• Title/Summary/Keyword: 부식물

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A Study on Corrosion Product Behavior Prediction for Domestic PWR Primary System by using CRUDTRAN (CRUDTRAN을 이용한 국내 PWR 1차계통내 부식생성물 거동예측에 관한 연구)

  • Song, Jong Soon;Yoon, Tae-Bin;Lee, Sang-Heon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.13 no.4
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    • pp.253-262
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    • 2015
  • Radionuclide deposited on the surface of several internal and external systems in a nuclear power plant is created by the activation of corrosion products from nuclear reactor structural materials and fission products. Especially, the constant contact between water and the surface corrodes the inside where primary system makes coolants and corrosion products mixed. Also, these are circulated along the systems. For comparing models, CRUDTRAN, DISER, MIGA-RT and CPAIR codes are analyzed to predict the quantity of radionuclide and corrosion product of primary reactor that are used at the stage of designing. The corrosion products behavior of domestic PWR primary system was predicted by using CRUDTRAN. This study aims to increase the reliability of corrosion product evaluation model by comparing the actual values and calculated values with the data of a Westing House-type Nuclear Power Plant.

Macrocell and Microcell Corrosion of Reinforcing Steel in Concrete Immersed in Saltwater (염수 환경하에서 콘크리트내 철근의 마크로 및 마이크로 셀 부식)

  • 이재봉;이수열;정영수;이광명;정원기;배수호
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.211-214
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    • 1999
  • 염화물 및 방청제가 함유된 철근 콘크리트의 부식특성을 마크로 셀 부식측정 방법인 갈바닉 전류 측정과 마이크로 셀 부식측정 방법인 선형분극 측정법 및 교류 임피던스법을 이용하여 염화물 및 방청제의 영향을 평가하였다. 마크로/마이크로 셀 부식측정기 Calcium Nitrite 방청제가 첨가된 시험체의 경우 갈바닉 전류 측정결과 낮은 전류값을 유지하였고, 교류 임피던스 측정결과 분극저항의 감소가 나타나지 않았으므로, 방청제의 첨가가 콘크리트내 철근의 부동태 피막을 보호하여 부식저항성을 향상시킴을 알 수 있었다.

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Application of Macrocell Sensor System for Monitoring of Steel Corrosion in Concrete Structure Exposed to Marine Environment (해양 콘크리트구조물의 철근부식 모니터링을 위한 매크로셀 센서 시스템의 적용)

  • Lee, Seung-Tae;Moon, Dae-Joong;Kim, Wan-Jong;Moon, Jae-Heum;Kim, Hak-Soo
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.22 no.4
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    • pp.241-247
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    • 2010
  • Corrosion of steel embedded in concrete is one of the foremost factors that affect the durability of concrete structures in marine environments. This paper presents an application technique of anode-ladder-system to evaluate corrosion behaviours of marine concrete structure. In order to investigate the behaviours quantitatively, the measurement of potential and current was performed on the concrete elements subjected to the penetration and diffusion of chloride ions. The main variable was the heights from seawater level; namely 3.7, 6.0 and 8.2 m. As a result of the monitoring, it was found that the corrosion characteristics differently behaved with the increasing height. Additionally, through migration test, the relationship between compressive strength of concrete and diffusivity of chloride ions was observed. It is suggested, ultimately, that in order to reduce or mitigate steel corrosion, both appropriate concrete cover depth and high-quality of concrete in early ages should be done.

Natural Occurring Substances as Corrosion Inhibitors for Tin inSodium Bicarbonate Solutions (중탄산소듐 용액에서 납의 부식방지제인 자연산물질들)

  • Abdallah, M.;El-Etre, A. Y.;Abdallah, E.;Eid, Salah
    • Journal of the Korean Chemical Society
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    • v.53 no.5
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    • pp.485-490
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    • 2009
  • The inhibitive action of the aqueous extract of lawsonia, licorice root and carob toward the corrosion of tin electrode in 0.1 M $NaHCO_3$ solutions was investigated using galvanostatic polarization measurements. It was found that the corrosion rate decreases in the presence of these extracts indicating the inhibiting of these compounds. The inhibition efficiency increases with increasing extract concentration. The inhibition action of these extracts was explained in view of adsorption of its compounds onto the tin surface, making a barrier to mass and charge transfer. The adsorption of these extracts on the tin surface was found to be a spontaneous process and follow Freundlich adsorption isotherm. It is also found that these extracts provide a good protection to tin against pitting corrosion in chloride containing solution using potentiodynamic anodic polarization technique.

아파트 물탱크 및 수도배관의 부식과 방식

  • 이의호
    • 월간 기계설비
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    • s.43
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    • pp.70-75
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    • 1994
  • 한국건설방식연구소(소장 이의호)가 지난해 12월5일 건설회관에서 제1회 국제방식기술세미나를 개최, 건설업계의 관심을 모았다. 이 세미나에서 $\ulcorner$아파트 물탱크 및 수도배관의 부식과 방식$\lrcorner$에 관한 주제발표를 한 이의호 소장은 국내 아파트의 급수관이 대부분 탄소강재나 철근 콘크리트재로 만들어져 부식이 급속히 진행되고 있으므로 이러한 부식현상을 예방하고 맑은 물을 마시기 위해서는 내식성이 우수한 스테인레스강이나 고분자 강력 합성수지로 교체해야 한다고 주장했다.

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Study on the Effect of Corrosion Gas and Acidic Falling Materials for Conservational Wax on the Copper based Sculpture (동(銅)이 주종을 이루는 조형물 보존용 왁스의 산성강하물 및 부식 가스에서의 영향성 연구)

  • Oh, Seung-Jun;Wi, Koang-Chul
    • Journal of Conservation Science
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    • v.26 no.4
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    • pp.437-443
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    • 2010
  • The influence of noxious corrosive gas, which is the product of fossil fuel, and the acidic descent material, which becomes the reason for such reaction, on wax which protects the cultural assets, and the habitat factor were researched. It could be viewed that corrosion occurred rapidly due to the acidic descent material, which have the long staying on the material, rather than harmful corrosive gas. Also, it could be figured out that such corrosion began from whitening phenomenon of coated wax. As the acidity increased, more whitening phenomenon occurred, and eventually, it could be found out that whitening effect began due to the acidic descent material, corrosive gas and various 0.1 M acid solution, which lead to the exposure of internal metal, and corrosion occurred. The wax with the greatest resistance to the acidity due to its least changing aspect seemed to be Renaissance wax, except sulfuric acid.

Corrosion control of drinking water pipes by corrosion inhibitor (부식억제제에 의한 상수도관의 부식제어)

  • Hwang, Byung-Gi
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.6
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    • pp.2306-2310
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    • 2010
  • Corrosion is a complex series of oxidation/reduction reactions between at the water-metal surfaces and materials in which the water is stored or transported. With respect to the corrosion potential of drinking water, the primary concerns include the potential presence of toxic metals, such as lead and copper; deterioration and damage to the household plumbing, and aesthetic problems such as stained laundry, and bitter taste. This study was performed to evaluate the effects of corrosion inhibitors on corrosion rates, Fe and Cu release concentration in water distribution pipes. Decrease of corrosion rates were strongly related to phosphate corrosion inhibitors. Considering that typical corrosion processes consists of a series of electrochemical reaction at the metal surface in contact with water, corrosion rates were positively correlated with Fe release.

Relationship between Half Cell Potential and Corrosion Amount Considering Saturated Cover depth and W/C ratios in Cement Mortar (습윤상태의 피복두께와 물-시멘트비를 고려한 반전위와 철근 부식량의 상관성)

  • Ryu, Hwa-Sung;Park, Jae-Sung;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.3
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    • pp.19-26
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    • 2017
  • Concrete is a construction material with porous media and corroded steel inside affects negatively to durability and structural safety. This study aims a derivation of quantitative relationship between measured HCP (Half Cell Potential) and corrosion amount considering cover depth and W/C (water to cement) ratio. For the work, cement mortar specimens with 3 different W/C ratios and 4 different cover depths are prepared, HCPs are measured with 3 different corrosion level. HCP measurement significantly increases in the saturated condition and linear relationship is observed between corrosion level and acceleration period. With increasing corrosion level and W/C ratio, and decreasing cover depth, HCP measurement increases. Considering total corrosion level and HCP measurements, relatively low COV(Coefficient of Variation) of 0.67 is evaluated through multi-linear regression analysis, however higher COVs over 0.90 can be obtained considering level of HCP measurement. In the room condition, corrosion level can be evaluated through measured HCP in the given conditions of cover depth, W/C ratio. diameter of steel inside.

Prediction of Concrete Corrosion using Electrodchemical Technique (전기화학적인 콘크리트 부식의 예측)

  • 이종권;박지환
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.3 no.2
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    • pp.80-83
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    • 2002
  • The effect of chloride content on the corrosion of reinforced bar in concrete was studied. The mixing ratio of the concrete was 1 : 1.78 : 5.35 : 4.73 (water : content : ballast : sand). The studied chloride content was in the range of 0∼3.5 wt%. The corrosion potentials were measured in every week for two years. The copper-copper sulfate electrode (CSE) was employed as a reference electrode. After two years, the corroded structure was examined and compared to measured corrosion potential. Any visible difference was founded in the specimen located indoor and outdoor. The chloride concentration enhanced rusting and reinforced bar, shifting the potential to active range. The results showed good argument with Van daveer criteria. In 3.5 wt% chloride, the potential shifted belong -350 mV after 58week. Specimen in 1.75 wt% chloride, showed the potential between -200 mV∼-350 mV. However those in free chloride solution maintained above -200 mV for the studied period. It can the concluded that the chloride enhanced corrosion of rebar in concrete and the electrochemical potential can be a promising corrosion monitoring technique.

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Morphology and Characteristics of Corrosion of Archaeological Bronzes (출토 청동유물 부식의 형태학적 고찰 및 부식생성물의 특성 연구)

  • Lee, Eun-woo;Kim, So-jin;Han, Woo-rim;Hwang, Jin-ju;Han, Min-Su
    • Korean Journal of Heritage: History & Science
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    • v.46 no.3
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    • pp.4-15
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    • 2013
  • The study of corrosion products generated by archaeological bronzes that have been buried for a long time can provide certain evidence that enables us to understand the natural corrosion process of bronze and helps us develop conservation and preservation methods. In the present study, the specimens taken from two bronze mirrors and three bronze swords were used to study the corrosion morphology and the related phenomena such as selective corrosion of ${\alpha}$ or ${\alpha}+{\delta}$ phases, decuprification, destannification, and secondary copper. Furthermore, corrosion development was discussed based on the ions distributed throughout the corrosion layers.