Browse > Article
http://dx.doi.org/10.6111/JKCGCT.2017.27.3.110

Synthesis and characterization of three-dimensional monodispersed NiO/NiCo2O4 via Ni3[Co(CN)6]2 PBA nanocubes  

Kwag, Sung Hoon (School of Advanced Materials Science & Engineering, Sungkyunkwan University)
Lee, Young Hun (School of Advanced Materials Science & Engineering, Sungkyunkwan University)
Kim, Min Seob (School of Advanced Materials Science & Engineering, Sungkyunkwan University)
Lee, Chul Woo (School of Advanced Materials Science & Engineering, Sungkyunkwan University)
Kang, Bong Kyun (School of Advanced Materials Science & Engineering, Sungkyunkwan University)
Yoon, Dae Ho (School of Advanced Materials Science & Engineering, Sungkyunkwan University)
Publication Information
Journal of the Korean Crystal Growth and Crystal Technology / v.27, no.3, 2017 , pp. 110-114 More about this Journal
Abstract
$NiO/NiCo_2O_4$ nanocubes were successfully synthesized via the calcination process of $Ni_3[Co(CN)_6]_2$ PBAs. The prepared monodispersed $Ni_3[Co(CN)_6]_2$ PBAs were aggregated by 'self-assembly' of the nuclei generated during the synthesis reaction. The self-assembly rate of the particles is affected by the temperature and the amount of surfactant SDBS (sodium dodecylbenzenesulfonate). FESEM analysis shows that monodispersed 200 nm PBA nanocubes are obtained at 0.25 g SDBS and $60^{\circ}C$ temperature. Thermal behavior was confirmed by thermogravimetric-differential thermal analysis (TG-DTA) to determine optimal calcination conditions. Then, field emission scanning electron microscopy (FESEM) and X-ray diffraction (XRD) analyzes were performed to investigate the morphology and crystallinity of the particles precursors and $NiO/NiCo_2O_4$ nanocubes.
Keywords
Metal-organic frameworks; Prussian blue analogues; Nanocube; $NiCo_2O_4$;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 Y. Zhang, L. Li, H. Su, W. Huang and X. Dong, "Binary metal oxide: advanced energy storage materials in supercapacitors", J. Mater. Chem. A 3 (2015) 43.   DOI
2 X.Y. Yu, X.Z. Yao, T. Luo, Y. Jia, J.H. Liu and X.J. Huang, "Facile synthesis of urchin-like $NiCo_2O_4$ hollow microspheres with enhanced electrochemical properties in energy and environmentally related applications", ACS Appl. Mater. Interfaces 6 (2014) 3689.   DOI
3 A.K. Mondal, D. Su, S. Chen, K. Kretschmer, X. Xie, H.J. Ahn and G. Wang, "A microwave synthesis of mesoporous $NiCo_2O_4$ nanosheets as electrode materials for lithium-ion batteries and supercapacitors", ChemPhysChem 16 (2015) 169.   DOI
4 J. Du, G. Zhou, H. Zhang, C. Cheng, J. Ma, W. Wei, L. Chen and T. Wang, "Ultrathin porous $NiCo_2O_4$ nanosheet arrays on flexible carbon fabric for high-performance supercapacitors", ACS Appl. Mater. Interfaces 5 (2013) 7405.   DOI
5 X. Gao, H. Zhang, Q. Li, X. Yu, Z. Hong, X. Zhang, C. Liang and Z. Lin, "Hierarchical $NiCo_2O_4$ hollow microcuboids as bifunctional electrocatalysts for overall watersplitting", Angew. Chem. Int. Ed. 55 (2016) 6290.   DOI
6 N. Padmanathan and S. Selladurai, "Solvothermal synthesis of mesoporous $NiCo_2O_4$ spinel oxide nanostructure for high-performance electrochemical capacitor electrode", Ionics 19 (2013) 1535.   DOI
7 T.Y. Wei, C.H. Chen, H.C. Chien, S.Y. Lu and C.C. Hu, "A cost-effective supercapacitor material of ultrahigh specific capacitances: spinel nickel cobaltite aerogels from an epoxide-driven sol-gel process", Adv. Mater. 22 (2010) 347.   DOI
8 S.S. Kaye and J.R. Long, "Hydrogen storage in the dehydrated prussian blue analogues $M_3[Co(CN)_6]_2$ (M = Mn, Fe, Co, Ni, Cu, Zn)", J. Am. Chem. Soc. 127 (2005) 6506.   DOI
9 H. Li, C. Yang, P. Xue, N. Li, Y. Zhang and J. Wang, "Structural evolution of a metal-organic framework and derived hybrids composed of metallic cobalt and copper encapsulated in nitrogen-doped porous carbon cubes with high catalytic performance", CrystEngComm. 19 (2017) 64.   DOI
10 Z. Liu, S. Li, Y. Yang, S. Peng, Z. Hu and Y. Qian, "Complex-surfactant-assisted hydrothermal route to ferromagnetic nickel nanobelts", Adv. Mater. 15 (2003) 1946.   DOI
11 S.D. Seul, J.K. Lim, J.M. Lim, J.B. Kwon and N.W. Lee, "A study on the environmental fraternized preparation of inorganic/organic core-shell binder", Journal of the KIIS 19 (2004) 81.
12 C. Yu, J. Yang, C. Zhao, X. Fan, G. Wang and J. Qiu, "Nanohybrids from NiCoAl-LDH coupled with carbon for pseudocapacitors: understanding the role of nanostructured carbon", Nanoscale 6 (2014) 3097.   DOI
13 G. Huang, L. Zhang, F. Zhang and L. Wang, "Metalorganic framework derived $Fe_2O_3@NiCo_2O_4$ porous nanocages as anode materials for Li-ion batteries", Nanoscale 6 (2014) 5509.   DOI
14 B.K. Kang, M.H. Woo, J.Y. Lee, Y.H. Song, Z. Wang, Y. Guo, Y. Yamauchi, J.H. Kim, B.K. Lim and D.H. Yoon, "Mesoporous Ni-Fe oxide multi-composite hollow nanocages for efficient electrocatalytic water oxidation reactions", J. Mater. Chem. A 5 (2017) 4320.   DOI
15 A. Opalinska, I. Malka, W. Dzwolak, T. Chudoba, A. Presz and W. Lojkowski, "Size-dependent density of zirconia nanoparticles", Beilstein J. Nanotechnol. 6 (2015) 27.   DOI
16 Z. Zhu, Y. Bai, T. Zhang, Z. Liu, X. Long, Z. Wei, Z. Wang, L. Zhang, J. Wang, F. Yan and S. Yang "High-performance hole-extraction layer of sol-gel-processed NiO nanocrystals for inverted planar perovskite solar cells", Angew. Chem. 126 (2014) 12779.   DOI
17 D.G. Dmitry and R.A. Caruso, "Template synthesis and photocatalytic properties of porous metal oxide spheres formed by nanoparticle infiltration", Chem. Mater. 16 (2004) 1834.
18 Y. Su, W. Yang, Q. Li and J.K. Shang, "Synthesis of mesoporous cerium-zirconium binary oxide nanoadsorbents by a solvothermal process and their effective adsorption of phosphate from water", Chem. Eng. J. 268 (2015) 270.   DOI
19 F.E. Annanouch, Z. Haddi, S. Vallejos, P. Umek, P. Guttmann, C. Bittencourt and E. Llobet, "Aerosol-assisted CVD-grown $WO_3$ nanoneedles decorated with copper oxide nanoparticles for the selective and humidity-resilient detection of $H_2S$", ACS Appl. Mater. Interfaces 7 (2015) 6842.   DOI
20 J.F. Marco, J.R. Gancedo, M. Gracia, J.L. Gautier, E.I. Rios, H. M. Palmer, C. Greavesc and F. J. Berry, "Cation distribution and magnetic structure of the ferromagnetic spinel $NiCo_2O_4$", J. Mater. Chem. 11 (2001) 3087.   DOI