• Title/Summary/Keyword: 내부전극

Search Result 394, Processing Time 0.028 seconds

Influence of Textural Structure by Heat-treatment on Electrochemical Properties of Pitch-based Activated Carbon Fiber (열처리 온도에 의한 피치계 활성탄소섬유의 기공구조 변화가 전기화학적 특성에 미치는 영향)

  • Kim, Kyung Hoon;Park, Mi-Seon;Jung, Min-Jung;Lee, Young-Seak
    • Applied Chemistry for Engineering
    • /
    • v.26 no.5
    • /
    • pp.598-603
    • /
    • 2015
  • In this study, electrochemical properties of pitch-based activated carbon fibers (ACFs) were investigated by different heat-treatment temperature of the pitch-based ACFs in order to improve the specific capacitance of electric double-layer capacitor (EDLC). The ACFs were prepared by different heat-treatment temperatures of 1050 and $1450^{\circ}C$, after activation with 4 M KOH at $800^{\circ}C$ using stabilized pitch fiber. The specific surface area of prepared ACFs increased from $828m^2/g$ to $987m^2/g$, also the micropore and mesopore volumes of prepared ACFs were increased. These results because pore was produced by desorbing oxygen and hydrogen elements within the ACFs, and pore size was increased by contraction ACFs by heat-treatment process. Because of the porous properties, the specific capacitance was increased from 73 F/g to 119 F/g using cyclic voltammetry with 1 M $H_2SO_4$ at scan rates of 5 mV/s.

Development of Multiwire Proportional Counter for Measurement of Environmental-level Alpha Particles (환경준위 알파입자측정을 위한 다중선 비례계수기 개발(I))

  • Oh, Pil Jae;Park, Tae Soon;Lee, Min Kie;Kim, Kyung Hwa
    • Analytical Science and Technology
    • /
    • v.9 no.3
    • /
    • pp.262-269
    • /
    • 1996
  • The muiltiwire proportional counter for the measurement of low-level and environmental $\alpha$ particles emitting nuclides was developed. External dimension of the devloped multiwire proportional counter is $350{\times}290{\times}30mm$ and the sensitivity area is $250{\times}200mm$. The wall material of the detector was selected the stainless steel to prevent the deformation by external impact and to obtain minimum background. The anode and cathode wires were used the stainless steel material of diameter $50{\mu}m$. The spacing of each wires are 10.0mm, 5.0mm and the numbers of total wire are 21, 42 lines, respectively. The multiwire proportional counter was designed that the measurement source is placed within the detector to prevent the wall absorption effect and the efficiency variation by various source heights. The characteristics of the developed detector have been investigated to obtain the plateau, operating voltage, background, counting efficiency, position sensitivity and energy resolution etc. For the $^{241}Am$ nuclide, the calculated LLD(Lower Limit of Detection) is 5.0mBq/L which is lower than 40mBq/L of recommended LLD value by ISO(International Organization for Standardization).

  • PDF

Fuel Supply of Direct Carbon Fuel Cells via Thermal Decomposition of Hydrocarbons Inside a Porous Ni Anode (다공성 니켈 연료 전극 내부에서 탄화수소의 열분해를 통한 직접 탄소 연료 전지의 연료공급)

  • Yi, Hakgyu;Li, Chengguo;Jalalabadi, Tahereh;Lee, Donggeun
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.39 no.6
    • /
    • pp.527-534
    • /
    • 2015
  • This study offers a novel method for improving the physical contact between the anode and fuel in a direct carbon fuel cell (DCFC): a direct generation of carbon in a porous Ni anode through the thermal decomposition of gaseous hydrocarbons. Three kinds of alkane hydrocarbons with different carbon numbers (CH4, C2H6, and C3H8) are tested. From electron microscope observations of the carbon particles generated from each hydrocarbon, we confirm that more carbon spheres (CS), carbon nanotubes (CNT), and carbon nanofibers (CNF) were identified with increasing carbon number. Raman scattering results revealed that the carbon samples became less crystalline and more flexible with increasing carbon number. DCFC performance was measured at $700^{\circ}C$ with the anode fueled by the same mass of each carbon sample. One-dimensional carbon fuels of CNT and CNF more actively produced and had power densities 148 and 210 times higher than that of the CS, respectively. This difference is partly attributed to the findings that the less-crystalline CNT and CNF have much lower charge transfer resistances than the CS.

Experimental Analysis of a Supersonic Plasma Wind Tunnel Using a Segmented Arc Heater with the Power Level of 0.4 MW (0.4 MW 급 분절형 아크 히터를 이용한 초음속 플라즈마 풍동 특성 실험)

  • Kim, Min-Ho;Lee, Mi-Yeon;Kim, Jeong-Soo;Choi, Chea-Hong;Seo, Jun-Ho;Moon, Se-Yeon;Hong, Bong-Guen
    • Journal of the Korean Society for Aeronautical & Space Sciences
    • /
    • v.41 no.9
    • /
    • pp.700-707
    • /
    • 2013
  • Experimental analyses on a supersonic plasma wind tunnel of CBNU (Chonbuk National University) were carried out. In these experiments, a segmented arc heater was employed as a plasma source and operated at the gas flow rates of 16.3 g/s and the total currents of 300 A. The input power reached ~350 kW with the torch efficiency of 51.4 %, which is defined as the ratio of total exit enthalpy to the input power. The pressure of plasma gas in the arc heater was measured up to 4 bar while it was down to ~45 mbar in a vacuum chamber through a Laval nozzle. During this conversion process, the generated supersonic plasma was expected to have a total enthalpy of ~11 MJ/kg from the measured input power and torch efficiency. In addition to the measurement of total enthalpy, a cone type probe was inserted into the supersonic plasma flow in order to estimate the angle between shock layer and surface of the probe. From these measurements, the temperature and the Mach number of the supersonic plasma were predicted as ~2,950 K and ~3.7, respectively.

Modeling of the dynamic behavior of a 12-V automotive lead-acid battery (12V 차량용 납축전지의 동적 거동 모델링)

  • Kim, Sung Tae;Lee, Jeong Bin;Kim, Ui Seong;Shin, Chee Burm
    • Journal of Energy Engineering
    • /
    • v.22 no.2
    • /
    • pp.175-183
    • /
    • 2013
  • For the optimal design of the vehicle electric system, it is important to have a reliable modeling tool to predict the dynamic behavior of the automotive battery. In this work, a one-dimensional modeling was carried-out to predict the dynamic behaviors of a 12-V automotive lead-acid battery. The model accounted for electrochemical kinetics and ionic mass transfer in a battery cell. In order to validate the modeling, modeling results were compared with the experiment data of the dynamic behaviors of the lead-acid batteries of two different capacities that were mounted on the automobiles manufactured by Hyundai Motor Company. The discharge behaviors were measured with various discharge rates of C/3, C/5, C/10, C/20 and combination. And dynamic behaviors of charge and discharge were measured. The voltage curves from the experiment and simulation were in good agreement. Based on the modeling, the distributions of the electrical potentials of the solid and solution phases, and the current density within the electrodes could be predicted as a function of charge and discharge time.

Effect of Phorbol ester on $K^+$channel in an G292 osteoblast-like cell (G292 세포에서 $K^+$통로에 대한 phorbol ester의 효과)

  • Kim, Mi-Kyung;Park, Su-Byung
    • The korean journal of orthodontics
    • /
    • v.32 no.3 s.92
    • /
    • pp.227-234
    • /
    • 2002
  • In order to investigate the action mechanism of protein kinase C on $K^+$ channel in osteoblastic cell, effects of phorbol 12, 13-dibutyrate on human osteoblast-like cells (G292) were studied by patch clamp technique with cell-attacked configuration. 111 this experiment, 45pS ion channel was dominant in G292 cell line according to their approximate conductances in symmetrical 140mM KCl saline at holding potential of 60mV. In torrent-voltage relationship, reversal potential was 5.5mV at the condition of potassium enriched saline in the pipette and -27 mV at the condition of standard extracellular saline In the pipette. Phorbol 12, 13-dibutyrate 10nM increased the open probability of 45pS channel and staurosporine, an inhibitor of protein kinase C, suppressed this effect. Phorbol 12,13-dibutyrate moved the reversal potential of 45pS channel to more negative potential and increased the single channel current at the same membrame potential. In order to check the activation of protein kinase C in G292 cell by phorbol 12,13-dibutyrate, western blot of protein kinase C was performed. Phorbol 12,13-dibutyrate $0.1{\mu}M$ translocated protein kinase C from cellular compartment to membrane compartment of the cell. These findings suggest that phorbol 12,13-dibutyrate, one of phorbol esters, activate 45pS channel In G292 cell and affect cell membrane potential, that regulate cellular function.

Technology Development of Entry-Level MiC Smart Photovoltaic System based on SOC (SoC 기반 보급형 MiC 스마트 태양광발전시스템 기술개발)

  • Yoon, Yongho
    • The Journal of the Institute of Internet, Broadcasting and Communication
    • /
    • v.20 no.3
    • /
    • pp.129-134
    • /
    • 2020
  • Moisture infiltration inside the solar cell module, filling of EVA sheet, melting of the frame seal, and deterioration of power generation performance in the module one year after installation are occurring. Whitening phenomenon, electrode corrosion phenomenon, and dielectric breakdown phenomenon are appearing in solar cell module installed in Korea before 5-7 years, leading to deterioration of power generation performance, and big problems for long-term reliability and long life technology are emerging. Therefore, in order to solve these problems, the development of a micro inverter (MiCrco Inverter Converter, MiC) including the function of securing the durability of the solar cell module and monitoring the aging progress and the solar cell based on the monitoring data from the MiC smart monitoring programs have been proposed to determine the aging of modules. In addition, in order to become a highly efficient solar smart monitoring system through systematic operation management through IT convergence with MiC that has enhanced monitoring function of solar cell module, SoC(System On Chip) in micro inverter is the environment for solar cell module. There is a demand for functions that can detect information in a complex manner and perform communication and control when necessary. Based on these requirements, this paper aims to develop SoC-based low-cost MiC smart photovoltaic system technology.

Threshold Voltage Variation of ZnS:Mn/ZnS:Tb Thin- film Electroluminescent(TFEL) Devices (ZnS:Mn/ZnS:Tb 박막 전계발광소자의 문턱전압 변화)

  • 이순석;윤선진;임성규
    • Journal of the Korean Institute of Telematics and Electronics D
    • /
    • v.35D no.6
    • /
    • pp.21-27
    • /
    • 1998
  • Electrical and optical characteristics of ZnS:Mn/ZnS:Tb multilayer TFEL devices were investigated for multi-color electroluminescent display applications. Emission spectra of M $n^{2+}$ and T $b^{3+}$ ions were observed from ZnS:Mn/ZnS:Tb multi-layer TFEL devices, and were very broad from 540 nm to 640 nm. Saturation luminance measured at 155 V was 1025 Cd/$m^2$. C-V, $Q_{t}$ - $V_{p}$ curves showed that the phosphor capacitance ( $C_{p}$ ) and the insulator capacitance ( $C_{i}$ ) were 13.5nF/$\textrm{cm}^2$ and 60 nF/$\textrm{cm}^2$, respectively. Threshold voltage( $V_{thl}$) was shown to decrease from 126 V to 93 V due to the increase of the applied voltage from 155 V to 185 V, which was attributed to the increase of the polarization charge. The equation for the calculation of the threshold voltage as a function of the applied voltage was proposed for the first time. The calculated threshold voltage agreed well with the data obtained from the measurement.t.t.t.

  • PDF

Physical and Electrochemical Properties of Gallium Oxide (β-Ga2O3) Nanorods as an Anode Active Material for Lithium Ion Batteries (리튬이온전지용 산화갈륨 (β-Ga2O3) 나노로드 (Nanorods) 음극 활물질의 물리적.전기화학적 특성)

  • Choi, Young-Jin;Ryu, Ho-Suk; Cho, Gyu-Bon;Cho, Kwon-Koo;Ryu, Kwang-Sun;Kim, Ki-Won
    • Journal of the Korean Electrochemical Society
    • /
    • v.12 no.2
    • /
    • pp.189-195
    • /
    • 2009
  • $\beta-Ga_{2}O_{3}$ nanorods were synthesized by chemical vapor deposition method using nickel-oxide nanoparticle as a catalyst and gallium metal powder as a source material. The average diameter of nanorods was around 160 nm and the average length was $4{\mu}m$. Also, we confirmed that the synthesis of nanorods follows the vapor-solid growth mechanism. From the results of X-ray diffraction and HR-TEM observation, it can be found that the synthesized nanorods consisted of a typical core-shell structure with single-crystalline $\beta-Ga_{2}O_{3}$ core with a monoclinic crystal structure and an outer amorphous gallium oxide layer. Li/$\beta-Ga_{2}O_{3}$ nanorods cell delivered capacity of 867 mAh/g-$\beta-Ga_{2}O_{3}$ at first discharge. Although the Li/$\beta-Ga_{2}O_{3}$ nanorods cell showed low coulombic efficiency at first cycle, the cell exhibited stable cycle life property after fifth cycle.

A Study on H-reflex Change and MVIC Change Depending upon Shouting Type (기합소리 유형에 따른 H-reflex변화와 MVIC변화 분석)

  • Jeong, Ik-Su;Oh, Cheong-Hwan;Lee, Dong-Jin;Lee, Gun-Hee;Lee, Jin
    • Korean Journal of Applied Biomechanics
    • /
    • v.19 no.4
    • /
    • pp.655-661
    • /
    • 2009
  • This study investigated the effects of different types of shouting actions on the strength of the human body. Both H-reflex and MVIC measures of the rectus femoris muscle were used to investigate effects on impact force and motor performance, in order to find optimum shouting methods. The H-reflex of the soleus muscle gave an electric stimulus to the curve of the knee that contains the tibial nerves. Surface electromyelography was used to collect muscle activity the amplitude increased 28% at action with shouting and 29% at the one immediately after short-time shouting than the one without shouting was. To assess the myoelectric activity of the rectus femoris, a surface electrode was attached to the right side of the lower extremity and to increase 10% and 1% depending upon shouting type. The findings were as follows. Shouting affected not only motor efficiency (H-reflex), but also the amplitude of MVIC, with a positive effect on increased muscle strength. Further comprehensive studies are needed to investigate the many variables of increased muscle strength for general purposes, for instance, shouting and breathing, brain waves, and so on.