• Journal of the Korean Society of Propulsion Engineers
• /
• v.24 no.1
• /
• pp.58-63
• /
• 2020

THPP is a type of metallic complex explosive used in initiators, consisting of TiH₂ and KClO₄. In this case KClO₄ includes ClO₄^- which is a harmful substance that may cause thyroid dysfunction or tumors. In this study KIO₄ is applied to a new type of environmentally friendly explosive as a substitute to the conventional KClO₄. Tests were carried out to see if KIO₄ can be made a successful replacement for KClO₄.

• Journal of the Korea Institute of Military Science and Technology
• /
• v.8 no.4 s.23
• /
• pp.120-129
• /
• 2005

To analyze a blast effect of developed explosives, three different kinds of aluminized tastable explosives and melted cast explosive TNT were used. Conventional explosive TNT was used as a reference. Each tested explosive charge of 340mm diameter spherical type was initiated at the charge center with DXD-65(${\sim}750g$) booster and RP-87 EBW detonator. Thirteen piezo type pressure sensors were located at a range from 4 to 50m away from the charge. From the blast wave profiles, we calculated a peak blast pressure and impulse of the explosion. The calculated pressures and in pulses were converted to TNT Equivalent Weight(TEW) factor by the scaling ]aw method. The average TEW factors based on the blast pressure of TX-01, TX-02, TX-03, TX-04 were 1.298, 1.05, 1.266, 1.274 and the average TEW factors based on impulse were 1.504, 1.686, 1.640, 1.679. From the results, we concluded that TEW factors based on blast pressure and based on impulse of aluminized explosives were superior to TNT. This results are owing to the high contents of aluminum in formulations.

• Polymer(Korea)
• /
• v.38 no.2
• /
• pp.213-219
• /
• 2014

The rheological characteristics of highly concentrated polymer bonded explosive simulant were studied. Hydroxyl terminated polybutadiene (HTPB) and polyethylene plastomer (Exact) were used as binders. Sugar and Dechlorane particles whose physical properties are similar to research department explosive (RDX) were used as fillers. When HTPB was used, diethyl hexyl adipate (DEHA or DOA) was used as a plasticizer together for some cases. Highly concentrated suspensions were mixed in a batch melt mixer (Rheomixer 600, Haake) and rheological properties were measured by plate-plate and capillary rheometers. Wall slip phenomena, thixotropy with shear hysteresis, and flow instability were investigated as shear rate and amount of fillers changed.

• Polymer(Korea)
• /
• v.38 no.2
• /
• pp.225-231
• /
• 2014

The rheological properties of highly concentrated polymer bonded explosive simulant were studied by using poly(ethylene-co-vinyl acetate) with 30 and 60% vinyl acetate (VA) content as a binder, respectively. Calcium carbonate and Dechlorane, whose physical properties are similar to resarch department explosive (RDX)'s, were used as fillers. The suspensions were mixed in a batch melt mixer and it was possible to fill 75 v% at maximum. From dynamic mechanical analysis, Dechlorane showed higher interaction with binder resins than that with calcium carbonate fillers. The effects of microstructural change on the rheological properties of the suspensions were investigated by a plate-plate rheometer with constant shear rate and constant shear stress modes, respectively. The theoretical maximum packing fraction of EVA31/Dechlorane suspension obtained from Krieger-Dougherty equation was 70 v% and it was thought that 2000 Pa was proper shear stress condition for this melt processing.

• Polymer(Korea)
• /
• v.38 no.3
• /
• pp.286-292
• /
• 2014

The rheology of highly concentrated polymer bonded explosive (PBX) simulant was studied. An energy material, polyethylene plastomer (Exact$^{TM}$) having similar properties to poly(BAMO-AMMO) was selected as a binder. Dechlorane with similar properties to RDX (Research Department eXplosive) was chosen as a filler. Mixing behavior in a batch melt mixer was investigated. During mixing a large amount of heat of viscous dissipation was generated and a continuous decrease in torque was observed when the filler content was above 70 v%. It was believed due to wall slip phenomena. From the SEM images, the fillers were well dispersed and the effect of mixing condition affected slightly on the dispersion. Owing to distinct shear thinning behavior of the suspensions, measuring viscosity of highly filled suspensions was possible in a high shear rate capillary rheometer though it was impossible even in a low shear rate plateplate rheometer.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.22 no.1
• /
• pp.66-71
• /
• 2018

The evaluation of the shelf-life of energetic materials is important. However, there are several difficulties associated with the evaluation. First, aging experiments require a considerable amount of time. Second, treating highly energetic materials is dangerous. For these reasons, many evaluation methods have been developed. Because most energetic materials decompose with the evolution of heat, it is important to analyze the thermal properties of energetic materials in order to understand decomposition and aging properties. In this paper, we describe the estimation of thermal aging properties and develop a kinetic model from spot data set of mechanical properties and estimate aging properties for mechanical results.

• Journal of the Korea Institute of Military Science and Technology
• /
• v.27 no.2
• /
• pp.222-229
• /
• 2024

As the operating condition for the penetrating missile has been more advanced, the survivability of main charge has been strongly required when the warhead impacts the target. Lots of efforts to desensitize explosives such as the development of insensitive molecular explosives or optimizing plastic-bonded explosives(PBX) systems has been made to enhance the survivability of main charge. However, these efforts face their limits as the weapon system require higher performance. Herein, we suggest a new strategy to secure the survivability of main charge. We applied structurally supportable aluminum honeycomb(HC) structure to cast PBX. The aluminum HC structure reinforces the mechanical strength of cast PBX and helps it to withstand external pressure without the reaction like detonation. In this study, impact resistance character, shock sensitivity and internal blast performance of PBXs reinforced with HC structure were investigated according to the application of aluminum HC structure. The newly suggested aluminum HC structure applied to cast PBX was proved to be a promising manufacturing method available for high-tech weapon systems.

• Explosives and Blasting
• /
• v.25 no.2
• /
• pp.11-21
• /
• 2007

The main structure of Gunsan steam power station was demolished by the toppling method using high explosives. Height of a main building is 58m and a total floor area is $292,000m^2$. It is Rahmen(rigid-frame) structure consisted of almost columns and beams and slabs exist only in one part of the building for the electricity generators equipments. To improve the efficiency of blasting work, it is separated into 4 sectors. Blasting floors were 1, 2, 3, & 4 stories from first sector to third sector, while 1, 2, 5, & 7 of fourth sector were blasted because it had not slabs. About 102.675 kg of the MegaMITE were used with 225 electric detonator and 638 non-electric detonators to check detonator connection and confidence of detonation. The blasting noise and vibration were monitored to evaluate the environment effect and the damage of the nearby structures.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2011.11a
• /
• pp.441-444
• /
• 2011

Type A and Type B and are commercial HTPB models, which are very popular prepolymer for polyurethane binder family. So the study has been performed on the physical, chemical characteristic of HTPB and viscosity, mechanical property of PBX-A applying to HTPB. But We excluded the Type A from Appication test, because of law Hydroxyl value. And in the case of Type B, Type B-1, 2 has mechanical disadvatage to apply to HTPB in the process comparing with B-3. It seems to make no problem if we change equivalence ratio or curing condition within standards. But if we are to apply process condition like R-45HT(US-sample), it would be essential to apply HTPB with higher Hydroxyl Value and hydroxyl Functionality.

• Explosives and Blasting
• /
• v.24 no.2
• /
• pp.1-8
• /
• 2006

In this study, a charging density has been differently applied to all holes to improve an excavated length per round on excavating a tunnel in quartzite mine and to prevent a dead pressure phenomena and sintering phenomena. A composition initiating system using simultaneously a direct initiating system and a indirect initiating system with 2 detonators in one hole has been introduced to cut holes. As a bottom part which is difficult to make a free face are charged with a higher charging density and a column part are charged with a lower charging density, the composition charging and initiating system which the power of explosives works effectively in the rock mass is developed. As the results, a dead pressure phenomena and a sintering phenomena being often produced in a hard rock or in a long hole could be prevented. Besides, the workability was improved by about 15% and the specific charge was reduced to about 20%, as an excavated length vs. a drilled length per round could be increased over 95%.