• Polymer(Korea)
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• v.37 no.5
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• pp.592-599
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• 2013

In this study, polyacrylonitrile (PAN)-based porous carbon nanofibers were prepared from PAN polymer solution by electrospinning and KOH activation with various concentrations, and the characterization of pore structures and carbon dioxide adsorption was investigated. Manufactured PAN-based activated carbon nanofibers tend to decrease diameter and increase surface oxygen functional groups depending on the increasing concentration of KOH solution. In addition, according to the results of nitrogen adsorption for pore properties analysis, it indicated increase of the specific surface area in conformity with increasing concentration of KOH solution. Micropore volume of treated activated carbon nanofibers (ANCF) by 4 M KOH was the largest compared with other samples and mesopore volume of treated ANCF by 8 M KOH was the largest volume, respectively. The concentration of KOH effects textural and surface properties, as represented by BET and XPS, which enhance carbon dioxide adsorption capacity at 0 and $25^{\circ}C$.

• Applied Chemistry for Engineering
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• v.32 no.1
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• pp.91-96
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• 2021

This study was conducted to improve the operating conditions of an adsorption tower filled with potassium impregnated activated carbon for high hydrogen sulfide capture capacity. Heat treatment modified the surface properties of activated carbon, and ultimately determined its adsorption capacity. The activated carbon doped with potassium showed 57 times more adsorption at room temperature than that of using the raw adsorbent. It is believed that uniform pore formation and strong bonding of the potassium on the surface of carbon contributed to the chemical and physical absorption of hydrogen sulfide. The SEM analysis on the surface structure of various commercial carbons showed that the modification of surface properties through the heat treatment generated the destruction of pore structures resulted in the decrease of the absorption performance. The pressure drop across the activated carbon bed was closely related with the grain size and shape. The optimum size of irregularly shaped activated carbon granules was 2~4 mesh indicating economical feasibility.

• Journal of the Korean Ceramic Society
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• v.41 no.3
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• pp.210-215
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• 2004

Porous ceramics for water-permeable paving brick was prepared by the sintering of mixed materials comprising of sewage sludge ash, waste porcelain fragment, waste glaze and low-grade clay at 1,000$^{\circ}C$ for 2 h, and the physical $.$mechanical properties, the permeability and the freeze-thaw resistance of specimens with preparation parameters were investigated. The physical mechanical properties were increased in specimens while porosity and permeability were decreased with increasing sewage sludge ash content and sintering temperature on the properties of specimens showed the opposite results. The bulk density, porosity, compressive strength and permeability (passed charge) of 30A60F specimens with 30 wt% of sewage sludge ash content, waste porcelain fragment size with 1∼2 mm and sintered at 1,000$^{\circ}C$ for 2 h were 2.17, 46.2%, 221 kgf/$\textrm{cm}^2$ and 3,150 coulombs, respectively. The permeability was increased with increasing waste porcelain fragment size, however compressive strength was decreased. The freeze-thaw resistance of 30A60F specimen with 1∼2 mm of fragment size was superior to that of the other specimens. The 30A60F specimens can be used for the water-permeable paving brick with the high permeability and adequate strength. The heavy metals included in the all specimens showed lower than the standard level.

• Applied Chemistry for Engineering
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• v.28 no.5
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• pp.576-580
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• 2017

In the present paper, the thermal deactivation characteristics of plate-type commercial $V_2O_5-WO_3/TiO_2$ SCR catalyst were investigated. For this purpose, the plate-type catalyst was calcined at different temperatures ranging from $500^{\circ}C$ to $800^{\circ}C$ for 3 hours. Structural and morphological changes were characterized byXRD, specific surface area, porosity, SEM-EDS and also NOx conversion with ammonia according to the calcine temperature. The NOx conversion decreased with increasing calcine temperature, especially when the catalysts were calcined at temperatures above $700^{\circ}C$. This is because the crystal phase of $TiO_2$ changed from anatase to rutile, and the $TiO_2$ grain growth and $CaWO_4$ crystal phase were formed, which reduced the specific surface area and pore volume. In addition, $V_2O_5$, which is a catalytically active material, was sublimated or vaporized over $700^{\circ}C$, and a metal mesh used as a support of the catalyst occurred intergranular corrosion and oxidation due to the formation of Cr carbide.

• Journal of the Korean Electrochemical Society
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• v.16 no.3
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• pp.129-137
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• 2013

From the cooked-rice as a raw material, activated carbons throughout a hydrothermal synthesis and vacuum soak of KOH for chemical activation were obtained. Activated carbon electrodes for electric double layer supercapacitors were prepared and electrochemical characteristics were examined. Including the specific surface area by BET method and pore size distribution by NLDFT method, physical properties of activated carbons were investigated by means of SEM, EDS, XRD, and TG analyses. Cycle voltammetry and AC-impedance measurements were conducted to confirm the electrochemical characteristics for the electrodes. From hydrothermal synthesis, $5{\sim}7{\mu}m$ diameters of spherical carbons were obtained. After the activation at $800^{\circ}C$, it was notable for the activated carbon to be the specific surface $1631.8cm^2/g$, pore size distribution in 0.9~2.1 nm, and micro-pore volume $0.6154cm^3/g$. As electrochemical characteristics of the activated carbon electrode in 6M KOH electrolyte, it was confirmed that the specific capacitances of 236, 194, and 137 F/g at the scan rate of 5, 100, and 500 mV/s respectively were exhibited and 91.2% of initial capacitance after 100,000 cycles at 200 mV/s was maintained.

• Korean journal of food and cookery science
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• v.13 no.1
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• pp.64-69
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• 1997

The experiments of rice bread processing were carried out to compare the varietal difference in processing adaptability to rice bread between brown and milled rice flour, and to analyze the interrelations among chemical properties of rice grain and some characteristics relevant to rice bread processing and quality There was varietal difference in adaptability to rice bread processing in both brown and milled rice, but there was not significant adaptability difference between brown and milled rice flours to rice bread processing. However, there was remarkable adaptability difference between brown and milled rice flours to rice bread processing in some rice varieties. Three high-amylose rices AC 27, IR 44, Suweonjo showed high quality of milled rice bread among tested rice materials. Brown rice revealed better adaptability to rice bread processing compared with milled rice in all varieties except the above three varieties. Especially, the glutinous rice Hangangchalbyeo failed to normal formation of rice bread from milled rice flour, but it showed the successful formation of rice bread from brown rice flour. The interrelations among chemical components of rice grain and some characteristics relevant to rice bread processing and quality exhibited quite different tendency between brown and milled rices. In the case of rice bread processing by brown rice flour, the larger volume expansion of dough during fermentation made the more springy rice bread and the more moist rice bread showed the more soft and cohesive physical property. In the case of rice bread processing by milled rice flour, the lower protein of rice flour was closely associated with the more moistness of rice bread and the higher lipid led to the more uniformal air pore distribution, the smaller pore size and the lower springiness of rice bread. Also, the larger volume expansion of dough during fermentation made the better loaf formation and the larger pore size of rice bread. The better loaf formation of rice bread revealed the softer hardness and the lower chewiness, and the lower springiness was closely correlated with the more uniformal size distribution of air pore and the smaller pore size in rice bread.

• Korean Journal of Food Science and Technology
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• v.54 no.2
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• pp.196-202
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• 2022

In this study, the quality characteristics of Jeung-pyun with different amounts of Makgeolli (50, 100, 150, and 200 mL) were investigated, and standardization of the Jeung-pyun production process is suggested. Higher Makgeolli contents resulted in an increase in Jeung-pyun qualities such as the b value, air cell size, springiness, and cohesiveness, whereas Jeung-pyun characteristics such as the L values, pH, number of air cells, hardness, and gumminess significantly decreased. The specific volume was highest following method M-150, and the expansion rate was lowest following method M-200. Altering the Makgeolli content did not significantly differ in moisture content and b values. In the sensory evaluation results, the M-150 method produced the highest-ranking results for all tested items (i.e., overall acceptability, appearance, flavor, taste, and texture). Therefore, this study suggests that Jueng-pyun produced with the M-150 mixing ratio has excellent quality and sensory characteristics. Furthermore, the results of this study can be used as preliminary data for the standardization of Jueng-pyun production.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2004.05b
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• pp.691-694
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• 2004

물리적 힘에 의한 초전도 분말의 균일한 표면 확보 및 고밀도화 가 필요하다. 그러나 전기영동전착법의 특성상 물리적 힘에 의한 고밀도화에 어려움이 따르고 전착후막의 기공과 크랙현상을 발생시키는 단점으로 인하여 전기영동전착법에 의한 입자의 고밀도화를 위해서는 전착과정에서 현탁분말입자의 치밀성 및 일정한 방향성을 위한 공정기술이 요구된다. 전기영동법에 의한 초전도 후막의 특성을 향상시키기 위한 방법으로 DC전계인가 와 AC보조전계 인가방식에 공정이 있으며 이들 두 공정에 의해 제작된 후막의 특성을 비교 분석하고 두 공정기술에 따른 최적화 방안을 연구 하였다. YBCO 초전도 후막의 균일한 표면과 초전도특성 향상을 위한 공정개선방법으로는 수직방향 교류전계 인가 방식을 적용한 공정기술을 전기영동전착 공정에 적용하였다.

• Membrane Journal
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• v.26 no.6
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• pp.421-431
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• 2016

Novel membrane technologies that harness ordered nanostructures have recently received much attention because they allow for high permeability due to their reduced flow resistance while also maintaining high selectivity due to their isoporous characteristics. In particular, the opaline structure (made from the self-assembly of colloidal particles) and its inverted form (inverse-opal) have shown strong potential for membrane applications on account of several advantages in processing and the resulting membrane properties. These include controllability over the pore size and surface functional moieties, which enable a wide range of applications ranging from size-exclusive separation to catalytically-reactive membranes. Furthermore, when combined with multiscale architecturing strategies, inverse-opal-structured membranes can be designed to have specific pores or channel structures. These materials are anticipated to be utilized for next-generation, high-performance, and high-value-added functional membranes. In this review article, various types of inverse-opal-structured membranes are reviewed and their functionalization through hierarchical structuring will be comprehensively investigated and discussed.

• Membrane Journal
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• v.26 no.1
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• pp.26-31
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• 2016

Polycaprolactone (PCL) has been fabricated into the membrane type scaffolds of 3 dimensional pore network for the tissue engineering applications by the blade method of salt (NaCl) leaching and solution casting. In this study, the experimental designs have each conditions of drying temperature, salt particle size, salt content. The modified dispensing pump connected up to homogenizing mixer system is used for mixing the $PCL/CHCl_3$ solution and NaCl particles. The membrane fabricated use by the film applicator to poured mixed solution on the glass plate. The great pore by NaCl particles and the small pore by the evaporated $CHCl_3$ in the frame wall of great pores are multiply formed in membrane scaffolds.