• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.178.2-178.2
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• 2011

바이오디젤이란 식물성 기름, 동물성 지방, 폐식용유 등의 재생 가능한 자원을 촉매 존재 하에 알코올과 반응시켜 생성되는 에스테르 혼합물을 말하며 경유와 물성이 유사하므로 경유에 혼합하여 압축착화 방식인 디젤엔진에 사용할 수 있다. 그러나 바이오디젤은 경유에 비하여 탄소-탄소 간 이중결합을 가지고 있는 성분을 많이 함유하고 있기 때문에 공기에 의해 산화가 일어나기 쉽다. 일반적으로 폐놀계 향산화제인 t-buthylhydroquinone(TBHQ)를 사용하여 산화안정성을 향상시키나 국내에서 사용되는 산화방지제는 전량 수입에 의존하고 있어 제품 개발에 의한 국산화가 시급한 실정이다. 본 연구에서는 폐유지로부터 생산한 바이오디젤의 산화안정성 향상을 위하여 폐놀 및 아민계 등의 산화방지제를 합성하여 바이오디젤에 적용하였으며, 다양한 물성시험방법을 적용하여 석유 및 석유대체연료 사업법에서 규정하는 바이오디젤의 품질기준을 확인하였다. 또한 EN 14112 바이오디젤 산화안정성 시험방법으로 폐놀 및 아민계 등의 산화안정성을 확인하였다. 본 연구는 산학연 공동기술개발 1차년도 사업으로 한국화학연구원과 공동으로 수행하였으며, 산화방지제 적용평가를 통해 우수한 제품을 선정하여 2차년도에는 차량 테스트를 통해 연료 첨가제로서의 적합성을 검증할 예정이다.

• Applied Chemistry for Engineering
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• v.20 no.2
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• pp.208-212
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• 2009

Biodiesel come from animal fat and vegetable oil by methanolysis was known for eco-friendly fuel for the alternative petrodiesel. But, various kinds of biodiesel need to analyze the cold characteristic due to poor fuel properties than petrodiesel in a cold condition. In this paper, 12 types of biodiesel were synthesized in 86~96% yields from 12 kinds of vegetable oil by transesterification. These synthesized biodiesels were analyzed in terms of the cold characteristics like cloud point, pour point, and cold filter plugging point (CFPP). The biodiesel comes from perilla oil which has rich olefin showed the excellent fuel characteristics in a low temperature.

• Korean Chemical Engineering Research
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• v.58 no.3
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• pp.396-407
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• 2020

As fossil fuels are depleted worldwide, alternative resources is required to replace fossil fuels, and biofuels are in the spotlight as alternative resources. Biofuels are produced from biomass, which is a renewable resource to produce biofuels or bio-chemicals. Especially, in order to substitute fossil fuels, the research focusing the biofuel (biodiesel) production based on CO₂ and biomass achieves more attention recently. To produce biomass-based biodiesel, the development of a supply chain network is required considering the amounts of feedstocks (ex, CO₂ and water) required producing biodiesel, potential locations and capacities of bio-refineries, and transportations of biodiesel produced at biorefineries to demand cities. Although many studies of the biomass-based biodiesel supply chain network are performed, there are few types of research handled the uncertainty in CO₂ supply which influences the optimal strategies of microalgae-based biodiesel production. Because CO₂, which is used in the production of microalgae-based biodiesel as one of important resources, is captured from the off-gases emitted in power plants, the uncertainty in CO₂ supply from power plants has big impacts on the optimal configuration of the biodiesel supply chain network. Therefore, in this study, to handle those issues, we develop the two-stage stochastic model to determine the optimal strategies of the biodiesel supply chain network considering the uncertainty in CO₂ supply. The goal of the proposed model is to minimize the expected total cost of the biodiesel supply chain network considering the uncertain CO₂ supply as well as satisfy diesel demands at each city. This model conducted a case study satisfying 10% diesel demand in the Republic of Korea. The overall cost of the stochastic model (US$ 12.9/gallon·y) is slightly higher (23%) than that of the deterministic model (US$ 10.5/gallon·y). Fluctuations in CO₂ supply (stochastic model) had a significant impact on the optimal strategies of the biodiesel supply network.

• KSBB Journal
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• v.25 no.1
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• pp.1-10
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• 2010

Biodiesel is a type of biofuel obtained from bioresources and able to use in diesel vehicles as an alternative/additive to petro diesel. In recent biodiesel research, there are three main issues which include high quality biodiesel, low cost feed stock and a highly efficient biodiesel production process. The sustainable production and use of biodiesel are attracting much attention in the renewable energy field. In this paper, we review some of the literatures related to environmental and economic evaluation for biodiesel production and analysis the issues including life cycle assessment (LCA), global warming potential (GWP), energy consumption, biodiesel production cost, production technologies and feedstock.

• Transactions of the Korean Society of Automotive Engineers
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• v.19 no.4
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• pp.130-136
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• 2011

This study describes the effect of EGR rate on the combustion and emissions characteristics of a four cylinder CRDI diesel engine using biodiesel (soybean oil) blended diesel fuel. The test fuel is composed of 30% biodiesel and 70% ULSD (ultra low sulfur diesel) by volumetric ratio. The experiment of engine emissions and performance characteristics were performed under the various EGR rates. The experimental results showed that ignition delay was extended, the maximum combustion pressure and heat release gradually were decreased with increasing EGR rate. Comparing biodiesel blended fuel to ULSD, the injection quantity of biodiesel blended fuel was further increased than ULSD. The emission results showed that $NO_x$ emission of biodiesel blended fuel becomes higher according to the increase of EGR rate. However, in the case of biodiesel blended fuel, HC, CO and soot emissions were decreased compared to ULSD.

• Journal of Energy Engineering
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• v.18 no.1
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• pp.69-73
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• 2009

The regulations for exhaust emission from vehicles have become much more stringent in recent years. These more stringent regulations require vehicle manufacturers to develop alternative fuels that reduce exhaust emission. This research is to analyze the characteristics of exhaust gas emission of same level vehicles that use gasoline, diesel, and LPG fuels. As for the test mode, we used the CVS-75 mode, which is the driving mode of the current domestic and North American emissions. The characteristics of the exhaust gas emitted under this driving condition was studied. We examined the emissions of THC, CO, and NOx of vehicles that use gasoline, diesel, and LPG fuels. As a result, vehicle exhaust gas emissions increased 9.8 % for vehicles using gasoline and it decreased 12.2 % for diesel-powered vehicles compared to vehicles using LPG fuel. Using gasoline and LPG fuel in the CVS-mode, over 80 % of THC and CO emission was produced for the cold start Phase 1.

• LP가스
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• v.22 no.5
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• pp.34-37
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• 2010

국가 에너지원의 다원화와 환경공해 저감은 정부의 저탄소 녹색성장 정책과 에너지 안보를 위해 달성해야만 하는 필수불가결한 과제로 자리 매김한지 오래이다. 또한, 화석연료의 환경문제 유발과 석유자원의 고갈위기 등으로 인해 이를 대체할 수 있는 신재생에너지 개발에 대한 관심이 고조되고 있으며 이러한 과제를 해결하기 위한 친환경 연료로써 DME(Dimethyl ether)에 대한 관심이 날로 증가하고 있는 추세이다. 특히 높은 세탄가를 지니고 물성이 LPG와 유사하여 디젤차량 및 LPG 대체 연료, 연료전지 등의 다양한 용도로 사용할 수 있고 수송 저장 수단, 인프라 구축 등의 장애가 적다는 장점이 있으며, LPG와 물리적 특성이 비슷해 기존 LPG 인프라를 개조하지 않고도 LPG와 혼합해 난방 및 취사뿐 아니라 차량 연료용으로도 시범사업이 활발히 추진되고 있는 상황이다. 그밖에도 액화상태로 저장 운송 등의 취급이 용이하다는 장점이 있다. 한국가스공사의 경제성 분석 결과, 본격 보급시 LPG대비 20~30% 저렴하게 공급가능하다고 판단되어짐에 따라 LPG사용자 부담을 완화할 수 있는 기대를 가지게 한다. 이에 우리협회는 지경부 한국가스공사등과 함께 프로판에 DME가 20%의 혼합된 DME혼합연료 소비자에게 보급하는 시범사업을 전개하고 있으며 현재까지 진행된 내용과 향후 계획등을 소개함으로써 DME에 대한 이해를 높이고자 한다.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.260-262
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• 2008

최근 고유가의 지속과 국제적인 환경 규제에 대응하기 위하여 환경친화적인 대체연료의 개발이 시급한 가운데 재생가능한 동식물성 유지로부터 생산되는 바이오 디젤에 대한 연구가 활발히 진행되고 있다. 특히 자원 재활용 및 에너지 생산관점에서 폐유지로부터 바이오디젤 원료로 사용하는 연구가 활발히 진행되어 왔다. 이러한 폐유지로부터 바이오디젤을 효율적으로 생산하기 위해서는 폐유지내 함유되어 있는 유리지방산을 전처리공정에서 산촉매에 의한 에스테르화 반응에 의해 전환제거하고자 한다. 본 연구에서는 폐유지내 함유된 유리지방산 전환제거에 효과적인 불균일계 이온교환수지 촉매를 이용하여 공정변수 즉 사용된 촉매의 양, 반응온도, 유리지방산 농도에 따른 유리지방산 전환제거특성을 조사해 보았다. 또한 각각의 반응조건에서 속도상수를 계산하여 이온교환수지 촉매를 사용한 유리지방산 전환 제거에 필요한 활성화 에너지 값을 구하였다.

• Journal of Power System Engineering
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• v.6 no.3
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• pp.11-16
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• 2002

This paper describes the power performance and emission characteristics of the high speed direct injection diesel engine (2.9 litter displacements) driven by soybean oil asknown a bio diesel fuel. The results were compared to diesel fuel with blending bio diesel fuels. The soybean bio diesel fuel was added in the diesel fuel in concentration varying from 25% to 75% volume rates. We measured the emissions according to ECE 13 mode and full load, fixedengine speed. When the 25% bio diesel fuel was used, NOx emission at the ECE 13 mode test slightly decreased compared with diesel base engine. Over engine speed of 2000 rpm, the level of unburned hydrocarbon(HC) and carbon monoxide(CO) were the same to the diesel engine. Smoke emission decreased asthe blending bio diesel fuel rate increased.

• Journal of the Korean Applied Science and Technology
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• v.29 no.3
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• pp.450-458
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• 2012

In order to reduce the effects of greenhouse gas (GHG) emissions, the South Korean government has announced a special platform of technologies as part of an effort to minimize global climate change. To further this effort, the Korean government has pledged to increase low-carbon and carbon neutral resources for biofuel derived from biomass to replace fossil and to decrease levels of carbon dioxide. In general, second generation biofuel produced form woody biomass is expected to be an effective avenue for reducing fossil fuel consumption and greenhouse gas (GHG) emissions in road transport. It is important that under the new Korean initiative, pilot scale studies evolve practices to produce biomass-to-liquid (BTL) fuel. This study reports the quality characteristics of F-T(Fischer-Tropsch) diesel for production of BTL fuel. Synthetic F-Tdiesel fuel can be used in automotive diesel engines, pure or blended with automotive diesel, due to its similar physical properties to diesel. F-T diesel fuel was synthesized by Fischer-Tropsch (F-T) process with syngas($H_2$/CO), Fe basedcatalyst in low temperature condition($240^{\circ}C$). Synthetic F-T diesel with diesel compositions after distillation process is consisted of $C_{12}{\sim}C_{23+}$ mixture as a kerosine, diesel compositions of n-paraffin and iso-paraffin compounds. Synthetic F-T diesel investigated a very high cetane number, low aromatic composition and sulfur free level compared to automotive diesel. Synthetic F-T diesel also show The wear scar of synthetic F-T diesel show poor lubricity due to low content of sulfur and aromatic compounds compared to automotive diesel.