• Title/Summary/Keyword: 물질흐름

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The Salt Removal Efficiency Characteristics of Carbon Electrodes Using Fabric Current Collector with High Tensile Strength in a Capacitive Deionization Process (인장강도가 뛰어난 직물집전체를 이용한 탄소전극의 축전식 탈염공정에서의 제염효과)

  • Seong, Du-Ri;Kim, Dae Su
    • Korean Chemical Engineering Research
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    • v.58 no.3
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    • pp.466-473
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    • 2020
  • Fabric current collector can be a promising electrode material for Capacitive Deionization (CDI) system that can achieve energy-efficient desalination of water. The one of the most attractive feature of the fabric current collector is its high tensile strength, which can be an alternative to the low mechanical strength of the graphite foil electrode. Another advantage is that the textile properties can easily make shapes by simple cutting, and the porosity and inter-fiber space which can assist facile flow of the aqueous medium. The fibers used in this study were made of woven structures using a spinning yarn using conductive LM fiber and carbon fiber, with tensile strength of 319 MPa, about 60 times stronger than graphite foil. The results were analyzed by measuring the salt removal efficiency by changing the viscosity of electrode slurry, adsorption voltage, flow rate of the aqueous medium, and concentration of the aqueous medium. Under the conditions of NaCl 200 mg/L, 20ml/min and adsorption voltage 1.5 V, salt removal efficiency of 43.9% in unit cells and 59.8% in modules stacked with 100 cells were shown, respectively. In unit cells, salt removal efficiency increases as the adsorption voltage increase to 1.3, 1.4 and 1.5 V. However, increasing to 1.6 and 1.7 V reduced salt removal efficiency. However, the 100-cell-stacked module showed a moderate increase in salt removal efficiency even at voltages above 1.5 V. The salt removal rate decreased when the flow rate of the feed was increased, and the salt removal rate decreased when the concentration of the feed was increased. This work shows that fabric current collector can be an alternative of a graphite foil.

Nitrogen Removal in Column Wetlands Packed with Synthetic Fiber Treating Piggery Stormwater (축산단지 강우 유출수 처리를 위한 합성섬유충진 습지의 질소제거에 관한 연구)

  • Cheng, Jing;Kim, Youngchul
    • Journal of Wetlands Research
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    • v.18 no.1
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    • pp.68-75
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    • 2016
  • A set of lab-scale polymer synthetic fiber packed column wetlands composing three columns (CW1, CW2 and CW3) with different hydraulic regimes, recirculation frequencies and pollutant loading rates, were operated in 2012. Synthetic fiber tested as an alternative wetland medium for soil mixture or gravel which has been widely used, has very high pore size and volume, so that clogging opportunity can be greatly avoided. The inflow to the wetland was artificial stormwater. All the wetlands achieved effective removal of TSS (94%~96%), TCOD (68%~73%), TN (35%~58%), TKN (62%~73%) and NH4-N (85%~ 99%). Particularly, it was observed that COD was released from the fiber during one distinct period in all wetlands. This was probably due to the degradation of polymer fiber, and the released organic matters were found to serve as carbon source for denitrification. In addition, with longer retention time and frequent recirculation, lower effluent concentration was observed. With higher pollutant loading rate, higher nitrification and denitrification rates were achieved. However, although organic matters were released from the fiber, the lack of carbon source was still the limiting factor for the system since the release persisted only for 40 days.

Estimation of Cadmium, Copper, Lead Mobility in Column Packed with Furnace Slag (제강슬래그로 충전된 컬럼에서의 카드뮴, 구리, 납의 이동성 평가)

  • Lee, Gwang-Hun;Chung, Jae-Shik;Nam, Kyoung-Phile;Park, Jun-Boum
    • Journal of Soil and Groundwater Environment
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    • v.13 no.4
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    • pp.54-61
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    • 2008
  • Permeable reactive barriers (PRBs) technology has been focused in contaminated groundwater remediation. It is necessary to select adequate reactive material according to characteristics of contaminant in groundwater. In this research, the reaction between reactive material and heavy metal contaminants was estimated through column test. Reactive material was slag, which has been produced in Gwangyang power plant, and heavy metal contaminants were cadmium, lead and copper. Column test was performed in the condition of 1) single and multi contaminated solution and 2) different initial concentration of cadmium. Retardation factor of cadmium is 3.94 in multi contamination. But that of copper is 40.3 in single and 25 in multi. The difference of retardation between cadmium and copper is due to affinity, resulted from the difference of electronegativity. In multi-contamination, copper effluent concentration was above initial copper concentration and at the same time lead effluent concentration was decreased. This phenomenon was considered that lead extract copper sorbed in slag and then lead was sorbed to the vacant sorption site instead. And as the initial concentration was increased, the retardation factor of cadmium became decreased.

Development of a Bioscrubber for Treatment of VOC Emissions from Contaminated Soil with Hydrocarbons (유류오염토양으로부터 발생하는 VOC가스처리를 위한 바이오스크러버 개발)

  • 장윤영;황경엽;곽재호;최대기
    • Journal of Korea Soil Environment Society
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    • v.2 no.1
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    • pp.83-90
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    • 1997
  • Aiming at the treatment of large volumes of gas with a low concentration of poorly water soluble VOC(Volatile Organic Compound), a new system is proposed: the combination absorption tower/bioreactor. In the scrubber part of the bioscrubbing system, the contaminating compounds are absorbed in a aqueous phase. The contaminated scrubbing liquid is transported to the bioreactor, where the compounds are biodegraded by aerobic microorganisms (mainly to carbon dioxide, water, and biomass). In this study, separation of a volatile organic compound(VOC) out of a waste gas stream has been carried out using a re-cyclable high boiling point extrant(HBE). The liquid stream containing a high boiling point entrant(HBE) scrubs the gas stream in a direct gas-liquid countercurrent contacting operation in a packed tower for the removal of said component from the gaseous stream. A packed-bed column using Pall Ring was set up in order to simulate practical conditions for the scrubbing tower. The liquid stream transported to the bioreactor is recovered and recycled to the scrubber. The model gas, which contained 400 mg/$\textrm{m}^3$ of toluene, at a rate of 100 L/min, flowed into the packed column where the scrubbing liquid trickled over the packing in countercurrent to the rising gas at 10~15L/min. The bioscrubber designed for large volume air streams containing VOCs showed removal efficiency up to 80% in an optimum operating conditions during the tests fer removing toluene from an air stream by scrubbing the air stream with HBE.

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A Comparative Study on the Application of RISP in the Context of Risk Types -Focusing on Typhoon and Hydrofluoric Acid Spill Risks (위험 유형에 따른 위험 정보 탐색과 처리 과정 연구 -불산 유출과 태풍 관련 위험 상황 비교 중심)

  • Huh, Seohyeon;Kim, Yungwook
    • Korean journal of communication and information
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    • v.70
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    • pp.246-276
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    • 2015
  • From a historical perspective of risk communication, risks can be classified by their associated level of responsibility. In the case of technical risks such as hazardous chemical accidents, people perceive that risk-related organizations have a high level of responsibility; however, they do not in traditional risks such as natural disasters. This study aims to examine risk information seeking and processing, as seen in two types of risk, based on the Risk Information Seeking and Processing(RISP) model. For this purpose, hypotheses and a research question are developed with current domestic risk issues, and the results show significant differences in risk information seeking and processing between the two types of risk. Specifically, in the case of the chemical spill accident, negative emotion against relevant institutions makes different information seeking and processing compared to the natural disaster. The low level responsibility risk such as typhoon comparatively follows the flow of the original RISP model. However, the high level responsibility risk such as the hydrofluoric acid spill did not match with the RISP model. Based on the research results, theoretical implications were discussed.

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Direction of Development of Reaction to Bio-terrorism (생물테러리즘 대응을 위한 기술적 측면의 발전방향)

  • Lee, Kwang-Iyeol;Kim, Chang-Ho
    • Korean Security Journal
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    • no.14
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    • pp.311-336
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    • 2007
  • This study examines the concepts of counter-act against the Bio-terrorism and the reaction system in advanced countries, thereby to find out reaction system necessary to Korea. Acts on anti-Bio-terrorism is divided to detection stage, protection stage, diagnosis stage and detoxication and neutralization stage according to flow of event occurrence. As for detection stage, Korea is developing it as contact type, while advanced countries are under development of the devices that may detect the terrorism from the remote distance. It is necessary for Korea to develop the remote-distant detection system as well as the contact type of device that may promptly operate. Among the protection gears, the quality of Korea's gas mask is recognized worldwide, but that of other outfits should be improved by applying the state-of-art science technology. The diagnosis device also should be developed to the extent that the dispatched initial action team may make immediate decisions necessary in the field. As the current trends for detoxication materials worldwide require the improvement to new materials harmless to human body and equipment, Korea is also required to acquire those materials. The technology for neutralization means the development of vaccine and antibiotics and it requires the development made by shared efforts worldwide. For this purpose, it is necessary to further develop Korea's medical technology. In addition, the further efforts are required in terms of reaction manual, training model, public communication efforts and preparation for trauma syndrome.

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Run-out Modeling of Debris Flows in Mt. Umyeon using FLO-2D (FLO-2D 모형을 이용한 우면산 토석류 유동 수치모의)

  • Kim, Seungeun;Paik, Joongcheol;Kim, Kyung Suk
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.3
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    • pp.965-974
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    • 2013
  • Multiple debris flows occurred on July 27, 2012 in Mt. Umyeon, which resulted in 16 casualties and severe property demage. Accurate reproducing of the propagation and deposition of debris flow is essential for mitigating these disasters. Through applying FLO-2D model to these debris flows and comparing the results with field observations, we seek to evaluate the performance of the model and to analyse the rheological model parameters. Representative yield stress and dynamic viscosity back-calculated for the debris flows in the northern side of Mt. Umyeon are 1022 Pa and 652 $Pa{\cdot}s$, respectively. Numerical results obtained using these parameters reveal that deposition areas of debris flows in Raemian and Shindong-A regions are well reproduced in 63-85% agreement with the field observations. However, the propagation velocities of the flows are significantly underestimated, which is attributable to the inherent limitations of the model that can't take the entrainment of bed material and surface water into account. The debris flow deposition computed in Hyeongchon region where the entrainment is not significant appears to be in very good agreement with the field observation. The sensitivity study of the numerical results on model parameters shows that both sediment volume concentration and roughness coefficient significantly affect the flow thickness and velocity, which underscores the importance of careful selection of these model parameters in FLO-2D modeling.

Sedimentation Deposit in Surcharged Manhole with 90 Degree Bend (과부하 $90^{\circ}$ 접합맨홀에서의 유사퇴적)

  • Song, Ju-Il;Kim, Ju-Hyung;Rim, Chang-Soo;Yoon, Sei-Eui
    • Proceedings of the Korea Water Resources Association Conference
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    • 2011.05a
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    • pp.317-317
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    • 2011
  • 맨홀 및 관로에 퇴적되는 유사는 우수관거의 통수능을 감소기키고 우수관거 시스템의 효율을 저하시켜, 맨홀에서 역류를 발생시켜 저지대 침수의 한 원인인 되고 있다. 또한 관거내에서 유수가 일정한 유속을 확보하지 못하면 오염물이 침전되고, 관거내 유하시간이 길어져 침전물 부패로 인한 황화물질 및 악취 등이 발생할 수 있다. 따라서 우수 및 하수관거 시스템에서 유사와 관련된 주된 연구는 관거내의 유사거동 특성을 규명하고자 하는 것이었다. 그러나 맨홀과 관련하여서는 맨홀내의 오염물 지체시간 및 확산 특성분석이 전부였고, 유사의 퇴적 및 배출 등과 관련된 거동특성 연구는 매우 미흡한 실정이다. 본 연구에서는 유입관과 유출관이 $90^{\circ}$로 접합된 맨홀을 대상으로 수리실험을 실시하고, 맨홀형태(사각형, 원형), 유사유입형태(연속주입, 일정기간주입), 유사종류(주문진표준사, 모래), 유사유입량 및 맨홀내부형상 변화에 따른 맨홀내 유사퇴적량을 확인하였다. 실험결과 그림 1과 같이 $90^{\circ}$ 접합맨홀에서는 유사유입형태와 무관하게 유입유사량이 증가할수록 퇴적량 또한 증가하였다. 그러나 유사퇴적량은 사각형맨홀보다 원형맨홀에서 적었다. 이는 관거가 $90^{\circ}$로 접합된 맨홀내에서의 유사거동 양상은 우선 유입되는 유사가 맨홀바닦에 퇴적되고 와류에 의해 부유되는 유사가 유출관을 통해 배출되는데 사각형맨홀에 비하여 원형맨홀에서 와류가 더 크게 형성되기 때문인 것으로 판단된다. 유사가 일정기간주입되는 경우 원형맨홀 내부에 퇴적되는 유사량은 거의 없었다. 사각형맨홀내부에 벤칭을 설치한 경우 설치전과 비교하여 퇴적량은 50%이상 저감되었고, 일정기간주입시에는 벤칭 설치 후 유사퇴적량은 거의 없었다. 유입유사가 모래인 경우 맨홀내 퇴적량은 주문진표준사와 비교하여 증가하였다. 모래는 주문진 표준사와 비교하여 중량이 크다. 따라서 같은 흐름조건에서 주문진표준사와 비교하여 부유되는 유사량이 적고, 배출되는 유사량 또한 적었다. 유량과 관거유속이 동일한 조건에서 유출관과 유입관이 일직선상으로 연결된 중간맨홀내부에 퇴적된 주문진표준사의량과 비교하여 $90^{\circ}$ 접합맨홀의 퇴적량이 상대적으로 적었다. 이 또한 앞서 기술한 와류의 영향으로 판단된다. 일반적으로 $90^{\circ}$접합맨홀내부에서 발생하는 와류가 중간맨홀보다 크고, 이로 인해 에너지손실은 커지지만 유사거동과 관련하여서는 와류가 크게 발생하는 맨홀조건에서 퇴적량이 적음을 실험적으로 확인하였다.

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Mineralogical Characteristics of Calcite observed in the KAERI Underground Research Tunnel (고준위폐기물 지하처분연구시설(KURT)에서 관찰되는 방해석의 광물학적 특징)

  • Lee, Seung-Yeop;Baik, Min-Hoon;Cho, Won-Jin
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.4 s.50
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    • pp.239-246
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    • 2006
  • KAERI Underground Research Tunnel (KURT) was recently constructed through the site investigation from the yea. of 2003 at KAERI site, Dukjin-dong, Yuseong-gu, Daejeon city. The geo-logic setting of the site has been slightly metamorphosed. There are small fractures developed in the rock and several kinds of secondary filling minerals exist in the fractures. We examined mineralogical characteristics of fracture-filling calcite, which is not only largely distributed, but also can significantly affect the radionuclides migration. The calcite is found along fractures like other secondary minerals, forming thick veins in part. Most calcite-filled fractures contain quartz, iron oxides, and dolomite as minor minerals. The calcite crystals show an characteristic appearance with an uniformly oriented growth, coated with goethite on the edge and the etch-pit sites of their surface. Some calcite crystals have been newly formed by the precipitation of elements dissolved from the tunnel shotcrete wall, and their morphology changed according to the chemistry and flow of groundwater. The calcite can modify the groundwater chemistry and significantly affect the sorption behavior of radionuclides. The characteristic crystal structure and surface morphology of the calcite examined in the KURT site will be used as important basic data for the radionuclide migration experiment in the future.

A Study on the Promotion of Combustible Construction Waste Recycling (가연성 건설폐기물의 자원화 제고를 위한 방안)

  • Park, Ji-Sun;Lee, Sea-Hyun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.1
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    • pp.89-95
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    • 2009
  • The current enforce decree of "The Act on the Promotion of Construction Waste Recycling" divides seventeen kinds of construction wastes by property and configuration. Mixed construction waste, one of them classified by the enforce decree, is composed two more than justified construction wastes except refuse soil and rock. In construction wastes justified by enforce decree of this law, most refuse concrete and asphalt concrete of construction wastes are recycled. As well as refuse metal is separated, sorted from bulk them, and merchandised for value. Finally this is used the secondary manufactured products. Even though combustible construction wastes like refuse wood, plastics, fiber can be recycled RDF(Refuse derived fuel) or RPF(Refuse plastic fuel) because of high caloric value and low heavy metal but most of them are discharged as mixed construction waste and then treated by treated by incineration and landfill. Therefore, to control construction waste flow efficiently, construction wastes are classifies first combustible, incombustible, mixed combustible, incombustible and etc. in this study. The combustible waste is consisted refuse wood, plastics, fiber and etc. and incombustible waste contains refuse concrete, asphalt, and etc. Mixed construction is construction waste that can not separate from mixed waste bulk with different kinds.

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