• Title/Summary/Keyword: 산화 안정성

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The influence of substrate temperature on the chemical stability of WO3Films prepared by electron beam deposition (기판온도가 전자비임으로 제작된 텅스텐 산화물박막의 화학적 안정성에 미치는 영향)

    • Journal of the Korean Vacuum Society
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    • v.5 no.4
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    • pp.365-370
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    • 1996
  • Electrochromic $WO_3$ films were prepared by using an electron-beam deposition method. The dependence of the chemical stability of film on the substrate temperature was studied. From the experimental results, The optical property and chemical stability of as-deposited films strongly depended on the substrate temperature. The $WO_3$ film prepared at a substrate temperature of $80^{\circ}C$ was found to be the most stable when subjected to repeated coloring and bleaching cycles in an organic 0.6M $LiClO_4$ solution.

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Lipid Oxidation and Antioxidant Changes in Perilla Seeds during Heating (가열에 의한 들깨의 지방질 산화와 산화방지제의 변화)

  • Wang, Seon-Yeong;Choe, Eun-Ok
    • Korean Journal of Food Science and Technology
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    • v.43 no.6
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    • pp.711-718
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    • 2011
  • Effects of heating conditions and seed roasting on the lipid oxidation and antioxidants of perilla seeds were studied. Perilla seeds, that were unroasted or roasted at $180^{\circ}C$ for 20 min, were ground and heated over steam at $100^{\circ}C/1$ atm or at $135^{\circ}C/2$ atm. Lipid oxidation was evaluated by peroxide value, conjugated dienoic acids contents, and fatty acid composition. Tocopherols and polyphenols were also determined. Lipid oxidation of perilla seeds was higher during heating at $135^{\circ}C/2$ atm than at $100^{\circ}C/1$ atm, and the oxidation rate was lower in unroasted seeds than in roasted seeds. Degradation of tocopherols and polyphenols in perilla seeds during heating was faster under high pressure and temperature, and was decreased by seed roasting. Contribution of polyphenols to the oxidative stability of perilla seeds during heating was higher than that of tocopherols, suggesting polyphenols and seed roasting as important factors in lipid oxidation of perilla seeds.

옻나무 첨가 급여기간이 한우육의 육질특성에 미치는 영향

  • Kim, Yong-Seon;Yang, Seong-Un;Kim, Dong-Uk;Gang, Seon-Mun;Lee, Seong-Gi
    • Proceedings of the Korean Society for Food Science of Animal Resources Conference
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    • 2004.05a
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    • pp.167-171
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    • 2004
  • 옻나무를 한우에 4%씩 출하(26개월령) 전 3, 4, 5, 6개월씩 급여시 육질의 육색과 지질 산화 안정성 및 품질특성 등에 미치는 영향을 분석한 결과, 4개월간 급여한 처리구가 다른 처리구들에 비해 밝고 선명한 적색을 저장기간 내내 유지하였으며 옻나무를 급여한 처리구들이 대조구에 비해 metmyoglobin 형성율이 지연되어 높은 육색안정성과 지질산화에 대해 안정성을 가지는 것으로 나타났다. 또한 MUFA/SFA과 oleic acid가 옻나무를 첨가급여한 처리구들에서 높게 나타나 소비자의 기호성에도 바람직한 결과를 얻을 수 있으리라 사료된다. 종합적으로 육색과 지질산화 및 보수력 측면에서 볼 때 옻나무 4%를 4개월간 첨가급여하는 것이 가장 바람직한 것을 알 수 있었다.

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Effect of the Formation of an Initial Oxide Layer on the Fabrication of the Porous Aluminium Oxide (초기 산화 피막의 형성이 다공성 알루미나 막 제작에 미치는 영향)

  • Park, Young-Ok;Kim, Chul-Sung;Kouh, Tae-Joon
    • Journal of the Korean Magnetics Society
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    • v.18 no.2
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    • pp.79-83
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    • 2008
  • We have investigated the effect of the formation of an initial oxide layer on the fabrication of the porous aluminium oxide. The porous aluminium oxide was fabricated by two-step anodization process with a electropolished aluminium foil. Before the first anodization step, the initial oxide layer with thickness of 10 nm was formed under the applied voltage of 1 V and later the anodization was continued under 40 V using oxalic acid solution. With the formation of the initial oxide layer, the anodization process was stable and the anodization current was constant throughout the process. In case of the absence of the initial oxide layer, the anodization was very unstable and the continuous increase in the anodization current was observed. This indicates the formation of the initial oxide layer on the aluminium surface prevents the burning of the surface due to the nonuniform distribution of the applied electric field, and allows the stable anodization process required for the porous aluminium oxide.

A Study of $\beta$-Amylase Modified $IO_4$-Oxidized Starch -Effects of $\alpha$-Cyclodextrin- ($IO_4$-산화 전분 변형 $\beta$-아밀라아제의 안정성 및 $\alpha$-Cyclodextrin의 영향)

  • 안용근;남포능지
    • The Korean Journal of Food And Nutrition
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    • v.11 no.2
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    • pp.159-164
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    • 1998
  • pH stability of sweet potato $\beta$-amylase modified with IO4-oxidized soluble starch was increased at pH 3, 5~9 and 11. And optimum pH was 3 and 5 for modification. Thermal stability of the enzyme modified with IO4-oxidized soluble starch was increased at 6$0^{\circ}C$ for 15 min. pH stability of barley $\beta$-amylase modified with IO4-oxidized soluble starch was increased at 3~4 and 8~11, and more increased at pH 3 and 8~11 in the presence of $\alpha$-cyclodextrin.

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Hydrocarbon Composite Membranes with Improved Oxidative Stability for PEMFC (산화안정성 향상을 위한 고분자연료전지용 탄화수소복합막의 제조 및 특성연구)

  • Lee, Hyejin;Choi, Young-Woo;Yang, Tae-Hyun;Bae, Byungchan
    • Journal of the Korean Electrochemical Society
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    • v.17 no.1
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    • pp.44-48
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    • 2014
  • Sulfonated poly(arylene ether sulfone)-cerium composite membranes with improved oxidative stability were prepared for proton exchange membrane fuel cell application. Oxidative stability of the composite membranes changed depending on the amount of incorporated metal. Their water uptake, IEC and proton conductivity were also affected. ICP analysis confirmed trace of cerium ion in the composite membranes and $^1H$-NMR indicated successful coordination of sulfonic acid groups with the metal ions. Increasing amount of the cerium ion resulted in decrease in proton conductivities and water uptake, but enhanced oxidative stabilities. A hydrogen peroxide exposure equipment was used for the test of oxidative stability of the composite membranes, which enabled to mimic fuel cell operating condition compared with conventional Fenton's test.

Characteristics of browning Materials in Perilla Oil and Change of Oxidative Stability of Blended Perilla Oil (들기름에 존재하는 갈색물질의 특성과 혼합 들기름의 산화 안정성 변화)

  • 김영언;김인환;이영철
    • The Korean Journal of Food And Nutrition
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    • v.9 no.4
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    • pp.504-508
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    • 1996
  • This study was performed to investigate the browning intensity and electron donating ability of browning material in perilla oils from seeds roasted at 150~21$0^{\circ}C$ for 10~30 min. It was also investigated the oxidative stability of the blended perilla oil on the basis of sensory property and oxidative stability. The browning intensity in perilla oil increased with the roasting temperature and time increased. The browning intensity of perilla oil from seed roasted at 21$0^{\circ}C$ for 30 min indicated 13 times higher than that of perilla oil from seed at 15$0^{\circ}C$ for 10 min. Electron donating ability on DPPH of browning materials presented in perilla oils increased with the roasting temperature and time increased. The electron donating ability of browning materials in perilla oil from seed reasted at 21$0^{\circ}C$ for 30 min indicated 3 times higher than those of perilla oil from seed at 15$0^{\circ}C$ for 10 min. In conclusion, for the improvement of oxidative stability of perilla oil, perilla seed should be roasted at 21$0^{\circ}C$ for 30 min. These results suggest that browning materials formed between sugars and amino acids attribute to improve quality of oil such as sensory properties and oxidative stabilities. For the improvement of sensory property and oxidative stability of oil, perilla oil from seed roasted at 19$0^{\circ}C$ for 20 min was blended with the oil from seed roasted at 21$0^{\circ}C$ for 30 min as ratio of 85 : 15.

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Tin-silver Electroplating Solution Containing Environment-friendly Antioxidants for Solder Bump (친환경 산화방지제를 함유하는 솔더범프용 주석-은 전기도금액)

  • Go, Jeong-U;Lee, Hyeong-Geun;Kim, Gyeong-Tae;Park, Gyu-Bin;Son, Jin-Ho;O, Jeong-Hun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.11a
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    • pp.285-286
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    • 2015
  • 반도체 패키지 솔더범프용 주석계 도금액에 적용 가능한, 친환경 산화방지제 몇 종에 대하여 연구하였다. 주석계 전기도금액에 포함된 산화방지제는 주석의 산화방지 외에도, 전류효율, 도금액의 안정성, 그리고 형성된 솔더범프의 특성 등에 영향이 있음을 확인 하였다.

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Chemical Stability of The Electrochromic Tungsten oxide Thin Films (전기적 착색 텅스텐 산화물 박막의 화학적 안정성)

  • Lee, G.D.
    • Solar Energy
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    • v.16 no.2
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    • pp.87-96
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    • 1996
  • Electochromic tungsten oxide thin films were prepared on the ITO coated glass by rf magnetron sputtering from a compressed powder tungsten oxide target in an argonoxygen atmosphere. The influence of the preparation conditions, especially the substrate temperature, on the chemical stability of film was investigated. These films were cycled in 0.6M $LiClO_4$ and 0.6M $H_2SO_4$ electrolyte respecitively, and exhibited electrochromic behavior upon the electrochemical insertion and extraction of ion. Among these tungsten oxide thin films, films prepared at a substrate temperature of $150^{\circ}C$ were found to be most stable in terms of cyclic durability.

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감마선조사 생약재(H-113)의 산화적 생체손상 억제효과 안정성 평가

  • Oh, Heon;Jung, Woo-Hee;Jung, Il-Yoon;Cheon, Eui-Hyun;Cho, Sung-Ki
    • Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
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    • 2003.04a
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    • pp.103.1-103
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    • 2003
  • 건조 생약재의 위생화 수단으로 방사선 조사 기술의 적용 가능성을 검토하기 위하여 감마선 조사 생약의 효능 변화유무를 평가하고자 하였다. 본 연구에서는 감마선 조사 시료와 비조사 시료가 생체의 산화적 손상을 억제하는 효과를 비교하기 위하여 방사선에 의한 산화적 손상에 대한 효과를 측정하였다. 감마선 조사(10 kGy) 생약재(H-113) 및 비조사 생약재(H-113) 추출물을 처리하여 배양한 사람 림프구에 방사선을 조사한 후, 단세포전기영동(single-cell gel electrophoresis, SCGE; comet assay)을 수행하여 DNA 상해 경감정도를 관찰하였다. 또한 방사선 조사 및 비조사 생약재(H-113) 추출물을 투여한 생쥐에 8 Gy의 감마선을 조사한 후, 간에서 지질과산화 정도를 비교·관찰하였다. 한편 DPPH 라디칼과 hydroxyl 라디칼 소거효과를 시험관내에서 상호 비교하였다. 감마선 조사 생약재(H-113)는 단세포전기영동, 지질과산화, DPPH 및 hydroxyl 라디칼 소거시험에서 비조사 생약재 (H-113)와 유사한 효과를 나타내어 효능 차이가 인정되지 않았다. 이는 생약재의 여러 가지 고유 효능 중 일부의 안정성을 확인한 것으로 생각되며, 이러한 결과를 바탕으로 감마선 조사 생약재의 고유 효능의 안정성에 관한 체계적인 연구결과를 얻는다면 생약재의 위생화 수단으로 감마선 조사 기술의 이용이 실용화될 수 있을 것으로 사료된다.

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