• Title/Summary/Keyword: 나노 제어

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Fabrication of Ceramic Line Pattern by UV-Nanoimprint Lithography of Inorganic Polymers (무기고분자의 나노임프린트법에 의한 세라믹 선형 패턴의 제조)

  • Park Jun-Hong;Pham Tuan-Anh;Lee Jae-Jong;Kim Dong-Pyo
    • Polymer(Korea)
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    • v.30 no.5
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    • pp.407-411
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    • 2006
  • The SiC-based ceramic nanopatterns were prepared by placing polydimethylsiloxane (PDMS) mold from DVD master on the spincoated polyvinylsilaeane (PVS) or allylhydridopolycaybosilane (AHPCS) as ceramic precursors to fabricate line pattern via UV-nanoimprint lithography (UV-NIL), and subsequent pyrolysis at $800^{\circ}C$ in nitrogen atmosphere. As the dimensional change of polymeric and ceramic patterns was comparatively investigated by AFM and SEM, the shrinkage in height was 38.5% for PVS derived pattern and 24.1% for AHPCS derived pattern while the shrinkage in width was 18.8% for PVS and 16.7% for AHPCS. It indicates that higher ceramic yield of the ceramic precursor resulted in less shrinkage, and the strong adhesion between the substrate and the pattern caused anisotropic shrinkage. This preliminary work suggests that NIL is a promissing route for fabricating ceramic MEMS devices, with the development on the shrinkage control.

외부충전없이 반영구적으로 사용이 가능한 $10mWh/cm^2$급 동위원소기반 전고상(全固相) 하이브리드 전지 원천기술 개발 사업소개

  • Lee, Myeong-Bok;No, Jin-Hui;Yun, Yeong-Mok;Hwang, Cheol-Gyun;Yeo, Seok-Gi;Choe, Gyeong-Sik;Choe, Byeong-Geon;Son, Gwang-Jae;Lee, Jae-Myeong;Yun, Yeong-Su;Lee, Seong-Man;Sin, Dong-Uk;Park, Yong-Jun;Kim, Jong-Dae;Kim, Han-Jun;Kim, U-Jeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.232-233
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    • 2013
  • 본 발표에서 2012년 나노융합산업원천기술개발사업 꼭지로 연구개발을 수행하고 있는 "외부 충전없이 반영구적으로 사용이 가능한 10 mWh/cm2급 동위원소기반 전고상(全固相) 하이브리드 전지 원천기술 개발" 사업의 핵심내용을 간략히 소개하고자 한다. 본 과제의 핵심내용은 국내 유일의 원자로인 하나로의 중성자 빔라인을 이용하여 ${\beta}$-선을 방출하는 동위원소파우더를 생산하고, 방출되는 ${\beta}$-선을 효율적으로 흡수할 수 있는 PN-접합 전지구조에 노출시켜 2차적인 e-h 쌍을 생성시키고, 분리시키고 전극으로 포집하여 전력을 생산하는 한국형 동위원소전지 개발에 있다. 더하여 실시간으로 생성되는 미세한 출력전력을 증폭시켜 저장할 수 있는 고효율 전고상 이차전지와 전력제어회로를 포함하는 한국형 하이브리드전지관련 원천기술 개발관련 세부 사업내용을 소개함으로 관련분야 연구에 대한 국내관심을 환기시켜 관련기술개발을 촉진하고자 한다.

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Developing an Instrument Ensuring Reliable Contact Conditions for Contact-Type Area-varying Capacitive Displacement Sensors (접촉식 면적변화형 정전용량 변위센서의 접촉 안정성을 위한 기구의 개발)

  • Kim, Sung-Joo;Lee, Won-Goo;Moon, Won-Kyu
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.11
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    • pp.1147-1156
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    • 2011
  • A contact-type area-varying capacitive displacement sensor, or CLECDiS, can measure displacements over millimeter ranges with nanometer resolution. However, a small changes in the contact condition due to the surface profile or friction, which are inherent characteristics of contact-type sensors, lead to significant distortion of the output signal. Therefore, ensuring reliable contact conditions during CLECDiS measurements is the most important area to be improved in their actual use. Herein, in order to design an instrument for ensuring reliable contact conditions, the contact condition is analyzed by characterizing the signal distortion, observing the pressure distribution between the contacting surfaces, and measuring the motional errors of the sensor using a laser Doppler vibrometer (LDV). The manufactured instrument enables a CLECDiS to be used in an ultraprecise positioning system with improved reliability.

Perpendicular Spin-transfer Torque in Asymmetric Magnetic Tunnel Junctions: Material Parameter Dependence (비대칭 자기터널접합에서의 수직 스핀 전달 토크: 물질 변수에 대한 의존성)

  • Han, Jae-Ho;Lee, Hyun-Woo
    • Journal of the Korean Magnetics Society
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    • v.21 no.2
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    • pp.52-55
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    • 2011
  • Spin-transfer torque is a useful tool to control the magnetic state in nanostructures. In magnetic tunnel junctions, the spin-transfer torque has two components, the in-plane spin torque and the perpendicular spin torque. While properties of the in-plane spin-transfer torque are relatively well understood, properties of the perpendicular spin-transfer torque still remain controversial. A recent experiment demonstrated that in asymmetric magnetic tunnel junctions, the bias voltage dependence of the perpendicular spin-transfer torque contains both linear and quadratic terms in the bias. However it still remains unexplored how the bias voltage dependence changes as a function of material parameters. In this paper, we systematically investigate the perpendicular spin-transfer torque in asymmetric magnetic tunnel junction by varying spin splitting energy, work function difference, and Fermi energy of the ferromagnetic metal leads.

Photoelectrochemical Properties of TiO2 Nanotubes by Well-Controlled Anodization Process (양극산화 제어에 의한 TiO2 나노튜브의 광전기화학 특성)

  • Jeong, Dasol;Kim, Donghyun;Jung, Hyunsung
    • Journal of the Korean institute of surface engineering
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    • v.52 no.6
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    • pp.298-305
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    • 2019
  • We investigated a correlation between morphology and photoelectrochemical properties of TiO2 nanotubes fabricated by well-controlled anodization processes. Anodization in an ethylene-glycol-based electrolyte solution accelerated the rapid grow rate of TiO2 nanotubes, but also cause problems such as delamination at the interface between TiO2 nanotubes and a Ti substrate, and debris on the top of the nanotube. The applied voltages for the anodization of TiO2 were adjusted to avoid the interface delamination. The heat treatment and the anodizing time were also controlled to enhance the crystallinity of the as-prepared TiO2 nanotubes and to increase the surface area with the varied length of the anodized TiO2 nanotubes. Additionally, a 2-step anodization process was utilized to remove the debris on the tube top. The photoelectrochemical properties of TiO2 nanotubes prepared with the carefully tailored conditions were investigated. By removing the debris on TiO2 nanotubes, applied bias photon-to-current efficiency (ABPE) of TiO2 nanotubes increased up to 0.33%.

Control of Microstructure on TiO2 Nanofibers for Photocatalytic Application (광촉매 응용을 위한 TiO2 나노 섬유의 미세구조 제어)

  • Lee, Chang-Gyu;Kim, Wan-Tae;Na, Kyeong-Han;Park, Dong-Cheol;Yang, Wan-Hee;Choi, Won-Youl
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.6
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    • pp.417-421
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    • 2018
  • $TiO_2$ has excellent photocatalytic properties and several studies have reported the increase in its specific surface area. The structure of $TiO_2$ nanofibers indicates promising improved photocatalytic properties and these nanofibers can thus potentially be applied in air pollution sensors and pollutant removal filters. In this study, a $TiO_2$ nanofiber was fabricated by the electrospinning method. The fabrication processing factors such as the applied voltage, the distance between nozzle and collector, and the inflow rate of solution were controlled. The precursor was titanium (IV) isopropoxide and as-spun $TiO_2$ nanofibers were heated at $450^{\circ}C$ for 2 h to obtain an anatase crystalline structure. The microstructure was analyzed using field emission scanning electron microscope (FE-SEM) and X-ray diffraction analysis (XRD). The anatase phase was observed in the $TiO_2$ nanofibers after heat treatment. The diameter of $TiO_2$ nanofibers increased with the flow rate, but decreased with decreasing applied voltage and nozzle to collector distance. The diameter of $TiO_2$ nanofibers was controlled in the range of 364 nm to 660 nm. These nanofibers are expected to be very useful in photocatalytic applications.

Numerical analysis on thermal-fluidic characteristics of the magnetic fluid in a cavity using GSMAC (GSMAC법을 이용한 밀폐된 정방형관내 자성유체의 열-유동 특성에 관한 해석적 연구)

  • Seo, Jae-Hyeong;Lee, Moo-Yeon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.3
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    • pp.997-1002
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    • 2013
  • The article is aiming to investigate the thermal-fluidic characteristics of magnetic fluid in a cavity using GSMAC (generalized-simplified marker and cell method). The transport equations of the magnetic fluid are including the continuity equation, momentum equation and energy equation for natural convection and Maxwell equation and magnetization equation of magnetite nano-sized particles motion. In addition, the heat transfer characteristics such as temperatures and Nusselt numbers and flow characteristics such as streamlines and isotherms of the magnetic fluid were analyzed with the intensity and direction of the magnetic fields. As a result, the thermal-fluidic characteristics of the magnetic fluid in a cavity were could be controlled by the intensity and direction of the magnetic fields.

A control dispersion of $TiO_2$ nano powder for electronic paper of electrophoresis (전기영동형 전자종이를 위한 $TiO_2$ 나노분말의 분산 제어)

  • Kim, Jung-Hee;Oh, Hyo-Jin;Lee, Nam-Hee;Hwang, Jong-Sun;Kim, Sun-Jae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.324-327
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    • 2005
  • An electrophoretic display using $TiO_2$ particles is the most promising candidate because it offers various advantages such as ink-on-paper appearance, good contrast ratio, wide viewing angle, image stability in the off-state and extremely low power consumption. The core technology of electrophoretic display is the dispersion controlling of $TiO_2$ nano particles in nonaqueous solution. To prepare an ink for electronic paper using electrophoretic properties of $TiO_2$ nano particles, cyclohexane with low dielectric constant and transparency, polyethylene for producing polymer coating layer which reduces apparent gravity of $TiO_2$, and $TiO_2$ powders were mixed together by planetary-mill. The zeta-potential value of $TiO_2$ particles in cyclohexane was measured about -40mV, but was measured over -110mV by dispersant attached to polyethylene-coated $TiO_2$ surface. Prepared electronic ink was filled in cross patterned micro-wall with $200{\mu}m$ in width and $40{\mu}m$ in height on ITO glass designed by photolithography. The response time of electronic paper evaluated by mobility of $TiO_2$ particle between micro-walls was measured 0.067sec, but the drift velocity from reflectance wave form during reverse from of electronic ink was measured 0.07cm/sec.

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Thickness Measurement of Ni Thin Film Using Dispersion Characteristics of a Surface Acoustic Wave (표면파의 분산 특성을 이용한 Ni 박막의 두께 측정)

  • Park, Tae-Sung;Kwak, Dong-Ryul;Park, Ik-Keun;Kim, Miso;Lee, Seung-Seok
    • Journal of the Korean Society for Nondestructive Testing
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    • v.34 no.2
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    • pp.171-175
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    • 2014
  • In this study, we suggest a method to measure the thickness of thin films nondestructively using the dispersion characteristics of a surface acoustic wave propagating along the thin film surface. To measure the thickness of thin films, we deposited thin films with different thicknesses on a Si (100) wafer substrate by controlling the deposit time using the E-beam evaporation method. The thickness of the thin films was measured using a scanning electron microscope. Subsequently, the surface wave velocity of the thin films with different thicknesses was measured using the V(z) curve method of scanning acoustic microscopy. The correlation between the measured thickness and surface acoustic wave velocity was verified. The wave velocity of the film decreased as the film thickness increased. Therefore, thin film thickness can be determined by measuring the dispersion characteristics of the surface acoustic wave velocity.

Mesoporous Control Effect of Porous Carbon Nanofibers for Electrical Double-Layer Capacitors (전기 이중층 커패시터를 위한 다공성 탄소나노섬유의 메조 기공 제어 효과)

  • Jo, Hyun-Gi;Shin, Dong-Yo;Ahn, Hyo-Jin
    • Korean Journal of Materials Research
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    • v.29 no.3
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    • pp.167-174
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    • 2019
  • To improve the performance of carbon nanofibers as electrode material in electrical double-layer capacitors (EDLCs), we prepare three types of samples with different pore control by electrospinning. The speciments display different surface structures, melting behavior, and electrochemical performance according to the process. Carbon nanofibers with two complex treatment processes show improved performance over the other samples. The mesoporous carbon nanofibers (sample C), which have the optimal conditions, have a high sepecific surface area of $696m^2g^{-1}$, a high average pore diameter of 6.28 nm, and a high mesopore volume ratio of 87.1%. In addition, the electrochemical properties have a high specific capacitance of $110.1F\;g^{-1}$ at a current density of $0.1A\;g^{-1}$ and an excellent cycling stability of 84.8% after 3,000 cycles at a current density of $0.1A\;g^{-1}$. Thus, we explain the improved electrochemical performance by the higher reaction area due to an increased surface area and a faster diffusion path due to the increased volume fraction of the mesopores. Consequently, the mesoporous carbon nanofibers are demonstrated to be a very promising material for use as electrode materials of high-performance EDLCs.