• Title/Summary/Keyword: 나노 실리카 입자

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Analysis of Effect of Surface Modified Silica Nanofluid Injection on Carbonate Rock (탄산염암 내 표면개질된 실리카 나노유체 주입 효과 분석)

  • Jang, Hochang
    • Journal of the Korean Institute of Gas
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    • v.26 no.2
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    • pp.1-8
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    • 2022
  • The purpose of this study is to prepare GPTMS((3-Glycidoxypropyl) trimethoxysilane)-SiO2 nanofluid and analyze the effect of nanofluid injection on carbonate reservoirs. Structural analysis of silica nanoparticles modified by GPTMS was investigated by FTIR(Fourier transform infrared spectroscopy). C-H stretching vibrations at 2,950 cm-1 indicating the silica surface modification with GPTMS were observed when the silane feed was over 0.5 mmol/g. Also, the coreflooding test by nanofluid injection on the aged limestone and dolomite plug samples was carried out with different particle concentration and flow rate. The incremental oil recovery was up to 18.9%, and contact angle and permeability of carbonate samples were changed by the effect of nanoparticle adsorption on pore which caused wettability alteration and pore size change. Therefore, the prepared nanofluid will be utilized as an injection fluid for enhancing oil recovery and modifying fluid flow properties such as change of rock wettability and permeability in carbonate reservoirs.

Synthesis of Nano-Colloidal Silica Coated with Silver (은을 코팅한 Nano-Colloidal Silica의 합성)

  • Lee, Joo-Heon;Lim, Yoon-Hee;Ham, Jae-Yong
    • Applied Chemistry for Engineering
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    • v.19 no.1
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    • pp.45-50
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    • 2008
  • The self assembled silver process and silver coating process after surface reforming for silica particle, were investigated to coat the silver to colloidal silica. The effects of silver amounts and reductant amounts on silver coating efficiencies were investigated. The silver coating process after surface reforming for silica particle using MPTS (3-Mercaptopropyl trimethoxysilane) and APTS (3-Aminopropyl trimethoxysilane), showed the higher coating efficiency and better antibacterial effect than the self assembled silver process.

Dispersion Method of Silica Nanopowders for Permalloy Composite Coating (퍼멀로이 합금도금을 위한 나노실리카 분산방법에 관한 연구)

  • Park, So-Yeon;Jung, Myung-Won;Lee, Jae-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.18 no.4
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    • pp.39-42
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    • 2011
  • The composite electroplating is accomplished by adding inert materials during the electroplating. Permalloy is the term for Ni-Fe alloy and it is used for industrial applications due to its high magnetic permeability, surface wear resistance, corrosion protection. Microhardness for microdevices is enhanced after composite coating and it increases the life cycle. However, the hydroxyl group on the silica makes their surface susceptible to moisture and it causes the silica nanoparticles to be agglomerated in the aqueous solution. The agglomeration problem causes poor dispersion which eventually interrupts uniform deposition of silica nanoparticles. In this study, the dispersion of silica nanoparticles in the permalloy electroplated layer is reported with variation of additives and current densities. The optimum current density was 20 $mA/cm^2$ and the silica content was 9 at% at $50^{\circ}C$. The amount of silica nanopowder codeposition and surface morphologies were influenced with variation of additives. In the bath, smooth surface morphology and relatively high contents of silica nanopowder codeposition were obtained with addition of sodium lauryl sulfate.

Characteristics of Energy Dissipation in Nano Shock Suspension System Using Silica Gel (세라믹 분말을 이용한 나노 충격 완화 장치의 에너지 소산 효율 특성에 대한 연구)

  • 문병영;정성원
    • Journal of the Earthquake Engineering Society of Korea
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    • v.7 no.3
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    • pp.17-22
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    • 2003
  • This paper presents an experimental investigation of a reversible colloidal seismic damper, which is statically loaded, The porous matrix is composed from silica gel (labyrinth or central-cavity architecture), coated by organo-silicones substances, in order to achieve a hydrophobic surface. Water is considered as associated lyophobic liquid. Reversible colloidal damper static test rig and the measuring technique of the static hysteresis are described. Influence of the pare and particle diameters, particle architecture and length of the grafted molecule upon the reversible colloidal damper hysteresis is investigated, for distinctive types and mixtures of porous matrices, Variation of the reversible colloidal damper dissipated energy and efficiency with temperature, pressure, is illustrated.

Synthesis of Sludge Waste-derived Semiconductor Grade Uniform Colloidal Silica Nanoparticles and Their CMP Application (슬러지 폐기물을 활용한 반도체급 균일한 콜로이달 실리카 나노입자의 제조 및 CMP 응용)

  • Kim, Dong Hyun;Kim, Jiwon;Jekal, Suk;Kim, Min Jeong;Kim, Ha-Yeong;Kim, Min Sang;Kim, Sang-Chun;Park, Seon-Young;Yoon, Chang-Min
    • Journal of the Korea Organic Resources Recycling Association
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    • v.30 no.3
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    • pp.5-12
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    • 2022
  • This study suggests the effective recycling method of sludge waste from various industrial fields to synthesize uniform colloidal silica nanoparticles. In detail, polymers are removed from the sludge waste to attain sludge-extracted silica (s-SiO2) micron-sized particles, and ammonia assisted sonication is applied to s-SiO2, which has effectively extracted the silanol precursor. The nano-sized silica (n-SiO2) particles are successfully synthesized by a typical sol-gel method using silanol precursor. Also, the yield amounts of n-SiO2 are determined by the function of s-SiO2 etching time. Finally, n-SiO2-based slurry is synthesized for the practical CMP application. As a result, rough-surfaced semiconductor chip is successfully polished by the n-SiO2-based slurry to exhibit the mirror-like clean surface. In this regard, sludge wastes are successfully prepared as valuable semicondutor grade materials.

Preparation of Langmuir-Blodgett Film of Silica Coated Gold Nanoparticles (실리카 코팅 AuNPs의 Langmuir-Blodgett 박막 제조)

  • Park, Minsung;Choi, Jaeyoo;Jung, Jaeyeon;Cheng, Jie;Hyun, Jinho
    • Journal of Adhesion and Interface
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    • v.11 no.4
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    • pp.144-148
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    • 2010
  • It reports the surface modification of gold nanoparticles (AuNPs) by the synthesis of thin silica layer and the fabrication of AuNPs monolayer on the glass surface. AuNPs of 10 nm in diameter were prepared in aqueous solution. A silica layer was synthesized at the different concentration of tetraethlyorthosilicate for the control of silica layer thickness. Langmuir-Blodgett (LB) film was fabricated by dispersing AuNPs on the aqueous solution and raising a surface pressure up to a solid phase. The change of AuNPs' size was observed by the change of UV/Visible spectra. Atomic force microscopic images confirmed the reliable fabrication of AuNPs LB films.