• Korean Journal of Materials Research
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• v.5 no.2
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• pp.169-177
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• 1995

The diffusion barrier property of 100-nm-thick titanium nitride (TiN) film between Cu and Si was investigated using sheet resistance measurements, etch-pit observation, x-ray diffractometry, Auger electron spectroscopy, and transmission electron microscopy. The TiN barrier fails due to the formation of crystalline defects (dislocations) and precipitates (presumably Cu-silicides) in the Si substrate which result from the predominant in-diffusion of Cu through the TiN layer. In contrast with the case of Al, it is identified that the TiN barrier fails only the in-diffusion of Cu because there is no indication of Si pits in the Si substrate. In addition, it appears that the stuffing of TiN does not improve the diffusion barrier property in the Cu/TiN/Si structure. This indicates that in the case of Al, the chemical effect that impedes the diffusion of Al by the reaction of Al with $TiO_{2}$ which is present in the grain boundaries of TIN is very improtant. On the while, in the case of Cu, there is no chemical effect because Cu oxides, such as $Cu_{2}O$ or CuO, is thermodynamically unstable in comparison with $TiO_{2}$. For this reason, it is considered that the effect of stuffing of TiN on the diffusion barrier property is not significant in the Cu/ TiN/Si structure.

• Journal of the Korea Concrete Institute
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• v.20 no.1
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• pp.59-66
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• 2008

This study is about manufacturing and producing girder, which is an essential component of bridge structure, in a composite of FRP + concrete. This has a higher competitive power in price than steel girder. The girder used in this study is made of glass fiber which has a lower elastic modulus than steel and thus has some technical limitations such as excessive deflection compared to steel girder and lack of production facilities in FRP production companies to make a large-section component material. Thus, this study suggested a section of a new module that will allow for applying a large section in order to solve the technical difficulties mentioned above and to secure low stiffness of FRP, developed a new FRP+concrete composite girder that is filled with the appropriate amount of concrete. To identify the structural behavior of this FRP+concrete composite girder, experiments were conducted to measure its flexural strength according to the difference in the strength of confined concrete and the existence of stud. The results of the flexural strength test confirmed the composite effect from confining concrete and the effect of increase in strength proportional to the strength of concrete. In developing FRP+concrete composite girder, NDT study was also conducted to analyze the interface characteristics of concrete and FRP.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.31 no.2B
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• pp.187-192
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• 2011

Nitrate nitrogen is common contaminant in groundwater aquifers, its concentration is regulated many countries below 10 mg/L as N (As per WHO standards) in drinking water. An attempt was made to get optimal results for the treatment of nitrate nitrogen in groundwater by conducting various experiments by changing the experimental conditions for ZVI bipolar packed bed electrolytic cell. From the experimental results it is evident that the nitrate nitrogen removal is more effective when the reactor conditions are maintained in acidic range but when the acidic environment changes to alkaline due to the hydroxide formed during the process of ammonia nitrogen there by increasing the pH reducing the hydrogen ions required for reduction which leads to low effectiveness of the system. In the ZVI bipolar packed bed electrolytic cell, the packing ratio of 0.5~1:1 was found to be most effective for the treatment of nitrate nitrogen because ZVI particles are isolated and individual particle act like small electrode with low packing ratio. It is seen that formation of precipitate and acceleration of clogging incrementally for packing ratio more than 2:1, decreasing the nitrate nitrogen removal rate. When the voltage is increased it is seen that kinetics and current also increases but at the same time more electric power is consumed. In this experiment, the optimum voltage was determined to be 50V. At that time, nitrate nitrogen was removed by 94.9%.

• Journal of Environmental Science International
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• v.6 no.2
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• pp.183-187
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• 1997

Organophosphate pesticides were extracted with 70% acetone and then transferred to dichloromethane. Extracts were applied to open-column chromatography with florisil. The florial extract was analyzed by gas chromatography with nitrogen-phosphorus detector(GC/NPD). Recoveries of the 18 organophosphate pesticides were ranged from 88.7% to 100. 0% for the narrow-bore capillary GC(Ultra-21. The minimum detectable level of this analytical method was 0.019 - 0.035 mg/kg. Sample throughput(extraction, open-column chro- matography, and GC analysts) was decreased considerably (8h per sample).

• Journal of the korean Society of Automotive Engineers
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• v.7 no.4
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• pp.24-31
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• 1985

본 논문은 Comprex압력파 과급기(Pressure-wave Supercharger;이하 PWS)의 공기 역학적인 원 리에 대해 기술하였으며, 또 기체 동력학적인 현상들이 별도의 제어장치없이도 우수한 운전성과 낮은 연료소모율, 적은 배기 배출물을 형성하는 차량들에 대해 기계적으로는 간단하면서도 완벽 한 boosting장치를 만들어 내는데 어떻게 사용될 수 있는지를 설명하였다. 근본적인 목적은 종 래의 turbo charger와 동일이지만 Comprex PWS는 현재 응용되고 있는 승용차가 요구하는 여러 가지면, 즉 1) 부하변동에 대한 충진공기압의 빠른 응답성 2) 엔진속도 전영역에 걸친 높은 boost 효과 3) 배기배출물특성을 좋게할 수 있는 배기가스 재순환(EGR)효과 등에서 종래의 것과 구별된다. 따라서 PWS의 중요한 특징들을 기술하였으며 마지막으로 최근 자동차용 Diesel Engine에의 몇 가지 예를 보았다.

• Journal of the Korean Society for Precision Engineering
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• v.22 no.9 s.174
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• pp.188-193
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• 2005

To provide the various machining materials with excellent quality and dimensional accuracy, high -speed machining is very useful tool as one of the most effective rapid manufacturing processes. However, high-speed machining is not suitable for microscale thin-walled structures because of the lack of the structure stiffness to resist the cutting force. A new method which is able to make a very thin-walled structure rapidly will be proposed in this paper. This method is composed two processes, high-speed machining and filling process. Strong workholding force comes out of the solidification of filling materials. Low-melting point metal alloys are used in order to minimize the thermal effect during phase change and to hold arbitrary shape thin-walled structures quickly during high-speed machining. To verify the usefulness of this method, we will show some applications, for examples thin -wall cylinders and hemispherical shells, and compare the experimental results to analyze the dimensional accuracy of typical parts of the structures.

• 한국가시화정보학회:학술대회논문집
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• 2003.11a
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• pp.83-86
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• 2003

Synchrotron X-ray micro imaging technique was employed to non-invasively monitor the water flow inside xylem vessels in a bamboo leaf. The phase contrast X-ray images clearly visualized plant anatomy and the rise of a water front inside the vessels. Consecutive X-ray images taken for 60 seconds revealed water rise kinetics against gravity in the xylem of a cut dry leaf taken from a bamboo tree. For the first time, traces of water rise, variation of contact angle between water and xylem wall as well as the internal structure of xylem were obtained. In xylem vessels, a repeating flow pattern has a typical flow velocity of $30.7{\mu}m/s$ and faster flow is established intermittently. It is concluded that the transmission type of X-ray micro imaging can be used as a powerful tool to investigate the ascent of sap in the xylem vessels at a resolution higher than that of MRI.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.09a
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• pp.483-486
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• 2003

본 연구는 운동장, 주차장, 도로측면, 보도, 기타 주거시설 등의 우수 찻집시설에 사용되는 콘크리트 구조물의 침투능 확보를 위한 투수성 찻집 구조물 개발에 관한 것이다. 투수성을 확보하기 위하여 일반 차집시설의 콘크리트 구조체 벽면에 천공을 하고 천공된 측구 내에 쇄석을 충진시켜 침투되는 우수의 수질도 개선할 수 있다. 본 제작방법은 별도의 침투소재를 사용하는 경우와 비교해 볼 때 경제성이 우수하며 동일시공방법과 규격으로 대체재로서 활용성이 높을 것으로 전망된다, 본 연구에서 개발하고 있는 여재를 이용한 침투시설은 침투능을 충분히 확보할 수 있음을 확인하였고 SS기준으로 27％∼86％의 제거율을 보였으며, COD기준 20％∼68％의 제거율을 나타냈으며, 탁도기준 29％∼88％의 제거율을 볼 수 이었다.

• Journal of the Korean Wood Science and Technology
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• v.25 no.2
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• pp.45-51
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• 1997

주목 잎을 채취하여 건조하고 아세톤-물 (7 : 3, v/v) 의 혼합액으로 추출한 후 에틸아세테이트 및 수용성 부분으로 분리하고 Sephadex-LH 20으로 충진한 칼럼을 이용하여 2개의 flavan 단량체와 2개의 후라보노이드 배당체를 단리하였다. 에틸아세테이트용성 추출물은 대부분 (+)-catechin 과 (-)-epicatechin으로 구성되어 있었으며 수용성 부분에서는 quercetin-3-0-arabinopyranosyl-($1"'{\rightarrow}6"$)-${\beta}$-D-glucoside와 quercetin-3-O-rutinoside 인 두 개의 탄수화물로 구성된 배당체를 분리하였으며 주목에서는 이들 화합물은 아직 보고된 바가 없다. 이들의 구조결정을 위하여 박층크로마토그래피를 실시하고 $^1H$-NMR과 $^{13}C$-NMR 스펙트럼을 기존의 스펙트럼과 비교, 분석하여 정확한 구조를 규명하였다.

• Journal of the Korean Wood Science and Technology
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• v.25 no.2
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• pp.110-116
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• 1997

생강나무의 수피를 아세톤-물 (7:3)의 혼합용액으로 추출하여 에틸아세테이트용성과 수용성 화합물로 분리하였고 이중에서 에틸아세테이트용성 부분을 Sephadex LH-20과 TSK 40F로 충진한 칼럼크로마토그래피를 사용하여 5개의 화합물, 즉 (+)-catechin, (-)-epicatechin, quercetin 그리고 epicatechin-($4{\beta}{\rightarrow}6$-catechin 이량체와 epicatechin-($2{\beta}{\rightarrow}7$, $4{\beta}{\rightarrow}8$)-epicatechin 이량체를 단리 하였다. 단일물의 확인을 위하여 박층크로마토그래피를 실시하였으며, 화합물의 정확한 구조는 $^1H$-NMR과 $^{13}C$-NMR 스펙트럼을 이용하여 규명하였다.