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Excess Volumes of Aqueous Solutions of Nonionic Amphiphile 2-(2-Hexyloxyethoxy)ethanol (비이온 양친매성 분자 2-(2-Hexyloxyethoxy)ethanol 수용액의 과잉 부피)

  • Lee, Jungno;Hwang, Yoonmi;Kang, Minhee;Lim, Kyung-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.37 no.3
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    • pp.516-525
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    • 2020
  • The densities of aqueous solutions of the amphiphile 2-(2-hexyloxyethoxy)ethanol (C6E2) were measured at 279.15 K and 282.15 K by vibrating-tube densitometry. Then using the density data of the binary C6E2 (1)/water(2) system, the excess volumes and partial molar volumes were determined at various compositions. Excess volume VE exhibits negative deviation for the whole region of composition, which implies relatively stronger attraction between molecules. At the C6E2 mole fraction of around 0.45, VE was at its minimum. Partial molar volume ${\bar{V}}_1$ increases monotonously with the mole fraction x1(=x) and ${\bar{V}}_2$ decreases with x. Any particular point in ${\bar{V}}_1$ and ${\bar{V}}_2$, which may point to molecular association, was unobserved.

A Study on the Mechanical Properties of AC8A/$Al_2O_3$ Composites. (용탕단조법에 의한 AC8A/$Al_2O_3$ 복합재료의 기계적 성질에 관한 연구)

  • Kim, Ki-Bae;Kim, Kyoung-Min;Cho, Soon-Hyung;Yoon, Eui-Park
    • Journal of Korea Foundry Society
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    • v.11 no.6
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    • pp.475-481
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    • 1991
  • In this study the fabrication technology and mechanical properties of AC8A/$Al_2O_3$ Composites by squeeze casting process were investigated to develope for application as the piston materials that require good friction, wear resistance, and thermal stability. AC8A/$Al_2O_3$ composistes without a porosity and the break of preform were fabricated at the melt temperature of $740^{\circ}C$, the preform temperature of $500^{\circ}C$, and mold temperature of $400^{\circ}C$ under the applied pressure of $1200kg/cm^2$ as the results of the observation of microstructures. As the results of this study, the tensile strength of AC8A/$Al_2O_3$ composites was not increased linearly with $Al_2O_3$ volume fraction and so it seemed not to agree with the rule of mixture, which had been used often in metal matrix composite. Also the tensile strength after thermal fatigue test was little different from that before the test. Consequently it was thought that AC8A/$Al_2O_3$ composites fabricated under our experimental conditions had a good thermal stability and subsequently a good interface bonding. Wear rate(i.e., volume loss per unit sliding distance) of AC8A/$Al_2O_3$ composites was decreased with $Al_2O_3$ volume fraction and the sliding speed at both room temperature and $250^{\circ}C$ and so there was a good correlation between wear rate and hardness. Also the wear rate of AC/8A20% $Al_2O_3$ composities was obtained the value of $1.65cm^3/cm$ at sliding speed of 1.14m/sec as compared with about $3.0\;{\times}10^{-8}cm^3/cm$ hyereutectie Al-Si alloy(Al-16%Si-2%Cu-1%Fe-1%Ni), which applied presently for piston materials. The wear behavior of $Al_2O_3$ composites was observed to a type of abrasive wear by the SEM view of wear surface.

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The Investigation on the Behavior of Beam-Column Joint with High and Low Strength Concerte (고강도와 보통강도 콘크리트를 사용한 보-기둥 접합부의 구조적 거동)

  • 신성우;이광수;문정일;안종문;박희민;장일영
    • Magazine of the Korea Concrete Institute
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    • v.4 no.1
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    • pp.119-126
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    • 1992
  • AC] 318-H9 Recommended that when the specified compressive strength of concrete in a column is greater than 1. 4 times that specified for a floor system, top surface of the colurrm concrete shall extend 2ftU;OOrrun) into the slab from the face of colUlml to avoid unexpected brittle failure. The purpose of this investigation is to suggest the basic information for the structural safety, The major variables are com preSSlve strength of concrete, shear confinement ratio, and loading types. The test results showed that the load capaCIty of speCImen subjected to monotOI1lC loading had more than that of specimen subjected to one way cyclic loading. The failure modes of specimens under cyclic loading were concentrated at 5-20cm apart region from beam-column joint face and ductility index are increased with increasing of shear confinement ratio. Keywords: ACI 318-89, High and Low Strength Concrete, Beam-Column Joint, Shear Confinement Ratio, Loading Type, Ductility Index, Extension Distance.

Effects of Fiber Blending Condition and Expansive Admixture Replacement on Tensile Performance of Rebar Lap Splice in Strain-Hardening Cement-Based Composites (SHCCs) (섬유혼입조건 및 팽창재 대체에 따른 변형 경화형 시멘트 복합체 내의 철근 겹침이음 성능)

  • Ryu, Seung-Hyun;Lee, Young-Oh;Yun, Hyun-Do
    • Journal of the Korea Concrete Institute
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    • v.24 no.2
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    • pp.111-120
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    • 2012
  • This paper is a report about lap splice performance of rebar embedded in the strain-hardening cement-based composites (SHCCs) under monotonic and repeated tension loading. Ten mix proportions of cement-based composites such as SHCCs and normal concrete were investigated. The study parameters are comprised of (1) types of reinforcing fibers (polyethylene and steel fiber), (2) replacement levels of expansive admixture (EXA, 0% and 10%), and (3) compressive strength (30 and 100 MPa) of cement-based composites. Lap splice lengths (ld) of rebars in SHCC materials and normal concrete were 60% and 100% of splice length calculated by code requirements for structural concrete, respectively. Test results indicated that SHCCs materials can lead to enhancements in the lap splice performance of embedded rebar. All of the fiber reinforcement conditions (PE-SHCC and PESF-SHCC) considered in this study produced considerable improvements in the tensile strength, cracking behavior, and bond strength of lap-spliced rebar. Furthermore, adding EXA to SHCC matrix improved the tensile lap splice performance of rebar in SHCC materials. However, for controlling crack behavior, the performance of PE-SHCC was better than that of PESF-SHCC due to its mechanical properties. This study demonstrated an effective approach for reducing required development length of lap spliced rebar by using SHCC materials.

An Analytical Study on the Optimum Application of Diaphragm in Circular Steel Piers (원형강교각의 다이아프램 최적 적용에 관한 해석적 연구)

  • Jang, Gab-Chul;Chang, Kyong-Ho
    • Journal of Korean Association for Spatial Structures
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    • v.7 no.2 s.24
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    • pp.91-96
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    • 2007
  • To improve the land use of urban, Construction of the circular steel column is required recently. The circular steel columns have a advantage for improving a load carrying capacity as wall as reducing a effective section area. However, the circular steel columns under service load, such as earthquake, shows a tendency to cause local buckling and large deformation. To prevent these phenomena, use of diaphragm is considered. It is reported that longitudinal stiffeners has a effect on improving a buckling and fatigue performance of steel structures. The research of effect on diaphragm is not sufficient. Under monotonic and cyclic loadings diaphragm make a important role to prevent local buckling and deformation of used steel structures. Therefore, influence of diaphragm on performance of used steel structures is investigated. In this study, the influence of diaphragm on seismic and deformation performance of circular steel piers was investigated by using elastic-plastic finite element analysis considered geometrical and material non-linearity. The seismic performance of circular steel columns was evaluated for analytical parameter of manufactured part. The seismic performance of circular steel columns was clarified by comparing an energy dissipation of circular steel piers.

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A Study of the Mutual Substitution State of Sr, Ca in $Bi_2Sr_2-\chi_LCa_1+\chi_LCu_2O_{8+d}$ Films Prepared by LPE Method (LPE법으로 작성한 $Bi_2Sr_2-\chi_LCa_1+\chi_LCu_2O_{8+d}$ 막 (film)에서 Sr, Ca의 상호치환상태에 관한 연구)

  • Sin, Jae-Su;Ozaki, Hajime
    • Korean Journal of Materials Research
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    • v.8 no.10
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    • pp.925-930
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    • 1998
  • EPMA and XPS on $Bi_2Sr_2-\chi_LCa_1+\chi_LCu_2O_{8+d}$($\chi_L$ = 0.01, 0.2, 0.3, 0.4, 0.5, 0.6) films by LPE method were performed in order to investigate Sr and Ca distributions in SrO- and Ca-layers. It is found that $T_C^{zero}$ carrier concentration and lattice parameter c monotonically decreases with increasing $\chi_L$. Sr and Ca contents in Ca-layer change in proportion to that in melt. On the other hand, in SrO-layer, Ca content strongly depends on Sr content in that layer and not on Ca content in melt. Since deficiency in SrO-layer increases and $T_C^{zero}$ creases with $\chi_L$,t is found that the deficiencies of Sr and Ca atoms in the SrO-layer has a influence on reducing $T_C^{zero}$.

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Lightweight Design of an Outer Tie Rod Using Meta-Model Based Optimization Technique (메타모델기반최적화를 이용한 아우터타이로드의 경량화 설계)

  • Kim, Young-Jun;Park, Soon-Hyeong;Lee, Kwon-Hee;Park, Young-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.11
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    • pp.7754-7760
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    • 2015
  • The outer tie rod is one of the part of steering system, the optimization process was executed to find the lightweight design. The inner tie rod was considered in the optimum design of an outer tie rod. it could be closer to the test condition than in the case of considering outer tie rod only. The aluminum forging material was considered as a weight reduction proposal. The target of optimization was the shape of the minimum weight to resist at the load of buckling. RSM and Kriging interpolation method were applied as a optimization method to consider the nonlinear shape optimization problem. Then, 16.3%, 16.6% of weight reduction was obtained from the result comparing with that of the initial model. The results of meta model optimization was compared with that of finite element method. The error values of buckling load estimation were 2.6%, 2.04%. and those of weight estimation were 0.17%, 0.13%. Therefore, it seemed that the result of Kriging model could be obtained closer to optimum value than that of RSM model.

Numerical Analysis of Nonlinear Shoaling Characteristics over Surf Zone Using SPH and Lagrangian Dynamic Smagronsky Model (Lagrangian Dynamic Smagronsky 난류모형과 SPH를 이용한 쇄파역에서의 비선형 천수거동에 관한 연구)

  • Cho, Yong-Jun;Lee, Heon
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.19 no.1
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    • pp.81-96
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    • 2007
  • Nonlinear shoaling characteristics over surf zone are numerically investigated based on spatially averaged NavierStokes equation. We also test the validity of gradient model for turbulent stresses due to wave breaking using the data acquainted during SUPERTANK LABORATORY DATA COLLECTION PROJECT(Krauss et al., 1992). It turns out that the characteristics length scale of breaking induced current is not negligible, which firmly stands against ever popular gradient model, ${\kappa}-{\varepsilon}$ model, but favors Large Eddy Simulation with finer grid. Based on these observations, we model the residual stress of spatially averaged NavierStokes equation after Lagrangian Dynamic Smagorinsky(Meneveau et al., 1996). We numerically integrate newly proposed wave equations using SPH with Gaussian kernel function. Severely deformed water surface profile, free falling water particle, queuing splash after landing of water particle on the free surface and wave finger due to structured vortex on rear side of wave crest(Narayanaswamy and Dalrymple, 2002) are successfully duplicated in the numerical simulation of wave propagation over uniform slope beach, which so far have been regarded very difficult features to mimic in the computational fluid mechanics.

Numerical Analysis of the Hydraulic Characteristics of a Boundary Layer Streaming over Surf-Zone Using LES and Dynamic Smagorinsky Turbulence Model (LES와 Dynamic Smagorinsky 난류모형을 이용한 쇄파역에서의 경계층 Streaming 수치해석)

  • Cho, Yong Jun
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.32 no.1
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    • pp.69-84
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    • 2020
  • Natural shoreline repeats its re-treatment and advance in response to the endlessly varying sea-conditions, and once severely eroded under stormy weather conditions, natural beaches are gradually recovered via a boundary layer streaming when swells are prevailing after storms cease. Our understanding of the boundary layer streaming over surf-zone often falls short despite its great engineering value, and here it should be noted that the most sediments available along the shore are supplied over the surf-zone. In this rationale, numerical simulation was implemented to investigate the hydraulic characteristics of boundary layer streaming over the surf zone in this study. In doing so, comprehensive numerical models made of Spatially filtered Navier-Stokes Eq., LES (Large Eddy Simulation), Dynamic Smagorinsky turbulence closure were used, and the effects of turbulence closure such as Dynamic Smagorinsky in LES and k-ε on the numerically simulated flow field were also investigated. Numerical results show that due to the intrinsic limits of k-ε turbulence model, numerically simulated flow velocity near the bottom based on k-ε model and wall function are over-predicted than the one using Dynamic Smagorinsky in LES. It is also shown that flow velocities near the bottom are faster than the one above the bottom which are relatively free from the presence of the bottom, complying the typical boundary layer streaming by Longuet-Higgins (1957), the spatial scope where boundary layer streaming are occurring is extended well into the surf zone as incoming waves are getting longer. These tendencies are plausible considering that it is the bottom friction that triggers a boundary layer streaming, and longer waves start to feel the bottom much faster than shorter waves.

Trend of the welding technology for surface modification (표면개질을 위한 오버레이용접 기술개발 현황)

  • 백응률
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 1998.11a
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    • pp.19-20
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    • 1998
  • 오버레이용접에 의한 표면개질기술(Weld Surfacing or Hardfacing Technology)은 내식성, 내 마모성, 또는 내열성을 갖는 합금의 용접재료를 모재 표면에 균일하게 용착(오버레이:Ovedayer)시킴으로써 목적하는 재료의 표면성질을 향상시키는 표면처리의 한 방법이으로써 1922년 Stoody가 Steel Tube에 Cr합금 분말을 충진한 용접봉을 제조하여 석유시추용 회전드릴의 선단 표면을 오버 레이 용접시켜 내마모성을 획기적으로 개선시킴으로써 이루어 졌다. 초기 오버레이 용접기술은 발전설비I 제철설비I 시벤트설비, 그리고 제지설비 등 주로 설비 부품들의 표면부 내마모성을 개선시키는 방향으로 주로 연구 개발이 이루어졌으나, 기술개발의 진전으로 탈황설비 둥의 표면부 내식성 향상, 연속주조롤 표면부의 내산화성, 내열피로성, 내마모 성 향상 둥을 위해 점차 산업전반에 널리 이용되고 있으며, 설비의 고도화 및 장수명화가 요구되 면서 본 기술의 중요성 또한 점차 부각되고 있다. 그림 1은 연강의 모재 위에 셀프쉴드플럭스코어드와이어(Self-Shield Flux Cored Wire:SS-FCW, 이하 55-FCW라 기술함)를 사용하여 오버레이 용접올 하는 장면을 도식적으로 나 타낸 것이다. 모재와 전극재인 용접봉(S5-FCW) 사이에서 아크가 발생되고, 아크열에 의해서 용접 봉 및 모재 일부가 용융되면서 모재 표면에 새로운 오버레이 표면층이 형성된다. 통상 오버레이 층의 1층 두께는 2-6mm 내외이며, 단층 혹은 다충 오버레이를 자유롭게 실시한다. 오버레이층의 물성은 아크열에 의한 모재로의 용입정도에 따라 1층부에서는 모재의 영향을 크게 받지만 오버레 이충 수가 증가된 3층부에서 부터는 전적으로 용접봉의 성분에 좌우된다. 사진 1은 연강(55-41)의 모재위에 크롬탄화물이 다량 함유된 고크롬 탄화물형 내마모재가 오버 레이된 내마모 복합강판 (wear plate)의 단면 미세조직 사진으로써 모재부와 오버레이충을 함께 보여주고 있다. 모재와 오버레이 충간의 경계면은 모재 일부가 용융된 후 웅고하면서 형성됨으로 인해서 도금이나 용사층과는 달리 매우 견고하게 결합되어 있다. 따라서 계면부의 탈락이라는 문 제점은 거의 없어 심한 응력을 받는 기계구조물 및 부품에도 본 기술은 널리 적용되고 있다. 그리고 사진 1에서 알 수 있는 바와 같이 모재와는 전혀 상이한 재료를 자유로이 선택하여 표면 유효층 일부만 오버레이시키며I 주조 및 단조가 불가능한 재료까지도 표면부에 오버레이 시킴으로 서 부품 및 설비의 제조에 있어 재료비의 절감과 제품의 수명이 획기적으로 개선될 수 있다. 그리고 최근에는 도금 빛 용사 둥과 같은 표면처리를 할 경우임의 소재 표면에 도금 및 용 사에 용이한 재료를 오버레이용접시킨 후 표면처리를 함으로써 보다 고품질의 표면층을 얻기위한 시도가 이루어지고 있다. 따라서 국내, 외의 오버레이 용접기술의 적용현황 및 대표적인 적용사례, 오버레이 용접기술 및 용접재료의 개발현황 둥을 중심으로 살펴봄으로서 아직 국내에서는 널리 알려지지 않은 본 기 술의 활용을 넓이고자 한다.

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