• Journal of Korean Society of Environmental Engineers
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• v.33 no.4
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• pp.289-299
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• 2011

We studied the characteristics of pollutant concentrations in 9 streams that flow into Shihwa Lake in order to provide the scientific data for effective implementation of total pollution loads management system (TPLMS) of the Lake. Suspended solid (SS), chemical oxygen demand (COD), dissolved nutrients ($NO_2$, $NO_3$, $NH_4$, $PO_4$ and $SiO_2$), total phosphorus (TP) and total nitrogen (TN) in stream water from industrial complexes, urban and agricultural regions were determined. Pollutant concentrations in December were higher than that in other sampling periods. COD concentration from industrial complex region with average of 12.6 mg/L was 2 times higher those from urban region (6.6 mg/L) and agricultural region (5.9 mg/L). TP concentration from industrial region also showed higher concentration than other regions. TN concentration in stream water was 5.89 mg/L for industrial region, 3.02 mg/L for urban region and 5.27 mg/L for agricultural region, respectively, suggesting inflow of TN due to fertilizer usage in agricultural field. Relative percentage of nitrogen compounds in TN follows the sequence: $NH_4$ (35.1%) > $NO_2$ (20.0%) > DON (22.8%) > PON (8.9%) > $NO_2$ (3.2%). Concentrations of dissolved nutrients, TP and TN in stream water were 3.2~37.2 times higher than that in Shihwa Lake seawater, therefore large amount of pollutants may be directly entered into Shihwa Lake without any treatment. For Gunja stream of industrial region, pollutants at midstream showed relatively higher concentration compared to upstream and downstream. It is necessary to manage the illegal discharging of sewage and waste water. Our results provide valuable informations on the estimation and reduction of total pollutant loads in the process of establishing adequately strategic and implemental plan of Shihwa Lake TPLMS.

• Korean Journal of Ecology and Environment
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• v.38 no.3 s.113
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• pp.341-351
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• 2005

Ecological stream health, based on the index of biological integrity (IBI) , was evaluated at five sampling locations of Youdeung Stream during August-October 2004. For the study, we also analyzed spatial and temporal patterns of conventional water quality over tine period of 1995 ${\sim}$ 2004, using the water chemistry dataset, obtained from the Ministry of Environment, Korea. The water quality parameters used here were conductivity, total suspended solids (TSS), biochemical oxygen demand $(BOD_5)$, chemical oxygen demand $(COD_{mn})$, total nitrogen (TN), and total phosphorus (TP). The multi-metric model values averaged 27.8 in the stream and ranged 24 ${\sim}$ 32. The health condition was judged as 'Fair' to 'Poor' conditions, according to the stream health criteria of US EPA (1993). Longitudinal variation occurred from the upstream to downstream reach; largest differences in all water quality variables occurred between Site 5 and the other sites. This was mainly attributed to the impacts of wastewater treatment plants near the locations. Also, relative proportions of tolerance and omnivore species increased in downstream reaches. The model values, however, did not match the values, based on water quality parameters. We assume that this may be associated with primarily reduced water volumn during dry season in the stream along with modified physical habitat conditions.

• Korean Journal of Ecology and Environment
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• v.38 no.3 s.113
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• pp.361-371
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• 2005

The objective of study was to diagnose integrative ecological health of Daejeon Stream, one of the tributaries of Guem River, during May 2004 ${\sim}$ April 2005. The research approach was primarily based on a Qualitative Habitat Evaluation Index (QHEI) and the Index of Biological Integrity (IBI) using fish assemblage. These outcomes were compared with conventional chemical dataset. For the experiment, four sampling sites were chosen from Daejeon Stream and long-term water quality data during 1995 ${\sim}$ 2004 (obtained from the Ministry of Environment) were analyzed in the spatial and temporal aspects. For the biological health assessment, we developed a stream health assessment model (SHA model) far regional applications. We found that current water quality conditions, based on the COD, BOD, TN and TP, were enhanced by 1.6 ${\sim}$ 5.3 fold over the period of 1995 ${\sim}$ 2004 and that the parameters showed a typical longitudinal decline from the upstream to downstream reach. The differences of water quality between the two reaches were more than 4.4 times, indicating a large spatial variations within the stream. The health conditions, based on the SHA model, averaged 23 and varied from 20 to 26 depending on the sampling stations. Values of the QHEI varied from 39 (Poor condition) to 124 (Cood condition)and values of QHEI in the reach of S2 ${\sim}$ S4 had significantly lower than in the headwater site (S1). Also, biological stream health, based on the criteria of US EPA (1993), was judged as 'Poor condition', in the S4 where TN, TP, BOD and COD were highest. In the meantime, maximum value of SHA (26) was found in the upstream reach (S1) where the water quality and QHEI were best. We also found that compositions of sensitive species showed a linear function with water quality conditions and this pattern was evident in the tolerant species. Thus, the biological stream health, based on the SHA model, matched well water chemistry. Overall outcomes suggest that the biological health impact was a function of chemical degradation and physical habitat quality in the stream.

• Economic and Environmental Geology
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• v.35 no.1
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• pp.43-54
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• 2002

The Chonju and Samchun streams are palling though Chonju City and several contamination sources are located along these streams. The Samchun stream joins the Chonju stream in the Gosapyeong waste disposal site and the Chonju stream finally joint to the Mankyeong River. The Chonju and Samchun streams are now contaminated with BOD, COD, T-N and T-P and the amounts of each contamination are increasing from upper stream to downstream. At the downstream the amounts of COD. T-N.T-P are several times higher than fifth grade of water quality thor lacustrine. Sewage from Chonju provides BOD, COD,T-N and T-P into the Chonju and Samchun streams and Chonju Waste Water Treatment Plant il a main source of COD, T-N and T-P contamination. Gosapyeong waste disposal site may be the source of BOD and COD contamination. T-N is higher than fifth grade of water quality for lacustrine at the upper stream indicationg that the rivers are contaminated with T-N before inflowing into Chonju by agricultural activity. The Chonju stream asffects the contamination of the Mankyeong river with BOD. COD, T-N,T-P. Other branch steams of the Mankyeong river also affects the contamination of the Mankyeong river by BOD, COD, T-N and T-P, Among the branch streams, the Ikasn stream is a main contamination source. Amounts of concentrations inflowing from the Chonju and Sanchun Streams on Aug. 1999 are calculated by using yeasured flow rate find concentrations of contaminants The result are as fikkiws; 1) the amounts of influent from the Gosan Stream are 0.49, 0.86, 1.61 and 0.01 ton/day for BOD, COD, T-N and T-P, respectively, 2) compared to the amounts of influent from the Gosan Stream, BOD, COD,T-N,T-P supplied from the Chonju river are higher by about 5, 7, 7. 36 times, respectively, and those supplied from the Iksan stream are higher by about 13, 10, 10, 147 times, respectively.

• Korean Journal of Ecology and Environment
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• v.39 no.2 s.116
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• pp.198-208
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• 2006

This research was to apply a multi-metric approach, so called the Index of Biological Integrity (IBI) as a tool for biological evaluations of water environments, to a wadable stream. For the study, we surveyed 5 sampling locations in Kap Stream during August 2004 ${\sim}$ September 2005. We also compared the biological data with long-term water quality data, obtained from the Ministry of Environment, Korea and physical habitat conditions based on the Quantitative Habitat Evaluation Index (QHEI). We used ten metric systems for the IBI model to evaluate biological stream health. Overall IBI values in Kap Stream averaged 24 (range: 20${\sim}$30, n=5), indicating a "fair ${\sim}$ poor" conditions according to the modified criteria of Karr (1981) and US EPA(1993). Exclusive of 4th survey, average IBI values at the upstream reach (S1 ${\sim}$ S3)and downstream reach (S4 ${\sim}$ S5) were 20 and 24, respectively. However, in 4th survey the averages were 21 and 20 in the upstream and downstream reaches, respectively. This difference was larger in the upstream than in the downstream because of physical condition disturbed during summer monsoon. Values of the QHEI varied from 75(fair condition) to 148 (good condition) and values of QHEI in the S3 were significantly (P=0.001, n=5) lower than other sites. Biochemical oxygen demand (BOD), chemical oxygen demand (COD), total nitrogen (TN) and total phosphorus (TP) were greater by 3 ${\sim}$ 8 fold in the downstream than in the upstream reach. We believe that present IBI approach applied in this study may be used as a key tool to set up specific goals for restoration of Kap Stream.

• Korean journal of applied entomology
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• v.54 no.1
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• pp.17-23
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• 2015

A complete control on quarantine insect pests is required for exporting domestic apples to other countries. To this end, a controlled atmosphere and heat treatment system (CATTS) has been developed as a post-harvest treatment. This study determined the CATTS conditions to control completely two lepidopteran insect pests, the smaller tea tortrix moth, Adoxophyes paraorana and the peach pyralid moth, Dichocrocis punctiferalis, which exhibit different feeding behviors. In both species, the fifth instar larvae were the most tolerant developmental stage to the heat treatment. Under CATTS conditions with 15% $CO_2$ and 1% $O_2$ for 1 h heat treatment at $46^{\circ}C$, the fifth instar larvae of A. paraorana exhibited a complete lethality, while those of D. punctiferalis underwent 88% mortality. To control completely the fifth instar larvae of D. punctiferalis, 2 h heat treatment required under the same atmosphere condition. These CATTS treatment effects were confirmed against over 3,000 fifth instar larvae of each species infesting apples. This study demonstrates that the longer exposure to CATTS conditions is required for the complete disinfestation of the internal apple feeder compared to the non-internal apple feeder.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.15 no.2
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• pp.43-47
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• 2009

Respiration and quality of persimmon fruits were monitored through the storage at 0, 5, 15 and $25^{\circ}C$. Respiration rate data at different temperatures were used for determining the $O_2$ and $CO_2$ permeabilities required to maintain the optimal package atmosphere (1~3% $O_2$, 4~7% $CO_2$). The estimated gas permeabilities were then compared to those of available plastic films for examining their potential application at various temperature conditions. $O_2$ consumption and $CO_2$ production were at similar order and leveled at stable value after initial time span with higher rates measured at higher temperatures. Major quality indexes during storage were observed to be ascorbic acid content change and firmness destruction with the most significant changes at $25^{\circ}C$ Higher $O_2$ and $CO_2$ permeabilites were required at higher temperatures, and common plastic films were shown to be unable to satisfy those requirements. Films or devices of high permeation property such as silicone rubber or microporous film may be combined to increase the permeation properties satisfying the required high gas permeabilities.

• Membrane Journal
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• v.27 no.2
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• pp.154-166
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• 2017

Polymeric films for gas barrier applications such as food packaging and electronic devices have attracted great interest due to their cheap, light and easy processability among gas barrier materials. Especially in electronic devices, extremely low gas permeance is necessary for maintaining the device performance. However, current polymeric barrier films still suffer from relatively high gas permeance than other materials. Therefore, there have been strong needs to enhance the gas barrier performance of polymeric barrier films while keep their own advantages. Recently, graphene is highlighted as a 2D-layered material for gas barrier applications. However, owing to the poor workability and difficulty to produce in engineering scale, graphene oxide (GO) is on the rise. GO consists of oxygen-containing functional groups on surface with intrinsic 2D-layered structure and high aspect ratio, and it can be well-dispersed in aqueous polar solvents like water, resulting in scalable mass production. Here, we prepared GO incorporated polyimide (PI) nanocomposites. PI is widely used barrier polymer with high mechanical strength and thermal and chemical stability. We demonstrated that PI/GO nanocomposites could perform as a gas barrier. Furthermore, surfactants (Triton X-100 (TX) and Sodium deoxycholate (SDC)) are introduced to enhance the gas barrier performance by improving the degree of dispersion of GO in PI matrix. As a result, TX enhanced the gas barrier performance of PI/GO nanocomposites which is similar to predicted value. This finding will provide new insight to polymer nanocomposites for gas barrier applications.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.210-210
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• 2013

그래핀은 뛰어난 기계적, 화학적, 광학적, 전기적 특성을 가지고 있는 2차원 물질로, 대면적 합성법과 전사 공정을 통해 다양한 기판에서의 사용이 가능해지면서 차세대 전자 소자로 활용하기위한 활발한 연구가 이루어지고 있다. 디스플레이, 태양전지의 전극과 전계 효과 트랜지스터의 채널로 적용한 연구에서 우수한 결과들을 보이고 있다. 특히, 금속/금속 산화물 전극은 염료 감응형 태양전지와 유기 발광 다이오드 구조에서 화학적으로 불안정할 뿐 아니라 일함수가 고정되어 쇼트키 접촉이 형성되면 저항을 낮추기 어렵지만, 그래핀은 금속/금속 산화물 전극보다 화학적으로 안정하고 일함수의 조절이 가능해 옴 접촉 형성에 용이하다. 그래핀의 일함수를 조절하는 연구는 크게 공유결합과 비공유 결합을 이용한 방법이 시도된다. 공유 결합을 이용한 방법은 합성과정에서 그래핀의 구조에 내재된 결함 혹은 새로운 결함을 형성하여 다른 원소를 첨가하는 방법이다. 이러한 방법은 그래핀의 결함 영역에서 작용하기 때문에 그래핀 전자 구조의 높은 수준 조절을 위해선 그래핀 구조의 파괴가 동반된다. 반면, 비공유 결합을 이용한 방법은 전하 이동 도핑 효과를 이용해 그래핀의 전자 구조를 제어하는 방법으로, 금속/금속산화물/기능기와 그래핀의 적층으로 복합 구조를 형성하는 방법이다. 금속/금속 산화물과의 복합구조는 안정적인 p-형 도핑이 보고되었지만, n-형 도핑은 대기중의 수분, 산소 그리고 기판과의 상호작용에 의해 대기중에서 불안정해 추가적인 피막공정이 요구된다. 기능기를 이용한 적층 구조는 그래핀과 기판사이의 상호작용 혹은 그래핀 전자 구조를 다양한 기능기를 이용해 제어하는 것으로, 이극성을 가진 자기정렬 단일층(self-assembled monolayers)이 대표적인 방법이다. 공간기(spacer)의 길이나 말단기(end group)의 종류로 p-형과 n-형의 도핑 수준을 제어할 수 있지만, 흡착기(chemisorbing groups)의 반응성이 기판의 화학적, 물리적 표면상태에 의존하기때문에 기판 선택이 제약되며 전처리 공정이 요구될 수 있는 한계가 있다. 본 연구에서는 다양한 기판에 적용가능한 용액 공정을 이용해 그래핀과 고분자를 적층하였고, 안정적이고 효과적으로 일함수를 낮추는 구조를 확인하였다.

• Journal of the KSME
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• v.21 no.1
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• pp.21-31
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• 1981

원자력발전소의 원자로냉각재 압력경계의 건전성과 안정성을 확보하기 위하여 법적 요구조건을 설정함에 있어 파괴역학이 어떻게 적용되었는 가를 설명하였다. 이를 요약하면 다음과 같다. 1) 압력경계에 사용되는 재료의 $RT_{NDT}$를 정의하였다. 이는 무연성천이온도와 같은 개 념의 것으로, 앞으로 재료의 파괴인성은 이 $RT_{NDT}$에 대한 상대온도의 함수로 주어진다. 2)비연성파괴를 방지하기 위한 설계조건으로서 선형탄성 파괴역학에 근거한 조건식을 인용하였다. 여기서 조건식이란 능력확대계수의 합계가 어떠한 조건에서도 이러한 조건식을 만족한다는 것을 해석적으로 확인하고 규제당국의 승인을 받아야 한다. 3) 가동중검사에 발견된 결함으로 합격수준을 초과하는 것은 파괴역학적으로 해석하여 구조적 으로 안전하다는 것은 파괴역학적으로 해석하여 구조적으로 안전하다는 것을 입증하여야 한다. 이때 결함은 원자로의 가동과 더불어 성장하므로 수명기간중 피로파괴에 이를 것인지의 여부도 평가하여야 한다. 이때의 대조균열성장률은 Paris의 power law에 따른다. 4) 고속중성자 (E>1. 0MeV)에 의한 조사취화를 감시하기 위하여 감시시험계획을 사전에 수립 하고 이에 따라 감시시험을 수행하여 조사에 수립하고 이에 따라 감시시험을 수행하여 조사에 의한 원자로용기 재료의 파괴인성의 저하를 평가하여 이를 고려한 충분한 안전여유를 갖는 운 전조건 즉, 압력-온도 한계곡선을 산출하여야 한다. 이때의 취화 정도는 DELTA. $RT_{NDT}$ 와 Upper Shelf Energy의 감소로 나타낸다. 또한, 압력-온도 한계곡선은 선형관성 파괴역학에 입각한 조건식을 이용하여 해당 온도에서의 압력을 산출한다. System을 개발 사용하기 위하여 기존 전자계산소를 이용하는 방법이 바람직하며 System의 도입은 자체운영을 결정하기 전에 경제적인 여건 등 여러가지 문제를 검토하여야 한다. 특히 Turn Key Base로 System를 도입할 경우에는 System의 도입목 적과 사용빈도, 앞으로의 확장성 현재 설계및 생산 과정과의 마찰가능성, 유지보수문제 등을 신 중히 검토하여야 한다. 이제 기계공업도 전자계산기를 이해하고 사용하므로 서 발전할 수 있는 단계가 되었다. 예로부터 좋은 공구를 개발하여 적절히 사용하는 것이 기계공업 발전의 첩경이 었다. 전자계산기는 현대 기술이 개발한 가장 강력하고 사용하기 좋은 공구이다.점에서 피로구열의 안정성장을 논하고, 과거 10여년간의 피로 crack문제에 대한 연구방법, 실험방법 등을 소개하는 방향으로 고 를 진행시켜 나가겠다.에 그 효과가 증대됨을 알 수 있었다.적용한 임상실험이 수행되어야 할 것이다. 또한 위치결정에서 획득한 좌표값의 정확성을 알아보기 위해서 팬톰을 이용한 방사선조사 실험이 추후에 실행되어져야 할 것이다. 그리고 제작된 프레임에 Rotating X선 시스템과 내부 장기의 움직임을 계량화하고 PTV에서의 최적 여유폭을 설정함으로써 정위 방사선수술 및 3 차원 업체 방사선치료에 대한 병소 위치측정과 환자의 자세에 대한 setup 오차측정 결정에 도움이 될 수 있을 것이라고 사료된다. 상대적으로 우수한 것으로 나타났으며, 혼합충전재는 암모니아의 경우 코코넛과 펄라이트의 비율이 7：3인 혼합 재료 3번과 소나무수피와 펄라이트의 비율이 7：3인 혼합 재료 6번에서 다른 혼합 재료에 비하여 우수한 것으로 나타났다. 4. 코코넛과 소나무수피의 경우 암모니아 가스에 대한 흡착 능력은 거의 비슷한 것으로 사료되며,