• Title/Summary/Keyword: 분광측색계

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알루미늄 양극산화 피막의 색조에 미치는 전해 인자의 영향

  • Choe, In-Cheol;Jo, Hyo-Jae;Son, In-Jun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.131-131
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    • 2017
  • 알루미늄은 내식성, 내마모성과 같은 물리적, 화학적 성질이 우수하지 못하여 이를 향상시키기 위해서 양극산화법이 산업적으로 널리 사용되고 있다. 알루미늄 양극산화법을 적용하면 강도, 내마모성 및 내식성이 향상될 뿐만 아니라 알루미늄 표면에 규칙적으로 배열된 30nm~100nm 크기의 pore에 염료를 흡착시켜 다양한 색상의 외관을 가지는 양극산화피막을 형성시킬 수 있다. Pore간의 간격은 수십nm~수백nm 정도이며, pore의 크기와 간격 및 깊이는 양극산화조건(양극산화 전압, 전해액의 종류와 농도 및 온도)에 의해 크게 변화된다. 또한 염료의 농도와 착색 시간에 따라서 양극산화 피막의 색조가 변화되는 것으로 알려져 있다. 따라서 본 연구에서는 양극산화피막의 색조에 미치는 전해조건의 영향을 조사하고, 분광측색계를 사용하여 산화피막의 색조를 정량적으로 분석하고 또한 산화피막의 pore에 흡착된 염료를 정량분석하기 위해서 UV-visible을 사용하여 분석하였다. Al5052 합금을 이용하여 에칭, 양극산화, 착색처리, 봉공(sealing)처리를 실시하였다. $55^{\circ}C$ 100g/L NaOH 용액에서 에칭을, $25^{\circ}C$ 10 vol.% $HNO_3$ 용액에서 디스머트를 실시한 다음, $25^{\circ}C$ 10 vol.% $H_2(SO_4)$ 용액에서 15V의 정전압으로 양극산화를 실시하였다. 이후, $55^{\circ}C$ 5~8g/L의 오렌지, 블랙 착색염료(일본 OKUNO 사(社)의 TAC-LH(301), TAC-BLH(411))를 사용하여 착색처리를, $85^{\circ}C$ 초산니켈 수용액에서 봉공처리를 실시하였다. 착색조건으로는 양극산화 시간(5분, 10분, 15분, 20분), 착색 시간(15초, 1분, 2분, 5분) 및 착색 농도(오렌지 -2.5g/L, 5g/L, 7.5g/L, 블랙 - 4g/L, 8g/L, 12g/L)를 변화시켰으며, 산화피막의 색조를 정량 분석하기 위해 분광측색계를 사용하였고 흡착된 염료의 농도를 정량 분석하기 위해서 $55^{\circ}C$, 1M NaOH에 재용해하여 UV-visible로 흡광도를 측정하였다. 양극산화피막의 색조는 양극산화 시간이 길어질수록, 착색시간이 길어질수록, 착색농도가 진할수록 산화피막에 흡착되는 염료의 양이 증가하며 색조가 더 선명해지고 진해지는 것을 확인하였다. 이를 분광측색계로 분석하였을 때 각 전해조건하에서 경향성을 나타내었다. 또한 흡광도 측정을 통해 계산한 염료의 양과 전해조건의 상관관계를 조사하였다. 양극산화 시간이 길어지면 산화피막의 두께가 증가하여 염료가 흡착될 수 있는 표면적이 넓어지고, 착색 시간이 길어지면 동일한 산화피막에 더 많은 염료가 흡착이 된다. 그리고 착색 농도가 진할수록 동일면적, 동일시간 하에서 더 많은 염료가 흡착되어 결과적으로 전해조건이 강해질수록 산화피막의 색조가 진해지는 것으로 판단된다.

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Development of Mobile Assistive Tool for People with Scotopic Sensitivity Syndrome (광과민성 증후군자를 위한 모바일 보조도구 개발)

  • Jung, Hun-Sung;Jang, Young-Gun
    • Proceedings of the Korea Information Processing Society Conference
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    • 2013.05a
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    • pp.383-385
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    • 2013
  • 안드로이드의 최상위 윈도우를 활용하여 광과민성 증후군자를 위한 모바일용 가상 색 오버레이를 구현하였다. 필름 오버레이의 색도 정보와 투과율을 분광측색계로 측정하여 가상 색 오버레이에 적용할 색상 정보를 추정하는 방법을 제안하였고, Intuitive Overlays에서 표현하는 모든 색상을 구현하였다. 시험 결과 기존의 필름 오버레이를 사용한 것과 동일한 효과를 얻었다.

균일막 형성을 위한 항공기 부품용 타이타늄의 양극산화 최적 공정

  • Lee, Da-Yeong;Han, A-Yeong;Jeong, Na-Gyeom;Choe, Jin-Seop
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.66.2-66.2
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    • 2018
  • 금속의 양극산화 공정(anodizing)은 전해질 내 금속에 인위적으로 전위를 가해 금속 표면에 얇은 산화막(oxide layer)을 형성하여 금속의 내식성, 내마모성을 증가시키는 공정이다. 타이타늄은 가볍고 단단하여 산업분야에 유용하게 사용되며 이와 같은 양극산화 공정을 통해 내식성, 내마모성을 크게 높일 수 있다. 본 연구에서는 항공기 부품용 타이타늄의 최적 양극산화 조건을 찾기 위해 전압의 파형, 전해액의 조성에 따라 양극산화 실험을 진행하였다. SEM, AFM, EDS, 분광측색계, 색채색차계 등을 이용하여 각 조건에 해당하는 타이타늄의 산화막($Tio_2$)의 두께, crack 형태, pore 형태, 균일도, 표면 조도, 내전압, 색 수치를 분석하였다. 그 결과 전압 DC 140 V, 주성분이 KOH $Na_3PO_4{\cdot}12H_2O$인 전해액으로 이루어진 양극산화 조건에서 가장 균일하고 색 재현성이 우수한 타이타늄의 산화막($Tio_2$)을 형성하였다.

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An Analysis on the Early Frost Damage According to the Component Thickness Changes of the Normal Strength Concrete Slab in Winter (겨울철 보통강도 콘크리트의 부재 두께 변화에 따른 초기동해 피해분석)

  • Kim, Tae-Woo;Lee, Yong-Jun;Kim, Dong-Gyu;Kim, Dae-Gun;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.145-146
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    • 2018
  • In this study, the purpose of the study is to determine the depth of damage caused by early frost damage in concrete slab structures under the conditions of external temperature during winter. In other words, we intend to analyze the depth variation of the early frost damage as the thickness of the normal strength concrete slab members changes. As a result, the thinner the component was, the deeper the early frost damage was found to be, and the resulting increase in brightness of the concrete was delayed. and It is analyzed that under this test condition, an early frost damage was created with a thickness of 50 mm for the member and a thickness of 39 mm for the member of 300 mm.

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Determining the Depth of Normal-Strength Concrete with Early-Frost Damage Through Dry Test (초기동해 피해를 입은 보통강도 콘크리트의 건조시험에 의한 깊이판정)

  • Kim, Tae-Woo;Beak, Cheol;Lee, Jae-Jin;Kim, Dong-Gyu;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.65-66
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    • 2017
  • Early-frost damages easily take place in smaller and thinner walls and slabs. In case of slabs, it is difficult to visually determine the depth of early-frost damage. As such, the current study aims to determine the depth of early-frost damage caused to concrete structures due to bad curing in the winter. As a result, the study found that the depth of early-frost damages increased from the top as the atmospheric temperature on the concrete surface decreased. The changes in the color allowed the observer to easily identify the depth of early-frost damage with the naked eye. In particular, the color difference between potentially damaged parts and undamaged parts were the greatest around thirty minutes of drying after wetting.

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Study on Color and Oxidation Thickness for Titanium Spectacle Frames Colored by Anodization (양극산화방법으로 착색한 티타늄 안경테의 산화막 두께에 따른 색상 연구)

  • Hyun, Seung-Cheol;Jin, Moon-Seog;Kim, Yong-Geun
    • Journal of Korean Ophthalmic Optics Society
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    • v.14 no.4
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    • pp.33-37
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    • 2009
  • Purpose: To examine the coloring condition of titanium spectacle frames with various colors by using anodization method. Methods: We made an anodization coater. Platinum plate with $3{\times}3cm^2$ was used for a cathode and titanium spectacle frame specimens was mounted on an anode in an electrolyte. An electric source device were designed to supply steady state current. The color of the coated spectacle frame specimens were measured by a spectrophotometer equipped with an integrating sphere. We use CIE $L^*a^*b$ color system as chromaticity coordinates. Results: The thickness of $TiO_2$ of titanium spectacle frame specimens was varied as controlling current flow time for electrodes. The specimens with various kinds of color as a walnut, a yellow brown, a navy blue, a blue, a light blue, a mung bean, a yellowish green, a light purple, a purple, a flower pink, a bluish green, an emerald, and a green color etc. were obtained. The values of CIE $L^*a^*b^*$ for these specimens were measured and analyzed to be changed clockwise in chromaticity coordinates as the thickness of $TiO_2$ increases. Conclusions: We identified the coloring mechanism by anodization method in titanium spectacle frame specimens.

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Change of color transfer of Photochromic lens (Photochromic 렌즈의 광변색 이동)

  • Kim, Yong-Geun;Seong, Jeong-Sub
    • Journal of Korean Ophthalmic Optics Society
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    • v.8 no.1
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    • pp.59-64
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    • 2003
  • To Photochoromic lens light irradiation side darkening status and fading status photo-transmittance decrease. If remove light irradiation, get into fading state and photo-transmittance has reversibility process that get back originally in state. Get CIE $L^*a^*b^*$ relationship colorimetric using darkening in Photochoromic lens and at fading process. Photochromism's spectrophotometer that produce itself. Darkening and fading state colorimetric ($a^*-b^*$) linear be curvy, and is gradidnt of (-) value. And change lineally. The colorimetric transfer amount is Blue ${\rightarrow}$ Yellow, Red ${\rightarrow}$ Green form. Colorimetric is low $b^*$ value than darkning state in fading state, and Photochromism's coodination transfer moves on the contrary with darkning state, photochoromism relationship estimation method about photochoromic lens can use by colorimetric difference about darkening and fading.

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A study on the testing method of discolored tap water by spectrophotometer (분광측색계에 의한 착색 수돗물 시험방법 연구)

  • Dongheon Kim;Jonggeum Lee;Jiyoon Oh;Gitae Kim;Hangbae Jun
    • Journal of Korean Society of Water and Wastewater
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    • v.37 no.4
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    • pp.187-202
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    • 2023
  • This study focuses on the application of a new measurement method that quantifies the residual color of filtered water using a spectrocolorimeter after filtering the discolored substances. It was confirmed through the color and turbidity cross-test that the discolored substances cannot be measured effectively with the current legal color and turbidity test method. Therefore, the National Institute of Environmental Research's filter testing method, which involves filtering the sample through 0.45 ㎛ filter and visually inspecting the color, was improved. A membrane filter colorimetry (MFC) method was established by measuring the color difference (ΔE*ab(65)) of the filtered filter using a spectrophotometer and expressing it as filter color unit (FCU). Using the MFC method, the FCU for reference materials such as iron and manganese, as well as field samples, was measured. The results showed a high correlation with turbidity, and the color difference patterns varied depending on the type of reference materials and field samples. This indicates that the MFC method is an effective new measurement method of discolored tap water.

Favorable Colors on the Facial Color Types of Korean Adult Females (한국 여성의 얼굴 피부색 유형에 어울리는 색채에 대한 연구)

  • Kim Ku-Ja
    • Journal of the Korean Society of Clothing and Textiles
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    • v.30 no.6 s.154
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    • pp.971-980
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    • 2006
  • The colors of apparel have a close relationship with the facial color types of consumers. To extract the favorable colors that flatter to consumer's facial color types, the facial colors of Korean females were analyzed. With color meter JX-777, 2 points of face were measured and classified into 3 clusters that had similar hue, value and chroma. Other new 10 college girls were measured and 3 subject among them were selected by the criteria that choose new subjects who have the classified facial color types. 175 respondents answered the degree of becomingness of color samples on three subjects. Data were analyzed by K-means cluster analysis, ANOVA and Duncan multiple range test using SPSS Win. 12. Findings were as follows: 1) 324 subjects who had YR facial colors were classified into 3 facial color groups. The average facial color Type 1 was 4.82YR 6.47/3.70 and composed 48.88% among total observations. Type 2 was 5.99YR 6.12/4.12 and 30.25%. Type 3 was 5.15YR 7.07/4.97 and 20.99% respectively. 2) Favorable colors for Type 1 were 18 colors that belonged to 'a' group from among colors that were divided into a, b, c group by Duncan post hoc test. 3) Type 2 showed that this type had many unfavorable colors. Unfavorable colors were 18 colors that belonged to 'c' by Duncan test. 4) Type 3 showed that black is the most favorable color and 18 colors were at middle level, which belonged to 'b' from among 18 colors that were divided into a, b, and c by Duncan test.

Clustering of Facial Color Types and Their Favorable Colors on Korean Adult Males (한국 남성의 얼굴 피부색 분류와 유형에 어울리는 색채 연구)

  • Kim, Ku-Ja
    • Journal of the Korean Society of Clothing and Textiles
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    • v.30 no.2 s.150
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    • pp.316-325
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    • 2006
  • The colors of apparel are getting more important to give the differentiated character on fiber and fabrics. This study was to extract the favorable colors that become to facial color types. Research was carried out to classify the facial colors into several similar facial color groups. With JX-777, 2 points of face: forehead and cheek, were measured and classified into 3 facial color types. Sample size was 418 Korean adult males and other 15 of new males subjects. New chosen 3 subjects who had the classified facial color types, wore silver gown and black hat on his head to minimize the interaction of the clothe color an hair. The 40 standardized color samples were used to extract the favorable colors. 187 respondents answered the degree of becomingness of color samples on 3 facial color types. Data were analyzed by K-means cluster analysis, ANOVA and Duncan multiple range test using SPSS Win. 12. Findings were as follows: 1. 418 subjects who had YR colors were classified into 3 kinds of facial color groups. Type 1 was 4.59YR 5.89/5.12, Type 2 was 5.61 YR 5.41/4.79 and Type 3 was 4.38YR 6.49/4.89 respectively. 2. Favorable colors for Type 1 were 2 colors that belonged to ' a ' group from among colors that were divided into a, b, c group and 18 colors that belonged to ' a ' group from among colors that were divided into a, b group by Duncan post hoc test. 3. Type 2 showed that this type had many unfavorable colors. Unfavorable colors were 16 colors that belonged to ' c ' by Duncan test. 5. Favorable colors for Type 3 were 14 colors that belonged to ' a ' from among colors that were divided into a, b, c and 16 colors that belonged to ' a ' from among colors that were divided into a, b by Duncan test.