• Explosives and Blasting
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• v.36 no.4
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• pp.26-34
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• 2018

Explosions of vapor cloud formed due to the leakage from installations with flammable fuels have often occurred in Korea and foreign countries. In this study, TNT equivalency method and Multi-Energy method for vapor cloud explosion blast modelling are described and demonstrated in a case study. As TNT equivalency method is simple and direct, it has been widely used for modelling a vapor cloud explosion blast. But TNT equivalency method found to be difficult to select a proper correlation between the amount of combustion energy produced from the vapor cloud explosion and the equivalent amount of TNT to model its blast effects. Multi-Energy method assumes that the strength of vapor cloud explosion blast depends on the layout of the space where the vapor cloud is spreading. Strictly speaking, the explosive potential of a vapor cloud is dependent upon the density of the obstructed regions. In this study, Flixborough accident are analyzed as a case study to assess the applicability of TNT equivalency method and Multi-Energy method. TNT equivalency method and Multi-Energy method found to be applicable if coefficient of TNT equivalency and coefficient of strength of explosion blast are selected properly.

• Explosives and Blasting
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• v.40 no.3
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• pp.44-53
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• 2022

This study evaluates the applicability of the TNT Equivalency Method, Multi-Energy Method, and Baker-Strehlow-Tang (BST) Method, which are blast prediction models used to determine the overpressure of blast wave generated from vapor cloud explosion. It is assumed that the propane leaked from a propane storage container with a capacity of 2000 kg installed in an area where studio houses and shopping centers are concentrated causes a vapor cloud explosion. The equivalent mass of TNT calculated by applying the TNT Equivalency Method is found to be 4061 kg. Change of overpressure with the distance obtained by the TNT Equivalency Method, Multi-Energy Method, and BST Method is rapid and the magnitude of overpressure obtained by the TNT Equivalency Method and BST method is generally similar within 100 m from explosion center. As a result of comparing the overpressure observed in the actual vapor cloud explosion case with the overpressure obtained by applying the TNT Equivalent Method, Multi-Energy Method, and BST Method, the BST Method is found to be the best fit. As a result of comparing the overpressure with the distance obtained by each explosion prediction model with the damage criteria for structure, it is estimated that the structure located within 90 m from explosion center would suffer a damage more than partial destruction, and glass panes of the structure separated by 600 m would be fractured.

• Tunnel and Underground Space
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• v.31 no.1
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• pp.52-65
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• 2021

In this study, authors analyzed the vapor cloud explosion induced by propane leak at the PEMIX Terminal, which is the propane storage facility outside of Mexico City. TNT equivalence mass for the leaked 4750 kg propane was estimated to be 9398 kg. Blast parameters such as peak overpressure, positive phase duration, and impact at 40-400 (m) away from the center of the explosion were calculated by applying TNT Equivalency Method and Multi-Energy Method. The probability of damage due to lung damage, eardrum rupture, head impact, and whole-body displacement impact by applying the probit function obtained using blast parameters was evaluated. The peak overpressure obtained using Multi-Energy Method was found to be greater than the peak overpressure obtained by applying the TNT Equivalency Method at all distances considered, but it was evaluated that there was no significant difference from the points above 200 m. The peak overpressure obtained by Multi-Energy Method was computed to assess the extent of damage to the structure, and it was shown that structures within 100 m of the explosion center would collapse completely, and that the glasses of the structures 400 m away would be almost broken. The probability of death due to lung damage was shown to vary depending on a human body's position located in the propagating direction of shock wave, and if there is a reflecting surface in the immediate surroundings of a human body, the probability of death was estimated to be the greatest. The impact of shock wave on lung damage, eardrum rupture, head impact, and whole-body displacement impact was evaluated and found to affect whole-body impact < lung damage < eardrum rupture

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.445-447
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• 2008

본 연구에서는 다중벽 탄소나노튜브용 표면개질제를 리빙라디칼중합법을 통하여 제조하고, 이를 이용하여 표면개질되고 분산제어된 다중벽탄소나노튜브를 제조하고 염료감응형 태양전지의 대전극 재료로 사용하였다. 우선 리빙라디칼중합법 중 nitroxide mediated polymerization (NMP) 기술을 이용하여 poly(maleic anhydride-co-p-acetoxystyrene)-block-poly(p-acetoxystyrene)를 합성하고, 공중합체중의 maleic anhydride기에 이미드화 반응을 통하여 pyrene기를 도입하였다. 공중합체 중의 p-acetoxystyrene 반복단위들은 가수분해 반응을 통하여 p-hydroxystyrene 반복단위로 변환하였으며, 제조된 공중합체의 구조와 열 특성 등을 GPC, GC, $^1H$-NMR, TGA을 통하여 분석하였다. 제조된 공중합체를 이용하여 다중벽 탄소나노튜브의 표면을 polymer wrapping법으로 처리하였고, 표면개질된 탄소나노튜브의 분산성을 다양한 용매에서 비교분석하였다. 표면이 개질되고 페이스트 내에의 분산성이 향상된 다중벽탄소나노튜브를 염료감응태양전지의 대전극 제조에 응용하였으며, 표면처리 및 분산제어 여부에 따른 제작 특성 및 동작특성 등을 평가하였다.

• Explosives and Blasting
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• v.41 no.3
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• pp.73-92
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• 2023

With the increase of risk of gas explosion, various methods for indirectly estimating the explosion paramaters, which are required for the prediction of gas explosion scale and impact. In this study, the characteristics of the most frequently used methods such as TNT equivalent method, TNO multi-energy method, and BST method and the processes for determining the parameters of the methods were compared. In the case of TNT equivalent method, an adequate selection of the efficiency factor for various conditions such as the type of vapor cloud explosion and explosion material is needed. There is no objective guidelines for the selection of class number in TNO multi-energy method and it is not possible to estimate negative overpressure. It was found that there were some mistakes in the reported parameter values and suggested corrected values. BST method provides more detailed guidelines for the estimation of the explosion parameters including negative overpressure, but the graphs used in this methods are not clear. In order to overcome the problem, the graphs were redrawn. A more convenient estimation of explosion parameters with the numerical expression of the redrawn graphs will be available in the future.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.444-444
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• 2013

변형 다중양자우물은 전자 소자와 광전자 소자에 응용할 수 있는 가능성 때문에 연구가 많이 진행되고 있다. 합성 물질들의 초격자를 연속적으로 증착, 성장하는 디지털 합금은 다중양자우물을 활용한 광전자 소자에서 응용가치가 상당히 높다. 현재 디지털 합금을 이용한 다중양자우물의 성장과 관련한 연구가 활발히 진행되고 있고, 특히 InzGaxAl1-z-xP/InAlP 다중양자우물은 광전자 소자로서의 응용가치가 부각되고 있다. 그러나 InzGaxAl1-z-xP/InAlP 다중양자우물의 성장 및 광학적 성질에 대한 연구는 많이 진행되었으나, InzGaxAl1-z-xP/InAlP 다중양자우물에서의 변형효과를 고려한 전자적 성질에 대한 연구는 미흡하다. InzGaxAl1-z-xP/InAlP 다중양자우물에 대한 전자적 성질의 연구는 광소자의 성능 향상을 위해 매우 필요하다. 본 연구에서는 디지털 합금 성장 방법으로 형성한 InzGaxAl1-z-xP/InAlP 다중양자우물의 부띠 사이 천이와 전자 분포를 고찰하였다. 온도에 따른 광루미네센스의 측정을 통해 InzGaxAl1-z-xP/InAlP 다중양자우물에서 나타나는 부띠 사이의 천이를 관찰하였다. 가변 메시 유한 차분법을 이용한 이산적 모델을 통해 변형효과가 다중양자우물 구조에서 부띠에 주는 영향을 조사하였다. 격자의 불일치로 인한 변형 효과와 8-band envelope function approximation을 고려한 슈뢰딩거 방정식을 사용하여 InzGaxAl1-z-xP/InAlP 다중양자우물에서의 전자 부띠 에너지와 에너지 파동 함수를 계산하였다. 계산한 부띠 사이 천이 에너지와 광루미네센스 측정에서 보인 엑시톤 천이 에너지를 비교하였을 때, 작은 차이 값이 나타났다. 증착과정에서의 이종접합사이에서 발생하는 불확실성을 고려한다면 이 차이 값은 오차범위 안에 포함되며, 계산 값과 실험 값이 잘 일치하는 것으로 볼 수 있다.

• Applied Chemistry for Engineering
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• v.33 no.5
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• pp.451-458
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• 2022

Semiconductor quantum dots (QDs) are optical probes with excellent fluorescence properties. Therefore, they have been applied to various bio-medical imaging techniques and biosensors. Due to the unique optical characteristics of wide absorption and narrow fluorescence energy bands, multiple types of signals can be generated by the combination of fluorescence wavelengths from different QDs, which enables the simultaneous detection of more than two biomarkers. In this review, the advantages and applications of QDs and QD nanobeads (QBs) in multiple biomarker assays were described, and new developments or improvements in multiplexed biomarker detection techniques were summarized. In particular, recent reports were summarized, focusing on the design strategies in immunoassay construction and signal transducing materials for fluorescence-linked immunosorbent assays using QDs and immunochromatographic assays using QBs. New detection platforms will be developed for early diagnosis of diseases and other fields if multiplexed detection technologies of excellent accuracy and sensitivity are combined with artificial intelligence algorithms.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.74.1-74.1
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• 2011

탄소나노튜브는 높은 전기 전도성과 열 전도성을 가지며, 이러한 특성 때문에 21세기를 주도해 나갈 수 있는 차세대 첨단 소재로서 각광을 받고 있다. 또한 최근에는 나노공학기술의 발달로 인하여 획기적으로 높은 열전도도를 나타내는 다중벽 탄소나노튜브(Multi-walled Carbon Nanotubes, MWCNTs)의 대량 생산이 가능하게 되면서 다중벽 탄소나노튜브의 높은 열전도도 특성을 이용하여 탄소나노튜브를 기본 유체 및 기능성 유체에 안정하게 분산 시킨 후 이를 이용하고자 하는 연구가 활발히 진행되고 있으며, 탄소나노튜브를 유체에 안정하게 분산시키기 위한 방법으로는 기계적 분산법, 물리적 흡착에 의한 분산법, 화학적 개질에 의한 분산법이 있다. 따라서 본 연구에서는 이들 분산 방법과 탄소나노튜브 입자의 물성치에 따른 나노유체의 특성을 알아보기 위하여 나노유체의 열전도도와 점도 특성을 비교 분석하였다. 모든 물성치는 같지만 탄소나노튜브의 길이만 다른 두 종류의 다중벽 탄소나노튜브에 각각 계면 활성제(Sodium Dodecyl Sulfate, SDS) 100 wt%와 고분자 화합물(Polyvinyl Pyrrolidone, PVP) 300 wt%를 첨가하여 나노유체를 제조하였으며, 산화처리 된 다중벽 탄소나노튜브(Oxidized Multi-Walled Carbon Nanotubes, OMWCNTs)를 증류수에 초음파 분산하여 산화나노유체를 제조하였다. 나노유체의 열전도도는 전기 전도성 유체의 비정상 열선법(Transient Hot-wire Method)을 이용하여 측정하였고, 나노유체의 점도는 회전형 디지털 점도계를 이용하여 측정하였다. 실험 결과, 상온에서 동일 혼합비의 나노유체를 비교했을 때, 산화나노유체가 SDS 100 wt%, PVP 300 wt%를 혼합한 다른 나노유체보다 높은 열전도도 특성을 보였으며 점도 특성 또한 가장 낮은 것으로 측정되었다. 특히 상온에서 0.1vol%의 산화 CM-100 나노유체는 증류수보다 열전도도가 8.34%가 증가하였고, $10^{\circ}C$의 저온에서는 상온에서 증류수와 비교하여 측정된 열전도도 값보다 0.36%가 감소한 7.98%가 증가함을 보였다. 본 연구를 통하여 얻어진 결과는 높은 열전도도를 필요로 하는 열교환기의 작동유체나 기타 활용 분야에 대한 기초 자료로써 유용한 정보를 제공할 것이라 판단된다.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.21 no.4
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• pp.391-399
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• 2008

In this paper, we further generalize the work of Lin and Abel to the case of the first and the second order derivatives of energy release rates for two-dimensional, multiply cracked systems. The direct integral expressions are presented for the energy release rates and their first and second order derivatives. The salient feature of this numerical method is that the energy release rates and their first and second order derivatives can be computed in a single analysis. It is demonstrated through a set of examples that the proposed method gives expectedly decreasing, but acceptably accurate results for the energy release rates and their first and second order derivatives. The computed errors were approximately 0.5% for the energy release rates, $3\sim5%$ for their first order derivatives and $10\sim20%$ for their second order derivatives for the mesh densities used in the examples. Potential applications of the present method include a universal size effect model and a probabilistic fracture analysis of cracked structures.

• Journal of the Institute of Electronics and Information Engineers
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• v.52 no.8
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• pp.3-9
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• 2015

Under the maximum transmit power constraint and the minimum rate constraint, we propose the optimal number of transmit antennas and transmit power which maximize energy-efficiency (EE) in multi-user multiple-input multiple-output (MIMO) downlink system with the maximal ratio transmission (MRT) precoding. Because the optimization problem for the instantaneous channel is difficult to solve, we use independence of individual channel, average channel gain and path loss to approximate the objective function. Since the approximated EE optimization problem is two-dimensional search problem, we find the optimal number of transmit antennas and transmit power using Lagrange multipliers and our proposed algorithm. Simulation results show that the number of transmit antennas and power obtained by proposed algorithm are almost identical to the value by the exhaustive search.