• Title/Summary/Keyword: 난연화

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Flame Retardancy and Physical Properties of Ethylene Vinyl Acetate/Aluminum Trihydroxide Composites (에틸렌 비닐아세테이트/수산화알루미늄 복합재료의 난연 및 물리적 특성)

  • Lee, Minho;Yu, Dayeong;Kim, Yeongho;Lee, Sunghee;Kim, Jeong Ho;Lee, Young Chul
    • Polymer(Korea)
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    • v.39 no.3
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    • pp.433-440
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    • 2015
  • Aluminum trihydroxide (ATH) has been commonly employed as a flame retardant for ethylene vinyl acetate (EVA) copolymers. In the present work, ATH was obtained from a recycling process of multi-layer packaging film wastes. EVA/ATH composite samples were prepared using a two roll-mill and flame retardancy of EVA/ATH composites were examined using limiting oxygen index (LOI) and flame retardancy test (UL94). We observed excellent flame retardancy in case of adding 150 phr or more of recycled ATH to EVA. Particle size and specific surface area play crucial roles in LOI value and UL-94 classification of the EVA/ATH composites. Smaller particle size and higher specific surface area of ATH was found out to improve the flame retardancy. Regarding tensile properties, crosslinked EVA/ATH compounds which is practically used for electric cables had similar to or even better tensile property values than the ones without ATH.

Thermal and Mechanical Properties of Flame Retardant ABS Nanocomposites Containing Organo-Modified Layered Double Hydoxide (유기변성 LDH를 사용한 난연 ABS 나노복합재료의 열적 및 기계적 물성)

  • Kim, Seog-Jun
    • Elastomers and Composites
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    • v.43 no.4
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    • pp.241-252
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    • 2008
  • ZnAl-LDH(layered double hydroxide) modified with oleic acid(SO-ZnAl LDH) was synthesized and added to the flame retardant ABS compounds containing brominated epoxy resin(BER) and antimony trioxide(${Sb_2}{O_3}$). Flame retardant ABS compounds were manufactured by using a twin-screw co-rotating extruder and subsequently injection molded into several specimen for flame retardancy and mechanical properties. The XRD patterns of ABS nanocomposites showed no peaks. The thermal stability of ABS nanocomposites was enhanced by the addition of SO-ZnAl LDH as shown in TGA results. However, these nanocomposites showed no rating in the UL 94 vertical test at 1.6 mm thickness. Only ABS nanocomposites with additional BER more than 1.5 wt% showed UL 94 V0 rating. Notched Izod impact strength, tensile modulus, and elongation at break of flame retardant ABS nanocomposites increased with the proportion of So-ZnAl LDH whereas their melt index decreased.

Performance of Structural Glulam Manufactured with Fire Retardants Treated Lumbers (난연처리 제재목으로 제조한 구조용 집성재의 강도 성능평가)

  • Son, Dong-Won;Eom, Chang-Deuk;Park, Jun-Cheol;Park, Joo-Saeng
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.4
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    • pp.477-482
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    • 2014
  • Consumer demand for wood use has diversified recently. Laminated wood has been used for large-scale buildings and public buildings, not only the durability but also the demand for fire safety has increased. In this study. it was performed for the purpose of developing a standard and flame-retardant treatment technology suitable for structural laminated wood, which was prepared in domestic larch. In this study, by using the domestic larch and Korean pine lumber which treated with flame-retardants, to manufacture the glulam, the effect of strength properties were investigated. In the case of fire retardant treated larch Glulam was satisfactory conditions of the strength of structural laminated wood, but had to be improved, such as the occurrence of delamination and decrease strength by the flame retardant treatment. Development of application-type flame retardant treatment technology or injection-type flame retardant treatment after production of laminated lumber were required.

Study on Mechanical Properties and Flame Retardancy of Polypropylene Based Self-reinforced Composites (폴리프로필렌 기반 자기강화 복합재료의 기계적물성 및 난연성 연구)

  • Lee, Dong-Woo;Park, Seung-Bhin;Song, Jung-Il
    • Composites Research
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    • v.30 no.3
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    • pp.223-228
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    • 2017
  • The article explains about development of flame retardant self-reinforced composites (FR-SRC) through compression molding technique by utilizing Polypropylene (PP), Ammonium polyphosphate (APP) and chitosan. The effect of APP and chitosan on mechanical, thermal and flame retardant properties in FR-SRC were studied. The mechanical strength of FR-SRC is enhanced than Pure SRC. However, the strength is decreased significantly with increasing the concentration of both flame retardant fillers. But comparison, chitosan filled FR-SRC is stronger than APP filled FR-SRC. In case of flame retardancy, APP is more effective than chitosan. These results can be applicable to provide light weight and recyclable flame retardant self-reinforced composites for automobile and packaging industries, etc.

Flame Retardancy and Electrical/Mechanical Properties of LDPF/EVA Blend (LDPE/EVA Blend의 난연성 및 전기/기계적 특성)

  • Ryu, Boo-Hyung;Lee, Chung;Kim, Ki-Yup
    • Journal of the Korean Society of Safety
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    • v.23 no.4
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    • pp.99-104
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    • 2008
  • In this research, magnesium hydroxide as a flame retardant agents and zinc borate as a synergist were mixed with LDPF/EVA blended samples, in order to improve their flame retardancy. We attempted to select the best mixing ratio of the LDPF/EVA blend and the optimum amount of magnesium hydroxide and zinc borate by the comparison and analysis of the flame retardancy, the electrical properties such as the volume resistivity and dielectric loss tangent, and the mechanical properties such as the tensile strength and elongation at break. Particularly, specimen which is the 6phr of zinc borate and 10phr of magnesium hydroxide 70/30phr adding to the LDPF/EVA blended samples has been most excellent in flame retardancy and electrical/mechanical properties.

Development of Eco-friendly Basalt Fiber-reinforced Furan-based Composite Material with Improved Fire and Flame Retardants for Shipbuilding and Offshore Pipe Insulation Cover (조선해양 파이프 단열재 커버 적용을 위한 내화/난연 성능을 갖는 친환경 바잘트섬유 강화 퓨란계 복합재료 개발 연구)

  • Kwon, Dong-Jun;Seo, Hyoung-Seock
    • Composites Research
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    • v.34 no.1
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    • pp.57-62
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    • 2021
  • As interest in the eco-friendly ships and lightweight equipment is increasing in the shipbuilding and marine industry, composite materials are applied to equipment such as pipes. In this study, a basalt fiber reinforced furan composite (BFC), an eco-friendly material, was manufactured to apply the pipe insulation cover that requires environment-friendly and heat/flame retardant performance. An optimization study of post-curing conditions of BFC was conducted, and experiments and analysis were performed on mechanical strength, heat/flame retardant properties, and affinity properties. Finally, as a result of the study BFC material is proved to be a good candidate to apply pipe insulation cover.

Comparison on the fire performance of additional insulation materials for improving the fire retardancy in engine-room of FRP vessel (FRP 선박 기관실 난연성 향상을 위한 추가 방열재의 화재성능비교)

  • Choi, Jung-Min;Um, Han-Chan;Jin, Young-Hwa
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.9
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    • pp.1150-1155
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    • 2014
  • To prevent the flame spread in FRP vessel in fire, the engine-room of the vessel should be constructed additionally with laminated fire-retardant resin over 3 times or equivalent insulation materials to former according to the relevant standard for FRP vessel structure. It is surveyed that insulation materials called 'Gel coat' are widely used in FRP fishing vessel, however, test method and its criteria for Gel coat are not clearly establish and have not been evaluated yet, while test method and criteria for fire-retardant resin and fire-retardant polyurethane composite are described in test standard for type-approval. In this study, 3 fire-retardant resins, 4 gel coats, 1 flame-retardant paint and 1 polyurethane composite were selected based on the survey and were evaluated according to both IMO FTP Code part 5 and flame-retardant test. When comparing based on CFE values from flame-spread test, average value for 4 gel coats were lower than that of 3 fire-retardant resins. As for flame-retardant test, there were no significant differences between fire-retardant resin and gel coat, based on charred area.