• Transactions of the Korean Society of Mechanical Engineers B
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• v.39 no.1
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• pp.1-9
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• 2015

To satisfy stricter $NO_X$ emission regulations for light- and heavy-duty diesel vehicles, a control algorithm needs to be developed based on a selective catalytic reaction (SCR) dynamics model for chemical reactions. This paper presents the development and validation of a SCR dynamics model through test rig experiments and MATLAB simulations. A nonlinear state space model is proposed based on the mass conservation law of chemical reactions in the SCR dynamics model. Experiments were performed on a test rig to evaluate the effects of the $NO_X$ and $NH_3$ concentrations, gas temperature, and space velocity on the $NO_X$ conversion efficiency for the urea-SCR system. The parameter values of the proposed SCR model were identified using the experimental datasets. Finally, a control-oriented model for an SCR system was developed and validated from the experimental data in a MATLAB simulation. The results of this study should contribute toward developing a closed-loop control strategy for $NO_X$ and $NH_3$ slip reduction in the urea-SCR system for an actual engine test bench.

• Applied Chemistry for Engineering
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• v.1 no.2
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• pp.207-214
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• 1990

The catalytic reaction between CO and NO on polycrystalline Pt surface, which is very important in the development of catalyst for automobile exhaust gas control, has been studied using thermal desorption spectrometry(TDS) and steady-state experiment under ultra-high vacuum(UHV) conditions. With the pressures of CO and NO of each $1{\times}10^{-7}Torr$, the $CO_2$ formation rate showed a maximum at 560K. At the reaction temperature of 560K and the NO pressure of $1{\times}10^{-7}Torr$, the production of $CO_2$ was first order in $CO_2$ was first order in CO pressure below $1.35{\times}10^{-7}Torr$ of CO pressure whereas at higher CO pressures the rate became minus 0.3 order in CO. But the efforts of reactant pressure on the reaction was understood in consideration of the surface concentrations of adsorbates. With the results, we proposed a new reaction mechanism for this reaction.

• Journal of the Korean Society of Marine Environment & Safety
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• v.19 no.5
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• pp.525-530
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• 2013

In this study, the generator engine of training ship M/S "HAE RIM" of Kunsan National University which is being operated for 20 years was used in the experiment. The experiment was carried out under the engine speed of 1200rpm, then the load was varied 30 kW intervals from 0 to 90 kW and the injection timing was varied $2^{\circ}$CA intervals from BTDC $19^{\circ}$ to $23^{\circ}$CA. In the case of advancing fuel injection timing from BTDC $21^{\circ}$CA to $23^{\circ}$CA, specific fuel consumption is decreased by 1.37%, NOx is increased by 11.59 %, soot is decreased by 23.5 % and $SO_2$ is decreased by 2.8 %. Accoring to the analysis of effects of fuel injection timing on combustion & exhaust emissions characteristics on an old marine diesel engine, it is proved that the optimum fuel injection timing is BTDC $23^{\circ}$ which is $2^{\circ}$ faster than that of original injection timing.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.2
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• pp.168-177
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• 2011

A set of kinetics study on the reduction with $CH_4$, oxidation with steam and oxidation with air was performed for $Fe_2O_3/ZrO_2$. $Fe_2O_3/ZrO_2$ was prepared by aerial oxidation method. The reactivity experiments were performed in a thermogravimetric analyzer (TGA) with different reacting gas concentrations and temperatures. The obtained activation energy of reduction by methane, oxidation by water and oxidation by air are 219 kJ/mol, 238 and 20 respectively.

• Journal of the Korean Chemical Society
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• v.11 no.4
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• pp.150-158
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• 1967

When anthracite burns by natural draft the mole percent of carbon monoxide (CO%) contained in exhaust gas is approximately expressed as follows in the early stage of combustion. (CO%)=$\frac{2{\alpha}}{1+{\alpha}}(CO_2%)$ exp $[-\vec{k}(No_2-Nc)^{1/2}{\tau}]$ where ${\alpha}=\frac{-0.395K_p+\sqrt{0.156K^2_p+(0.83+0.21K_p)K_p}}{0.83+0.21K_p}$ and $logK_p =-\frac{8593}{T} + 2.45logT -1.08{\times}10^{-3}T + 1.12{\times}10^{-7}T^2+2.77\vec{k},\;No_2$ and $N_c$ are the rate constant for the reaction ($CO+\frac{1}{2}O_2{\to}CO_2$), mole fraction of oxygen and oxides of carbon contained in the exhaust gas, respectively. From experimental evidence obtained in this work with natural draft combustion of briquettes the percent of carbon monoxide to the total quantity of oxides of carbon produced and rate of air flow into the furnace were: 1.76% and 0.53 l/sec (When lid is used in the furnace) 12.35% and 2.4 l/sec (without use of a lid). is the rate constant for the reaction($CO+\frac{1}{2}O_2{\to}CO_2$) and $N_0,\;and\;N_c$ are respectively the molefraction of oxygen and oxide of carbon contained in the exhaust gas.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2009.11a
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• pp.231-235
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• 2009

The mainly objectives of this study was a combustion dynamics and instability characteristics in a model dump type combustor which is scale down of GE 7FA+e DLN 2.6 gas turbine combustor with running at Seo-Inchon combined cycle power plant. Model gas turbine injector has 2-stage swirl vane and it's reduced 1/3 size of the original one. The shape of plenum and combustor were designed for similar acoustic characteristics. As the result, this research have been shows the peak frequency of model combustor was changed quarter-wave mode to Helmholtz resonator mode in plenum and longitudinal mode in dump combustor at unstable flame conditions caused by the different of combustor temperature and fuel-air mixture distributions.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2011.05a
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• pp.281-284
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• 2011

Recently, many drivers was the damage caused by similar oil product sales and gas station by not using quantitative gas. so, these damages is expected to rise damages by increasing these problem. By using similar oil products, caused damage in the fuel lines' working of lubrication and self-cleaning function for the occurred trouble in the part of the early obsolescence and the accumulation of impurities in the fuel lines, combustion rate due to the difference between retail gasoline engine, the burden of weight, Toxic substances in exhaust emissions, engine oil and unresolved issue is the chemical reaction can occur. to prevent these damages, using the system use in-vehicle state data with OBD-II protocol and measure quantitative gas and similar oil. In this paper, there implement similar oil identification and quantitative gas system through OBD-II scanner to provide WiFi communcation by using WinCe development Board.

• Journal of the Korean Society of Marine Environment & Safety
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• v.27 no.5
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• pp.647-655
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• 2021

The IMO (International Maritime Organization) is discussing the improvement of energy ef iciency of ships in order to reduce greenhouse gas emissions from ships. Currently, by applying an ORC power generation system using waste heat generated from ships, high energy conversion efficiency can be expected from ships. This technology uses an organic medium based on Freon or hydrocarbons as the working fluid, which evaporates at a lower temperature range than water. Through this, it is possible to generate steam (gas) and generate power at a low and low temperature relatively. In this study, the analysis of heat flow between the refrigerant and waste heat in the ORC power generation system, which is an organic Rankine cycle, is analyzed using 3D simulation techniques to determine the temperature change, velocity change, pressure change, and mass change of the fluid flowing of the WHRU (Waste Heat Recovery Unit) inside and the outside the structure. The purpose of this study is to analyze how the mass change affects the structure, and this study analyzed the heat transfer of the heat exchanger from the refrigerant and the exhaust gas of the ship's main engine in the ORC power generation system using this technique.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.258-258
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• 2013

최근 건조 제품의 양질화, 고급화 및 편의화가 요구되어 이를 충족시키기 위한 새로운 건조방법이 계속 개발 되어 왔다. 이러한 방법들 중에서 저온과 진공하에서 건조가 이루어지는 진공 동결 건조는 가장 완벽한 건조 방법으로 최근 실용화 되고 있다. 진공동결건조란 건조의 한 종류로 수분을 함유한 시료를 동결시킨 후 진공펌프를 이용하여 수증기압을 3중점 이하로 낮추어 얼음을 직접 증기로 만드는 승화의 원리에 의해서 얻어진다. 분무진공동결건조의 특징은 (1) 물리적구조의 보존성, (2) 화학적인 안정성, (3) 생물학적인 활동의 보존성, (4) 제품의 높은 복원성 및 재생성이다. 따라서 분무진공동결건조 기술은 크게 진공, 분무, 동결, 건조, 멸균 등과 같은 요소기술의 복합기술이라 할 수 있다. 분말을 제조하기 위해서 진공동결건조 후 분쇄하는 방법을 사용하나 본 방법에서는 정밀화학품 제조를 위해서 분무진공동결건조 방식을 사용한다. 이를 통하여 적당한 크기인 5~10 um의 입경 제조가 가능하고, 공기동력학적인 입경이 기존 방식에 비해 작아서 허파까지의 운반효율이 1.5~2배 우수하다. 화학, 의학 분야에서의 분무동결 건조는 주로 민감한 제품, 즉 생물학적 고유성의 손상 없이 물을 제거하는데 사용되어 영구적으로 저장 가능한 상태로 보관할 수 있으며 물의 첨가로 원상태로 복구할 수 있어서 매우 각광을 받고 있다. 의약용 냉동건조 제품은 항생물질, 박테리아, 혈청, 백신, 검사 약물, 단백질을 포함하는 생물공학 제품들, 세포, 섬유, 화학제품 등이 있으며 주로 vial 또는 ampule 상태로 건조가 이루어진다.본 연구에서는 원료를 $-194^{\circ}C$의 액체질소에 분무시켜 동결된 미립자를 형성한 후 진공 및 저온상태에서얼음의 승화(sublimation)에 기반한 1차 건조와 수증기 탈착(desorption)에 기초한 2차 건조 과정으로 구성된 분무진공동결건조기를 개발하였다. 분무동결 과정의 해석을 통해 2유체식 노즐을 통해 분무된 미세 입경의 액적이 액체 질소 표면까지 도달하는 회수률, 분무 노즐의 위치, 운전 조건 및 용기의 설계의 최적화를 수행하였다. 초기 액적속도, 분무노즐의 높이, 흡입구 추가에 따른 액적 유동 및 회수의 특성을 제시하였으며 이를 통한 분사시스템 고도화 가능성을 제시하였다. 구형의 미세 입자가 적층된 제품의 동결건조 공정의 해석은 흡착승화 모델(sorption sublimation model)을 기반으로 다음과 같은 열전달, 물질전달, 상변화 모델을 고려하여 유도되었다. 분무노즐 및 냉동/진공 배기계 시작품을 개발하여, 표면의 고다공도를 갖춘 입경 3~20 m 정도의 시료를 얻을 수 있으며, 동역학적 입경 5 m 충족함을 확인하였다.

• Journal of Korean Tunnelling and Underground Space Association
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• v.21 no.3
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• pp.363-375
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• 2019

Since the double-deck tunnel is deeply constructed in the city, it is necessary to secure the installation space of air supply and exhaust, escape passage stairs, elevator, distribution facilities and connection tunnels in the vertical shaft for the double-deck tunnel. Also, in order to minimize the effect of construction on adjacent area, it is necessary to construct the concrete structures at high speed in vertical shaft after tunnel excavation. Therefore, the slabs and the stairs in vertical shaft are needed to be constructed using precast concrete, and the rapid construction techniques of bracket for supporting the inner precast structure are needed. The bracket installation methods include cast-in-place concrete, precast concrete and steel. In this study, the improvement of the steel brackets with good economical efficiency and good workability was carried out in consideration of the improvement of the construction speed. We have developed a new bracket that is optimized through bracket shape improvement, anchor bolt position adjustment and quantity optimization. As a result of the structural performance test, it was confirmed that the required load supporting capacity was secured. As a result of structural performance test for bar type anchor bolt and bent anchor anchor bolt, it was confirmed that the required load carrying capacity was secured and that the load bearing capacity of bent anchor bolt was large.