• Journal of the Mineralogical Society of Korea
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• v.30 no.2
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• pp.59-70
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• 2017

$SiO_2$ is one of the most abundant constituents of the Earth's crust and mantle. Probing its electronic structures at high pressures is essential to understand their elastic and thermodynamic properties in the Earth's interior. The in situ high-pressure x-ray Raman scattering (XRS) experiment has been effective in providing detailed bonding transitions of the low-z materials under extreme compression. However, the relationship between the local atomic structures and XRS features at high pressure has not been fully established. The ab initio calculations have been used to overcome such experimental difficulties. Here we report the partial density of states (PDOS) of O atoms and the O K-edge XRS spectra of ${\alpha}-quartz$, ${\alpha}-cristobalite$, and $CaCl_2$-type $SiO_2$ phases calculated using ab initio calculations based on the full-potential linearized augmented plane wave (FP-LAPW) method. The unoccupied O PDOSs of the $CaCl_2$-type $SiO_2$ calculated with and without applying the core-hole effects present significantly distinctive features. The unoccupied O p states of the ${\alpha}-quartz$, ${\alpha}-cristobalite$ and $CaCl_2$-type $SiO_2$ calculated with considering the core-hole effect present similar features to their calculated O K-edge XRS spectra. This confirms that characteristic features in the O K-edge XRS stem from the electronic transition from 1s to unoccupied 2p states. The current results indicate that the core-hole effects should be taken in to consideration to calculate the precise O K-edge XRS features of the $SiO_2$ polymorphs at high pressure. Furthermore, we also calculated O K-edge XRS spectrum for $CaCl_2$-type $SiO_2$ at ~63 GPa. As the experimental spectra for these high pressure phases are not currently available, the current results for the $CaCl_2$-type $SiO_2$ provide useful prospect to predict in situ high-pressure XRS spectra.

• Elastomers and Composites
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• v.35 no.2
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• pp.122-131
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• 2000

In this work, the effect of chemical surface treatments on morphology of carbon blacks was investigated in terms of cure behavior and tearing energy ($G_T$) of carbon blacks/rubber composites. As experimental results, the polar or nonpolar chemical treatment led to a significant physical change of carbon black morphology. The cure activation energies (Ea) and frequency factor (A) obtained from Kissinger equation decreased with improving the dispersion of carbon flacks, resulting in high reactivity. However, a significant advantage of carbon black/rubber composites is gained by carbon blacks treated in basic (BCB) or nonpolar (NCB) chemical solution, resulting in increasing the tearing energy. These results could be explained by changes of dispersion, agglomerate, surface functional group, void volume, and cross-linking density of carbon black/rubber composites.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.9 no.1
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• pp.1-12
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• 2004

Sedimentary facies and high-resolution echo facies were analyzed to elucidate sedimentation pattern of the late Quaternary glacial-marine deposits in the northern continental margin of the South Shetland Islands. Six sedimentary facies are classified, based on grain texture and sedimentary structures in gravity cores. The high-resolution (3.5 ㎑) echo characters are classified into 6 echo facies on the basis of clarity, continuity, and shape of bottom and subbottom echoes together with seafloor topography. Distribution of the echo and sedimentary facies suggest that there was a significant change in sedimentation pattern between the Last Glacial Maximum (LGM) and subsequent glacier-retreating period. When the grounded glaciers extended to the present shelfbreak during LGM, coarse-grained subglacial tills were widespread in the shelf area, and deep troughs in the shelf were carved beneath the fast-flowing ice steam. As the glacial margin retreated landward after LGM, dense meltwater plumes released from the retreating ice-front were funneled along the glacier-carved troughs, and accumulated channel- or cannyon-fill deposits in the shelf and the upper to mid slope. At that time, slope sediments seem to have been reworked by slope failures and unsteady contour currents, and further transported by fine-grained turbidity currents along the South Shetland Trench. After the glacial retreat, sediments in the shelf and slope areas have been mainly introduced by persistent (hemi) pelagic settling, and fine-grained turbidity currents frequently occur along the axis of the South Shetland Trench.

• 한국해양학회지
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• v.26 no.1
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• pp.1-12
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• 1991

A multi-disciplinary geophysical study including gravity, magnetic, and seismic reflection profiling was carried out in the area between the Clarion fracture zone and the Clippertone fracture zone o the northeastern equatorial Pacific basin. There are small free-air gravity anomalies of less than 20 mgal over seamounts and the east-west trending abyssal hills. The negative residual gravity anomalies over seamounts may indicate the existence of low density seamount roots compared to surrounding oceanic crust. Non-existence of magnetic lineations and the magnetic anomalies of small smplitude with no polarity change in the east-west direction support that the study area belongs to the Cretaceous magnetic quite zone. Positive magnetic anomalies over seamounts offset 100 km in the east-west direction in the southern part of the study area suggest a possibility of left-lateral movement of those seamounts along unknown fractures. The sedimentary section in the study area can be divided into three units (Unit I, unit IIA, and Unit IIB) n the basis of reflection characteristics. the total thickness of sedimentary section varies from 200 to 400 meters and the sedimentary section is thicker in the southern area of rough topography near the seamount belt than in the northern flat area. Manganese nodules are abundant in the southern part of the study area where the ridges are developed and the Unit I layer is thicker than 100 meters.

• Korean journal of food and cookery science
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• v.16 no.2
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• pp.128-134
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• 2000

Cysteine, a thiol group-containing reducing agent which is known to relax the strain and increase the viscosity of dough, was added to Korean and imported wheat flour noodles to investigate the effect on the properties of raw, dried, and cooked noodles and to determine the optimum cooking time and amount to improve the color of noodles. Addition of cysteine up to 1% of flour (8.25 mmole/100 g flour) was not effective in increasing the brightness of raw and dried noodles and in changing the water activity of dried noodle. However, cysteine improved the brightness of cooked noodle made of both Korean and imported wheat flours. Also, there were notable differences in cooking and sensory properties of cysteine-added cooked noodles such as less firm and stickier texture due to the extraction of organic compounds into broth. When the noodles were cooked for their optimum cooking time, no difference was noticed in the texture and overall preference regardless of the addition of cysteine. Overall, the addition of 1 % cysteine increased the brightness of cooked noodles and reduced the cooking time.

• Economic and Environmental Geology
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• v.45 no.6
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• pp.661-672
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• 2012

Lab scale experiments to investigate the dissolution reaction among supercritical $CO_2$-sandstone-groundwater by using sandstones from Gyeongsang basin were performed. High pressurized cell system (100 bar and $50^{\circ}C$) was designed to create supercritical $CO_2$ in the cell, simulating the sub-surface $CO_2$ storage site. The first-order dissolution coefficient ($k_d$) of the sandstone was calculated by measuring the change of the weight of thin section or the concentration of ions dissolved in groundwater at the reaction time intervals. For 30 days of the supercritical $CO_2$-sandstone-groundwater reaction, physical properties of sandstone cores in Gyeongsang basin were measured to investigate the effect of supercritical $CO_2$ on the sandstone. The weight change of sandstone cores was also measured to calculate the dissolution coefficient and the dissolution time of 1 g per unit area (1 $cm^2$) of each sandstone was quantitatively predicted. For the experiment using thin sections, mass of $Ca^{2+}$ and $Na^+$ dissolved in groundwater increased, suggesting that plagioclase and calcite of the sandstone would be significantly dissolved when it contacts with supercritical $CO_2$ and groundwater at $CO_2$ sequestration sites. 0.66% of the original thin sec-tion mass for the sandstone were dissolved after 30 days reaction. The average porosity for C sandstones was 8.183% and it increased to 8.789% after 30 days of the reaction. The average dry density, seismic velocity, and 1-D compression strength of sandstones decreased and these results were dependent on the porosity increase by the dissolution during the reaction. By using the first-order dissolution coefficient, the average time to dissolve 1 g of B and C sandstones per unit area (1 $cm^2$) was calculated as 1,532 years and 329 years, respectively. From results, it was investigated that the physical property change of sandstones at Gyeongsang basin would rapidly occur when the supercritical $CO_2$ was injected into $CO_2$ sequestration sites.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.3C
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• pp.201-207
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• 2006

Soil tests are generally conducted using a membrane to measure a pore water pressure. However, it has also been recognized that the membrane penetrates into the specimen by the change of the confining pressure, and it results in the erroneous measurement in the pore water pressure and the volumetric strain. This study examined the effectiveness of the correction equation of the membrane penetration on the basis of the experimental data acquired during the isotropic unloading and the cyclic shear process using the hollow cylindrical shear test equipment. The results showed that the membrane penetration by the correction equation could be overestimated when the mean effective stress was lower than 20kPa in this study. The limitations originated from the sudden increase near the zero effective stress, and in order to prevent the overestimation in low effective stress condition, the use of the constant a was proposed in this study. Furthermore, the correction equation for the membrane penetration had to be applied carefully when the initial relative density was high and the density changes were occurred by the relocation of the soil particle by the liquefaction.

• Journal of the Korean Geotechnical Society
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• v.34 no.10
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• pp.5-16
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• 2018

The ever-increasing amount of waste vinyl is causing big environmental problems. In particular, those from farming industry are sometimes left on site or even illegally reclaimed due to the lack of environmental concerns and capacity for collection, which worsens the situation. It is, therefore, believed that the recycling of waste vinyl is the most ideal solution in the viewpoint of environmental preservation. In this context, the potential of vinyl strip as a ground reinforcing material is investigated to expand the application of waste vinyl recycling. In this study, a series of uniaxial compression tests and resonant column tests were performed for sand specimens reinforced with vinyl strips and cement to investigate their reinforcing effects on static and dynamic behaviors. The changes in the uniaxial compressive strength (UCS), the shear modulus and the damping ratio according to the mixing ratio of vinyl strips and cements were analysed for sand specimens, having 40% and 60% relative densities, under various mixing conditions. As a result, both the static and dynamic reinforcing effects of vinyl strip-cement mixture were confirmed and the optimum mixing ratio was proposed.

• The Journal of Engineering Geology
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• v.26 no.1
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• pp.101-115
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• 2016

We carried out laboratory material tests on two cements (KS-1 ordinary Portland and Class G) with changing W/S (Water/Solid) and the content of fly ash in order to evaluate their physical and mechanical properties. The specimens of KS-1 ordinary Portland cement were prepared with varying W/S (Solid=cement) in weight, while those of Class G cement were prepared with changing the content of fly ash in volume but maintaining W/S (Solid=cement+fly ash). The results of the material tests show that as the W/S in KS-1 ordinary Portland cement and the content of fly ash in Class G cement increase, the properties (density, sonic wave velocity, elastic constants, compressive and tensile strengths, thermal conductivity) decrease, but porosity and specific heat increase. In addition, an increase in confining pressure and in the content of fly ash leads to plastic failure behavior of the cements. The laboratory data were then used in a stability analysis of cement sheath for which an analytical solution for computing the stress distribution induced around a cased, cemented well was employed. The analysis was carried out with varying the injection well parameters such as thickness of casing and cement, injection pressure, dip and dip direction of injection well, and depth of injection well. The analysis results show that cement sheath is stable in the cases of relatively lower injection pressures and inclined and horizontal wells. However, in the other cases, it is damaged by mainly tensile failure.

• Composites Research
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• v.12 no.4
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• pp.71-78
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• 1999

To determine the effect of chemical structure of linear amine curing agents on thermal and mechanical properties, standard epoxy resin DGEBA was cured with diaminodiphenyl methane (DDM), diaminodiphenyl sulphone (DDS) in a stoichiometrically equivalent ratio. From this work, the effect of aromatic amine curing agents. In contrast, the results show that the DGEBA/DDS cure system having the sulfone structure between the benzene rings had higher values in the conversion of epoxide, density, shrinkage (%), glass transition temperature, tensile modulus and strength, flexural modulus and strength than the DGEBA/DDM cure system having methylene structure between the benzene rings, whereas the DGEBA/DDM cure system presented higher values in the maximum exothermic temperature, thermal expansion coefficient, and thermal stability. These results are caused by the relative effects of sulfone group having strong electronegativity and methylene group having (+) repulsive property and stem from the effect of the conversion ratio of epoxide group. The result of fractography shows that the each grain size of the DDM/DGEBA system with feather-like structure is larger than that of the DDS/DGEBA system.