• Title/Summary/Keyword: 물질흐름

Search Result 683, Processing Time 0.026 seconds

Activity and Selectivity in Low Temperature for Dibenzothiophene Hydrodesulfurization based Zeolite Support (제올라이트 담체상의 디벤조티오펜 수첨탈황반응에서 저온활성 및 선택성)

  • Kim, Moon-Chan
    • Applied Chemistry for Engineering
    • /
    • v.9 no.1
    • /
    • pp.101-106
    • /
    • 1998
  • Two types of CoMo/zeolite as well as $NiMo/{\gamma}-Al_2O_3$ were prepared and their activities and selectivities of low-temperature dibenzothiophene(DBT) hydrodesulfurization(HDS) were studied in high pressure fixed bed reactor. The HDS activities of CoMo/zeolites were higher than that of $NiMo/{\gamma}-Al_2O_3$ at temperatures below $225^{\circ}C$ while they were lower than that of $NiMo/{\gamma}-Al_2O_3$ at temperatures higher than $275^{\circ}C$. The main products from $NiMo/{\gamma}-Al_2O_3$ were biphenyl and cyclohexylbenzene. The product distribution of CoMo/zeolite catalysts was different from that of $NiMo/{\gamma}-Al_2O_3$. It is speculated that DBT is converted to alkylcyclohexane over zeolite based catalysts through both alkylation and hydrogenation reactions. The crystal structure of molybdenum was $MoO_3$ in fresh zeolite support while mixtures of $MoO_3$ and $MoS_2$ were observed in the aged catalyst.

  • PDF

Analytic study on arsenic content in plastic materials (플라스틱 소재의 비소 함유량 분석에 관한 연구)

  • Lee, Jae-In;Choi, Zel-Ho;Choi, Ki-In;Ko, Byung-Rae;Choi, In-Suk;Cho, Hun-Sik
    • Analytical Science and Technology
    • /
    • v.25 no.6
    • /
    • pp.402-409
    • /
    • 2012
  • Quantitative analytical condition for arsenic in plastic materials by the flow injection-hydride generation-inductively coupled plasma-atomic emission spectrometry was studied. The plastic samples were dissolved by wet-acid digestion method and microwave-acid digestion method. The reproducibility and accuracy in this method was verified using of certified reference materials(CRMs) CRM-EC680k and CRM-EC681k. The analyical results agrees with certified value within the range of uncertainty. The results of CRM-EC680k wer 4.1~4.3 mg/kg (certified value $4.1{\pm}0.5$ mg/kg), and the results of CRM-EC681k were 28.9~30.6 mg/kg (certified value $29.1{\pm}1.8$ mg/kg).

Water-well Management Data Modeling using UML 2.0 based in u-GIS Environment (u-GIS 환경에서 UML 2.0을 활용한 지하수 관리 데이터 모델링)

  • Jung, Se-Hoon;Kim, Kyung-Jong;Sim, Chun-Bo
    • The Journal of the Korea institute of electronic communication sciences
    • /
    • v.6 no.4
    • /
    • pp.523-531
    • /
    • 2011
  • Many of the wells which were constructed to use ground water resource are abandoned and not managed efficiently after its use. And a variety of heavy metals and organic compounds are released from the abandoned wells and this can cause ground water pollution. Therefore in this paper implemented to monitor locational information drill holes and underground water sensing information on real time basis using u-GIS environment to combined ubiquitous sensor node and GIS technology to improve these problems. In addition, this system suggests using system by UML 2.0 by analyzing variety requirement of user and between system internal modules interaction and data flow. It provides graphical user interfaces (GUI) to system users to monitor water-well related property information and its managements for each water-well at remote site by variety platform by GIS map and web environment and mobile device based on smart phone.

A Study on Numerical Analysis and Performance Improvement of Ventilation Systems in Coating Room (코팅 룸 배기시스템 수치해석 및 성능개선에 대한 연구)

  • Lee, Ki Yeon;Kim, Kug Weon
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.14 no.5
    • /
    • pp.2086-2091
    • /
    • 2013
  • One of the most important objects for the industrial ventilation is to protect worker's health from the harmful substances. Mainly in industrial ventilation, the harmful substances broken out through manufacturing process are to be quickly emitted outside. Recently the importance of the industrial ventilation increases with the recognition change of industrial ventilation from manufacturing focusing to human focusing. In this paper, the air flow simulation inside the coating room is performed. All the coating room and the ventilation system are modeled by SolidWorks program and air flow distribution and ventilation performance are analyzed by Flow simulation program. And the air flow directions and the air flow velocities inside the coating room are enhanced with the use of local ventilation.

A Study on Physical Dechlorination of Mixed Plastics using Screw Reactor (스크류반응기를 이용한 흔합플라스틱의 물리적 탈염소에 관한 연구)

  • Kim Sang-Guk;Eom Yujin;Chung Soo-Hyun
    • Resources Recycling
    • /
    • v.15 no.1 s.69
    • /
    • pp.20-27
    • /
    • 2006
  • PVC is the thermoplastic offering excellent material properties. PVC has been used in wide variety of applications, however, it causes environmental problems when it is discarded because of its high chlorine content. Since dechlorination reaction of PVC is taking place at relatively low temperature compared to the pyrolysis temperature of plastics, study on the dechlorination reaction has been carried out as a pre-treatment process. Twin screw reactor which shows excellent mixing capabilities is employed. Experimental variables are the first and second reactor temperature, PVC content in mixed plastics, viscosity of mixed plastics, feeding rate, rotational speed or the second reactor. Over $90\%$ of dechlorination ratio can be obtained under proper operation conditions. Chlorine gas evolved from reactor is absorbed in water and can be recovered as a hydrochloric acid. Analysis had been done on chlorine flows by taking material balance over realtor.

Experimental Study on Thermal NOx and CO Emission in a Laboratory-Scale Incinerator with Reversed Secondary Air Jet Injection (역방향 2차 공기 주입 방식을 적용한 소각 연소로의 Thermal NOx 및 CO 배출특성에 대한 축소모형실험 연구)

  • Choi, Chonggun;Choi, Woosung;Shin, Donghoon
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.40 no.8
    • /
    • pp.503-510
    • /
    • 2016
  • Incinerators generally emit pollutants such as NOx and CO during the combustion process. In this paper, pollutant emissions and temperature distributions were studied in a simulated incinerator with a reversed (relative to the flue gas flow) secondary air injection system. The experiments were performed by using a lab-scale furnace in order to evaluate the effects of the injection location, direction and flow rate of secondary air jets. The emission of NOx was lower in the case of reversed secondary air injection than in the case of cross injection, due to the recirculation and mixing of the exhaust gas. In the reversed air injection cases, thermal NOx emissions decreased as secondary air ratio increased from 30 to 60 and slightly increased at secondary air ratios higher than 60. In most cases, CO emissions were not detected except for a few reversed secondary air injection cases, in which cases CO concentrations below 2ppm were observed.

Back-Analysis for Estimating Transmissivity in Riverbank Filtration (강변여과 대수층의 투수량계수 추정을 위한 역해석)

  • Park Seo-Hwa;Lee Sang-Il;Lee Sang-Sin
    • Journal of Korea Water Resources Association
    • /
    • v.39 no.6 s.167
    • /
    • pp.503-510
    • /
    • 2006
  • Riverbank filtration is a natural process, using alluvial aquifers to remove contaminants and pathogens in river water for the production of drinking water. Back analysis which minimizes the objective function that is typically the sum of squares of the differences between the calculated and measured quantities is used for the estimation of aquifer parameters. In this study, transmissivity is back-analysed using the BFGS (Broyden-Fletcher-Goldfarb-Shanno) scheme for optimization. MOC is used to obtain calculated groundwater level. The developed inverse model was applied to Dae-san, Chang-won city where riverbank filtration is being undertaken. The model showed good convergence behavior for different groundwater conditions. The performance of the model was better than a widely-used commercial software package in terms of error between calculated and observed groundwater level.

Study to Reduce Sedimentation Deposit in Straight Path Manholes (중간맨홀내의 유사퇴적 저감방안 연구)

  • Song, Ju Il;Kim, Jung Soo;Rim, Chang Soo;Yoon, Sei Eui
    • 한국방재학회:학술대회논문집
    • /
    • 2011.02a
    • /
    • pp.97-97
    • /
    • 2011
  • 관로 및 맨홀에 퇴적된 유사는 우수관거의 통수능을 감소시키고 전체 우수관거 시스템의 효과를 저하시켜, 저지대 침수 및 맨홀역류의 원인이 되고 있다. 또한 관로의 최소 유속이 유지되지 않으면 오염물이 침전되고, 관로내의 유하시간이 길어져 침전물 부패로 인한 황하물질 및 악취 등이 발생될 수 있다. 따라서 관로의 유사와 관련된 주된 연구는 관로내의 유사거동 특성을 규명하는 것이었다. 그러나 맨홀에서의 유사퇴적 및 배출 등과 관련된 연구는 매우 미흡한 실정이다. 본 연구에서 유입관과 유출관이 일직선상으로 연결된 중간맨홀을 대상으로 수리실험을 실시하고, 맨홀형태(사각형, 원형), 유사유입형태(연속주입, 일정기간주입), 유사유입량 및 맨홀내부 구조변화에 따른 맨홀내 유사퇴적량을 확인하였다. 또한 맨홀내에 퇴적된 유사를 완전히 배출할 수 있는 관거 유속을 측정하였다. 유사퇴적량을 확인한 결과 맨홀내부의 구조변화가 없는 기본형에서는 유사유입형태가 연속주입 또는 일정기간주입인지와는 관계없이 유입유사량이 증가하면 퇴적량 또한 증가하였고, 맨홀형태가 사각형 또는 원형인지와도 관계없이 맨홀내부의 유사퇴적량은 비슷하였다. 기본형과 비교하여 맨홀내부에 벤칭을 설치하였을 경우 유사퇴적량을 50 % 이상 저감시킬 수 있었다. 이러한 결과는 사각형과 원형맨홀에서 동일하였으며 유사유입형태가 연속적으로 유입되는지 또는 일정기간동안만 순간적으로 유입되는지와도 관계없이 동일하였다. 그러나 벤칭이 설치된 사각형 맨홀의 경우 맨홀내부에 퇴적된 유사를 완전히 배출시킬 수 있는 유입관거유속이 기본형과 비교하여 30 % 증가하는 것으로 나타났다. 그러나 원형맨홀에서는 벤칭을 설치함으로써 유사 완전배출을 위한 관거유속 또한 저감시킬 수 있었다. 본 연구에서 제안한 개선안의 경우 사각형, 원형, 연속주입, 일정기간주입 등의 조건과 관계없이 퇴적량을 50 % 이상 저감시킬 수 있었고, 유사 완전배출을 위한 관거유속 또한 기본형과 벤칭이 설치된 맨홀과 비교하여 50 % 이상 저감시킬 수 있음을 실험적으로 확인하였다. 원형 맨홀의 경우 완전배출 관거유속은 벤칭설치 시와 같았지만 완전배출까지의 소요시간은 본 연구의 개선안이 현저히 짧았다. 따라서 본 연구를 통해 제시안 맨홀내부 구조변화 개선안이 흐름개선과 함께 맨홀내부에 퇴적되는 유사량을 저감시킬 수 있는데 효과가 있다고 판단된다.

  • PDF

Flow Lab. : Flow Visualization and Simulation (핵종이동 가시적 현상관찰및 수치모사)

  • Park Chung-Kyun;Cho Won-Jin;Hahn Pi1-Soo
    • Proceedings of the Korean Radioactive Waste Society Conference
    • /
    • 2005.11a
    • /
    • pp.134-142
    • /
    • 2005
  • The experimental setups for flow visualization and processes identification in laboratory scale (so cal led Flow Lab.) has developed to get ideas and answer fundamental questions of flow and migration in geologic media. The setup was made of a granite block of $50{\times}50cm$ scale and a transparent acrylate plate. The tracers used in this experiments were tritiated water, anions, and sorbing cations as well as an organic dye, eosine, to visualize migration paths. The migration plumes were taken with a digital camera as a function of time and stored as digital images. A migration model was also developed to describe and identify the transport processes. Computer simulation was carried out not only for the hydraulic behavior such as distributions of pressure and flow vectors in the fracture but also for the migration plume and the elution curves.

  • PDF

Visualization and Image Processing for Measurement of Propagational Velocity of Shear Front (유동장의 이동속도측정을 위한 가시화 및 영상처리 방안)

  • Kim Jae-Won;Han Sang-Hoon;Ahn Eun-Young
    • Journal of Korea Multimedia Society
    • /
    • v.8 no.10
    • /
    • pp.1322-1328
    • /
    • 2005
  • The circulation flows passing through the Ekman boundary layer on the rotating disk and transfer the angular momentum into the interior region of the container. Consequently, the circulation enhances the momentum transfer and the interior fluid is divided by a propagating shear front. This investigation focuses on computer vision and image processing technique for analysis of Non-Newtonian Fluids. To visualize marching velocity shear front for the transient flow, a particular shaped particles and light are used. To validate the proposed method, quantitative image are compared with the optical data acquired by a direct measurement of LDV (Laser Doppler Velocimetry).

  • PDF