• Title/Summary/Keyword: 나노슬래그

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Study of Non Sintered Cement Mortar Using Nanoslag and Alkali Activator (나노슬래그와 알칼리 자극제를 활용한 비소성 시멘트 모르타르에 관한 연구)

  • Jeong, Sung-Wook;Lim, Nam-Gi
    • Journal of the Korea Institute of Building Construction
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    • v.10 no.6
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    • pp.61-66
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    • 2010
  • As global warming has had harmful effects on the environment, the construction industry has made efforts to reduce the amount of $CO_2$ generated in the process of cement production. There is an urgent need for an alternative material that can replace cement. To improve the initial strength and economical efficiency pointed out as problems, this research was conducted for Blast Furnace Slag (BFS), an industrial byproduct. Non-sintering cement (NSC) was used by minimizing the amount of high-priced alkali activators. By using Nano-technology, fineness has been maximized, to enhance the initial strength of BFS. This research is based on non-sintered cement replaced by nano-slag using alkali activators, and the fundamental properties and quality of the non-sintered cement were investigated. A variety of activators were used, up to 10 percent of the slag weight. This research aims to present fundamental data through a comparative analysis of flexural strength, compressive strength, time of setting, diabetic temperature, and rising heat.

The basic study for the proposal standard of Nano-Slag on an alternation material for Silica-fume (실리카퓸 대체 재료로서 나노슬래그의 규격제안을 위한 기초적 연구)

  • Heo, Jae-Won;Im, Nam-Gi
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2008.11a
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    • pp.67-71
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    • 2008
  • Blast Furnace slag a pigiron waste that is produced more than 800 thousand tons per year, and micronized double quenching blast furnace slag improves flexibility of concrete, and even shows improvement effect of long-term intensity. However, the concrete that used micronized double quenching blast furnace slag is restricted in its use because of many problems to assure early intensity. Even micronized blast furnace slag can assure its early intensity of concrete when maximizing, and is considered that can be applied in high strength of blast furnace slag as an alternation material for Silica-fume that depends on overall import. Hereby this paper is revised activity index and fluidity of mortar that used Nano Slag that is produced by rotten Nano crush equipment to propose its size, and possible utility of Nano Slag that was produced by blast furnace slag made in Korea as an alternation material, with the conclusion as following. 1. To measure micronized Nano slag, it is judged that it should be in progress with BET method that is based on micronized Silica-fume for concrete. 2. As a result, the test based on KS L ISO 679 is shown to satisfy the basic additive size of KS F 2563 and of KS F 2567, and to determine new combination of stipulations. 3. The strength development of Nano Slag was shown excellent in the daily initial installment of 1, 3, 7 days against the basic additive. This is judged that contains CaO controlling initial strength against Silica-fume, and contributes to higher fineness than the basic blast furnace slag 1 type.

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Evaluation on the thermoelectric energy harvesting performance of multi-walled carbon nanotube-embedded alkali activated slag composites (다중벽 탄소나노튜브 혼입 알칼리 활성 슬래그 복합재료의 열전 에너지 수확 성능평가)

  • Park, Hyeong-Min;Yang, Beomjo
    • Journal of Urban Science
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    • v.9 no.1
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    • pp.1-6
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    • 2020
  • The thermoelectric characteristics of alkali activated slag composites containing multi-walled carbon nanotubes (MWCNT) was investigated in the present study. Three different MWCNT contents and exposed temperatures were considered, and their thermoelectric-related properties and internal structures were analyzed. It was found that the alkali activated slag composite with MWCNT 2.0 wt.% and the exposed temperature of 150℃ were the optimal condition to obtain the highest Seebeck coefficient and power factor. Based on the feasibility study, the extended size thermoelectric module with 130 elements was fabricated, and tested the electricity production capacity. Consequently, the present thermoelectric module produced 30.83 ㎼ of electricity at ∆T=178.4℃.

Accelerated Aging of Electric Arc Funace Slag with CO2 Nano Bubble by X-Ray Diffraction (X-선 회절 분석을 통한 CO2 나노버블수 침지 전기로 슬래그 촉진 에이징 검토)

  • Lim, Chang-Min;Im, Geon-Woo;Kim, Young-Min;Lee, Gun-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.61-62
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    • 2023
  • In this study, the steel slag was immersed in CO2 nano-bubble water by Electric arc funace it was accelerated aging was reviewed through XRD analysis. The main minerals of the electric furnace oxidized slag were spinel and gehlenite, and there was no change with the number of CO2 nano-bubbles. Minerals such as larnite, calcio-olivine, agnetite, calcite, and spinel were distributed in electrically reduced slag, and the content of calcite more than doubled with CO2 nano-bubble immersion. Therefore, it is judged that the acceleration aging of Electric arc funace reduced slag is effective according to the immersion of CO2 nano-bubble.

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Chemical Properties of Converter Slag according to CO2 Nanobubble Acceleration Aging Time (CO2 나노버블 에이징 시간에 따른 전로슬래그의 화학적 특성)

  • Lim, Chang-Min;Im, Geon-Woo;Kim, Young-Min;Lee, Gun-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.91-92
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    • 2023
  • In this study, the chemical composition of converter slag according to CO2 nanobubble promotion aging time was examined. The CO2 nanobubble water immersion time was 0, 12, 24, 36, 48 hours, and then dried and pulverized to perform XRD analysis. As a result, the longer the sample was immersed in CO2 nanobubble water, the higher the amount of calcite produced, and the change after 36 hours was minimal.

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Investigation on the Mechanical Properties of High-Strength Recycled Fine Aggregate Mortar Made of Nanosilica Dispersed by Sonication (나노실리카 혼입률이 실리카퓸 및 고로슬래그 미분말을 혼입한 4성분계 고강도 순환잔골재 모르타르의 역학적 성능에 미치는 영향)

  • Seong-Woo Kim;Rae-Gyo Moon;Eun-Bi Cho;Chul-Woo Chung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.2
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    • pp.97-104
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    • 2023
  • In order to maximize the utilization of recycled fine aggregate, high strength mortar made of 100 % recycled fine aggregate was prepared, and its physical properties were evaluated to determine the possibility of using recycled fine aggregate as structural aggregate. The effect caused by the amount of nanosilica on the physical properties of w/b 0.2 recycled fine aggregate mortar consisting of cement, silica fume, and blast furnace slag. To improve the dispersion of nanosilica inside mortar, an aqueously dispersed nanosilica solution by ultrasonic tip sonication was prepared, and incorporated into the mortar to evaluate changes in mortar flow, porosity and compressive strength depending on nanosilica content. According to the experimental results, mortar flow decreased as the replacement ratio of nano-silica increased. As the replacement ratio of nanosilica increased up to 0.75 %, the porosity decreased and the compressive strength increased, but, at a replacement ratio of 1 %, the porosity increased and the compressive strength decreased. It was confirmed that the nano-silica replacement ratio of 0.75 % was optimum proportion to maximize the mechanical performance of high-strength recycled fine aggregate mortar.

Characteristics of Mine Liner According to the Replacement Ratio of Nano-Silica and Silica-Fume (나노실리카 및 실리카흄 대체율에 따른 차수재의 특성)

  • Kang, Suk-Pyo;Lee, Hee-Ra;Kang, Hye-Ju;Nam, Seong-Young;Kim, Chun-Sik
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.1
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    • pp.66-73
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    • 2019
  • Approximately 80% of the mines are vacated or abandoned mines and are mostly left without suitable environmental treatment facilities. In the area around the abandoned mine site, problems such as drainage of acidic city drainage and leakage of leachate occur, and ground subsidence caused by this can cause a safety accident due to sink hole occurrence. In this study, flow, compressive strength, water uptake, pore and hydration characteristics were investigated to investigate the basic properties of liner and cover material based on the replacement ratio of nano silica and silica fume in the existing blast - furnace slag fine powder. As a result, as the substitution ratio of nano silica and silica fume increased, the flow and compressive strength of nano silica specimens increased and the absorption rate decreased. In the case of pore characteristics, the amount of pores decreased as the substitution ratio of nano silica and silica fume increased. Especially, the capillary porosity of 10-1,000 nm diameter decreased. Ray diffraction analysis and SEM measurement showed that the peak positions of the hydration products were almost the same when compared with the 5% alternative test samples of Plain and silica fume.

Basic Analysis on Fractal Characteristics of Cement Paste Incorporating Ground Granulated Blast Furnace Slag (고로슬래그 미분말 혼입 시멘트 페이스트의 프랙탈 특성에 관한 기초적 분석)

  • Kim, Jiyoung;Choi, Young Cheol;Choi, Seongcheol
    • Journal of the Korea Concrete Institute
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    • v.29 no.1
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    • pp.101-107
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    • 2017
  • This study aimed to conduct the basic analysis on the fractal characteristics of cementitious materials. The pore structure of cement paste incorporating ground granulated blast furnace slag (GGBFS) was measured using mercury intrusion porosimetry (MIP) and the fractal characteristics were investigated using different models. Because the pore structure of GGBFS-blended cement paste is an irregular system in the various range from nanometer to millimeter, the characteristics of pore region in the different scale may not be adequately described when the fractal dimension was calculated over the whole scale range. While Zhang and Li model enabled analyzing the fraction dimension of pore structure over the three divided scale ranges of micro, small capillary and macro regions, Ji el al. model refined analysis on the fractal characteristics of micro pore region consisting of micro I region corresponding to gel pores and micro II region corresponding to small capillary pores. As the pore size decreased, both models suggested that the pore surface of micro region became more irregular than macro region and the complexity of pores increased.

Influence on mechanical property of C-S-H(I) due to its structural modification (C-S-H(I)의 분자구조변형을 통한 기계적 거동의 변화)

  • Oh, Jae-Eun;Monteiro, Paulo J.M.
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.473-474
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    • 2010
  • This high pressure synchrotron X-ray diffraction study examined the change of bulk modulus of C-S-H(I), core material creating strength in alkali-activated slag cement as well as structural model of C-S-H, mainly attributed to Al-substitution for Si, which occurs at the bridging tetrahedral sites in dreierketten silicate chains in the nanostructure of C-S-H(I). This study presents that Al-substitution in C-S-H(I) does not affect the bulk modulus of C-S-H(I), which is surprising because many researchers have expected that Al-substitution should induce some critical change in mechanical properties of C-S-H(I).

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Mechanical and Electrical Properties of Low-Cement Mortar Using a Large Amount of Industrial By-Products (산업부산물을 다량활용한 저시멘트 모르타르의 역학적·전기적 특성)

  • Kim, Young-Min;Im, Geon-Woo;Lim, Chang-Min;Lee, Gun-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.43-44
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    • 2023
  • This study evaluated the mechanical and electrical properties of low-cement mortar using a large amount of industrial by-products to reduce carbon emissions from the cement industry. As types of industrial by-products, blast furnace slag and fly ash, which are representative materials, were used, and ultra-high fly ash was mixed and evaluated to solve the problem of initial strength loss. In addition, in order to evaluate the electrical properties, 1% of MWCNT was incorporated relative to the powder mass. As experimental items, the compressive strength was measured on the 1st, 3rd, 7th and 28th days of age, and the rate of change in electrical resistance was measured on the 28th day of age. As a result of the experiment, the initial strength of the test specimen mixed with blast furnace slag and fly ash was significantly lower than that of 100% cement, and the specimen mixed with blast furnace slag showed strength equal to that of cement at 28 days of age. As an electrical characteristic, the electrical resistance was reduced when the load was loaded, and this reason is judged to be the effect of improving the conductivity as the connection between CNTs is narrowed by the compressive load.

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