• Title/Summary/Keyword: 다공형

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Laser Fabrication of Graphene-based Materials and Their Application in Electronic Devices (레이저 유도에 의한 그래핀 합성 및 전기/전자 소자 제조 기술)

  • Jeon, Sangheon;Park, Rowoon;Jeong, Jeonghwa;Hong, Suck Won
    • Journal of the Microelectronics and Packaging Society
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    • v.28 no.1
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    • pp.1-12
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    • 2021
  • Here, we introduce a laser-induced graphene synthesis technology and its applications for the electric/electronic device manufacturing process. Recently, the micro/nanopatterning technique of graphene has received great attention for the utilization of these new graphene structures, which shows progress developments at present with a variety of uses in electronic devices. Some examples of practical applications suggested a great potential for the tunable graphene synthetic manners through the control of the laser set-up, such as a selection of the wavelength, power adjustment, and optical techniques. This emerging technology has expandability to electric/electronic devices combined together with existed micro-packaging technology and can be integrated with the new processing steps to be applied for the operation in the fields of biosensors, supercapacitors, electrochemical sensors, etc. We believe that the laser-induced graphene technology introduced in this paper can be easily applied to portable small electronic devices and wearable electronics in the near future.

Current Status of Legal Regulations Regarding Gas- and Moisture-removing Active Packaging for Food: A Review (식품용 가스 및 수분 제거 활성포장 사용 및 법정 규정에 대한 현황)

  • Kim, Dowan;Oh, Jae-Min;Lee, Soonho;Kim, Hyun-Ah;Hwang, Joungboon;Ko, Seonghyuk
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.28 no.1
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    • pp.31-38
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    • 2022
  • Due to the increasing consumer demands for the safety, shelf life, and quality of food, the application and development of active packaging in the food and packaging industry have been improved. According to the standards and specifications of the Republic of Korea for utensils, containers, and packages, the function of active packaging is to remove or alleviate factors that degrade food quality. Although extensive reviews regarding the development and commercialization of active packaging have been conducted, the legal regulations and safety assessments concerning active packaging have rarely been examined. This review provides information regarding the definition, structure, components, operational mechanisms, and applications for active packaging that actively removes oxygen, moisture, carbon dioxide, and ethylene. Furthermore, the legal regulations and research results related to the development of test methods for safety assessments of active packaging are investigated.

Continuous Time Markov Process Model for Nuclide Decay Chain Transport in the Fractured Rock Medium (균열 암반 매질에서의 핵종의 붕괴사슬 이동을 위한 연속시간 마코프 프로세스 모델)

  • Lee, Y.M.;Kang, C.H.;Hahn, P.S.;Park, H.H.;Lee, K.J.
    • Nuclear Engineering and Technology
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    • v.25 no.4
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    • pp.539-547
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    • 1993
  • A stochastic approach using continuous time Markov process is presented to model the one-dimensional nuclide transport in fractured rock media as a further extension for previous works[1-3]. Nuclide transport of decay chain of arbitrary length in the single planar fractured rock media in the vicinity of the radioactive waste repository is modeled using a continuous time Markov process. While most of analytical solutions for nuclide transport of decay chain deal with the limited length of decay chain, do not consider the case of having rock matrix diffusion, and have very complicated solution form, the present model offers rather a simplified solution in the form of expectance and its variance resulted from a stochastic modeling. As another deterministic way, even numerical models of decay chain transport, in most cases, show very complicated procedure to get the solution and large discrepancy for the exact solution as opposed to the stochastic model developed in this study. To demonstrate the use of the present model and to verify the model by comparing with the deterministic model, a specific illustration was made for the transport of a chain of three member in single fractured rock medium with constant groundwater flow rate in the fracture, which ignores the rock matrix diffusion and shows good capability to model the fractured media around the repository.

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Comparative Evaluation of Behavior Analysis of Rectangular Jet and Two-dimensional Jet (사각형제트와 2차원제트의 거동해석의 비교 평가)

  • Kwon, Seok Jae;Cho, Hong Yeon;Seo, Il Won
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.6B
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    • pp.641-649
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    • 2006
  • The behavior of a three-dimensional pure rectangular water jet with aspect ratio of 10 was experimentally investigated based on the results of the mean velocity field obtained by PIV. The saddle back distribution was observed in the lateral distribution along the major axis. The theoretical centerline velocity equation derived from the point source concept using the spreading rate for the axisymmetric jet was in good agreement with the measured centerline velocity and gave the division of the potential core region, two-dimensional region, and axisymmetric region. The range of the two-dimensional region divided by the criterion of the theoretical centerline velocity decay for the aspect ratio of 10 was observed to be smaller than that of the transition region. The applicability of the two-dimensional model to the behavior of the rectangular jet with low aspect ratio or the wastewater discharged from a multiport diffuser in the deep water of real ocean may result in significant error in the transition and axisymmetric regions after the two-dimensional region. In the two-dimensional region, the Gaussian constant tended to be conserved, and the spreading rate slightly decreased at the end of the two-dimensional region. The normalized turbulent intensity along the centerline of the jet initially abruptly increased and showed relatively higher intensity for higher Reynolds number.

Research Trends on Hydrocarbon-Based Polymer Electrolyte Membranes for Direct Methanol Fuel Cell Applications (직접 메탄올 연료전지용 탄화수소계 고분자 전해질 막 연구개발 동향)

  • Yu-Gyeong Jeong;Dajeong Lee;Kihyun Kim
    • Membrane Journal
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    • v.33 no.6
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    • pp.325-343
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    • 2023
  • Direct methanol fuel cells (DMFCs) have been attracting attention as energy conversion devices that can directly supply methanol liquid fuel without a fuel reforming process. The commercial polymer electrolyte membranes (PEMs) currently applied to DMFC are perfluorosulfonic acid ionomer-based PEMs, which exhibit high proton conductivity and physicochemical stability during the operation. However, problems such as high methanol permeability and environmental pollutants generated during decomposition require the development of PEMs for DMFCs using novel ionomers. Recently, studies have been reported to develop PEMs using hydrocarbon-based ionomers that exhibit low fuel permeability and high physicochemical stability. This review introduces the following studies on hydrocarbon-based PEMs for DMFC applications: 1) synthesis of grafting copolymers that exhibit distinct hydrophilic/hydrophobic phase-separated structure to improve both proton conductivity and methanol selectivity, 2) introduction of cross-linked structure during PEM fabrication to reduce the methanol permeability and improve dimensional stability, and 3) incorporation of organic/inorganic composites or reinforcing substrates to develop reinforced composite membranes showing improved PEM performances and durability.

A Study on Fish Movement Efficiency in Biopolymer and Aggregate Mixed Fishway (피마자유기반 바이오폴리머와 골재를 혼합한 어도의 어류이동효율 실험연구)

  • Dong-Jin Lee;Min Ho, Jang;Joongu Kang;Hong-Kyu Ahn
    • Ecology and Resilient Infrastructure
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    • v.11 no.1
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    • pp.11-22
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    • 2024
  • A fishway is an artificial waterway or device used to resolve difficulties in the movement of fish in a river. Most existing fishways are made of concrete and emit toxic substances, which has a negative impact on the river environment. Accordingly, there is a need to develop fishway construction technology that is eco-friendly and can increase movement efficiency. The technology presented in this study is an integrated porous structure that combines the aggregate with a biopolymer material extracted from castor oil, a non-toxic material. It is a fishway construction technology using eco-friendly materials that can allow vegetation to grow on the surface. In this study, an eco-friendly fishway mixed with biopolymer and aggregate was built on a real scale and the fish movement efficiency was tested and analyzed. As a result of the experiment, a total of 201 fish of 14 species were released with tags inserted, and the detection rate of released fish was confirmed to be 82.6% on average. A total of 40 fish of 6 species were transported upstream through the fishway, and the average passage rate was confirmed to be 21.7%. As a result of checking the circadian migration pattern, it was found that all fish mainly migrate during the day. It was confirmed that there was no significant functional difference between a fishway using biopolymer and a concrete fishway. It is believed that a fishway using biopolymer can be used as a replacement for a concrete fishway.

Preparationand Characterization of Rutile-anatase Hybrid TiO2 Thin Film by Hydrothermal Synthesis

  • Kwon, Soon Jin;Song, Hoon Sub;Im, Hyo Been;Nam, Jung Eun;Kang, Jin Kyu;Hwang, Taek Sung;Yi, Kwang Bok
    • Clean Technology
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    • v.20 no.3
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    • pp.306-313
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    • 2014
  • Nanoporous $TiO_2$ films are commonly used as working electrodes in dye-sensitized solar cells (DSSCs). So far, there have been attempts to synthesize films with various $TiO_2$ nanostructures to increase the power-conversion efficiency. In this work, vertically aligned rutile $TiO_2$ nanorods were grown on fluorinated tin oxide (FTO) glass by hydrothermal synthesis, followed by deposition of an anatase $TiO_2$ film. This new method of anatase $TiO_2$ growth avoided the use of a seed layer that is usually required in hydrothermal synthesis of $TiO_2$ electrodes. The dense anatase $TiO_2$ layer was designed to behave as the electron-generating layer, while the less dense rutile nanorods acted as electron-transfer pathwaysto the FTO glass. In order to facilitate the electron transfer, the rutile phase nanorods were treated with a $TiCl_4$ solution so that the nanorods were coated with the anatase $TiO_2$ film after heat treatment. Compared to the electrode consisting of only rutile $TiO_2$, the power-conversion efficiency of the rutile-anatase hybrid $TiO_2$ electrode was found to be much higher. The total thickness of the rutile-anatase hybrid $TiO_2$ structures were around $4.5-5.0{\mu}m$, and the highest power efficiency of the cell assembled with the structured $TiO_2$ electrode was around 3.94%.

Analysis of Building Energy Reduction Effect based on the Green Wall Planting Foundation Type Using a Simulation Program (건물일체형 패널형 벽면녹화 식재기반 유형별 건물에너지 성능 분석)

  • Kim, Jeong-Ho;Kwon, Ki-Uk;Yoon, Yong-Han
    • Korean Journal of Environment and Ecology
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    • v.29 no.6
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    • pp.936-946
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    • 2015
  • This study is aimed to analyze the reduction performance of building energy consumption according to planting base types of panel-type green walls which can be applied to existing buildings. The performance was compared to the general performance of green walls that have demonstrated effects of improving the thermal environment and reducing building energy consumption in urban areas. The number of planting base types was 4 in total, and simulations were conducted to analyze the thermal conductivity, thermal transmittance, and overall building energy consumption rate of each planting base type. The highest thermal conductivity by the planting base type was Case C (0.053W/mK), followed by Case B (0.1W/mK) and Case D (0.17W/mK). According to the results of energy simulation, the most significant reduction of cooling peak load per unit area was Case C (1.19%), followed by Case B (1.14%) and Case D (1.01%) when compared to Case A to which green wall was not applied; and the most significant reduction of heating peak load per unit area was estimated to be Case C (2.38%), followed by Case B (1.82%) and case D (1.50%) when compared to Case A. The amount of yearly cooling and heating energy use per unit area showed 3.04~3.22% of reduction rate. The amount of the 1st energy use showed 5,844 kWh/yr of decrease on average for other types when compared to Case A. The amount of yearly $CO_2$ emission showed 996kg of decrease on average when compared to Case A to which the green wall was not applied. According to the results of energy performance evaluation by planting location, the most efficient energy performance was eastward followed by westward, southward and northward. According to the results of energy performance evaluation by planting location by green wall ratio, it was found that as the ratio of green wall increased, the energy performance displayed better results, showing approx. double reduction rate in energy consumption at 100% of green wall ratio than the reduction rate at 20% to 80% of green wall ratio.

The Hydrochemistry of ChusanYongchulso Spring, Cheonbu-ri, Buk-myeon, Northern Ulleung Island (울릉도 북면 천부리 추산 용출소의 수질화학적 특성)

  • Lee, Byeong Dae;Cho, Byong Wook;Choo, Chang Oh
    • The Journal of Engineering Geology
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    • v.28 no.4
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    • pp.565-582
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    • 2018
  • We investigated the hydrochemical properties of ChusanYongchulso Spring located in Buk-myeon, Ulleung Island, focusing on the formation and characteristics of aquifers in and around the Nari caldera. Abundant pumice with high permeability and numerous fractures (including faults and joints) that formed as a result of caldera subsidence are widely distributed in the subsurface, favoring the formation of aquifers. Because of the presence of porous pyroclastic rocks with a high internal surface area, the water type of the springs is characterized by $NaHCO_3$, with upper stream waters and the upper spring being characterized by $NaHCO_3$ and NaCl, respectively. Components with a high coefficient of determination with EC are $HCO_3$, Na, F, Ca, Mg, Cl, $SiO_2$, and $SO_4$. The high concentrations of Na and Cl might be attributable to the main lithologies in the area, given that alkaline volcanic rocks are distributed extensively across Ulleung Island. Eh and pH, which are considered to be important indicators of water-rock interaction, are unrelated to most components. According to the results obtained from factor analysis, the variance explained by factor 1 is 54% and by factor 2 is 25.8%. Components with a high loading on factor 1 are F, Na, EC, Cl, $HCO_3$, $SO_4$, $SiO_2$, Ca, $NO_3$, and Mg, whereas components with a high loading on factor 2 are Mg and Ca, along with K, $NO_3$, and DO with negative loadings. It is suggested that the high concentrations of Na, Cl, F, and $SO_4$ are closely related to the presence of fine-grained alkaline pyroclastic rocks with high permeability and porosity, which favorintensewater-rock interaction. However, a wide-ranging investigation that encompasses methods such as geophysical prospecting and geochemical analysis (including isotope, trace-element, and tracer techniques) will be necessary to gain a better understanding of the groundwater chemistry, aquifer distribution, and water cycling of Ulleung Island.

Performance of a Molten Carbonate Fuel Cell With Direct Internal Reforming of Methanol (메탄올 내부개질형 용융탄산염 연료전지의 성능)

  • Ha, Myeong Ju;Yoon, Sung Pil;Han, Jonghee;Lim, Tae-Hoon;Kim, Woo Sik;Nam, Suk Woo
    • Clean Technology
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    • v.26 no.4
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    • pp.329-335
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    • 2020
  • Methanol synthesized from renewable hydrogen and captured CO2 has recently attracted great interest as a sustainable energy carrier for large-scale renewable energy storage. In this study, molten carbonate fuel cell's performance was investigated with the direct conversion of methanol into syngas inside the anode chamber of the cell. The internal reforming of methanol may significantly improve system efficiency since the heat generated from the electrochemical reaction can be used directly for the endothermic reforming reaction. The porous Ni-10 wt%Cr anode was sufficient for the methanol steam reforming reaction under the fuel cell operating condition. The direct supply of methanol into the anode chamber resulted in somewhat lower cell performance, especially at high current density. Recycling of the product gas into the anode gas inlet significantly improved the cell performance. The analysis based on material balance revealed that, with increasing current density and gas recycling ratio, the methanol steam reforming reaction rate likewise increased. A methanol conversion more significant than 90% was achieved with gas recycling. The results showed the feasibility of electricity and syngas co-production using the molten carbonate fuel cell. Further research is needed to optimize the fuel cell operating conditions for simultaneous production of electricity and syngas, considering both material and energy balances in the fuel cell.