• 제목/요약/키워드: 부형제

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The Improvement of Radiation Characteristics of Low Density Polyethylene by Addition of Treeing Inhibitors (트리 억제제 첨가에 의한 저밀도 폴리에틸렌의 내방사선성 향상)

  • Kim, Ki-Yup;Lee, Chung;Ryu, Boo-Hyung;Lim, Kee-Joe
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.8
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    • pp.455-461
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    • 2000
  • The inhibiting effects of electrical treeing and insulation properties of LDPE contained with treeing inhibitors was studied under radiation environment. Barbituric acid and its derivatives were selected as treeing inhibitors. The inception voltage and growth of tree, AC breakdown strength, volume resistivity, high frequency capacitance, and dissipation factor were observed as a function of dose(up to 1000 kGy). And also, measurements of thermo-luminescence(TL), and gel content were carried out. Crosslinked low density polyethylene(XLPE) contained with treeing inhibitors shows better insulation characteristics such as electrical tree propagation, AC breakdown strength, and volume resistivity than those of pure LDPE. The most effective treeing inhibitor was found on the barbituric acid contained XLPE.

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A study on insulation Characteristics of XLPE by various additives (다양한 첨가제에 따른 가교폴리에틸렌의 절연특성 분석)

  • Song, Sang-Min;Kim, Gyu-Sik;Son, Won-Keun;Ryu, Boo-Hyung;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05c
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    • pp.193-196
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    • 2001
  • XLPE is occasionally happened to deteriorate cable insulation characteristics. It is happened to do a breakdown state by the degradation of electrical characteristic and electrical breakdown strength. I prepared TR-XLPE (Tree-Retardant XLPE) as adding various additives to prevent its states. Various additives are treeing retardants, anti-oxidants. Treeing retardants three kinds of aromatic compounds as adding each additive. Anti-oxidants use quinone compound and cresol compound as adding each additive. In order to observe each electrical characteristics, I measured breakdown strength, relative dielectric constant$({\varepsilon}_r)$, dielectric loss tangent$(tan{\delta})$. TR-XLPE specimens as adding treeing retardants and anti-oxidants enhance breakdown strength, ${\varepsilon}_r$, $tan{\delta}$ than pure XLPE.

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Electrical Properties of XLPE Power Cable by DCP and TMPTA Content (전력 cable용 XLPE의 제조과정 중 가교제와 가교조제의 함량이 미치는 전기적 특성)

  • Kim, Gyu-Sik;Lim, Kee-Joe;Ryu, Boo-Hyung;Park, Soo-Gil
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.2077-2080
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    • 2000
  • We studied about electrical, chemical and mechanical characteristics of XLPE by dicumyl peroxide(DCP) and trimethylolpropane triacrylate(TMPTA) content ratio. DCP content was changed from 1.0 to 2.5phr increasing 0.5phr. TMPTA content was changed 0.5 to 1.5phr increasing 0.5phr. Thermal analysis (DSC) was carried out in order to observe tendency of 79 according to DCP and TMPTA content. In experimental results, content DCP 2.0phr and TMPTA 1.0phr has highest breakdown strength. Content DCP 2.0phr and TMPTA 0.5phr has lowest dielectric constant. Tendency of Tg did not affected by DCP and TMPTA content. Breakdown strength and Specific inductive capacity was measured.

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A Study on Insulation Characteristics of Low Density Polyethylene Contained Various Additives (첨가제를 함유한 저밀도 폴리에틸렌의 절연특성에 관한 연구)

  • Lee, Chung;Kim, Gyu-Baek;Ryu, Boo-Hyung;Kim, Ki-Yup;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.483-486
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    • 1999
  • The treeing inhibitors of barbituric acid derivatives and azocompounds effects on the electrical properties of crosslinked low density polyethylene were investigated. The electrical treeing parameters for tree inception voltage, AC breakdown strength. volume resistivity, capacitance and dissipation factor at 1Mz and thermoluminescence measurements were discussed. From the results, 4- (4-nitrophenylazo) resorcinol among the treeing inhibitors was shown good insulation characteristics.

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The Effects on Antioxidants for Improving to Radiation Resistance of LDPE (저밀도 폴리에틸렌의 내방사선성 향상을 위한 산화방지제 첨가효과)

  • Kim, Ki-Yup;Kim, Pyeong-Jong;Lee, Chung;Kim, Jin-Ah;Ryu, Boo-Hyung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.457-460
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    • 2004
  • Many of the physical and chemical properties of polymer materials can be altered by high energy radiation. In the present work the exposure to radiation of low density polyethylene(LDPE) included antioxidants was carried out at various doses up to 600kGy at a dose rate of 5kGy/hr in the presence of air at room temperature. The study of the irradiation effects on the material properties has been make by different methods in an integrated way. The experimental data indicate that the decomposition onset temperature(DOT), the crystallinity and the thermoluminescence(TL) with radiation dose. DOT, crystallinity and TL analysis from irradiated PE samples provides useful data for the characterization of radiation-induced oxidation effects on these samples.

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The Effect on Antioxidant for Improving to Radiation Resistance on Irradiated PVDF (PVDF의 내방사선 특성 향상을 위한 산화방지제 첨가효과)

  • Kim, Ki-Yup;Lee, Chung;Ryu, Boo-Hyung;Lim, Kee-Joe
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.252-253
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    • 2005
  • The dielectric relaxation properties of $^{60}Co$ gamma-ray irradiated Poly(vinylidene fluoride) (PVDF) containing various antioxidants have been investigated for radiation degradation. Cole-Cole's circular arcs were induced from the results of temperature and frequency dependency of dielectric properties with radiation dose. The magnitude of polarization of PVDF was decreased by adding antioxidants. The values of dielectric relaxation intensity calculated by using the Cole-Cole's circular arcs showed a certain tendency for radiation degradation.

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Effects of Chitosan on Fracture Healing in Fractured Rat Model. (골절모델 쥐에서 키토산 투여가 골절치유에 미치는 영향)

  • 서정욱;김은주;한상섭
    • Journal of Life Science
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    • v.14 no.3
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    • pp.385-390
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    • 2004
  • Chitosan is abundant polysaccharide polymer in nature Chitosan has been the subject of much research regarding its potential as a nutritional adjunct and pharmaceutical ingredient. In the present study, we examined fracture-healing process with chitosan administration and low calcium diet in rats. Left femur was fractured and fixed with intramedullary pin. The rats were fed normal diet or low calcium diet and administered chitosan with the doses of 0, 50, 100 and 150ng/ml orally 5 times a week for 10 weeks. Soft X-ray and mechanical testing of all fractured femora was taken. Radiographical finding showed that the callus formation and process of fracture healing was present in all the fractured femora. Mechanical testing indicated that the maximum load and stiffness of femur in rat fed low calcium diet was lower than those of that in rat fed normal diet. No difference in maximum load and stiffness of fractured femora in chitosan treated rat were observed as compared to vehicle treated rat. Chitosan or/and low calcium diet did not affect the ratio of fractured/unfractured femur about maximum load and stiffness. The results suggest that chitosan dose not affect the bone mechanical strength and the process of fracture healing. Low calcium diet does decrease the bone mechanical strength.

Effect of Suboptimal Temperature Incubation on the Resistance of Lactobacillus acidophilus CT 01 to Storage and Drying (저온배양에 따른 Lactobacillus acidophilus CT 01의 저장 및 건조에 대한 저항성)

  • Yu Keun-Hyung;Kwon Il-Kyoung;Kim Gur-Yoo
    • Food Science of Animal Resources
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    • v.25 no.1
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    • pp.92-97
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    • 2005
  • This study was carried out to determine the storage, cryotolerance, heat and drying resistance, when Lactobacillus acidophilus CT 01 isolated from preweaned piglet feces growing at suboptimal temperature. L. acidophilus CT 01 suboptimal temperature incubated for 48 hours had the slowest growth rate at 22℃ but the highest viable cell number after 36 hours at 22℃, with 1.3×10/sup 9/ CFU/mL. In case of 4 and 20℃ storage, the suboptimal temperature incubated groups had a viability higher than the control (p<0.01). The cryotolerance of suboptimal temperature incubated L. acidophilus CT 01 was a higher than the control (p<0.01). When L. acidophilus CT 01 was heat treated at 60℃ for 15 minutes and 30 minutes, the suboptimal temperature incubated L. acidophilus CT 01 at 22℃ had a viability higher more than the control (p<0.01). L. acidophilus CT 01 incubated suboptimal temperature was inoculated by 30% to the carrier, and dried at 50℃ for 12 hours had the highest viability in the suboptimal temperature incubated L. acidophilus CT 01 at 28℃.

Preparation of Amino Acid Copolymers/water-insoluble Drug Nanoparticles: Polymer Properties and Processing Variables (아미노산 공중합체/난용성 약물 나노입자의 제조: 고분자 특성 및 가공변수)

  • Yoo Ji Youn;Lee Soo-Jeong;Ahn Cheol-Hee;Choi Ji-Yeun;Lee Jonghwi
    • Polymer(Korea)
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    • v.29 no.5
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    • pp.440-444
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    • 2005
  • An increase in the surface area of drugs by reducing particle sizes from microns to nanometers has been known as an efficient method to improve the bioavailability of water-insoluble drugs. To prevent drug nanoparticles from aggregation during the processes of drug formulation, a limited number of pharmaceutical inactive ingredients such as hydroxypropyl cellulose has been employed as stabilizers or dispersants. In this study, copolymers of hydrophilic and hydrophobic amino acids were synthesized by the ring opening polymerization of their N-carboxyanhydride monomers and evaluated as novel candidates to stabilize the nanoparticles of a water insoluble drug, naproxen. Naproxen nanoparticles stabilized by synthesized amino acid copolymers were successfully prepared in the size of $200\~500nm$ in 60 min by a wet comminution process. Particle size analysis showed that the effective stabilization performance of copolymers required the hydrophobic moiety content to be higher than $10 mol\%$. However, the molecular weight and morphology of copolymers was not the critical parameters in determining the particle size reduction. Their particle size was found to be stable up to 14 days without significant aggregation.

Effects of Gemifloxacin on Achilles Tendon in Immature Rats (Gemifloxacin이 미성숙 랫드의 아킬레스건에 미치는 영향)

  • Bae, Jin-Gye;Kim, Young-Soo;Kim, Se-Eun;Shim, Kyung-Mi;Kang, Seong-Soo;Cho, Ik-Hyun;Lee, Soo-Han;Park, Chang-Hyun;Uhm, Chang-Sub;Jeong, Moon-Jin;Han, Song-Iy;Lim, Sung-Chul;Bae, Chun-Sik
    • Applied Microscopy
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    • v.36 no.2
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    • pp.93-99
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    • 2006
  • Gemifloxacin is a synthetic fluoroquinolone antimicrobial agent that exhibits potent activity against most Gram-negative and Gram-positive organisms, and has a comparatively low chondrotoxic potential in immature animals. This study examined the effects of gemifloxacin on the Achilles tendons in immature Sprague-Dawley rats treated by oral intubation once daily for 5 consecutive days from postnatal week 4 onward at doses of 0 (vehicle), and 600mg/kg body weight Ofloxacin was used for comparison. The Achilles tendon sperimens were examined by electron microscopy. In comparison with the vehicle-treated controls, there were ultrastructural changes in all samples from the gemifloxacin- and ofloxacin-treated rats. Degenerative changes were observed in the tenocytes, and the cells that detached from the extracellular matrix were recognizable. The degree of degenerative changes and the number of degenerated cells in the Achilles tendon were significantly higher in the treated group than in the control group. Moreover, among the quinolone treated groups, these findings were more significant in the ofloxacin treated group, and less significant in the gemifloxacin treated group. It is unclear what these findings mean with respect to the possible risk ill juvenile patients treated with gemifloxacin or other quinolones. However, these results show that gemifloxacin causes fewer changes in the connective tissue structures.