• Title/Summary/Keyword: 사용후연료

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Optimum Mix of Extrusion panel Using Low Energy Curing Admixture (LA) based on Ground Granulated Blast-Furnace Slag and Ladle Furnace Slag (고로슬래그와 환원슬래그를 기반으로 한 저에너지양생용 결합재를 사용한 압출성형패널의 최적배합)

  • Kim, Ha-Seog;Baek, Dae-Hyun;Lee, Sea-Hyun
    • Resources Recycling
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    • v.24 no.2
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    • pp.13-22
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    • 2015
  • $CO_2$ emitted from building materials and construction materials industry reaches about 67 million tons, which occupy about 30 % of $CO_2$ emitted from the construction field. Controls on the use of consumed fossil fuels and reduction of emission gases are essential for the reduction of $CO_2$ in the construction area as we reduce the second and third curing to emit $CO_2$ in the construction materials industry. Accordingly, this study applied the low energy curing admixture (hereinafter "LA") to the extruded panels to observe the physical properties, depending on the mixing amount of fiber, type of fiber and mixing ratio of fiber. The type of fiber did not appear to be a main factor to affect strength, while the LA mixing ratio and mixing amount of fiber appeared to be major factors to affect strength. Especially, the highest strength was developed when the LA mixing ratio was 40%, whereas the test object with the mixing ratio of 50% resulted in the decrease of strength. In addition, it appeared that the mixing ratio of fiber greatly affected flexural strength and strength increased as the mixing ratio increased.

Influence of Charging Condition of Al-dross on Maximum Concentration of Al in Molten Steel : Fundamental study for improvement of chemical energy in EAF process (용강 중 Al 최대 농도에 대한 Al 드로스 장입 조건의 영향: 전기로 공정 내 화학 에너지 향상을 위한 기반 연구)

  • Kim, Gyu-Wan;Kim, Sun-Joong
    • Resources Recycling
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    • v.28 no.4
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    • pp.44-50
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    • 2019
  • In the electric arc furnace process, the chemical energy such as the heat of oxidation reaction and the heat of carbon combustion etc. is consumed as 30% of the total input energy. In order to reduce $CO_2$ emission in EAF, it is necessary to decrease the use of electric power energy during scrap melting stage and increase the use of chemical energy. In general, when the carbon materials is individually charged into the molten steel, the carbon materials floated to the slag layer due to low density before it is dissolved in molten steel. When the concentration of carbon in the molten steel is high, the combustion energy of carbon by oxygen injection can lower the electric power energy and improve the chemical energy consumption. Therefore, an efficient charging methods of carbon material is required to increase the efficiency of carbon combustion heat. On the other hand, Al-dross, which is known as a by-product after Al smelting, includes over 25 mass% of metallic Al, and the oxidation heats of Al is lager than that of carbon. However, the recycling ratio fo Al-dross was very low and is almost landfilled. In order to effectively utilize the heats of oxidation of Al in Al-dross, it is necessary to study the application of Al-dross in the steel process. In this study, the dissolution efficiency of carbon and aluminum in molten steel was investigated by varying the reaction temperature and the mixing ratios of coke and Al-dross.

Research Trend on Precious Metal-Based Catalysts for the Anode in Polymer Electrolyte Membrane Water Splitting (고분자 전해질막 수전해의 산화 전극용 귀금속 촉매의 연구 동향)

  • Bu, Jong Chan;Jung, Won Suk;Lim, Da Bin;Shim, Yu-Jin;Cho, Hyun-Seok
    • Journal of the Korean Electrochemical Society
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    • v.25 no.4
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    • pp.154-161
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    • 2022
  • The carbon-neutrality induced by the global warming is important for the modern society. Hydrogen has been received the attention as a new energy source to replace the fossil fuels. Polymer electrolyte membrane fuel cells, which convert the chemical reaction energy of hydrogen into electric power directly, are a type of eco-friendly power for future vehicles. Due to the sluggish oxygen reduction reaction and costly Pt catalyst in the cathode, the research related to the replacement of Pt-based catalysts has been vitally carried out. In this case, however, the performance is significantly different from each other and a variety of factors have existed. In this review paper, we rearrange and summarize relevant papers published within 5 years approximately. The selection of precursors, synthesis method, and co-catalyst are represented as a core factor, while the necessity of research for the further enhancement of activity may be raised. It can be anticipated to contribute to the replacement of precious metal catalysts in the various fields of study. The final objective of the future research is depicted in detail.

The Current Status of Recycling Process and Problems of Recycling according to the Packaging Waste of Korea (국내 포장 폐기물에 따른 재질별 재활용 공정 현황 및 재활용 문제점)

  • Ko, Euisuk;Shim, Woncheol;Lee, Hakrae;Kang, Wookgeon;Shin, Jihyeon;Kwon, Ohcheol;Kim, Jaineung
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.24 no.2
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    • pp.65-71
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    • 2018
  • Paper packs, glass bottles, metal cans, and plastic materials are classified according to packaging material recycling groups that are Extended Producer Responsibility (EPR). In the case of waste paper pack, the compressed cartons are dissociated to separate polyethylene films and other foreign substance, and then these are washed, pulverized and dried to produce toilet paper. Glass bottle for recycling is provided to the bottle manufacturers after the process of collecting the waste glass bottle, removing the foreign substance, sorting by color, crushing, raw materializing process. Waste glass recycling technology of Korea is largely manual, except for removal of metal components and low specific gravity materials. Metal can is classified into iron and aluminum cans through an automatic sorting machine, compressed, and reproduced as iron and aluminum through a blast furnace. In the case of composite plastic material, the selected compressed product is crushed and then recycled through melt molding and refined products are produced through solid fuel manufacturing steps through emulsification and compression molding through pyrolysis. In the recycling process of paper packs, glass bottles, metal cans, and plastic materials, the influx of recycled materials and other substances interferes with the recycling process and increases the recycling cost and time. Therefore, the government needs to improve the legal system which is necessary to use materials and structure that are easy to recycle from the design stage of products or packaging materials.

Trace Element Analysis and Source Assessment of Household Dust in Daegu, Korea (대구지역 일반주택의 축적먼지 중 미량원소성분 분석과 오염원 평가)

  • Do, Hwa-Seok;Song, Hee-Bong;Jung, Yeoun-Wook;Yoon, Ho-Suk;Kwak, Jin-Hee;Han, Jeong-Uk;Kang, Hye-Jung;Phee, Young-Gyu
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.1
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    • pp.69-78
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    • 2010
  • In order to investigate the degree of household dust contamination, 48 samples of household dust (24 from urban area and 24 from rural area) in Daegu city were collected in vacuum cleaner during January to February 2009. Samples were sieved below 100 ${\mu}m$, and 14 elements (Al, Ca, Cd, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, V, Zn) were analyzed using ICP after acid extraction. Results obtained from the source assessment of trace elements using enrichment factor showed that Ca, Fe, K, Mg, Mn, Na, and V were influenced by natural sources such as weathered rock and resuspended soil, while Cd, Cr, Cu, Ni, Pb and Zn were influenced by anthropogenic sources such as fuel combustion and waste incineration. Concentrations were remarkably higher in components from natural sources than in components from urban anthropogenic sources. Household dust in urban area was more affected by anthropogenic sources compared with that of rural area. Pollution index of heavy metals revealed that urban area was 1.8 times more contaminated with heavy metal components than rural area. The correlation analysis among trace elements indicated that components were correlated with natural sources-natural sources (Al-Mg, Al-Mn, Fe-Mn) and natural sources-anthropogenic sources (Al-V, Fe-Cr, V-Mn) in both urban area and rural area. Trace element components of rural area were more correlated than those of urban area. Houses that use oil for heating fuel had relatively higher contents of heavy metals rather than those using gas or electricity for heating fuel. Houses with children also had higher contents of heavy metals. In addition, the age of houses was found to influence the heavy metal levels in household dusts, with older houses (>10years) having higher concentrations than newer houses (<10years) and houses located near the major road (<10 m) were found to have relatively higher heavy metal levels in household dust.

Modeling and mapping fuel moisture content using equilibrium moisture content computed from weather data of the automatic mountain meteorology observation system (AMOS) (산악기상자료와 목재평형함수율에 기반한 산림연료습도 추정식 개발)

  • Lee, HoonTaek;WON, Myoung-Soo;YOON, Suk-Hee;JANG, Keun-Chang
    • Journal of the Korean Association of Geographic Information Studies
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    • v.22 no.3
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    • pp.21-36
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    • 2019
  • Dead fuel moisture content is a key variable in fire danger rating as it affects fire ignition and behavior. This study evaluates simple regression models estimating the moisture content of standardized 10-h fuel stick (10-h FMC) at three sites with different characteristics(urban and outside/inside the forest). Equilibrium moisture content (EMC) was used as an independent variable, and in-situ measured 10-h FMC was used as a dependent variable and validation data. 10-h FMC spatial distribution maps were created for dates with the most frequent fire occurrence during 2013-2018. Also, 10-h FMC values of the dates were analyzed to investigate under which 10-h FMC condition forest fire is likely to occur. As the results, fitted equations could explain considerable part of the variance in 10-h FMC (62~78%). Compared to the validation data, the models performed well with R2 ranged from 0.53 to 0.68, root mean squared error (RMSE) ranged from 2.52% to 3.43%, and bias ranged from -0.41% to 1.10%. When the 10-h FMC model fitted for one site was applied to the other sites, $R^2$ was maintained as the same while RMSE and bias increased up to 5.13% and 3.68%, respectively. The major deficiency of the 10-h FMC model was that it poorly caught the difference in the drying process after rainfall between 10-h FMC and EMC. From the analysis of 10-h FMC during the dates fire occurred, more than 70% of the fires occurred under a 10-h FMC condition of less than 10.5%. Overall, the present study suggested a simple model estimating 10-h FMC with acceptable performance. Applying the 10-h FMC model to the automatic mountain weather observation system was successfully tested to produce a national-scale 10-h FMC spatial distribution map. This data will be fundamental information for forest fire research, and will support the policy maker.

Esterification of Indonesia Tropical Crop Oil by Amberlyst-15 and Property Analysis of Biodiesel (인도네시아 열대작물 오일의 Amberlyst-15 촉매 에스테르화 반응 및 바이오디젤 물성 분석)

  • Lee, Kyoung-Ho;Lim, Riky;Lee, Joon-Pyo;Lee, Jin-Suk;Kim, Deog-Keun
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.1
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    • pp.324-332
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    • 2019
  • Most countries including Korea and Indonesia have strong policy for implementing biofuels like biodiesel. Shortage of the oil feedstock is the main barrier for increasing the supply of biodiesel fuel. In this study, in order to improve the stability of feedstock supply and lower the biodiesel production cost, the feasibility of biodiesel production using two types of Indonesian tropical crop oils, pressed at different harvesting times, were investigated. R. Trisperma oils, a high productive non-edible feedstocks, were investigated to produce biodiesel by esterification and transesterification because of it's high impurity and free fatty acid contents. the kindly provided oils from Indonesia were required to perform the filtering and water removal process to increase the efficiency of the esterificaton and transesterification reactions. The esterification used heterogeneous acid catalyst, Amberlyst-15. Before the reaction, the acid value of two types oil were 41, 17 mg KOH/g respectively. After the pre-esterification reaction, the acid value of oils were 3.7, 1.8 mg KOH/g respectively, the conversions were about 90%. Free fatty acid content was reduced to below 2%. Afterwards, the transesterification was performed using KOH as the base catalyst for transesterification. The prepared biodiesel showed about 93% of FAME content, and the total glycerol content was 0.43%. It did not meet the quality specification(FAME 96.5% and Total glycerol 0.24%) since the tested oils were identified to have a uncommon fatty acid, generally not found in vegetable oils, ${\alpha}$-eleostearic acid with much contents of 10.7~33.4%. So, it is required to perform the further research on reaction optimization and product purification to meet the fuel quality standards. So if the biodiesel production technology using un-utilized non-edible feedstock oils is successfully developed, stable supply of the feedstock for biodiesel production may be possible in the future.

Characteristics of bioethanol production using sweet sorghum juice as a medium of the seed culture (단수수 착즙액이용 배양종균의 바이오에탄올 생산 특성 연구)

  • Cha, Young-Lok;Moon, Youn-Ho;Yu, Gyeong-Dan;Lee, Ji-Eun;Choi, In-Seung;Song, Yeon-Sang;Lee, Kyeong-Bo
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.4
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    • pp.627-633
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    • 2016
  • Sweet sorghum [Sorghum bicolor (L)] is one of the major crops for biofuels such as sugarcane and sugar beet which raw materials rich in saccharide. Sweet sorghum juice was extracted from the stem. It's composed of fermentable sugars such as glucose, fructose and sucrose. Ethanol from the extracted sweet sorghum juice can be easily produced by yeast fermentation process. Sweet sorghum juice is consisted of not only sugars but also various nutrients like nitrogen and phosphate. For commercial production of bioethanol, seed culture is one of the important parts of fermentation, so that optimal culture medium should be selected for the reduction of processing costs. In this study, sweet sorghum juice was estimated as a culture medium for seed culture of cellulosic bioethanol. For the comparison of cultures with various substrates, it used YPD including each 5 g/L yeast extract and peptone, sweet sorghum juice and hydrolyzed Miscanthus was taken part in the culture with 2%, 5% and 10% sugar conditions. Based on media of YPD and sweet sorghum juice, cell-mass concentration was obtained maximum more than $2.5{\times}10^8CFU/mL$ after 24 h of cultivation. Consequently sweet sorghum juice is suitable for the cell culture with more than $1.0{\times}10^8CFU/mL$ after 12 h of cultivation. This can be used as a culture medium for the cellulosic bioethanol industry.

Prediction of field failure rate using data mining in the Automotive semiconductor (데이터 마이닝 기법을 이용한 차량용 반도체의 불량률 예측 연구)

  • Yun, Gyungsik;Jung, Hee-Won;Park, Seungbum
    • Journal of Technology Innovation
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    • v.26 no.3
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    • pp.37-68
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    • 2018
  • Since the 20th century, automobiles, which are the most common means of transportation, have been evolving as the use of electronic control devices and automotive semiconductors increases dramatically. Automotive semiconductors are a key component in automotive electronic control devices and are used to provide stability, efficiency of fuel use, and stability of operation to consumers. For example, automotive semiconductors include engines control, technologies for managing electric motors, transmission control units, hybrid vehicle control, start/stop systems, electronic motor control, automotive radar and LIDAR, smart head lamps, head-up displays, lane keeping systems. As such, semiconductors are being applied to almost all electronic control devices that make up an automobile, and they are creating more effects than simply combining mechanical devices. Since automotive semiconductors have a high data rate basically, a microprocessor unit is being used instead of a micro control unit. For example, semiconductors based on ARM processors are being used in telematics, audio/video multi-medias and navigation. Automotive semiconductors require characteristics such as high reliability, durability and long-term supply, considering the period of use of the automobile for more than 10 years. The reliability of automotive semiconductors is directly linked to the safety of automobiles. The semiconductor industry uses JEDEC and AEC standards to evaluate the reliability of automotive semiconductors. In addition, the life expectancy of the product is estimated at the early stage of development and at the early stage of mass production by using the reliability test method and results that are presented as standard in the automobile industry. However, there are limitations in predicting the failure rate caused by various parameters such as customer's various conditions of use and usage time. To overcome these limitations, much research has been done in academia and industry. Among them, researches using data mining techniques have been carried out in many semiconductor fields, but application and research on automotive semiconductors have not yet been studied. In this regard, this study investigates the relationship between data generated during semiconductor assembly and package test process by using data mining technique, and uses data mining technique suitable for predicting potential failure rate using customer bad data.

A Survey on the Break-down and Repair of the Power Tillers in Korea (동력경운기(動力耕耘機) 이용실태(利用實態) 조사분석(調査分析)(II) -고장(故障) 및 수리(修理)에 관(關)하여-)

  • Hong, Jong Ho;Lee, Chai Shik
    • Journal of Biosystems Engineering
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    • v.6 no.1
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    • pp.28-38
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    • 1981
  • A survey has been conducted to investigate the presents of breaks down and repair of power tiller for efficient use. Eight provinces were covered for this study. The results are summarized as follows. A. Frequency of breaks down. 1) Power tiller was breaken down 9.05 times a year and it represents a break down every 39.1 hours of use. High frequency of breaks down was found from the fuel and ignition system. For only these system, the number of breaks down were 2.02 and it represents 23.3% among total breaks down. It was followed by attachments, cylinder system, and traction device. 2) For the power tiller which was more than six years old, breaks down accured 37.7 hours of use and every 38.6 hours for the power tiller which was purchased in less than 2 years. 3) For the kerosene engine power tiller, breaks down occured every 36.8 hours of use, which is a higher value compared with diesel engine power tiller which break down every 42.8 hours of use. The 8HP kerosene engine power tiller showed higher frequency of break down compared with any other horse power tiller. 4) In October, the lowest frequency of break down was found with the value of once for every 51.5 hours of use, and it was followed by the frequency of break down in June. The more hours of use, the less breaks down was found. E. Repair place 1) 45.3% among total breaks down of power tiller was repaired by the owner, and 54.7% was repaired at repair shop. More power tiller were repaired at repair shop than by owner of power tiller. 2) The older the power tiller is, the higher percentage of repairing at the repair shop was found compared with the repairing by the owner. 3) Higher percentage of repairing by the owner was found for the diesel engine power tiller compared with the kerosene engine power tiller. It was 10 HP power tiller for the kerosene power tiller and 8 HP for the diesel engine power tiller. 4) 66.7% among total breaks down of steering device was repaired by the owner. It was the highest value compared with the percentage of repairing of any other parts of power tiller. The lowest percentage of repairing by owner was found for the attachments to the power tiller with the value of 26.5%. C. Cause of break down 1) Among the total breaks down of power tiller, 57.2% is caused by the old parts of power tiller with the value of 5.18 times break down a year and 34.7% was caused by the poor maintenance and over loading. 2) For the power tiller which was purchased in less than two years, more breaks down were caused by poor maintenance in comparison to the old parts of power tiller. 3) For the both 8-10 HP kerosene and diesel engine power tiller, the aspects of breaks down was almost the same. But for the 5 HP power tiller, more breaks down was caused by over loading in comparison to the old parts of power tiller. 4) For the cylinder system and traction device, most of the breaks down was caused by the old parts and for the fuel and ignition system, breaks down was caused mainly by the poor maintenance. D. Repair Cost 1) For each power tiller, repair cost was 34,509 won a year and it was 97 won for one hoar operation. 2) Repair cost of kerosene engine power tiller was 40,697 won a year, and it use 28,320 won for a diesel engine power tiller. 3) Average repair cost for one hour operation of kerosene engine power tiller was 103 won, and 86 won for a diesel engine power tiller. No differences were found between the horse power of engines. 4) Annual repair cost of cylinder system was 13,036 won which is the highest one compared with the repair cost of any other parts 362 won a year was required to repair the steering device, and it was the least among repair cost of parts. 5) Average cost for repairing the power tiller one time was 3,183 won. It was 10,598 won for a cylinder system and 1,006 won for a steering device of power tiller. E. Time requirement for repairing by owner. 1) Average time requirements for repairing the break down of a power tiller by owner himself was 8.36 hours, power tiller could not be used for operation for 93.58 hours a year due to the break down. 2) 21.3 hours were required for repairing by owner himself the break down of a power tiller which was more than 6 years old. This value is the highest one compared with the repairing time of power tiller which were purchased in different years. Due to the break down of the power tiller, it could not be used for operation annually 127.13 hours. 3) 10.66 hours were required for repairing by the owner himself a break down of a diesel engine power tiller and 6.48 hours for kerosene engine power tiller could not be used annually 99.14 hours for operation due to the break down and it was 88.67 hour for the diesel engine power tiller. 4) For both diesel and kerosene engine power tiller 8 HP power tiller required the least time for repairing by owner himself a break down compared with any other horse power tiller. It was 2.78 hours for kerosene engine power tiller and 8.25 hours fur diesel engine power tiller. 5) For the cylinder system of power tiller 32.02 hours were required for repairing a break down by the owner himself. Power tiller could not be used 39.30 hours a year due to the break down of the cylinder system.

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