• Title/Summary/Keyword: 물질적 어려움

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Application Assessment of Passive Sampling to Monitor Polybrominated Diphenyl Ethers in Water Environment as Alternative Sampling Method for Grab Sampling (수계 중 폴리브롬화 디페닐에테르 모니터링을 위한 Passive Sampling 적용 및 그랩 시료채취법의 대체 활용가능성 평가)

  • Kim, Un-Jung;Seo, Chang Dong;Im, Tae-Hyo;Oh, Jeong-Eun
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.1
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    • pp.45-51
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    • 2015
  • PBDEs (polybrominated diphenyl ehters) are rarely dissolved in water due to their strong hydrophobicity and large molecular mass so not many researches were done in aqueous environment compared to other environmental compartments. However, the mass loading from wastewater treatment plant into aquatic environment, re-suspension from bottom sediment and partitioning from floating particles and colloids may not be negligible. It is, therefore, important but also difficult to investigate PBDEs in water environment. Recent overcoming resolution towards this barrier to monitor hydrophobic organic compounds in aquatic environment is using passive sampling technique like semipermeable membrane device. By using passive sampling, it might be possible to obtain long-term reproducible monitoring result and detect the trace amounts of PBDEs, with controlling fluctuation of surrounding environmental factors during the sampling event. So therefore, this study is purposed to confirm the possibility of using SPMD (semi-permeable membrane device) as water monitoring tool. Grab samples, composite samples and SPMDs were applied in river bank to evaluate the concentration difference and temporal fluctuation by various water sampling method, and to assess the water concentration prediction capability of SPMD for the PBDEs.

Evaluation on Applicability of the Real-time Prediction Model for Influent Characteristics in Full-scale Sewerage Treatment Plant (하수처리장 유입수 성상 실시간 예측모델 및 활용성 평가)

  • Kim, Youn-Kwon;Kim, Ji-Yeon;Han, In-Sun;Kim, Ju-Hwan;Chae, Soo-Kwon
    • Proceedings of the Korea Water Resources Association Conference
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    • 2010.05a
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    • pp.1706-1709
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    • 2010
  • Sewerage Treatment Plants(STPs) are complexes systems in which a range of physical, chemical and biological processes occur. Since Activated Sludge Model(ASM) No.1 was published, a number of new mathematical models for simulating biological processes have been developed. However, these models have disadvantages in cost and simplicity due to the laboriousness and tediousness of their procedures. One of the major difficulties of these mathematical model based tools is that the field-operators mostly don't have the time or the computer-science skills to handle there models, so it mainly remains on experts or special engineers. In order to solve these situations and help the field-operators, the $KM^2BM$(K-water & More-M Mass Balance Model) based on the dynamic-mass balance model was developed. This paper presents $KM^2BM$ as a simulation tools for STPs design and optimization. This model considers the most important microbial behavioral processes taking place in a STPs to maximize potential applicability without increasing neither model parameter estimation nor wastewater characterization efforts.

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Technical Review on Thorium Breeding Cycle (토륨 핵연료 주기 기술동향)

  • Noh, Taewan
    • Journal of Energy Engineering
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    • v.25 no.2
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    • pp.52-64
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    • 2016
  • The production of nuclear energy from thorium which is non-fissile material was a main issue until the middle of 1970's, because of the thorium's abundance as energy resources, its capability of breeding fissile material U233, and the reduction of long-lived actinides. However, to use thorium as nuclear fuel, some obstacles such as the necessities of external neutron source and long-term neutron irradiation for effective breeding, and the production of high radioactive isotopes in the course of thorium breeding cycle should be overcome. The difficulties to resolve these cons of thorium cycle became the reason of interruption of the related researches in the middle of 1970's. But in the 21st century, the change of societal perspective regarding nuclear energy and the appearance of accelerator-driven nuclear reactor shift those cons into pros and rehabilitate the study of thorium. The high activity of thorium cycle turned out to be a good option as higher resistance and easier detectibility of nuclear proliferation and the employment of subcritical accelerator-driven reactor as external neutron sources is considered to enhance the nuclear safety. In this study we compare the thorium cycle with the currently-used uranium cycle and analyze the technical status and perspective of thorium researches which use accelerator-driven reactors.

Development of novel markers for the characterization of chicken primordial germ cells

  • Lee, Bo-Ram;Kim, Duk-Kyung;Lee, Young-Mok;Jung, Jin-Gyoung;Kim, Jin-Nam;Lee, Seon-Duk;Park, Tae-Sub;Lim, Jeong-Mook;Han, Jae-Yong
    • Proceedings of the Korea Society of Poultry Science Conference
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    • 2004.11a
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    • pp.9-10
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    • 2004
  • We developed a new panel of markers for the characterization of chicken PGCs. The results of immunostaining demonstrated that anti-SSEA-3, anti-SSEA-4, anti-integrin 6, and anti-integrin 1 antibodies. and STA and DBA bound specifically to chicken PGCs. These reagents could be used to characterize chicken PGCs together with conventional marker reagents such as PAS and anti-SSEA-1 antibody. We also showed that double staining of PGCs with the newly developed markers was feasible, which might contribute to rapid detection and accurate characterization of chicken PGCs.

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Comparison of Performances of Forward Osmosis and Membrane Distillation Processes for Shale Gas Plant Water Treatment (셰일가스 플랜트 용수 처리를 위한 정삼투(FO)와 막증발(MD) 공정의 성능 비교)

  • Koo, Jaewuk;Lee, Sangho;Shin, Yonghyun;Yun, Taekgeun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.3
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    • pp.279-284
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    • 2015
  • As non-conventional oil resources such as shale gas have been widely developed, proper treatment of flowback and produced water is becoming important. However, application of conventional water treatment techniques is limited due to high concentration of pollutants such as oil and grease, organics, harmful chemicals, and inorganic ions. In this study, we examined the feasibility of using forward osmosis (FO) and air gap membrane distillation (AGMD) as novel treatment options for shale gas wastewater. Laboratory-scale FO and MD devices were fabricated and used for the experiments. Results showed that FO could be used to treat the synthetic wastewater. Using 5 M NaCl as the draw solution, the flux was approximately $6L/m^2-hr$ during the treatment of low range wastewater (TDS: 66,000 mg/L). Nevertheless, AGMD was more effective to treat high range wastewater (Total Dissolved Solid: 260,000 mg/L) than FO.

An Examination on the Dispersion Characteristics of Boil-off Gas in Vent Mast Exit of Membrane Type LNG Carriers (멤브레인형 LNG선박 화물탱크 벤트 마스트 출구에서의 BOG 확산 특성에 관한 연구)

  • Kang, Ho-Keun
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.19 no.2
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    • pp.225-231
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    • 2013
  • Liquefied gas carriers generally transport cargoes of flammable or toxic nature. Since these cargoes may cause an explosion, fire or human casualty, the accommodation spaces, service spaces and control stations of liquefied gas carriers should be so located as to avoid ingress of gas. For this reason, the paragraph 8.2.9 of IGC Code in IMO requires that the height of vent exits should be not less than B/3 or 6 m whichever is greater, above the weather deck and 6 m above the working area and the fore and aft gangway to prevent any concentration of cargo vapor or gas at such spaces. Besides as known, the LNG market has been growing continually, which has led to LNG carriers becoming larger in size. Under this trend, the height of a vent will have to be raised considerably since the height of a vent pipe is generally decided by a breadth of a corresponding vessel. Accordingly, we have initiated an examination to find an alternative method which can be used to determine the safe height of vent masts, instead of the current rule requirement. This paper describes the dispersion characteristics of boil-off gas spouted from a vent mast under cargo tank cool-down conditions in the membrane type LNG carriers.

Development of Numerical Model for Simulating Remediation Efficiency Using Surfactant in a NAPL Contaminated Area (계면활성제에 의한 NAPL 오염의 정화효율 수치 모의를 위한 모델 개발)

  • Suk, Heejun;Son, Bongho;Park, Sungmin;Jeon, Byonghun
    • Clean Technology
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    • v.25 no.3
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    • pp.206-222
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    • 2019
  • Recently, various multiphase flows have been developed, and among them some models have been commercialized. However, most of them have been developed based on a pressure-based approach; therefore, various numerical difficulties were involved inherently. Accordingly, in order to overcome these numerical difficulties, a multiphase flow model, MultiPhaSe flow (MPS), following a fractional-flow based approach was developed. In this study, by combining a contaminant transport module describing an enhanced dissolution effect of a surfactant with MPS, a MultiPhaSe flow and TranSport (MPSTS) model was developed. The developed model was verified using the analytical solution of Clement. The MPSTS model can simulate the process of surfactant enhanced aquifer remediation including interphase mass transfer and contaminant transport in multiphase flow by using the coupled particle tracking method and Lagrangian-Eulerian method. In this study, a surfactant was used in a non aqueous phase liquid (NAPL) contaminated area, and the effect of hydro-geological heterogeneity in the layered media on remediation efficiency was studied using the developed model. According to the numerical simulation, when hydraulic conductivity in a lower layer is 10 times, 20 times, and 50 times larger than that in an upper layer, the concentration of dissolved diesel in the lower layer is much higher than that in the upper layer because the surfactant moves faster along the lower layer owing to preferential flow; thus, the surfactant enhances dissolution of residual non aqueous phase liquid in the lower layer.

The Film Property and Deposition Process of TSV Inside for 3D Interconnection (3D Interconnection을 위한 실리콘 관통 전극 내부의 절연막 증착 공정과 그 막의 특성에 관한 연구)

  • Seo, Sang-Woon;Kim, Gu-Sung
    • Journal of the Microelectronics and Packaging Society
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    • v.15 no.3
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    • pp.47-52
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    • 2008
  • This investigation was performed in order to study the properties of deposition and layers by Silicon Dioxide, SiO2, as dielectric onto Via and Trench which have high Aspect Ratio (AR). Thus, in order to confirm these properties, three types of CVD, which were PECVD, PETEOS, and ALD, were selected. On the experiment each of the property sections was estimated that step overage of PECVD: <30%, PETEOS: 45%, ALD: 75% and the RSM of PECVD: 27.8 nm, PETEOS: 2.1 nm, ALD: <2.0 nm. As a result of this experiment for the property of electric film, ALD was valuated to be the most favorable outcome. However, ALD was valuated to have the least quality for the deposition rate. ALD deposition rate, $10\;\AA/min$ by $1\;\AA$/1cycle, was prominently lower than PETEOS, which had the deposition rate of $5000\;\AA$/min. Since electric film requires at least $1000\;\AA$ thicknesses, ALD was not suitable for the deposition rate. which is the most important component in a practical use. Therefore, in this particular study, PETEOS was evaluated to be the most suitable recipe.

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A Study on Environmental and Economic Analysis for Each Treatment of Sewage Sludge(III) - Results of Environmental Assessment - (하수슬러지 처리방법별 환경성 및 경제성 분석에 대한 연구(III) - 환경성 분석 중심으로 -)

  • Bae, Jisu;Lee, Suyoung;Cho, Yuna;Kwon, Younghyun;Lee, Dongjin
    • Journal of the Korea Organic Resources Recycling Association
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    • v.24 no.3
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    • pp.5-13
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    • 2016
  • This study investigated the environmental and economical assessment for sewage sludge treatment options including biogasification, incineration, carbonization, drying, and solidification. For the economical feasibility the 30 plants with anaerobic digestion treatment and the 17 plants without anaerobic digestion treatment were investigated. In regarding to the environmental assessment, the air emission pollutants (SOx, NOx, etc) from incineration and carbonization plants were assessed and 1~34 % of emission limits was emitted. Drying and solidification plants emitted about 30 % of odour limits. And the rest of the pollutants were emitted either at not-detectable level or at below the limits. When the by-products from the solidification treatment was used as landfill cover materials, the unconfined compression strength could be below the limit and it could cause an unsafe condition for those passing vehicles and the possibility of the ground subsidence. There has been a maintenance difficulty due to frequent blockage and operational failure. The result of the comparison of sewage sludge treatment options showed that anaerobic digestion+incineration was the most economically feasible considering incineration and drying. For smaller treatment capacity, solidification was the most economically feasible considering carbonization and solidification and anaerobic digestion+carbonization was the most economically feasible considering carbonization and solidification.

Recent Progress on Metal-Organic Framework Membranes for Gas Separations: Conventional Synthesis vs. Microwave-Assisted Synthesis (기체분리용 금속유기구조체 분리막의 최근 연구 동향 및 성과)

  • Ramu, Gokulakrishnan;Jeong, Hae-Kwon
    • Membrane Journal
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    • v.27 no.1
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    • pp.1-42
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    • 2017
  • Metal-organic frameworks (MOFs) are nanoporous materials that consist of organic and inorganic moieties, with well-defined crystalline lattices and pore structures. With a judicious choice of organic linkers present in the MOFs with different sizes and chemical groups, MOFs exhibit a wide variety of pore sizes and chemical/physical properties. This makes MOFs extremely attractive as novel membrane materials for gas separation applications. However, the synthesis of high-quality MOF thin films and membranes is quite challenging due to difficulties in controlling the heterogeneous nucleation/growth and achieving strong attachment of films on porous supports. Microwave-based synthesis technology has made tremendous progress in the last two decades and has been utilized to overcome some of these challenges associated with MOF membrane fabrication. The advantages of microwaves as opposed to conventional synthesis techniques for MOFs include shorter synthesis times, ability to achieve unique and complex structures and crystal size reductions. Here, we review the recent progress on the synthesis of MOF thin films and membranes with an emphasis on how microwaves have been utilized in the synthesis, improved properties achieved and gas separation performance of these films and membranes.