasing Pb concentration. Most of Pb-organic ligand complexation occurred within 30 min. Afterwards, ${\kappa}$ values were relatively small and not affected much by time. Pb was precipitated by humic acid more readily than Cu when metal concnetrations were $200{\sim}300{\mu}M$. However, when metal concentrations were in the ranges of $400{\sim}500{\mu}M$, a reversed tendency was observed.

• Proceedings of the Korean Environmental Sciences Society Conference
• /
• 2002.05b
• /
• pp.422-425
• /
• 2002

Application of biostimulants, humate-based products marketed as aids to plant establishment, may increase root growth of turfgrass and maple tree. We tested three types of biostimulants on root growth of creeping bentgrass (Agrosfic palustris Huds.) and maple (Acer rubrum L.). Roots were first observed in the 2-3 weeks after treatments. Biostimulant-treated tufgrass and tree had more root length than nontreated controls. Turfgrass nutrient absorption was increased with biostimulant application.

• Journal of Industrial Technology
• /
• v.31 no.B
• /
• pp.127-132
• /
• 2011

Humic substances is accounted for for the largest proportion in natural organic matter(NOM) and NOM is widely distributed in varying concentration in all aquatic and soil. They can affect water quality adversely in several ways by contributing undesirable color, complexing with metal and yielding metal concentrations exceeding normal solubility. Ozonation is one of the efficient treatments for degradation of humic substances which cause some problems in water treatment. Especially, the combination of ozone and granular activated carbon was applied to degradation humic acid in aquatic system. The aim of this work to test the available of acid-treated granular activated carbon as catalyst in the ozonation of humic acid.

• Journal of Auto-vehicle Safety Association
• /
• v.7 no.2
• /
• pp.19-24
• /
• 2015

Ferritic Nitro Carburizing (FNC) cast iron brake discs is known to improve corrosion resistance and brake creep groan noise as well as prevent corrosion-induced pulsation. But, it is necessary to treat honing machining on braking surface to avoid grinding noise during braking.

• Korean Journal of Environment and Ecology
• /
• v.5 no.1
• /
• pp.68-78
• /
• 1991

To investigate edge vegetation structure and species in the Chrisan National Park, filed survey was excuted from August to October, 1991 and the results were as follows. Importance values of species in lower layer were changed according to the distance from edge to forest interior at the northeastern slope of a highland. Change of vegetation structure was observed from edge up to 30m of forest interior and edge depth was estimated as 15~20m. The dominance and frequency of edge species seemed to be affected by the factors of altitude, aspect and topographic location. Especially, edge vegetation showed severe difference according to topographic location between a ridge and a foot of a mountain, and according to aspect between southern and northern slope above midslope region of a mountain. Comparing vegetation structure of lower layer for southern and northern slope, more no. of individuals and crown coverage were observed at northern slope, while more no. of species, species diversity and coverage of Sasa purpurascen at southern slope.

• Analytical Science and Technology
• /
• v.22 no.2
• /
• pp.136-140
• /
• 2009

To improve the carbon recovery yield of chemical pretreatment in soil and sediment for $^{14}C$ age dating using AMS (Accelerator Mass Spectrometry), we have developed ultrasonic method in chemical pretreatment to replace with stirring method which has been generally used in each step of humic acid extraction for soil and sediment samples. Extraction conditions such as ultrasonic power, temperature and reaction time have been optimized. Six times higher carbon recovery yield could be obtained from low carbon content samples using ultrasonic method. We also compared the dating results by AMS obtained using ultrasonic method with the ages of samples treated by the stirring method. It was found that this new method could be applied to the pretreatment process of low carbon content samples for AMS age dating without effects on the dated ages, and with highly improved carbon recovery yields.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2018.06a
• /
• pp.66.1-66.1
• /
• 2018

최근 자동차 배기가스 규제 및 전기자동차, 무인항공기 개발 등의 경량 소재에 대한 필요성이 지속적으로 증가하고 있다. 마그네슘 및 마그네슘 합금은 구조용 금속 소재 중 가장 밀도가 낮은 금속으로서 자동차, 항공, 기계 부품류 및 주방용품이나 전자제품 케이스류 등 다양한 산업분야에서 활용성이 크게 증가하고 있다. 하지만 마그네슘 합금은 화학적 반응성이 매우 크고 표면에 존재하는 피막의 치밀성과 화학적 안정성이 낮아서 쉽게 부식되는 단점이 있다. 따라서 내식성 향상을 위한 표면처리 기술 개발에 대한 필요성이 증대되고 있다. 양극 산화법은 금속표면에 양극 전류를 인가하여 산화피막을 인위적으로 형성시켜줌으로써 내식성을 향상시켜 주는 방법으로서 산업적으로 널리 사용되고 있는 표면처리 방법 중의 하나이다. 본 연구에서는 주석산나트륨의 농도에 따른 AZ31 마그네슘 합금의 양극 산화 피막 형성 거동을 연구하였다. DC 전류를 인가하여 양극산화 피막을 형성하였으며, 피막형성 전압 및 형성된 피막의 두께, 표면 거칠기 및 피막의 구조 등을 분석하여 주석산나트륨 농도에 따른 양극산화 피막의 형성 특성에 대하여 자세하게 고찰하였다.

• Journal of Korean Society of Forest Science
• /
• v.87 no.2
• /
• pp.230-238
• /
• 1998

This study was conducted to compare the regeneration of the seedlings under different vegetation types and to identify the presence of allelopathy in Abies koreana(Ak) natural forest in Banyabong Peak(elevation, 1715m), of Mt. Chiri. Twenty quadrats($10m{\times}10m$) were placed in May, 1996 to classify vegetation structure using TWINSPAN. Water-soluble extracts from leaves and soil humus of different vegetation types were collected to test their effects on both seed germination of Ak and mycelial growth of ectomycorrhizal fungi. Phenolic compounds from soil humus were quantified using HPLC. Among the four vegetation types, Sasa borealis(Sb) was found in both Ak-Quercus mongolica(Qm) and Ak-Rhododendron schlippenbachii(Rs) communities. Natural seeding of Ak was $230,000{\pm}90,000seeds/ha$ in 1995 and their germination rate was 25% in an ideal laboratory condition. Density of Ak seedlings less than 5cm in height was 52,000/ha in 1996, while that of seedlings taller than 5cm in height was only 4,000/ha. In the case of Ak-Qm community, density of Ak seedlings with Sb understory was only 7% of the density of seedlings with Rs understary, suggesting the inhibitory effect of Sb. The germination rate of Ak seeds was significantly reduced by leaf extracts of Sb, and Rhododendron mucronulatum var. ciliatum(Rm) and Ak. Soil humus extract of Ak-Qm-Sb subcommunity reduced germination of Ak seeds by 81% and also reduced by 19% the respiration of mycelia of ectomycorrhizal fumgus, Lactarius sp. Among the seven phenolic compounds identified from the soil humus, extract, Ak-Qm-Sb subcommunity contained significantly high content of p-hydroxybenzoic acid, vanillic acid, and syringic acid. Particularly, p-hydroxybenzoic acid was present at 4.2ppm in the Sb roots and at 16.5ppm in the Sb humus, suggesting that it could be the primary allelopathic compound in Abies koreana forests with Sasa borealis understory.

• Journal of the korean academy of Pediatric Dentistry
• /
• v.29 no.4
• /
• pp.509-518
• /
• 2002

The purpose of this study was to evaluate the bonding of compomer to deciduous dentin which is known to have been developed to improve the weak properties of glass ionomer cement and composite resin. 120 sound primary molars were used for the shear bond strength test and another 24 for the scanning electron microscopic evaluation. Each material was ailed into polyethylene mold attached to exposed dentinal surface($3{\times}4mm$ in diameter) of sample blocks. Shearbond strength was measured using Universal testing machine and data were analyzed statistically with Oneway-ANOVA and Scheffe test. Scanning electron microscopic observation was performed in order to evaluate the pattern of distribution and penetration of resin tags and hybrid layer. Compomer groups(II-V) showed significantly higher bond strength values than glass ionomer group(I)(p<.05). Etching-compomer groups(III, V) showed the significantly higher bond strength than non-etching compomer groups(II, IV)(p<.05), but slightly lower values than composite resin group(VI) with no statistically significant difference(p>.05). No significantly different bond strength was found between compomer groups of different bonding system(p>.05). Scanning electron micrographs showed more irregular distribution of short and thin resin tags in non-etching compomer groups(II, IV) whereas the more regular and intimate distribution of long and thick tags in etching compomer groups(III, V) and composite resin group(VI). The evaluation of hybrid layer also showed more regular formation of thicker layer in etching compomer groups(III, V). Based on the results of present study, the use of compomer as an esthetic restorative material for primary molars might be justified.

• Korean Journal of Environment and Ecology
• /
• v.1 no.1
• /
• pp.35-45
• /
• 1987

To survey trail damage and vegetational change around trail at Bukhan Mountain National Park in Korea, field survey was executed over Bukhan mountain district during August, 1987. Trail damage was surveyed for he section of 7.18km from Ui valley to Jeongnung valley in which user's density was high. Ground vegetation was surveyed with a belt-transect method from trail edge to forest and edge species were surveyed with a belt method along trail edge. Interrelation between trail damage and user's density was not dear. Damage class II of trail showed 23.9% of the surveyed section and class III showed 8.0% and class II and III of natural trail showed 19.7% and those of facilitated trail showed 12.3%. The length of damage class II and III requiring readjustment were estimated as 3.65 km and 1.22km from the main trail course of 15.3km at Bukhan mountain district. In case of no intervention to forest by users, vegetational change around trails was appeared up to 6-8 m from trailside. But in case of intervention to forest by users, vegetational change was not coincident with the change of soil hardness and was diverse locally. Quercus mongolica, Lespedeza cyrtobotrya and Rbo-dodendron mucronulatum were appeared as Raunkiaer frequency class E, and Weigela subsessilis. Lespedeza maximowiczii, Rhododendron schlippenbachii and Sorbus alnifolid were appeared as class D at trail edge of ridge-Quercus mongolica was appeared as class E and Rhododenderon mucrounulatium. Stephanandra incisa were appeared as class D at trail edge of midslope. Rhododenron mucronulatum. Lespedeza maximowiczii and Stepanandra incisa were appeared as class D at trail edge of valley. Lespedeza cyrtobotrya. Lespedeza maximowiczii and Stephanandra incisa were appeared as class D at trail edge of valley beside motorway.