• Title/Summary/Keyword: 김용식

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The analysis of products from base-catalyzed depolymerization of kraft lignin (크라프트 리그닌의 염기 촉매 분해(BCD)에 의한 부산물의 조성 분석)

  • Kim, Seok Ju;Kim, Yong Sik
    • Journal of the Korean Wood Science and Technology
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    • v.41 no.6
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    • pp.583-593
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    • 2013
  • The based-catalyzed depolymerization (BCD) of kraft lignin isolated from black liquor which the chemical pulping of a mixture of various Southeast Asia hardwood chips was carried out in a batch reactor in the presence of different NaOH concentrations with supercritical methanol. The S:G ratio of the kraft lignin determined by pyrolysis-GC/MS analysis turned out roughly 1.4:1 and main products were vanillic acid, syringol and 3-methoxy catechol. The diethyl ether extracts as phenolic monomers from BCD reaction were produced similar yield among different NaOH concentrations. The 21 compounds were identified by GC/MS analysis in all experiments and major products were catechol, 3-methoxycatechol, 4-methylcatechol, syringol and isovanillic acid. However, it had been shown to be different monomer contents depending on the dosage of NaOH. Catechol, 4-methylcatechol and 3-methoxycatechol were shown to be the dominant monomer from BCD reaction using 7.5 and 3.25% of NaOH concentration whereas syringol, isovanillic acid, 3-methoxycatechol and 4-methylcatechol were determined to be the most typical products under the condition of 1.63% NaOH.

The Development of the Lens of the Optical System for High Concentration Solar PV System (고집광 태양광 발전을 위한 광학시스템 렌즈 개발)

  • Ryu, Kwang-Sun;Cha, Won-Ho;Shin, Goo-Hwan;Cho, Hee-Keun;Kim, Young-Sik;Kang, Seong-Won;Kang, Gi-Hwan
    • Journal of the Korean Solar Energy Society
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    • v.31 no.2
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    • pp.82-88
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    • 2011
  • The artificial increase in the solar intensity incident on solar cells using lenses or mirrors can allow solar cells to generate equivalent power with a lower cost. There are two types of concentration optics for solar energy conversion. One is to use mirrors, and the other is to use Fresnel lenses. The gains that can be achieved with a Fresnel lens or a parabolic mirror are compared. The result showed the gains are comparable and the two configurations were developed competitively. In application areas of Fresnel lenses as solar concentrators, several variations of design were devised and tested. Some PV systems still use commercially available flat Fresnel lenses as concentrators. A convex linear Fresnel lens to improve the concentration ratio and the efficiency is devised and flat linear Fresnel lens in thermal energy collection is utilized. In this study, we designed and optimized flat Fresnel lens and the 'light pipe' to develop 500X concentrated solar PV system. In the process, we compare the transmission efficiencies according to groove types. We performed rigorous ray tracing simulation of the flat Fresnel lenses. The computer aided simulation showed the 'grooves in case' has the better efficiency than that of 'grooves out case'. Based on the ray-trace results we designed and manufactured sample Fresnel lenses. The optical performance were measured and compared with ray-trace results. Finally, the optical efficiency was measured to be above 75%. All the design and manufacturing were performed based on that InGaP/InGaAs/Ge triple junction solar cell is used to convert the photon energy to electrical power. Field test will be made and analyzed in the near future.

Status of Exotic Plant Species in Gyeongju Yangdong Village (경주 양동마을의 외래식물 현황)

  • Kim, Gi Song;Shin, Hyun Tak;Yi, Myung Hun;Yoon, Jung Won;Kim, Yong Shik
    • Korean Journal of Heritage: History & Science
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    • v.45 no.1
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    • pp.174-189
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    • 2012
  • This study aims to examine the traditional living space to reflect the environment-friendly design methods and principles of reestablishment. To do so, this study carried on a related literature study and field survey. The traditional living space in terms of the environmental friendliness is reflected on site selection and space composition, and utilization of natural energy and natural materials. Focused on the Kwangajeong in Yangdong Village, this study is to identify eco-friendly techniques on the traditional living space. As a result, it shows that Kwangajeong with the side of the southeast in site selection had been considered in aspect of environmental control such as sunshine and solar radiation. Also building construction techniques had been used to minimize the variation of terrain. In aspect of environmental conservation, Kwangajeong had structurally arranged the gate, an inner yard and an inner floor to allow good ventilation. In aspect of space composition, Kwangajeong with the emphasis of scenic view had utilized the methods that attract external landscape through the control of its fences. Environment-friendly techniques and control principles in traditional space had been developed by a long experience through the long periods and the traditional techniques suitable for local climate and local environment have been developed. The technical development of these techniques to resolve the global environmental and energy issues and create a more pleasant living environment of human beings might be critical.

Obesity Regulation through Gut Microbiota Modulation and Adipose Tissue Browning (장내 미생물의 조절과 지방세포의 갈색지방화를 통한 비만 조절 연구)

  • Cho, Yejin;Shamim, Rahman Md.;Kim, Yong-Sik
    • Journal of Life Science
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    • v.29 no.8
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    • pp.922-940
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    • 2019
  • Obesity, represented by abnormal fat accumulation due to an imbalance between energy intake and expenditure, is a major public health issue worldwide, leading to multiple noncommunicable diseases, including atherosclerosis, hypertension, type 2 diabetes, and cancer. Diverse solutions have been proposed to combat obesity. Attention has focused on two types of adipose tissues as a promising therapeutic target in obesity: traditional brown and beige or brite. Unlike energy-storing white adipose (endocrine) tissue, traditional brown adipose tissue and beige adipose tissue have energy-dissipating thermogenic properties. Both types of tissue are present in adult humans and inducible through external stimuli, such as cold exposure, ${\beta}3$-adrenergic receptor agonists, and phytochemicals. Among these stimuli, microbiota present in the human intestinal tract participate in multiple metabolic activities. Modulation of gut microbiota may offer a potent and possibly curative strategy against various metabolic diseases. Numerous studies have focused on the effects of established antiobesity treatments on the gut microenvironment or brown-adipose-tissue activation. In this review, we focus mainly on stimuli known to alleviate obesity, weight gain, and metabolic diseases, in addition to known and possible inter-relations between gut microbiota modulation and similar interventions and adipose tissue browning. The findings may pave the way toward new strategies against obesity.

Depositional Processes of Pyroclastic Density Currents in Lacustrine Environments: An Example from the Cretaceous Jeonggaksan Formation in Danjang-myeon, Miryang City (호수 내 화쇄밀도류의 퇴적과정: 밀양시 단장면 일원 백악기 정각산층의 예)

  • Gihm, Yong Sik;Park, Seung-Ik
    • Economic and Environmental Geology
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    • v.55 no.3
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    • pp.295-307
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    • 2022
  • We studied the Cretaceous Jeonggaksan Formation to determine depositional processes of pyroclastic density currents entering into the lacustrine environments. This formation is composed largely of sandstone-mudstone couplets and (tuffaceous) normally graded sandstones deposited in lacustrine environments, interbedded with two pyroclastic beds: welded massive lapilli tuff and normally graded lapilli tuff. The welded massive lapilli tuff (10 m thick) is composed of poorly sorted, structureless lapilli supported by a welded ash matrix. The normally graded lapilli tuff (4 m thick) is characterized by moderately to well sorted natures and multiple normally graded divisions in the lower part of the bed with internal boundaries. The contrasting depositional features between these lapilli tuff are suggestive of different physical characteristics and depositional processes of pyroclastic density currents in the lake. Overall poorly sorted and massive natures of the thick, welded massive lapilli tuff are interpreted to have been formed by rapid settling of pyroclastic sediments from highly concentrated and sustained pyroclastic density currents. In this case, the pyroclastic density currents were able to displace lake water from shoreline and the pyrolclastic density currents preserved their own heat except for frontal parts of the currents. As a result, welded textures can be formed despite entrance of pyroclastic density currents into the lake. The internal boundaries of the normally graded lapilli tuff reflect unsteady natures of the pyroclastic density currents at the time of the deposition and the pyroclastic density currents can not provide sufficient pressure to displace lake water. As a consequence, the pyroclastic density currents transformed into water-saturated turbidity currents, forming relatively well sorted, normally graded lapilli tuff.

Rare and Endangered Plants of Naesorak in Soraksan National Park (설악산 국립공원 내설악지역의 희귀 및 멸종위기 식물)

  • Kim, Yong-Shik;Kang, Ki-Ho;Bae, Jun-Kyu;Kim, Jong-Keun
    • Korean Journal of Environment and Ecology
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    • v.11 no.4
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    • pp.407-414
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    • 1998
  • The rare and endangered plants in Naesorak area were investigated for four months during May to August in 1997, and the results were summarized as 35 taxa which is classified as 19 families, 32 species, and 3 varieties. At the level of families, 19 families such as Pinaceae(1 species), Taxaceae(1 species), Cupressaceae(1 species and 1 variety), Liliaceae(5 species and 1 variety), Aristolochiaceae(2 species), Ranunculaceae(4 species), Berberidaceae(1 species), Saxifragaceae(2 species), Rosaceae(1 species), Oleaceae(2 species and 1 variety), Solanaceae(1 species), Scrophulariaceae(1 species), Valerianaceae(1 species), Campanulaceae(1species), and Compositae(1 species) were recorded. The most of the habitats of the species was easily found along the major mountain trails, and a kind of destructions of these plants by human interferences is due to the fact that the illegal collections for food and medicine are occurred. Those species of Taxus caespitosa, Rhododendron aureum, Vaccinium bracteatum, Allium victoralis var. platyphullum and Leontice microryncha has a few individuals in habitats and also shows the unfavorable growing state, so the intensive and continuous habitat management of the habitats were inevitably dimanded.

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Flora of Oesorak in Soraksan National Park (설악산 국립공원 외설악의 관속식물상)

  • Kim, Yong-Shik;Kang, Ki-Ho;Bae, Jun-Kyu;Shin, Hyun-Tak
    • Korean Journal of Environment and Ecology
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    • v.10 no.2
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    • pp.211-239
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    • 1997
  • The flora of Oesorak in the Soraksan National Park including Chombongsan(Mountain) and Kwanmobong(Peak) were surveyed from February to August, 1996. These areas have very rich and diverse flora;620 taxa with 89 families, 321 genera, 526 species, 2 subspecies, 89 varieties and 3 forms in the Oesorak, 404 taxa with 251 genera, 350 species, 1 subspecies, 51 varieties and 2 forms in the Chombongsan(Mountain), 286 taxa with 206 genera, 233 species, 1 subspecies, 50 varieties and 2 forms in Kwanmobong(peak). The Oesorak had very distinct floristic characteristics such as the wild habitats of Asarum maculatum(Aristolochiaceae) and Ilex macropoda(Aquifoliaceae). In the phyorgeographical point of view, the six species such as Sapium japonicum (Euphorbiaceae), Euphorbia joldini(Euphorbiaceae), Ilex macropoda (Aquifoliaceae), Styrax japonica (Styracaceae), Carex sideros ticta (Cyperaceae) and Asarum maculatum (Aristolochiaceae) were naturalized into this region, while the 17 taxa such as Abies neprolepis(Pinaceae), Pinus pumila(Pinaceae), Thuja koraiensis(Cupressaceae), Allium senescens(Liliaceae), Lilium distichum(Liliaceae), Saxifraga punctata(Saxfragaceae), Rosa marretii(Rosaceae), Bupleurum euphorbioides(Umbelliferae), Androsace cortusaefolia (Primulaceae), Peducularis mandshurica(Scrophulariaceae) and Leontopodium coreanum (Compositae) were distrivuted to this region. The colonizing weedy species such as Ixris repens (Compositae) were distributed to this region. The colonizing weedy species losa(Labiatae) and Rosa rugosa(Rosaceae) were naturalized into ca. 900m at sea level mainly due to the sand soil from the seashore. Mountain roadbed is susceptible than other areas to the slippery road problems, due largely to snow and rain, particularly during winter. Sand soils from seashore are utilized to minimize this slip in traffic operation.

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The effect of managerial ability on short-term or long-term firm performance in Chaebol (재벌기업에서 경영자능력이 장·단기 기업성과에 미치는 영향)

  • Kang, Sun-A;Kim, Yong-Shik
    • Management & Information Systems Review
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    • v.36 no.1
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    • pp.233-249
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    • 2017
  • This study investigates the relation of managerial ability and firm performance in case of Chaebol in Korea. We employ non-financing firms at Korean markets for the period 2000-2015. Most important decision is made by the head of Chaebol which increases firm value eventually and he has such a strong dominant power that managers belongs to Chaebol have to follow mother firm's decision directions. So it is expected that managers belongs to Chaebol have to focus on long term performance rather than short term profits, which means they concentrate their managerial ability much on the firm value. Otherwise, managers in which non-Chaebol focus their ability on periodic accounting earnings. Thus, this study examines an empirical analysis on the relation of managerial ability and firm performance and the effect of Chaebol on the relation of managerial ability and firm performance. Empirical results are as follows: First, there exists a statistically significant positive relation between managerial ability and firm performance either short- or long-term. Second, we extend this relationship into Chaebol condition and find that managerial ability of Chaebol positively influences on the firm value which is long-term performance, rather than return on assets which is short-term performance. These results imply that managers belongs to Chaebol much concentrate their ability on long-term value which is differenciated from the case of non-Chaebol samples. Chaebol is an important issue in Korea because it dominates most of Korean local economy so its' impact from small changes on our economy is big enough. Our study examining the relationships between managerial ability of Chaebol and firm performance is meaningful and it is a good signal that they concentrate their ability much on the long-term value rather than short-term profits. We expect that the results of this study will provide the academic and practical references. This study will contribute to the future research in accounting through an analysis of managerial ability which is a new measure, Chaebol, and firm value.

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Treatment of Benign Bone Lesions with Autologous Bone Marrow Stromal Cell Transplantation (자가 골수 기질 세포 이식을 이용한 장관골 양성 골 병변의 치료)

  • Rhee, Seung-Koo;Kang, Yong-Koo;Kim, Yong-Sik;Bahk, Won-Jong;Chung, Yang-Guk;Kim, Hyoung-Jun;Ok, Ji-Hoon
    • The Journal of the Korean bone and joint tumor society
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    • v.10 no.1
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    • pp.13-21
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    • 2004
  • Purpose: We analyzed the result of autologous bone marrow stromal cell transplantation with or without cancellous chip bone allograft for benign long bone lesions. Materials and methods: Since July 1996, eight benign bone lesions treated by curettage, cancellous chip bone allograft and bone marrow or marrow stromal cell transplantation were observed for resolution of clinical symptoms, new bone formation and consolidation. There were 6 males and 2 females. Average age was 24 (range 8 to 47) years old. Histologic diagnoses were 5 fibrous dysplasia, 2 simple bone cysts and one chondroblastoma and fibrous cortical defect each. Mean follow-up period was 16.3 (range 3 to 84) months. Results: In all four symptomatic patients, the pain was subsided in two weeks after surgery. New bone formation in the lesion was observed at 4 weeks, which incorporated into surrounding normal bone around 8 weeks. There were one pathologic fracture through the lesion at 3 weeks and one recurrence of simple bone cyst at 5 months postoperatively. Conclusion: Bone marrow or marrow stromal cell transplantation for bone defects from curettage of benign bone lesions, with or without cancellous chip bone allograft revealed rapid healing. Though it was the result of short-term follow up, it supports that bone marrow stromal cell transplantation will be very useful for the treatment of benign long bone cysts or other lesions. The complete curettage of inner cystic wall is important to prevent later recurrence, and the rigid internal fixation is also needed in selected high risk lesions of fracture.

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Comparison of Paraquat Actions on Oxygen Radical Generation and Lipid Peroxidation between Submitochondrial Particle and Microsome of Mouse Liver (Paraquat에 의한 산소 Radical 생성 및 지질과산화 작용의 Mouse 간 Submitochondria Particle과 Microsome에서의 비교)

  • Choi, Jung-Hwan;Kim, Yong-Sik;Park, Jong-Hwan;Chung, Myung-Hee;Yunn, Chong-Ku
    • The Korean Journal of Pharmacology
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    • v.27 no.2
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    • pp.155-166
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    • 1991
  • In order to evaluate a potential role of mitochondria in the mediation of toxicity of paraquat (PQ), submitochondrial particle and microsome of mouse liver were compared by oxygen radical generation and lipid peroxidation. With NADH in submitochondrial particle and NADPH in microsome as electron donors, PQ stimulated production of superoxide anion and $H_2O_2$ in both fractions. Under the same conditions, PQ enhanced the generation of ethylene from methional suggestiong stimulation of OH production by PQ. But these effects by PQ were somewhat lower in submitochondrial particle than in microsome. In addition, lipid peroxidation(measured as MDA production) was stimulated by PQ in both fractions. The stimulation of lipid peroxidation in both fractions seemed to occur by the same mechanism probably through perferryl ion. This was supported by the following findings: i) The lipid peroxidation in both fractions was partially inhibited by SOD and completely inhibited by DETAPAC(an iron chelator) but not by catalase or OH scavenger. ii) Addition of $ADP-Fe^{3+}$ further increased PQ-induced lipid peroxidation but decreased ethylene production from methional suggesting no correlation between OH production and lipid peroxidation. The redox-cycling of PQ in mitochondria appeared to be linked to NADH dehydrogenase, not to CoQ since all of the observed stimulations by PQ in submitochondrial particle were inhibited by p-hydroxymercuribenzoate(a NADH dehydrogenase inhibitor) but not affected by other respiratory chain blockers. The above results demonstrate that redox-cycling properties of PQ leading to oxygen radical generation and lipid peroxidation can also occur in mitochondria in the same manner as in microsome. Therefore, the observed actions of PQ in mitochondria suggest that mitochondria may also contribute to toxicity of this drug in vivo.

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