• Title/Summary/Keyword: 무가습

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Effect of Root Zone Warming by Hot Water on Fruit Characteristics and Yield of Greenhouse- Grown Oriental Melon (Cucumis melo L.) (온수 지중가온이 참외의 과실특성 및 수량에 미치는 영향)

  • 신용습;이우승;연일권;최성국;최부술
    • Journal of Bio-Environment Control
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    • v.6 no.2
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    • pp.110-116
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    • 1997
  • This experiment was conducted to investigate the effects of root zone warming on fruit yield of oriental melon (Cucumis melo L. var. Makuwa) in winter season. Root zone was warmed by hot water flowing through pipe set at 35cm depth from the ridge. Treatments of minimum soil temperature at 20cm depth were 17, 21, $25^{\circ}C$ and non-warming from Jan. 18 to Apr. 18. The results are summarized as follows. 1. The blooming of female flower was faster 1 days in 17$^{\circ}C$ plot, 6 days in 21$^{\circ}C$ plot, and 7 days in $25^{\circ}C$ plot than in control plot and the days from blooming to harvesting were shorter 5 days in 17$^{\circ}C$ plot, 11 days in 21$^{\circ}C$ plot, and 12 days in $25^{\circ}C$ plot than in control plot. 2. Mean fruit weight was the highest in 21$^{\circ}C$ plot, followed $25^{\circ}C$, 17$^{\circ}C$ and control plots, respectively, and flesh thickness was the highest in $25^{\circ}C$ plot, followed by 21, 17$^{\circ}C$ and control plots, respectively. 3. Early and middle-phase yield was the highest in $25^{\circ}C$ plot, followed by 21$^{\circ}C$, 17$^{\circ}C$ and control plots but late yield was the highest in 17$^{\circ}C$ plot, followed by control, 21, and $25^{\circ}C$ plots. Total yield per 10a was higher 33% in 17$^{\circ}C$ plot, 49% in 21$^{\circ}C$ plot, and 37a in $25^{\circ}C$ plots than in control plot, harvested 1, 490kg per 10a. 4. Total yield was highest in 21$^{\circ}C$ plot, followed by $25^{\circ}C$, 17$^{\circ}C$, and control plots. Malformed and fermented fruit rates were the highest in control, followed by 17, 25, and 21$^{\circ}C$ plots and marketable fruit rate was 21, 25, 17$^{\circ}C$, and control plot in order.

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Preparation of Proton Conducting Anhydrous Membranes Using Poly(vinyl chloride) Comb-like Copolymer (Poly(vinyl chloride) 빗살형 공중합체를 이용한 무가습 수소이온 전도성 전해질막의 제조)

  • Kim, Jong-Hak;Koh, Joo-Hwan;Seo, Jin-Ah;Ahn, Sung-Hoon;Zeng, Xiaolei
    • Membrane Journal
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    • v.19 no.2
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    • pp.89-95
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    • 2009
  • A comb-like copolymer consisting of a poly(vinyl chloride) backbone and poly(hydroxy ethyl acrylate) side chains, i.e. PVC-g-PHEA, was synthesized through atom transfer radical polymerization (ATRP). This comb-like copolymer was crosslinked with 4,5-imidazole dicarboxylic acid (IDA) via the esterification of the -OH groups of PHEA in the graft copolymer and the -COOH groups of IDA. Upon doping with phosphoric acid (PA, $H_3PO_4$) to form imidazole-PA complexes, the proton conductivity of the membranes continuously increased with increasing PA content. A maximum proton conductivity of 0.011 S/cm was achieved at $100^{\circ}C$ under anhydrous conditions. The PVC-g-PHEA/IDA/PA complex membranes exhibited good mechanical properties, i.e. 575 MPa of Young's modulus, as determined by a universal testing machine (UTM). Thermal gravimetric analysis (TGA) shows that the membranes were thermally stable up to $200^{\circ}C$.

Mesoporous SiO2 Mediated Polybenzimidazole Composite Membranes for HT-PEMFC Application (고온 PEMFC 응용을 위한 다공성 SiO2 기반 폴리벤즈이미다졸 복합막)

  • HAN, DAEUN;YOO, DONG JIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.2
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    • pp.128-135
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    • 2019
  • In this study, the mesoporous $SiO_2$ (5, 10, or 15 wt%) was incorporated into the polybenzimidazole matrix in order to improve the proton conduction as well as physiochemical properties of composite membrane. The chemical structure of mesoporous $SiO_2$ and crystallinity of as-prepared membranes were analyzed by Fourier-transform infrared (FT-IR) spectroscopy and X-ray diffraction (XRD) analysis, respectively. The thermal stability of the pristine $X_1Y_9$ and composite membranes were evaluated by thermogravimetric analyzer (TGA). On other side, the physical and chemical properties of the pristine $X_1Y_9$ and composite membranes were also determined by acid uptake and oxidative stability tests, respectively. With the incorporation of 15 wt% $SiO_2$, the composite membrane exhibits the higher proton conductivity that may be applicable for non-humidified high temperature fuel cell applications.

Characteristics of composite membranes containing ionic liquid and acid for anhydrous high temperature PEFCs (무가습 고온 PEFC용 이온성 액체 및 산이 함유된 복합막의 특성)

  • Baek, Ji-Suk;Park, Jin-Soo;Park, Seung-Hee;Yang, Tae-Hyun;Park, Gu-Gon;Yim, Sung-Dae;Kim, Chang-Soo;Shul, Young-Gun
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.378-378
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    • 2009
  • The ionic liquid-based sulfonated hydrocarbon composite membranes was prepared for use in anhydrous high temperature-polymer electrolyte fuel cells (HT-PEFCs). Ionic liquid behaves like water in the composite membranes under anhydrous condition. However the composite membranes show a low conductivity and high gas permeability as the content of ionic liquid increases due to its high viscosity and content of ionic liquid, respectively. Hence, in order to enhance the proton conductivity and to reduce the gas permeability of the composite membranes with low content of ionic liquids, the acid containing a common ion of ionic liquid was added to the composite membranes. The characterization of composite membranes was carried out using small-angle X-ray scattering (SAXS), thermogravimetric analyzer (TGA) and impedance spectroscopy. As a result, the composite membranes containing acid showed higher proton conductivity than those with no acid under the un-humidified condition due to a decrease in viscosity. In addition, the proton conductivity of composite membranes increased with increasing mole concentration of acid.

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Effect of Temperature on Electrochemical Degradation of Membrane in PEMFC (PEMFC 고분자 막의 전기화학적 열화에 미치는 온도의 영향)

  • Lee, Ho;Kim, Taehee;Son, Ik Jae;Lee, Jong Hyun;Lim, Tae Won;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.47 no.4
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    • pp.441-445
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    • 2009
  • Effect of temperature on membrane degradation in PEMFCs was studied. After cell operation at different temperatures($60{\sim}90^{\circ}C$) under accelerating degradation conditions(OCV, anode dry, cathode RH 65%) for 144 h, cell performance decreased from 12 to 35%. The results of FER in effluent water showed that this decrease in cell performance was caused by membrane degradation by the attack of $H_2O_2$ or oxygen radicals(${\cdot}OH$, $HO_2{\cdot}$) and that resulted in increase in gas crossover for radical formation. Radical formation on the electrode was confirmed by ESR. Activation energy of 66.2 kJ/mol was obtained by Arrhenius plot used to analyze the effect of temperature on membrane degradation. Increase of cell temperature enhanced gas crossover rate, radical formation rate and membrane degradation rate.

Preparation of Self-humidifying Pt/Nafion Membranes using Supercritical $CO_2$ for PEMFCs (초임계유체를 이용한 PEMFC용 자가 가습 백금/나피온 막의 제조)

  • Byun, Jung-Yeon;Kim, Hyo-Won;Sung, Joon-Yong;Kim, Hwa-Yong
    • Clean Technology
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    • v.13 no.2
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    • pp.99-103
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    • 2007
  • Pt/Nafion self-humidifying membranes for Polymer Electrolyte Membrane Fuel Cell (PEMFC) were synthesized via a supercritical-impregnation method. The Nafion 112 membranes were impregnated with Pt(II) acetylacetonate from a supercritical carbon dioxide ($scCO_2$) solution at $80^{\circ}C$ and 19.8 MPa. After the impregnation, the Pt-impregnated Nafion membrane was converted Pt deposited Nafion(Pt/Nafion) membrane by reducing agent, sodium borohydride ($NaBH_4$) under $50^{\circ}C$ and 2 hours. The prepared Pt/Nafion membranes were investigated by SEM, EDS and EPMA. The performance of the Pt/Nafion membranes was examined in PEMFC as a self-humidifying membrane. The cell performance of the Pt/Nafion membrane at $65^{\circ}C$ is better than that of Nafion 112.

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Anhydrous Crosslinked Polymer Electrolyte Membranes Based On ABA Triblock Copolymer (ABA 트리블록 공중합체를 이용한 무가습 가교형 고분자 전해질막)

  • Kim, Jong-Hak;Koh, Jong-Kwan;Lee, Do-Kyoung;Roh, Dong-Kyu;ShuI, Yong-Gun
    • Membrane Journal
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    • v.19 no.3
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    • pp.228-236
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    • 2009
  • ABA type triblock copolymer of poly(hydroxyl ethyl acrylate )-b-polystyrene-b-poly(hydroxyl ethyl acrylate), i.e. PHEA-b-PS-b-PHEA, was synthesized throughatom transfer radical polymerization (ATRP). This block copolymer was thermally crosslinked with 4,5-imidazole dicarboxylic acid (IDA) via the esterification between the -OH groups of PHEA in block copolymer and the -COOH groups of IDA. Upon doping with ${H_3}{PO_4}$ to form imidazole-${H_3}{PO_4}$ complexes, the proton conductivity of membranes continuously increased with increasing ${H_3}{PO_4}$ content. The PHEA-b-PS-b-PHEA/IDA/${H_3}{PO_4}$ polymer membrane with [HEA]:[IDA]:[${H_3}{PO_4}$]=3:4:4 exhibited a maximum proton conductivity of 0.01 S/cm at $100^{\circ}C$ under anhydrous conditions. Thermal gravimetric analysis (TGA) shows that the PHEA-b-PS-b-PHEA/IDA/${H_3}{PO_4}$ complex membranes were thermally stable up to $350^{\circ}C$, indicating their applicability in fuel cells.

Anhydrous Polymer Electrolyte Membranes Prepared From Polystyrene-b-Poly (hydroxyl ethyl methacrylate) Block Copolymer (Polystyrene-b-Poly(hydroxyl ethyl methacrylate) 블록 공중합체를 이용한 무가습 고분자 전해질막)

  • Kim, Jong-Hak;Seo, Jin-Ah;Lee, Do-Kyung;Roh, Dong-Kyu;Shul, Yong-Gun
    • Membrane Journal
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    • v.19 no.4
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    • pp.302-309
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    • 2009
  • A block copolymer of polystyrene-b-poly (hydroxyl ethyl methacrylate), PS-b-PHEMA, was synthesized via atom transfer radical polymerization (ATRP) and crosslinked with 4,5-imidazole dicarboxylic acid (IDA) via esterification of the -OH groups of PHEMA in the block copolymer and the -COOH groups of IDA. Upon doping with $H_3PO_4$ to form imidazole-$H_3PO_4$ complexes, the proton conductivity of the membranes continuously increased as the content of $H_3PO_4$ increased. In addition, both the tensile strength and the elongation at break increased with IDA content. A proton conductivity of 0.01 S/cm at $100^{\circ}C$ was obtained for the PS-b-PHEMA/IDA/$H_3PO_4$ membrane with [HEMA]:[IDA]:[$H_3PO_4$] = 3:4:4 under anhydrous conditions. All of the PS-b-PHEMA/IDA/$H_3PO_4$ membranes were thermally stable up to $350^{\circ}C$, as revealed by thermal gravimetric analysis (TGA).

Effect of Root Zone Warming by Hot Water on Rhizosphere Environment and Growth of Greenhouse- grown Oriental Melon (Cucumis melo L.) (온수 지중가온이 참외의 근권환경 및 생육에 미치는 영향)

  • 신용습;이우승;도한우;배수곤;최성국
    • Journal of Bio-Environment Control
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    • v.6 no.2
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    • pp.103-109
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    • 1997
  • This experiment was conducted to investigate the effects of root zone warming on rhizosphere temperature of Oriental melon (Cucumis melo L. var. Makuwa) in winter season. Root zone was warmed by hot water flowing through pipe set at 35cm depth from the ridge. Treatments of minimum soil temperature at 20cm depth were 17, 21, $25^{\circ}C$, and non-warmed from Jan. 18 to Apr. 18. The results are summarized as follows. 1. The cumulative soil temperature for 1 month after planting oriental melon was 441, 558, 648, and 735$^{\circ}C$ at control, 17, 21, and $25^{\circ}C$ plot, respectively. 2. As soil temperature was higher, air temperature in tunnel was higher. The lowest temperature in control plot at night was 9.5$^{\circ}C$, 11.$0^{\circ}C$ in 17$^{\circ}C$ plot, 13.5$^{\circ}C$ in 21$^{\circ}C$ plot, and 16.5$^{\circ}C$ in $25^{\circ}C$ plot, respectively. 3. The xylem exudate amount of control plot for 24 hours just after basal stem abscission was 8.1$m\ell$. It was 1.2 times higher in 17$^{\circ}C$ plot, 1.3 times higher in 21 $^{\circ}C$ plot, and 4.8 times higher in $25^{\circ}C$ plot than in control plot at 30 days after planting. The xylem exudate amount at 67 days after planting of control plot was 10.4$m\ell$, those of 17, 21, $25^{\circ}C$ plots were 1.1, 3.2, and 3.3 times as compared to control plot. 4, Early growth in leaf length, stem diameter, leaf number and leaf area for 30 days after planting were better in higher temperature plots than in control plot. Particularly, the increase of leaf area was striking in higher temperature plots. Leaf area of control plot was 279.5$\textrm{cm}^2$ for 30 days after planting, 153.4% in 17$^{\circ}C$ plot, 745.6% in 21$^{\circ}C$ plot and 879.4% in $25^{\circ}C$ plot were increased as compared to in control plot.

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Microclimate of Greenhouses Covered with Functional Film (기능성 연질필름 온실의 미기상)

  • Chun, Hee;Choi, Young-Jun;Choi, Young-Ha;Kim, Hark-Joo;Lee, Si-Young;Jeong, Du-Seok;Shin, Yong-Seub;Choi, Chung-Don
    • Journal of Bio-Environment Control
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    • v.16 no.2
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    • pp.96-100
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    • 2007
  • There was no difference in total light transmissivity of covering materials. But the light transmittance of J-2 in greenhouse was by 78.25 which was higher than any other film. The high light transmittance of J-2 was come from low water condensation and dust attached in film surface. The ultraviolet light of J-3 was completely intercepted. The ultraviolet transmittance rate of others was from 62 to 76%. In no heating oriental melon cultivation, the air temperature in tunnel was 15 to $21^{\circ}C$ higher than outer, and the soil temperature in tunnel was 20 to $25^{\circ}C$ higher than outer. Air temperature and soil temperature of J-2 were higher than any other film.