• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.20 no.4
• /
• pp.458-463
• /
• 2019

Palladium (Pd) is widely used as a catalyst and noxious gas sensing materials. Especially, various researches of Pd based hydrogen gas sensor have been studied due to the noble property, Pd can be adsorbed hydrogen up to 900 times its own volume. In this study, palladium oxide (PdO) nanostructures were grown on Si substrate ($SiO_2(300nm)/Si$) for 3 to 5 hours at $230^{\circ}C{\sim}440^{\circ}C$ using thermal chemical vapor deposition system. Pd powder (source material) was vaporized at $950^{\circ}C$ and high purity Ar gas (carrier gas) was flown with the 200 sccm. The surface morphology of as-grown PdO nanostructures were characterized by field-emission scanning electron microscopy(FE-SEM). The crystallographic properties were confirmed by Raman spectroscopy. As the results, the as-grown nanostructures exhibit PdO phase. The nano-cube structures of PdO were synthesized at specific substrate temperatures and specific growth duration. Especially, PdO nano-cube structrures were uniformly grown at $370^{\circ}C$ for growth duration of 5 hours. The PdO nano-cube structures are attributed to vapor-liquid-solid process. The nano-cube structures of PdO on graphene nanosheet can be applied to fabricate of high sensitivity hydrogen gas sensor.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.27 no.3
• /
• pp.110-114
• /
• 2017

$NiO/NiCo_2O_4$ nanocubes were successfully synthesized via the calcination process of $Ni_3[Co(CN)_6]_2$ PBAs. The prepared monodispersed $Ni_3[Co(CN)_6]_2$ PBAs were aggregated by 'self-assembly' of the nuclei generated during the synthesis reaction. The self-assembly rate of the particles is affected by the temperature and the amount of surfactant SDBS (sodium dodecylbenzenesulfonate). FESEM analysis shows that monodispersed 200 nm PBA nanocubes are obtained at 0.25 g SDBS and $60^{\circ}C$ temperature. Thermal behavior was confirmed by thermogravimetric-differential thermal analysis (TG-DTA) to determine optimal calcination conditions. Then, field emission scanning electron microscopy (FESEM) and X-ray diffraction (XRD) analyzes were performed to investigate the morphology and crystallinity of the particles precursors and $NiO/NiCo_2O_4$ nanocubes.

• Journal of Space Technology and Applications
• /
• v.3 no.2
• /
• pp.144-153
• /
• 2023

The existing military satellite communication system was based on geostationary satellites equipped with special communication payloads against enemy's jamming and signal reception. With the advent of new weapon systems such as unmanned systems, the need for low-orbit satellite-based communication system is increasing. This paper introduces various waveform technologies suitable for cube satellite-based communication system and the operational concept of a future military nanosatellite communication system.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.50 no.6
• /
• pp.423-433
• /
• 2022

This paper introduces the case studies of launch environmental test for cube nanosatellites and lessons learned of the design and integration from those. Generally, nanosatellites are launched and deployed in space while being contained in nanosatellite deployers, mechanical loads of launch are transferred through the deployer. This characteristic make nanosatellites under larger loads and higher possibilities of mechanical failure. This study represents guidelines of the design and the integration of the nanosatellites by showing the cases of launch environmental test of nanosatellite system. Moreover, it is suggested that the modern nanosatellite deployer with the capability of fixing the internal nanosatellite be preferable to conventional deployer by comparing the test results with those deployers.

• Composites Research
• /
• v.32 no.6
• /
• pp.355-359
• /
• 2019

The high efficient water splitting system should involve the reduction of high overpotential value, which was enhanced by the electrocatalytic reaction efficiency of catalysts, during the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER) reaction, respectively. Among them, transition metal-based compounds (oxides, sulfides, phosphides, and nitrides) are attracting attention as catalyst materials to replace noble metals that are currently commercially available. Herein, we synthesized optimal monodisperse Co₃[Co(CN)₆]₂ PBAs by FESEM, and confirmed crystallinity by XRD and FT-IR, and thermal behavior of PBAs via TG-DTA. Also, we synthesized monodispersed Co₃O₄ nanocubes by calcination of Co₃[Co(CN)₆]₂ PBAs, confirmed the crystallinity by XRD, and proceeded OER measurement. Finally, the synthesized Co₃O₄ nanocubes showed a low overpotential of 312 mV at a current density of 10 mA·cm^-2 with a low Tafel plot (96.6 mV·dec^-1).

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.34 no.10
• /
• pp.80-91
• /
• 2006

A method of multidisciplinary education has been implemented for satellite design, based on HAUSAT-1 and 2 ultra-small satellite development projects, in order to provide practical knowledge and experience to students studying satellite engineering. HAUSAT-1 was the nation's first 1kg-class ultra-small satellite. HAUSAT-2 nano-satellite is currently under a Proto-Flight Model development. These design projects make it possible to achieve the goal of science and technical research, which is representative of a university function, and the goal of molding professionals through providing an integrated function of system design education. An integrated system design, like satellite system, provides all participating students with an opportunity to directly/indirectly experience the entire system development process and encourage growth of multidisciplinary system education that has lately become an important issue.

• Transactions of the Korean hydrogen and new energy society
• /
• v.15 no.2
• /
• pp.108-118
• /
• 2004

To find out rational design and synthetic strategies toward efficient hydrogen storage materials, molecular modeling and quantum mechanical studies have been carried out on the MOFs(Metal-Organic Frameworks) having various organic linkers and nanocube frameworks. The calculation results about the free volume ratio, surface area, and electron density variation of the frameworks indicated that the capacity of the hydrogen storage of MOFs was largely dependent on the specific surface area and electron localization around benzene ring rather than the free volume of MOFs. The prediction of the modeling study could be supported by the hydrogen adsorption experiments using IRMOF-1 and -3, which showed more enhanced hydrogen storage capacities of IRMOF-3 compared with the IRMOF-1's at both experimental conditions, 77K, ∠ $H_2$ 1 atm and ambient temperature, ∠ $H_2$ 35 atm.

• The Transactions of The Korean Institute of Electrical Engineers
• /
• v.67 no.3
• /
• pp.413-418
• /
• 2018

In this paper, we describe the development of a non-enzymatic glucose sensor based on copper nanocubes(Cu NCs) electroplated laser induced graphene(LIG) electrodes which can detect a certain range of glucose concentrations. $CO_2$ laser equipment was used to form LIG electrodes on the PI film. This fabrication method allows easy control of the LIG electrode size and shape. The Cu NCs were electrochemically deposited on the LIG electrodes to improve electron transfer rates and thus enhancing electrocatalytic reaction with glucose. The average sheet resistances before and after electroplating were $15.6{\Omega}/{\Box}$ and $19.6{\Omega}/{\Box}$, respectively, which confirmed that copper nanocubes were formed on the laser induced graphene electrodes. The prepared electrode was used to measure the current according to glucose concentration using an electrochemical method. The LIG electrodes with Cu NCs demonstrated a high degree of sensitivity ($1643.31{\mu}A/mM{\cdot}cm^2$), good stability with a linear response to glucose ranging from 0.05 mM to 1 mM concentration, and a limit of detection of 0.05 mM. In order to verify that these electrodes can be used as flexible devices, the electrodes were bent to $30^{\circ}$, $90^{\circ}$, and $180^{\circ}$ and cyclic voltammetry measurements were taken while the electrodes were bent. The measured data showed that the peak voltage was almost constant at 0.42 V and the signal was stable even in the flexed condition. Therefore, it is concluded that these electrodes can be used in flexible sensors for detecting glucose in the physiological sample like saliva, tear or sweat.