• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.2
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• pp.97-104
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• 2023

In order to maximize the utilization of recycled fine aggregate, high strength mortar made of 100 % recycled fine aggregate was prepared, and its physical properties were evaluated to determine the possibility of using recycled fine aggregate as structural aggregate. The effect caused by the amount of nanosilica on the physical properties of w/b 0.2 recycled fine aggregate mortar consisting of cement, silica fume, and blast furnace slag. To improve the dispersion of nanosilica inside mortar, an aqueously dispersed nanosilica solution by ultrasonic tip sonication was prepared, and incorporated into the mortar to evaluate changes in mortar flow, porosity and compressive strength depending on nanosilica content. According to the experimental results, mortar flow decreased as the replacement ratio of nano-silica increased. As the replacement ratio of nanosilica increased up to 0.75 %, the porosity decreased and the compressive strength increased, but, at a replacement ratio of 1 %, the porosity increased and the compressive strength decreased. It was confirmed that the nano-silica replacement ratio of 0.75 % was optimum proportion to maximize the mechanical performance of high-strength recycled fine aggregate mortar.

• Journal of the Korean Applied Science and Technology
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• v.33 no.3
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• pp.483-491
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• 2016

Even though the antifogging property of nanosilica coated glass surface is highly increased due to the hydrophilic hydroxyl groups on nanosilica surface, the durability of this property on outdoor glass was diminished rapidly after rain washing. In addition the topology of nanosilica coated glass surface plays very important roles to control an light transmittance or antireflection property. To improve these coating durability and characteristics a hydrophilic nanosilica coating on glass was prepared by coating with 1.5 wt% of nanosilica (Ludox) suspension in the presence of hydrolyzed tetraethylorthosilicate (TEOS). The optimum hydrolysis condition of TEOS in acidic or basic aqueous solution was also examined by contact angle measurement. The final transparent hydrophilic coating layer coated with nanosilica-TEOS in acidic condition (pH=4) showed much improved durability of hydrophilic surface as well as higher visible light transmittance than original uncoated glass by 2 % point.

• Journal of the Korean Applied Science and Technology
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• v.36 no.2
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• pp.531-540
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• 2019

Hydrophilic and hydrophobic nanosilica and tetraethyl orthosilicate (TEOS) as a coupling agent was used to form a coarse spike structure as well as an excellent reactive hydroxyl groups on the glass surface. Then, a second treatment was carried out using a trichloro-(1H,1H,2H,2H)perfluorooctylsilane(TPFOS) solution for ultimate water repellent glass surface formation. The formation of hydrophobic coating layer on glass surface using silica aerosol, which is hydrophobic nanosilica, was not able to form a durable hydrophobic coating layer due to the absence of reactive -OH groups on the surface of nanosilica. On the other hand, a glass surface was first coated with a coating liquid prepared with hydrophilic hydroxyl group-containing nanosilica and hydrolyzed TEOS, and then coated with a TPFOS solution to introduce a hydrophobic surface on glass having a water contact angle of $150^{\circ}$ or more. The sliding angle of the coated glass was less than $1^{\circ}$, which meant the surface had a super water-repellent property. In addition, as the content of hydrophilic nanosilica increased, the optical transmittance decreased and the optical transmittance also decreased after 2nd coating with the TPFOS solution. The super-hydrophobic property of the coated glass was remained up to 50 times of rubbing durability test, but only hydrophobic property was shown after 200 times of rubbing durability test. Conclusively, the optimal coating conditions was double 1st coatings with the HP3 coating solution having a hydrophilic nanosilica content of 0.3 g, and subsequent 2nd coating with the TPFOS solution. It is believed that the coating solution thus prepared can be used as a surface treatment agent for solar cells where light transmittance is also important.

• Proceedings of the Korea Concrete Institute Conference
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• 2010.05a
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• pp.377-378
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• 2010

This study was performed an evaluation of engineering properties of cement composite according to type and content of Nano-silica as admixture for marine concrete. As the results of study, when considering the porosity and compressive strength, the proper type and content are thought to be type of sodium silicate and under 5%.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.1
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• pp.66-73
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• 2019

Approximately 80% of the mines are vacated or abandoned mines and are mostly left without suitable environmental treatment facilities. In the area around the abandoned mine site, problems such as drainage of acidic city drainage and leakage of leachate occur, and ground subsidence caused by this can cause a safety accident due to sink hole occurrence. In this study, flow, compressive strength, water uptake, pore and hydration characteristics were investigated to investigate the basic properties of liner and cover material based on the replacement ratio of nano silica and silica fume in the existing blast - furnace slag fine powder. As a result, as the substitution ratio of nano silica and silica fume increased, the flow and compressive strength of nano silica specimens increased and the absorption rate decreased. In the case of pore characteristics, the amount of pores decreased as the substitution ratio of nano silica and silica fume increased. Especially, the capillary porosity of 10-1,000 nm diameter decreased. Ray diffraction analysis and SEM measurement showed that the peak positions of the hydration products were almost the same when compared with the 5% alternative test samples of Plain and silica fume.

• Journal of the Korean Geosynthetics Society
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• v.22 no.4
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• pp.51-61
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• 2023

In this study, in order to improve the fire resistance performance of structures in case of fire in buildings and structures, PVA fibers and the ZnO particles combined with mesoporous nano silica (MSNs) were mixed with cement mortar, and the specimen was exposed to a temperature range of 20~1100℃. Then the residual compressive strength and weight change rate were measured to determine whether the fire resistance performance changed. As a result of the study, it was found that mixing mesoporous nano silica and PVA fiber together did not contribute to improving the fire resistance performance of cement mortar. On the other hand, mixing 0.5% of mesoporous nano silica and 0.1 vol% of PVA fiber showed the best improvement test results, showing that it was advantageous for fire resistance performance.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.05a
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• pp.185-186
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• 2023

Recently, a lot of nano-scale material technology development and research have been conducted in construction fields to improve the compressive strength and durability of cement-based Composites. There are some studies that have confirmed the properties and application effects of cement-based complex using each nanomaterial, but development and research using both materials are relatively limited. This study sought to confirm the effect of multi-wall carbon nanotubes (MWCNT) and nanosilica, which are representative construction nanomaterials, on the compressive strength, voids, and microstructure formation of cement. The purpose was to produce a cement composite by changing the mixing rate of the two nanomaterials, and to find the optimal mixing amount considering its mechanical and rheological properties.

• Cement Symposium
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• s.37
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• pp.182-187
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• 2010

• Proceedings of the Korea Concrete Institute Conference
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• 2009.05a
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• pp.399-400
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• 2009

This study arranged the result corrosion inhibition using Nano-silica for efficient prevention to diffusion of chloride ion. For the results, significant difference was not found on slump and air content, and there were superior effect to preventing diffusion of chloride ion on hardened concrete. It seemed to be Nano-silica prevented diffusion of chloride ion.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2020.11a
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• pp.151-152
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• 2020

When concrete is exposed to fire, the thermal decomposition of hydrates of Portland cement paste results in critical damage to the concrete structure of a building. Recently, nanosilica arose as the effective nano-additive which can enhance the thermal resistance of the cementitious materials. However, the mechanism of the enhancement was not elucidated specifically. In this study, we investigated the properties of calcium silicate hydrates(C-S-H)of the nanosilica incorporated cement paste after heating to different heating temperatures (200℃, 500℃, and 800℃) by 29Si nuclear magnetic resonance. The results showed that the polymerization of C-S-H of nanosilica incorporated samples was larger than ordinary cement paste after heating to 200℃, and C-S-H formed during heating process to 500℃ due to the pozzolanic reaction during heating process.