• Proceedings of the Korea Water Resources Association Conference
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• 2023.05a
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• pp.56-56
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• 2023

남양호는 농업용수 공급을 위해 건설된 하구 담수호로 과도한 영양물질 축적으로 인해 매년 여름 녹조류가 번성한다. 따라서 본 연구에서는 조류발생 특성을 분석하고자 식물성 플랑크톤 및 관련 분해 산물에 의해 고유 광학특성을 가지고 있는 Chlorophyll-a(Chl-a)의 추정을 통한 녹조 발생을 파악하고자 Sentinel-2 Multi Spectral Image(MSI)의 원격 반사율 광학 스펙트럼을 사용하였다. Chl-a 추정알고리즘 개발을 위하여 Sentinel-2 A, B의 교차 방문주기인 5일 간격에 맞추어 현장수질자료(2022년: 27회 2023년: 27회)를 측정하였다. Chl-a 농도는 EXO-YSI를이용하여 측정하였으며 해당기간동안 9.4 ~ 127.1 mg/L의 범위를 보였으며, Sentine-2 자료는 A, B자료에서 B1(443 nm) ~ B8A(865 nm)파장의 값을 기상조건(구름, 안개, 강수)을 고려하여 현장수질측정 위치에서 반사도를 추출하였다. 입력자료는 대기 및 방사영향을 고려해 반사도 간의 비율자료와 선행연구에서 활용된 반사도를 활용하였으며 알고리즘은 다중선형회귀분석(Multi Linear Regression Model)과 Random Forest를 활용하였다. MLR의 경우 결정계수(R2)가 학습 및 검증에서 각각 0.68, 0.59의 성능을 보였으며, RF의 경우 각각 0.94, 0.85의 성능을 보였다. 해당알고리즘으로 생성된 Chl-a 시공간농도 자료는 담수호내 조류발생 특성을 분석하고 효율적 조류관리 및 대처에 활용될 것으로 판단된다.

• Composites Research
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• v.19 no.3
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• pp.1-6
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• 2006

As the structures of the high performance electronic equipments and devices recently become more complex, the electromagnetic interference (EMI) and compatibility (EMC) have been very essential for commercial and military purposes. Thus, sensitive electrical devices and densely packed systems need to be protected from electromagnetic wave. In this research, glass fabric/epoxy composites containing conductive multi-walled carbon nanotube (MWNT) and carbon fiber/epoxy composites as electrical shielding materials were fabricated and electrical properties of the composites were measured. The concerning frequency band is from 300 MHz to 1 GHz. The performances of composite shielding enclosures were predicted using electromagnetic wave 3-D simulation tool, CST Microwave Studio. The shielding enclosure made of carbon fiber/epoxy composites were fabricated and the shielding effectiveness (SE) was measured in the anechoic chamber.

• Journal of the Korean Applied Science and Technology
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• v.40 no.5
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• pp.1116-1125
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• 2023

Zinc oxide film is a transparent conductive material and is used in optoelectronic devices in various fields. Therefore, characterization of the zinc oxide film will play a very important role in improving the performance of optoelectronic devices. Here, we will evaluate the morphological and structural characteristics of such a zinc oxide film based on the solution process. Specifically, the sol-gel method will be repeatedly performed to observe the change in material properties of the zinc oxide film according to the number of times of spin-coating. It was confirmed that crystallization proceeded as a result of performing the sol-gel method repetitively 5 times under constant solution conditions. At 7 times or more, the element composition and crystallinity tended to converge to a specific value. The average crystal size of the final zinc oxide film was calculated to be about 10.7 nm. In this study, the number of processes showing optimal crystallization was 7 times. The results and methodology of this study can be applied while varying various solution process variables and are expected to contribute to establishing optimal process conditions.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.7 no.4
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• pp.229-236
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• 2009

There are two types of spent fuels generated from nuclear power plants, CANDU type and PWR type. PWR spent fuels which include a lot of reusable material can be considered to be recycled. CANDU spent fuels are considered to directly disposed in deep geological formation, since they have little reusable material. In this study, based on the Korean Reference spent fuel disposal System(KRS) which is to dispose both PWR and CANDU spent fuels, the more effective CANDU spent fuel disposal systems have been developed. To do this, the disposal canister has been modified to hold the storage basket which can load 60 spent fuel bundles. From these modified disposal canisters, the disposal systems to meet the thermal requirement for which the temperature of the buffer materials should not be over $100^{\circ}C$ have been proposed. These new disposals have made it possible to introduce the concept of long tenn storage and retrievabililty and that of the two-layered disposal canister emplacement in one disposal hole. These disposal concepts have been compared and analyzed with the KRS CANDU spent fuel disposal system in terms of disposal effectiveness. New CANDU spent fuel disposal concepts obtained in this study seem to improve thermal effectiveness, U-density, disposal area, excavation volume, and closure material volume up to 30 - 40 %.

• Journal of Korean Society of Forest Science
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• v.101 no.4
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• pp.574-578
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• 2012

This study was carried out to clarify the influences of forest environmental factors on turbidity of Stream water on three stands (Castanea crenata, Pinus densiflora and Plantation Land) of small watershed in Samgyeri Naedong-myeon Jinju-si Gyeongsangnam-do. The relationship between turbidity and forest environmental factors was a positive correlation at 1% level with chromaticity, suspended solid, sediment runoff erosion, slope, rainfall intensity, preceding dry days, watershed area and stream length and at 5% level with accumulative rainfall. The important factors that affected turbidity in small watershed showed in order of preceding dry days, rainfall intensity, stream length, chromaticity and suspended solid. In the stepwise regression between turbidity and forest environmental factors, the estimation equation is as follow; Y=-28.125+0.047x (suspended solid)+0.058x (chromaticity)+1.518x (rainfall intensity)+0.264x (stream length)+1.837x (preceding dry days). The results indicates that dangerous areas of landslide and soil runoff by land use could be applied to the mitigation measures such as afforestation, erosion check dam and revetment for erosion control and water quality management in small watershed.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.32 no.4 s.59
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• pp.209-217
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• 2006

Emulsion is a dispersion system among liquids which are not miscible together. There are numerous cosmetic raw materials which have different physicochemical properties. Therefore, emulsion technology is very useful in cosmetics. With the development of emulsifier, several emulsification technologies have been developed. Since HLB method by Griffin in 1950's, PIT method, gel method, and D-phase methods, etc, have been developed. Recently, the application of natural emulsifier and polymeric emulsifier increases in cosmetics in order to achieve enhanced safety and biocompatibility. Besides nano-emulsion, multiple-emulsion, liquid crystal emulsion, and Pickering emulsion have been developed and applied as means of differentiating appearance and texture of products and achieving enhanced delivery of active ingredients. Meanwhile, the application studies of nano-dispersed structural system such as liposome or cubosome are on progress. Liposome is a bi- or multi-lamella layer dispersion system composed of amhiphilic molecules - phospholipids which are main components of plasma membrane. Cubosome also is a nano-sized dispersion system composed of a specific molecule like glyceryl monoloeate derived from natural products. And it has a cubic bicontinuous structure in water due to its unique molecular structure. Incorporating compounds (active materials) into such nano-particles can increase biocompatibility and delivery efficiency of target compounds. Manufacturing process and application of cosmetic emulsions and nano-particles are briefly introduced in this paper.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.28 no.1
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• pp.47-53
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• 2022

Recently, intelligent packaging of foods has been increasingly developed in response to the growing interest of consumers in checking food quality. Indicators, an important element in intelligent packaging, change color to detect specific substances or indicate food quality changes. Gas indicators can be built into food packaging to detect volatile substances that are released when food quality changes. Ethylene gas is produced as climacteric fruits ripen. Climacteric fruit ripening results from a rapid increase in ethylene production and respiration. In the case of packaged fruits, the ethylene gas concentration in the headspace is closely related to the ripeness of each fruit variety. If an ethylene gas indicator that can be used in fruit packaging is available, the consumer will be able to eat the fruit at the optimal time. In this paper, the characteristics and pros and cons of the ethylene gas indicators developed so far were analyzed by reviewing various types of indicators such as metal reduction-based indicator, fluorescence-based indicator, pH indicator-based indicator, and liposome-based indicator.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.425-426
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• 2013

IIIN계 물질 기반의 광 반도체는 직접 천이형 넓은 밴드갭 구조를 갖고 있기 때문에 적외선부터 가시광선 및 자외선까지를 포함한 폭 넓은 발광파장 조절이 가능하여 조명 및 디스플레이 관련 차세대 광원으로 많은 관심을 받고 있다. 일반적인 청색 및 녹색 발광영역의 활성층으로는 InGaN/GaN 다중양자우물구조를 사용하고 있으나, 장파장의 녹색 발광을 얻기 위해서는 인듐의 함유량이 증가하여야 한다. 하지만, 인듐의 함유량이 증가함에 따라서 InGaN/GaN 다중양자우물 구조내에서 인듐의 편석현상의 발생이 용이하게 되어 계면 특성을 저하할 뿐 아니라, 비발광 센터를 증가하여 발광 효율을 급격히 감소시키는 원인이 되고 있다. 또한, InGaN과 GaN의 큰 성장온도의 차이에 따라 800도 부근의 저온 영역에서 성장된 InGaN층이 1,000도 이상의 고온 영역에서 GaN층이 성장시 InGaN층의 열화 현상이 급격히 발생되고 있다. 이를 억제하기 위해서 금속유기화학증착법의 성장 변수 최적화, 응력제어, 도핑 등의 편석 억제기술 및 보호층이 사용되고 있다. 본 연구에서는 인듐함유량이 증가된 녹색 InGaN/GaN 다중양자우물구조에서 InGaN 우물층 상하부에 도입된 GaN 보호층에 따라 발생되는 양자우물구조의 광학 및 결정학적 특성 분석을 통해 GaN 보호층의 역할을 분석하고자 한다. 본 연구에서는 금속유기화학증착장치를 이용하여 사파이어 기판위에 GaN 템플릿을 성장하고, n-형 GaN, InGaN/GaN 다중양자우물구조 및 p-형 층을 성장하였다. 앞선 언급하였듯이, InGaN/GaN 다중양자우물구조내에 GaN 보호층의 역할을 규명하기 위하여 샘플 A의 경우는 보호층이 전혀 없는 구조이고, 샘플 B의 경우는 InGaN 우물층의 상단부에만, 샘플 C의 경우에는 우물층 상부 및 하단부 모두에 약 2.0 nm 두께의 GaN 보호층을 형성하였다. 이 보호층의 유무에 따른 다중양자우물구조의 계면 특성을 확인하기 위한 X-선 회절을 이용하였고, 광학적 특성을 확인하고 상온 포토루미네선스법을 이용하여 녹색 발광 파장의 변화 및 발광세기를 관찰하였다. 우선적으로, 상온 포토루미네선스법을 이용하여 각 샘플의 발광특성을 확인한 바 상하부 모두에 GaN 보호층이 존재하는 샘플 C의 경우 약 510 nm 부근에서 발광이 관찰되었지만, 상단부에 GaN 보호층이 존재하는 샘플 B는 약 495 nm영역에 발광이 확인되었다. 특히, 전혀 보호층이 존재하지 않는 샘플 A의 경우 약 440 nm에서 발광하는 현상을 관찰하였다. 이는 우물층 상단부 및 하단부에 존재하는 GaN 보호층이 In의 확산을 억제하는 것으로 판단된다. 또한, 발광파장 및 세기를 확인한 바, 보호층의 존재하지 않을수록 단파장화가 발생함에도 불구하고 발광세기는 급격히 약해지는 것으로 보아 계면특성이 저하되어 비발광센터가 증가되는 것으로 판단된다. 이를 구조적으로 확인하기 위하여 X-선 회절법을 통한 ${\omega}$/$2{\Theta}$ 스캔의 결과는 In의 0차 피크가 GaN 보호층이 없을 경우 GaN의 피크 방향으로 이동하는 것으로 보아 GaN 보호층은 우물층 성장 후 GaN 장벽층을 성장하기 위해 온도를 증가시키는 과정에서 In의 확산되는 것으로 판단된다. 또한, 하부 GaN 보호층의 경우 GaN 장벽층 성장 후 온도를 감소시키는 과정에서 성장되므로, 우물층으로부터 In의 탈착현상이 아닌 장벽층과의 상호 확산으로 판단된다. 또한, 계면특성을 확인하기 위해 InGaN의 X-선 위성 피크를 확인한 바 샘플 A의 경우 매우 넓고 약한 피크가 관찰된 반면, 보호층이 존재하는 샘플 B와 C의 경우 강하고 얇은 피크가 확인되었다. 이는 GaN 보호층의 도입으로 인해 계면특성이 향상되는 것으로 판단된다. 따라서, 우리는 InGaN/GaN 다중양자우물구조에서 GaN 보호층은 상부의 열화 억제 뿐아니라, 하부의 장벽층 및 우물층 사이의 상호확산을 억제하는 GaN 보호층의 도입을 통하여 우수한 계면 특성 및 비발광센터의 억제를 얻을 수 있을 것으로 생각되며, 이는 향후 GaN계 발광다이오드의 전계 발광특성을 증가하여 우수한 발광소자를 개발할 수 있을 것으로 기대된다.

• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.113.2-113.2
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• 2010

We report that the novel covalent organic frameworks (COFs) are capable of reversibly providing an extremely high uptake capacity of carbon dioxide and hydrogen at room temperature. These COFs are designed based on the multiscale simulations approach via the combination of ab initio calculations and force-field calculations. For this goal, we explore the adsorption sites of carbon dioxide and hydrogen on COFs, their porosity, as well as carbon dioxide adsorption isotherms. We identify the binding sites and energies of $CO_2$ on COFs using ab initio calculations and obtain the carbon dioxide adsorption isotherms using grand canonical ensemble Monte Carlo calculations. Moreover, the calculated adsorption isotherms are compared with the experimental values in order to build the reference model in describing the interactions between the $CO_2/H_2$ and the COFs and in predicting the $CO_2$ and $H_2$ adsorption isotherms of COFs. Finally, we design three new COFs, 2D COF-05, 3D COF-05 (ctn), and 3D COF-05 (bor), for the high capacity $CO_2/H_2$ and $H_2$ storage.

• Clean Technology
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• v.12 no.2
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• pp.107-111
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• 2006

Two types of mesoporous carbons, CMK-3 and CMK-5, were prepared using mesoporous silica as a removable template, and their hydrogen storage capacities were evaluated. For the purpose of comparison, MWCNT (multi-walled carbon nanotubes) was selected and the adsorption of hydrogen was measured. The amount of hydrogen adsorbed on carbon materials was found to be closely related to the surface areas of carbon samples: The higher the surface area of the carbon material, the larger amount of hydrogen was adsorbed. The hydrogen storage capacity increased in the order of CMK-5 > CMK-3 > MWCNT. In addition, hydrogen storage capacity was greatly enhanced by the Pd-doping onto CMK-5. When the metallic Pd was doped on the carbon material, the adsorption amount of hydrogen via a hydrogen spill-over mechanism was crucial to the hydrogen storage capacity of Pd-doped CMK-5.